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1.发明授权Alkyl polyglycoside compositions having reduced viscosity and inhibited crystallization 失效具有降低的粘度和抑制结晶的烷基多糖苷组合物
公开(公告)号：US6110977A
公开(公告)日：2000-08-29
申请号：US95677
申请日：1998-06-10
申请人： Stephen F. Gross , Michael S. Wiggins , Ronald W. Broadbent , David I. Devore , Timothy C. Morris
发明人： Stephen F. Gross , Michael S. Wiggins , Ronald W. Broadbent , David I. Devore , Timothy C. Morris
CPC分类号： C08G65/24 , B01D19/04 , B01D19/0404 , B01D19/0431 , C08G65/2609 , C08G65/337
摘要： Products of the reaction of epichlorohydrin and compounds having the formula IIR.sub.3 (EO).sub.n (PO).sub.m OH (II)wherein R.sub.3 is an alkyl, alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 10; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are extremely efficient defoamers for aqueous surfactant systems are effective as defoamers, viscosity reducers and crystallization preventives for aqueous surfactant solutions, particularly alkyl polyglycosides.
摘要翻译： 表氯醇与具有式IIR 3（EO）n（PO）mOH（II）的化合物的反应产物，其中R 3是具有4至22个碳原子的烷基，链烯基或异戊基; 具有4至22个碳原子的取代的烷基或烯基，其中： n为0〜50的数，m为0〜10的数。 其中表氯醇与（II）的摩尔比为约0.60 / 1至约2/1是用于水性表面活性剂体系的非常有效的消泡剂作为用于表面活性剂水溶液，特别是烷基多糖苷的消泡剂，降粘剂和结晶预防剂是有效的。
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公开(公告)号：US06387962B1
公开(公告)日：2002-05-14
申请号：US09606092
申请日：2000-06-27
IPC分类号： B01D1904
CPC分类号： B01D19/04 , B01D19/0404 , B01D19/0427 , B01D19/0431 , B01D19/0436 , C08G65/24 , C08G65/2609 , C08G65/337 , C09D5/024
摘要： The products of the reaction of epichlorohydrin and compounds having the formula II R3(EO)n(PO)mOH (II) wherein R3 is an alkyl alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 50; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are used in defoaming compositions for defoaming aqueous systems such as latex paints.
摘要翻译： 环氧氯丙烷与R3具有式II化合物的反应产物是具有4至22个碳原子的烷基烯基或异氰酸酯基; 具有4至22个碳原子的取代的烷基或烯基，其中： n为0〜50的数，m为0〜50的数; 其中表氯醇与（II）的摩尔比为约0.60 / 1至约2/1用于消泡组合物中用于消泡水性体系如乳胶漆。
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公开(公告)号：US06960304B1
公开(公告)日：2005-11-01
申请号：US10610892
申请日：2003-07-01
CPC分类号： C02F1/76 , C02F1/68 , C02F2101/325 , C02F2103/001 , C02F2303/12 , Y02W10/37
摘要： Methods for treating wastewater comprising adding to wastewater a defoaming and/or surfactant-effective quantity of at least one base-catalyzed branched reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group or a C1–C6 alkylamino group, n is at least 1; wherein the mole ratio of the linking compound a) to b) is from 0.1:1 to 5:1; and to wastewaters containing the above base-catalyzed reaction products.
摘要翻译： 用于处理废水的方法包括将消泡和/或表面活性剂有效量的至少一种碱催化的支化反应产物加入到废水中，所述支化反应产物包含以下反应物：A）至少一种式I化合物<？在线配方说明= “在线公式”end =“lead”？> R <1>（X）3（I）<？in-line-formula description =“In-Line Formulas “end =”tail“？>其中每个X基团是卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R 1中的两个相邻碳原子连接， / SUP>基团以形成环氧基，R 1是含有3至10个碳原子的烷三基; 和B）至少一种具有式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> R 2 X（AO）n Y（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 2是取代或未取代的饱和或不饱和的， 具有1至36个碳原子的有机基团; X是-O-，-S-或-NR 3 - ，其中R 3是氢或C 1 -C 3 - 18个烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; 并且Y是氢，或Y可以是巯基或氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是 当Y是巯基或氨基或C 1 -C 6烷基氨基时，n至少为1; 其中所述连接化合物a）至b）的摩尔比为0.1:1至5:1; 以及含有上述碱催化反应产物的废水。
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公开(公告)号：US06770129B1
公开(公告)日：2004-08-03
申请号：US10352530
申请日：2003-01-28
IPC分类号： C09D706
摘要： Aqueous paper coating compositions containing at least one of a clay, a starch, casein, a resin, and a wax; and wherein the composition contains from about 0.001% to about 5% by weight of at least one base-catalyzed branched reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group (amino or C1-C6 alkylamino group) in place of a terminal —OH group, provided that when Y is mercapto or an amino group, n is at least 1; wherein the mole ratio of the linking compound A) to B) is from 0.1:1 to 5:1.
