摘要:
A nozzle for catalyst injection for olefin polymerization is provided. In one or more embodiments the nozzle includes a first conduit including a body, a tapered section, and an injection tip. The nozzle also includes a second conduit having an inner surface and an outer surface. The first conduit is disposed about the second conduit defining a first annulus therebetween. The nozzle further includes a support member at least partially disposed about the outer surface of the first conduit defining a second annulus therebetween. The support member has a converging outer surface at a first end thereof.
摘要:
A method of performing a polymerization reaction in a gas phase polymerization reactor to produce a bimodal polymer while controlling activity of a bimodal polymerization catalyst composition in the reactor by controlling concentration of at least one induced condensing agent (‘ICA’) in the reactor is provided. In some embodiments, the ICA is isopentane (or another hydrocarbon compound) and the bimodal catalyst composition includes a Group 15 and metal containing catalyst compound (or other HMW catalyst for catalyzing polymerization of a high molecular weight fraction of the product), and a metallocene catalyst compound (or other LMW catalyst for catalyzing polymerization of a low molecular weight fraction of the product).
摘要:
A method of performing a polymerization reaction in a gas phase polymerization reactor to produce a bimodal polymer while controlling activity of a bimodal polymerization catalyst composition in the reactor by controlling concentration of at least one induced condensing agent (‘ICA’) in the reactor is provided. In some embodiments, the ICA is isopentane (or another hydrocarbon compound) and the bimodal catalyst composition includes a Group 15 and metal containing catalyst compound (or other HMW catalyst for catalyzing polymerization of a high molecular weight fraction of the product), and a metallocene catalyst compound (or other LMW catalyst for catalyzing polymerization of a low molecular weight fraction of the product).
摘要:
A system and method for olefin polymerization is provided. The method includes polymerizing one or more olefins within a reactor having one or more injection tubes in fluid communication therewith, at least one of the one or more injection tubes having two or more concentric flow paths; flowing a catalyst through a first flow concentric path of the injection tube into the reactor; flowing one or more monomers through a second concentric flow path of the injection tube into the reactor; measuring rate of heat removal within the reactor; and adjusting the one or more monomers flow through the injection tube in response to the rate of heat removal in the reactor.
摘要:
A system and method for olefin polymerization is provided. The method includes polymerizing one or more olefins within a reactor having one or more injection tubes in fluid communication therewith, at least one of the one or more injection tubes having two or more concentric flow paths; flowing a catalyst through a first flow concentric path of the injection tube into the reactor; flowing one or more monomers through a second concentric flow path of the injection tube into the reactor; measuring rate of heat removal within the reactor; and adjusting the one or more monomers flow through the injection tube in response to the rate of heat removal in the reactor.
摘要:
The instant invention discloses fibers. The fibers according to the instant invention comprise a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition.
摘要:
The instant invention is a high-density polyethylene composition, method of producing the same, closure devices made therefrom, and method of making such closure devices. The high-density polyethylene composition according to the present invention comprises (a) a first component comprising a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.927 to 0.938 g/cm3, and a melt flow rate (I21) in the range of 4 to 10 g/10 minutes, and (b) a second component comprising a low molecular weight ethylene polymer having a density in the range of 0.960 to 0.975 g/cm3, and a melt index (I2) in the range of 100 to 1200 g/10 minutes; and wherein the high-density polyethylene composition has a melt index (I2) in the range of from 2 to 10 g/10 minutes, a density in the range of from 0.950 to 0.960 g/cm3, and a flow direction shrinkage to cross flow direction shrinkage ratio in the range of from 2 to 3.2, and an environmental stress crack resistance (ESCR) (F50) according to ASTM D-1693, condition B at 50° C., and using 10 percent Branched Octylphenoxy Poly(Ethyleneoxy) Ethanol, in the range of equal to or greater than 50 hours.
摘要翻译:本发明是高密度聚乙烯组合物,其制造方法,由其制成的封闭装置,以及制造这种闭合装置的方法。 根据本发明的高密度聚乙烯组合物包含(a)包含密度在0.927至0.938g / cm 3范围内的高分子量乙烯α-烯烃共聚物和熔体流动速率(I21)的第一组分, 在4至10g / 10分钟的范围内,和(b)包含密度在0.960至0.975g / cm 3范围内的低分子量乙烯聚合物的第二组分和在该范围内的熔体指数(I 2) 为100〜1200g / 10分钟; 并且其中所述高密度聚乙烯组合物具有在2至10g / 10分钟范围内的熔体指数(I 2),在0.950至0.960g / cm 3范围内的密度和横向流动方向收缩 方向收缩率在2至3.2范围内,以及根据ASTM D-1693,条件B在50℃下的环境应力开裂抗力(ESCR)(F50),并使用10%支链辛基苯氧基聚(乙烯氧基)乙醇 在等于或大于50小时的范围内。
摘要:
An instant lottery game and a draw based lottery game may be established. The instant lottery game is based on a set of rules of a playing card game. The draw based lottery game is based on a symbol matching set of rules. A random selection of a subset of a deck of playing card indicia may be generated concurrently with a purchase of a lottery ticket having the instant lottery game and the draw based lottery game. A ticket printer prints the subset of the deck of playing card indicia on a lottery ticket according to an order of the random selection and a plurality of order indicia such that each indicium in the plurality of order indicia has an association with a playing card indicium in the deck of playing card indicia to indicate an order in the subset of the deck of playing card indicia.
摘要:
A multi-priced instant lottery game with a first price point and a second price point is provided such that (i) the first price point corresponds to a first known potential fixed prize and a first known potential percentage of a progressive prize and (ii) the second price point corresponds to a second known potential fixed prize and a second known potential percentage of the progressive prize. The second price point is greater than the first price point. The second known potential fixed prize being greater than the first known potential fixed prize. The second known potential percentage of the progressive prize is greater than the first known potential percentage of the progressive prize. Further, a set of indicia associated with an instant lottery game ticket is generated. In addition, the instant lottery game ticket with the set of indicia is printed with a lottery ticket printer.
摘要:
The instant invention is a polyethylene composition, method of producing the same, fibers made therefrom, and method of making the same. The polyethylene composition according to instant invention comprises: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers. The polyethylene composition according to instant invention has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for producing the inventive polyethylene composition comprises the steps of: (1) (co)polymerizing ethylene and optionally one or more α-olefin comonomers in the presence of a hafnium based metallocene catalyst via a gas phase (co)polymerization process in a single stage reactor; and (2) thereby producing the polyethylene composition having a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The fibers according to the instant invention comprise a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for making a fiber according to instant invention comprises the steps of: (1) selecting a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition; (2) spinning the polyethylene composition into a fiber; and (3) thereby forming the fiber.