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1.发明授权Branched polymeric surfactant reaction products, methods for their preparation, and uses therefor 有权支化聚合物表面活性剂反应产物，其制备方法及用途公开(公告)号：US06465605B2
公开(公告)日：2002-10-15
申请号：US09783855
申请日：2001-02-15
IPC分类号： C08G5900
CPC分类号： C08G65/337 , B01D19/0427 , C08G65/33306 , C08G2650/06 , C08G2650/50 , C08L71/02 , C08L71/03 , C08L79/02 , C09D5/024 , C09D7/65
摘要： Polymeric compounds useful as low foaming surfactants and defoaming and stabilizing agents for aqueous-and nonaqueous-based compositions, and to processes for the preparation of the polymeric compounds, wherein the polymeric compounds are the reaction products of reactants comprising A) at least one linking compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) compounds of formula 11 R2(OA)nX (II) wherein R2 is an organic group containing from 4 to 36 carbon atoms, n is a number of from 0 to 200, X is —OH, —NHR′, or —SH and each OA group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group.
摘要翻译： 可用作低泡表面活性剂的聚合化合物和用于水基和非水基组合物的消泡和稳定剂以及制备聚合物的方法，其中聚合物是反应物的反应产物，其包含：A）至少一种连接化合物 式I其中X基团为卤素原子或一个X基团为卤素原子，两个X基团表示环氧氧原子，其与R1基团中两个相邻的碳原子连接形成环氧基团，R1为烷基三 含3至10个碳原子的基团; 和B）式11的化合物，其中R2是含有4至36个碳原子的有机基团，n是0-200的数，X是-OH，-NHR'或-SH，各个OA基团独立地是亚乙基氧基， 1,2-亚丙氧基或1,2-亚丁氧基。
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公开(公告)号：US06960304B1
公开(公告)日：2005-11-01
申请号：US10610892
申请日：2003-07-01
CPC分类号： C02F1/76 , C02F1/68 , C02F2101/325 , C02F2103/001 , C02F2303/12 , Y02W10/37
摘要： Methods for treating wastewater comprising adding to wastewater a defoaming and/or surfactant-effective quantity of at least one base-catalyzed branched reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group or a C1–C6 alkylamino group, n is at least 1; wherein the mole ratio of the linking compound a) to b) is from 0.1:1 to 5:1; and to wastewaters containing the above base-catalyzed reaction products.
摘要翻译： 用于处理废水的方法包括将消泡和/或表面活性剂有效量的至少一种碱催化的支化反应产物加入到废水中，所述支化反应产物包含以下反应物：A）至少一种式I化合物<？在线配方说明= “在线公式”end =“lead”？> R <1>（X）3（I）<？in-line-formula description =“In-Line Formulas “end =”tail“？>其中每个X基团是卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R 1中的两个相邻碳原子连接， / SUP>基团以形成环氧基，R 1是含有3至10个碳原子的烷三基; 和B）至少一种具有式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> R 2 X（AO）n Y（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 2是取代或未取代的饱和或不饱和的， 具有1至36个碳原子的有机基团; X是-O-，-S-或-NR 3 - ，其中R 3是氢或C 1 -C 3 - 18个烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; 并且Y是氢，或Y可以是巯基或氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是 当Y是巯基或氨基或C 1 -C 6烷基氨基时，n至少为1; 其中所述连接化合物a）至b）的摩尔比为0.1:1至5:1; 以及含有上述碱催化反应产物的废水。
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公开(公告)号：US06770129B1
公开(公告)日：2004-08-03
申请号：US10352530
申请日：2003-01-28
IPC分类号： C09D706
摘要： Aqueous paper coating compositions containing at least one of a clay, a starch, casein, a resin, and a wax; and wherein the composition contains from about 0.001% to about 5% by weight of at least one base-catalyzed branched reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group (amino or C1-C6 alkylamino group) in place of a terminal —OH group, provided that when Y is mercapto or an amino group, n is at least 1; wherein the mole ratio of the linking compound A) to B) is from 0.1:1 to 5:1.