摘要翻译： 含有粘土，淀粉，酪蛋白，树脂和蜡中的至少一种的水性纸涂料组合物; 并且其中所述组合物含有约0.001重量％至约5重量％的至少一种碱催化的支化反应产物，其包含以下反应物：A）至少一种式I化合物，其中每个X基团为卤素原子或一个X基团 是卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，R 1是含有3至10个碳的烷基三 原子 和B）至少一种具有式II的化合物，其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S - 或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y是氢，Y可以是巯基或氨基（氨基或C1-C6烷基氨基）代替末端-OH基团，条件是当Y是巯基或氨基时，n至少为1 ;其中连接化合物A）与B）的摩尔比为0.1:1至5:1。
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公开(公告)号：US06572691B2
公开(公告)日：2003-06-03
申请号：US10229723
申请日：2002-08-28
IPC分类号： C09D1100
摘要： Ink compositions containing a surfactant-effective and/or defoaming-effective quantity of at least one reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or NR33— where R3 is hydrogen or a C1-C18 group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200, preferably from 1 to 100, more preferably from 2 to 20; and Y is hydrogen, or Y can be a mercapto group or an amino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, n is at least 1.
摘要翻译： 含有表面活性剂有效和/或消泡有效量的至少一种包含以下反应物的反应产物的油墨组合物：A）至少一种式I化合物，其中每个X基团是卤素原子或一个X基团是卤素原子 并且两个X基团表示环氧氧原子，其与R1基团中的两个相邻碳原子连接以形成环氧基，并且R 1是含有3至10个碳原子的烷三基; 和B）至少一种具有式II的化合物，其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O-，-S-或NR33-，其中R3是氢或C1-C18基团; 每个AO基团独立地为乙烯氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200，优选1至100，更优选2至20的数; Y是氢，Y可以是巯基或氨基代替末端-OH基团，条件是当Y是巯基或氨基时，n至少为1。
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6.发明申请Coating for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, latex compositions and processes therefor 审中-公开金属容器涂层，金属加工润滑剂组合物，用于电镀和电解沉积的组合物，胶乳组合物及其工艺公开(公告)号：US20100288644A1
公开(公告)日：2010-11-18
申请号：US12803263
申请日：2009-11-12
CPC分类号： C25D3/02 , C10M159/12 , C10M173/00 , C10M2207/042 , C10M2207/046 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10N2260/06
摘要： Coatings for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, and latex compositions comprising a base-catalyzed reaction product of (a) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (b) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1-C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, or a C1-C6 alkylamino group, n is at least 1; wherein the mole ratio of component a) to b) is from 0.1:1 to 5:1; are described.
摘要翻译： 用于金属容器，金属加工润滑剂组合物，用于电镀和电解提取的组合物的涂料，以及包含（a）至少一种式I的化合物R1（X）3（I）的碱催化的反应产物的胶乳组合物，其中每个X基团为 卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1是含有3至10个碳的烷基三 原子 和（b）至少一种具有式II R2X（AO）nY（II）的化合物，其中R2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S-或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y为氢原子，Y为巯基或氨基或C1-C6烷基氨基而不是端基-OH，条件是当Y为巯基或氨基时，或为C1-C6烷基氨基 ，n至少为1; 其中组分a）至b）的摩尔比为0.1:1至5:1; 被描述。
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7.发明授权Polyfluorinated compounds useful as surfactants, foam control agents and/or rheology modifiers 失效可用作表面活性剂，泡沫控制剂和/或流变改性剂的多氟化合物公开(公告)号：US07169858B2
公开(公告)日：2007-01-30
申请号：US10788136
申请日：2004-02-26
CPC分类号： C07C41/03 , C07C43/11 , C08G65/2639 , C08G65/337 , C08L71/03 , C09D5/024 , C09D7/65 , Y10T428/25 , C07C43/23
摘要： Reaction products prepared by processes which comprise reacting: A) at least one compound having the general formula I: R1(X)3 (I) wherein each X group independently represents a halogen atom or one X group represents a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group having from 3 to 10 carbon atoms; and B) at least one compound having the general formula II R2X(AO)nY (II) wherein R2 represents a polyfluorinated organic group having from 1 to 36 carbon atoms and at least two fluorine atoms; X represents —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y represents hydrogen, a mercapto group, an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, with the proviso that when Y is a mercapto, amino, or a C1–C6 alkylamino group, n is at least 1; are described.
摘要翻译： 通过以下方法制备的反应产物：A）至少一种具有通式I的化合物：<？in-line-formula description =“In-line formula”end =“lead”→> R 1> （X）3（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中每个X基团独立地表示卤素原子或一个X 基团表示卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1 >是具有3至10个碳原子的烷基三胺基; 和B）至少一种具有通式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO） Y（II）<？在线公式描述=“在线式”end =“tail”？>其中R 2表示多氟化有机基团，其具有1至 36个碳原子和至少两个氟原子; X表示-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y表示氢，巯基，氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是当Y 是巯基，氨基或C 1 -C 6烷基氨基，n为至少1; 被描述。
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公开(公告)号：US07017490B1
公开(公告)日：2006-03-28
申请号：US10436587
申请日：2003-05-13
CPC分类号： B41N3/08
摘要： Lithographic fountain solutions containing a surfactant-effective quantity of at least one reaction product comprising the following reactants: (A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (B) at least one compound having formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group or a C1–C6 alkylamino group, n is at least 1.
