公开(公告)号：US4734392A

公开(公告)日：1988-03-29

申请号：US38132

申请日：1987-04-14

申请人： Keshab Ganguli ,  Peter Nootenboom ,  Cornelis Lok

发明人： Keshab Ganguli ,  Peter Nootenboom ,  Cornelis Lok

IPC分类号： C07B35/02 ,  B01J21/12 ,  B01J21/16 ,  B01J23/74 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  C07B31/00 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/03 ,  C11C3/12 ,  B01J21/04

CPC分类号： C11C3/123 ,  B01J23/755 ,  B01J35/10 ,  B01J21/12 ,  B01J35/0006 ,  B01J35/0053 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109

摘要： The invention provides a nickel/alumina catalyst, with an atomic ratio of nickel/aluminum between 10 and 2, an active nickel surface area between 70 and 150 m.sup.2 /g nickel and an average pore size, depending on the above atomic ratio, between 4 and 20 nanometers. Preferably the nickel/aluminum atomic ratio is between 10 and 4. Preferably the catalyst has a specific porous structure.The invention also provides a method for preparing the catalyst by a two step process involving precipitating nickel ions and adding during a second, so-called aging step a soluble aluminum compound.The catalyst is useful for hydrogenating unsaturated organic compounds in particular oils.

公开(公告)号：US20070270514A1

公开(公告)日：2007-11-22

申请号：US11791769

申请日：2005-11-21

申请人： Cornelis Lok ,  Sharon Bale

发明人： Cornelis Lok ,  Sharon Bale

IPC分类号： B01J35/00 ,  B01J21/04 ,  B01J35/02 ,  B01J37/02 ,  B01J23/75

CPC分类号： B01J35/008 ,  B01J21/04 ,  B01J23/75 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0203 ,  B01J37/16 ,  C10G2/332 ,  C10G45/00 ,  C10G45/48

摘要： A method for the preparation of an eggshell catalyst is described comprising the steps of i) immersing shaped units of an oxidic support having a smallest unit dimension ≦0.5 mm in a solution of cobalt ammine carbonate, ii) heating the solution to a temperature between 60 and 120° C. to precipitate cobalt compounds onto the surface of the shaped units, iii) separating the resulting supported cobalt compounds from the remaining solution, and iv) drying the supported cobalt compounds. The cobalt compounds may be reduced to provide catalysts suitable for the hydrogenation of unsaturated compounds or the Fischer-Tropsch synthesis of hydrocarbons.

摘要翻译： 描述了制备蛋壳催化剂的方法，其包括以下步骤：i）将具有最小单位尺寸<= 0.5mm的氧化载体的成形单元浸入碳酸钴铵溶液中，ii）将溶液加热至 60℃和120℃，以将钴化合物沉淀到成形单元的表面上，iii）将所得负载的钴化合物与剩余的溶液分离，以及iv）干燥负载的钴化合物。 可以将钴化合物还原以提供适用于不饱和化合物的氢化或烃的费 - 托合成的催化剂。

公开(公告)号：US20070259974A1

公开(公告)日：2007-11-08

申请号：US11661231

申请日：2005-08-19

申请人： Cornelis Lok ,  John West

发明人： Cornelis Lok ,  John West

IPC分类号： B01J23/75 ,  B01J35/10 ,  B01J37/03 ,  C10G2/00

CPC分类号： B01J35/0053 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/864 ,  B01J23/8892 ,  B01J23/8896 ,  B01J23/8913 ,  B01J33/00 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/14 ,  C10G2/332

摘要： A particulate catalyst comprises an intimate mixture of cobalt and aluminium compounds at an atomic ratio in the range 10:1 to 2:1 (Co:Al), which when reduced at 425° C., has a cobalt surface area as measured by hydrogen chemisorption at 150° C. of at least 30 m2/g of catalyst. The catalyst is prepared by sequential precipitation of cobalt with aluminium ions in the presence of an alkaline precipitation agent. The catalyst may be used for the hydrogenation of unsaturated compounds or the Fischer-Tropsch synthesis of hydrocarbons.

摘要翻译： 颗粒催化剂包含原子比为10:1至2:1（Co:Al）的钴和铝化合物的紧密混合物，当在425℃下还原时，其具有由氢测量的钴表面积 在150℃下化学吸附至少为30m 2 / g的催化剂。 催化剂是通过在碱性沉淀剂的存在下用铝离子连续沉淀钴来制备的。 催化剂可用于不饱和化合物的氢化或烃的费 - 托合成。

公开(公告)号：US20050272827A1

公开(公告)日：2005-12-08

申请号：US10528527

申请日：2003-09-25

申请人： Cornelis Lok

发明人： Cornelis Lok

IPC分类号： B01J21/06 ,  B01J23/75 ,  B01J37/03 ,  C07C209/32 ,  C07C209/48 ,  C10G2/00 ,  C07C27/06

CPC分类号： B01J21/063 ,  B01J23/75 ,  B01J37/031 ,  C07C209/32 ,  C07C209/48 ,  C10G2/332 ,  C10G2300/202 ,  C10G2300/703

摘要： Catalysts comprising cobalt on a titania support are produced by mixing together particles of a solid titania support and an aqueous solution of cobalt ammine carbonate, and heating to an elevated temperature sufficient to effect decomposition of the cobalt ammine carbonate and precipitation of a cobalt species onto said support. The catalysts are useful in hydrogenation and Fischer-Tropsch reactions.

摘要翻译： 包含二氧化钛载体上的钴的催化剂通过将固体二氧化钛载体的颗粒和碳酸氨铜的水溶液混合在一起并加热到足以实现碳酸钴铵分解的高温并将钴物质沉淀到所述 支持。 催化剂可用于氢化和费 - 托反应。