摘要翻译： 含有粘土，淀粉，酪蛋白，树脂和蜡中的至少一种的水性纸涂料组合物; 并且其中所述组合物含有约0.001重量％至约5重量％的至少一种碱催化的支化反应产物，其包含以下反应物：A）至少一种式I化合物，其中每个X基团为卤素原子或一个X基团 是卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，R 1是含有3至10个碳的烷基三 原子 和B）至少一种具有式II的化合物，其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S - 或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y是氢，Y可以是巯基或氨基（氨基或C1-C6烷基氨基）代替末端-OH基团，条件是当Y是巯基或氨基时，n至少为1 ;其中连接化合物A）与B）的摩尔比为0.1:1至5:1。
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公开(公告)号：US06572691B2
公开(公告)日：2003-06-03
申请号：US10229723
申请日：2002-08-28
IPC分类号： C09D1100
摘要： Ink compositions containing a surfactant-effective and/or defoaming-effective quantity of at least one reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or NR33— where R3 is hydrogen or a C1-C18 group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200, preferably from 1 to 100, more preferably from 2 to 20; and Y is hydrogen, or Y can be a mercapto group or an amino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, n is at least 1.
摘要翻译： 含有表面活性剂有效和/或消泡有效量的至少一种包含以下反应物的反应产物的油墨组合物：A）至少一种式I化合物，其中每个X基团是卤素原子或一个X基团是卤素原子 并且两个X基团表示环氧氧原子，其与R1基团中的两个相邻碳原子连接以形成环氧基，并且R 1是含有3至10个碳原子的烷三基; 和B）至少一种具有式II的化合物，其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O-，-S-或NR33-，其中R3是氢或C1-C18基团; 每个AO基团独立地为乙烯氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200，优选1至100，更优选2至20的数; Y是氢，Y可以是巯基或氨基代替末端-OH基团，条件是当Y是巯基或氨基时，n至少为1。
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5.发明申请Coating for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, latex compositions and processes therefor 审中-公开金属容器涂层，金属加工润滑剂组合物，用于电镀和电解沉积的组合物，胶乳组合物及其工艺公开(公告)号：US20100288644A1
公开(公告)日：2010-11-18
申请号：US12803263
申请日：2009-11-12
CPC分类号： C25D3/02 , C10M159/12 , C10M173/00 , C10M2207/042 , C10M2207/046 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10N2260/06
摘要： Coatings for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, and latex compositions comprising a base-catalyzed reaction product of (a) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (b) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1-C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, or a C1-C6 alkylamino group, n is at least 1; wherein the mole ratio of component a) to b) is from 0.1:1 to 5:1; are described.
摘要翻译： 用于金属容器，金属加工润滑剂组合物，用于电镀和电解提取的组合物的涂料，以及包含（a）至少一种式I的化合物R1（X）3（I）的碱催化的反应产物的胶乳组合物，其中每个X基团为 卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1是含有3至10个碳的烷基三 原子 和（b）至少一种具有式II R2X（AO）nY（II）的化合物，其中R2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S-或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y为氢原子，Y为巯基或氨基或C1-C6烷基氨基而不是端基-OH，条件是当Y为巯基或氨基时，或为C1-C6烷基氨基 ，n至少为1; 其中组分a）至b）的摩尔比为0.1:1至5:1; 被描述。
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6.发明授权Polyfluorinated compounds useful as surfactants, foam control agents and/or rheology modifiers 失效可用作表面活性剂，泡沫控制剂和/或流变改性剂的多氟化合物公开(公告)号：US07169858B2
公开(公告)日：2007-01-30
申请号：US10788136
申请日：2004-02-26
CPC分类号： C07C41/03 , C07C43/11 , C08G65/2639 , C08G65/337 , C08L71/03 , C09D5/024 , C09D7/65 , Y10T428/25 , C07C43/23
摘要： Reaction products prepared by processes which comprise reacting: A) at least one compound having the general formula I: R1(X)3 (I) wherein each X group independently represents a halogen atom or one X group represents a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group having from 3 to 10 carbon atoms; and B) at least one compound having the general formula II R2X(AO)nY (II) wherein R2 represents a polyfluorinated organic group having from 1 to 36 carbon atoms and at least two fluorine atoms; X represents —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y represents hydrogen, a mercapto group, an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, with the proviso that when Y is a mercapto, amino, or a C1–C6 alkylamino group, n is at least 1; are described.