摘要翻译： 含有表面活性剂有效量的至少一种包含以下反应物的反应产物的平版印刷喷泉溶液：（A）至少一种式I的化合物<？in-line-formula description =“In-line Formulas”end =“lead” （X）3（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X 基团是卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻碳原子连接以形成环氧基团，并且 R 1是含有3至10个碳原子的烷基三烷基; 和（B）至少一种具有式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO）n Y（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 2是取代或未取代的饱和或不饱和的， 具有1至36个碳原子的有机基团; X是-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; 并且Y是氢，或Y可以是巯基或氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是 当Y是巯基或氨基或C 1 -C 6烷基氨基时，n至少为1。
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9.发明授权Compounds and compositions useful as surfactants and methods for their preparation 有权可用作表面活性剂的化合物和组合物及其制备方法公开(公告)号：US06576736B2
公开(公告)日：2003-06-10
申请号：US10091798
申请日：2002-03-06
IPC分类号： B01D1904
CPC分类号： C08G65/337 , C08G18/283 , C08G65/327 , C08G65/329 , C08G65/3322 , C08G65/33348 , C08L71/02 , C08L63/00
摘要： Products of the reaction between I) the reaction product of reactants comprising A) a linking agent of formula I R4(Y)3 (I) wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an oxygen atom, which is attached to two adjacent carbon atoms in the R4 group to form an epoxy group, and R4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound formula II R3(EO)n(PO)m(BO)pX (II) wherein R3 is a substituted or unsubstituted, saturated or unsaturated, aliphatic or araliphatic oxy or thio group having from 1 to 36 carbon atoms or a secondary amino group having from 2 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or X can be a mercapto group or an amino group in place of a terminal —OH group, provided that when X is mercapto or amino; the sum of n, m, and p must be at least 1; and the mole ratio of A:B is from about 0.2:1 to about 5:1; and II) a reactant selected from the group consisting of an epoxy compound, an isocyanate, a phosphate compound, a sulfate compound, an organic acid, an acrylate, and methylol urea.
摘要翻译： I）反应物的反应产物包括A）式I的连接剂，其中每个Y基团是卤素原子或一个Y基团是卤素原子，两个Y基团代表氧原子，其连接到两个相邻的 R 4基团中的碳原子形成环氧基，并且R 4是含有3至10个碳原子的烷撑三基; 和B）式II化合物，其中R 3是具有1至36个碳原子的取代或未取代的饱和或不饱和的脂族或芳脂族氧基或硫基或具有2至36个碳原子的仲氨基; n为0〜50的数; m是从0到50的数字; p是从0到50的数字; X是氢，X可以是巯基或氨基代替末端-OH基团，条件是当X是巯基或氨基时; n，m和p的和必须至少为1; 并且A:B的摩尔比为约0.2:1至约5:1; 和II）选自环氧化合物，异氰酸酯，磷酸酯化合物，硫酸酯化合物，有机酸，丙烯酸酯和羟甲基脲的反应物。
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公开(公告)号：US06472440B2
公开(公告)日：2002-10-29
申请号：US09291866
申请日：1999-04-14
IPC分类号： B01D1904
CPC分类号： B01D19/0404 , B01D19/0427 , B01D19/0431 , C08G65/24 , C08G65/2609 , C08G65/337 , C11D1/662 , C11D1/72 , C11D1/722 , C11D1/8255 , C11D3/0026
摘要： Defoamers are the products of the reaction of epichlorohydrin and compounds having the formula II R3(EO)n(PO)mOH (II) wherein R3 is an alkyl, alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 10; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are extremely efficient defoamers for aqueous surfactant systems. The defoamers are added to a surfactant in an amount sufficient to reduce or eliminate foam and have the advantage of being totally dispersible in water, are readily biodegradable, contain no organic solvents and do not affect the detergency of surfactants with which they are used because they are nonionic surfactants in themselves.
摘要翻译： 消泡剂是表氯醇与式II化合物反应的产物，其中R3是具有4-22个碳原子的烷基，链烯基或异氰酸酯基; 具有4至22个碳原子的取代的烷基或烯基，其中： n为0〜50的数，m为0〜10的数。 其中表氯醇与（II）的摩尔比为约0.60 / 1至约2/1是用于水性表面活性剂体系的非常有效的消泡剂。 消泡剂以足以减少或消除泡沫的量加入到表面活性剂中，并且具有完全分散在水中的优点，易于生物降解，不含有机溶剂，并且不影响使用它们的表面活性剂的去污力，因为它们 本身是非离子表面活性剂。
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