摘要翻译： 通过以下方法制备的反应产物：A）至少一种具有通式I的化合物：<？in-line-formula description =“In-line formula”end =“lead”→> R 1> （X）3（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中每个X基团独立地表示卤素原子或一个X 基团表示卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1 >是具有3至10个碳原子的烷基三胺基; 和B）至少一种具有通式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO） Y（II）<？在线公式描述=“在线式”end =“tail”？>其中R 2表示多氟化有机基团，其具有1至 36个碳原子和至少两个氟原子; X表示-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y表示氢，巯基，氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是当Y 是巯基，氨基或C 1 -C 6烷基氨基，n为至少1; 被描述。
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公开(公告)号：US07017490B1
公开(公告)日：2006-03-28
申请号：US10436587
申请日：2003-05-13
CPC分类号： B41N3/08
摘要： Lithographic fountain solutions containing a surfactant-effective quantity of at least one reaction product comprising the following reactants: (A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (B) at least one compound having formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group or a C1–C6 alkylamino group, n is at least 1.
摘要翻译： 含有表面活性剂有效量的至少一种包含以下反应物的反应产物的平版印刷喷泉溶液：（A）至少一种式I的化合物<？in-line-formula description =“In-line Formulas”end =“lead” （X）3（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X 基团是卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻碳原子连接以形成环氧基团，并且 R 1是含有3至10个碳原子的烷基三烷基; 和（B）至少一种具有式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO）n Y（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 2是取代或未取代的饱和或不饱和的， 具有1至36个碳原子的有机基团; X是-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; 并且Y是氢，或Y可以是巯基或氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是 当Y是巯基或氨基或C 1 -C 6烷基氨基时，n至少为1。
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公开(公告)号：US6107394A
公开(公告)日：2000-08-22
申请号：US91064
申请日：1999-01-11
CPC分类号： C08G65/329 , C08L71/02
摘要： Latexes are thicknened by a blend of a urethane compound effective as an associative thickener and a non-urethane compound of the formula: R.sup.1 --(O--A).sub.a --B.sup.1 --R.sup.2 --(B.sup.2 --R.sup.3).sub.d --(B.sup.3 --(A'--O).sub.b-f --(A'--B.sup.4).sub.f --R.sup.4 --(B.sup.5 --R.sup.5).sub.e).sub.n --B.sup.6 --(A"O).sub.c --R.sup.6, wherein R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl; B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5 and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylated group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.4 --C(O)--O--, an amino group to form the amine linkage R.sup.2 --N(R)-- and/or R.sup.4 --N(R)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl), and an amido group (to form the amide linkage R.sup.2 --N(R)--C(O)-- and or R.sup.4 --N(R)--C(O)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl); each of a, b, c, d, e, f and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; and each of A, A' and A" is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.
摘要翻译： PCT No.PCT / US96 / 19136 Sec。 371日期1999年1月11日 102（e）1999年1月11日PCT PCT 1996年12月4日PCT公布。 出版物WO97 / 21743 日期：1997年6月19日通过作为缔合增稠剂和下式的非氨基甲酸酯化合物的共混物，将化合物加成：R1-（OA）a-B1-R2-（B2-R3）d-（B3 - （A'-O）bf-（A'-B4）f-R4-（B5-R5）e）n-B6-（A''O）c-R6，其中R1和R6是独立选择的一价疏水基团 由脂肪族基团，取代脂肪族基团，芳香族基团和取代芳香族基团组成的组; R2和R4独立地选自脂族，取代的脂族，芳族或取代的芳族基团，每个基团是二价或三价的; R3和R5独立地选自氢，低级烷基和低级芳烷基; B1，B2，B3，B4，B5和B6是独立地选自氧原子（形成醚键-O-）的连接基团，羧基（形成酯键R2-C（O） -O-和/或R 4 -C（O）-O-，形成胺键R2-N（R） - 和/或R4-N（R） - 的氨基，其中R是氢，低级烷基， 低级芳烷基或低级酰基）和酰氨基（形成酰胺键R2-N（R）-C（O） - 和/或R4-N（R）-C（O） - ，其中R是氢， 低级烷基，低级芳烷基或低级酰基）; a，b，c，d，e，f和n各自为整数，其中a和c各自独立地为大于20至约200的任何整数; b是大于20至约450的任何整数; d，e和f为零或1; n为1〜5的整数; 并且A，A'和A“各自独立地为乙烯，1,2-亚丙基，1,2-亚丁基单元或其组合。
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9.发明授权Alkyl polyglycoside compositions having reduced viscosity and inhibited crystallization 失效具有降低的粘度和抑制结晶的烷基多糖苷组合物
公开(公告)号：US6110977A
公开(公告)日：2000-08-29
申请号：US95677
申请日：1998-06-10
申请人： Stephen F. Gross , Michael S. Wiggins , Ronald W. Broadbent , David I. Devore , Timothy C. Morris
发明人： Stephen F. Gross , Michael S. Wiggins , Ronald W. Broadbent , David I. Devore , Timothy C. Morris
CPC分类号： C08G65/24 , B01D19/04 , B01D19/0404 , B01D19/0431 , C08G65/2609 , C08G65/337
摘要： Products of the reaction of epichlorohydrin and compounds having the formula IIR.sub.3 (EO).sub.n (PO).sub.m OH (II)wherein R.sub.3 is an alkyl, alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 10; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are extremely efficient defoamers for aqueous surfactant systems are effective as defoamers, viscosity reducers and crystallization preventives for aqueous surfactant solutions, particularly alkyl polyglycosides.
摘要翻译： 表氯醇与具有式IIR 3（EO）n（PO）mOH（II）的化合物的反应产物，其中R 3是具有4至22个碳原子的烷基，链烯基或异戊基; 具有4至22个碳原子的取代的烷基或烯基，其中： n为0〜50的数，m为0〜10的数。 其中表氯醇与（II）的摩尔比为约0.60 / 1至约2/1是用于水性表面活性剂体系的非常有效的消泡剂作为用于表面活性剂水溶液，特别是烷基多糖苷的消泡剂，降粘剂和结晶预防剂是有效的。
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公开(公告)号：US06387962B1
公开(公告)日：2002-05-14
申请号：US09606092
申请日：2000-06-27
IPC分类号： B01D1904
CPC分类号： B01D19/04 , B01D19/0404 , B01D19/0427 , B01D19/0431 , B01D19/0436 , C08G65/24 , C08G65/2609 , C08G65/337 , C09D5/024
摘要： The products of the reaction of epichlorohydrin and compounds having the formula II R3(EO)n(PO)mOH (II) wherein R3 is an alkyl alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 50; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are used in defoaming compositions for defoaming aqueous systems such as latex paints.
摘要翻译： 环氧氯丙烷与R3具有式II化合物的反应产物是具有4至22个碳原子的烷基烯基或异氰酸酯基; 具有4至22个碳原子的取代的烷基或烯基，其中： n为0〜50的数，m为0〜50的数; 其中表氯醇与（II）的摩尔比为约0.60 / 1至约2/1用于消泡组合物中用于消泡水性体系如乳胶漆。
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