公开(公告)号：US08946357B2

公开(公告)日：2015-02-03

申请号：US13698279

申请日：2011-05-18

申请人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Kiyoshi Sakai ,  Koichi Ayama

发明人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Kiyoshi Sakai ,  Koichi Ayama

IPC分类号： C08F30/08 ,  C09D183/04 ,  C07F7/21 ,  C08G77/04 ,  H01L23/29 ,  C09K3/10 ,  C08G77/20 ,  C08G77/00 ,  H01L33/56

CPC分类号： C08F30/08 ,  C07F7/21 ,  C08G77/045 ,  C08G77/12 ,  C08G77/20 ,  C08G77/50 ,  C08G77/80 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04 ,  C09D183/04 ,  C09K3/1018 ,  H01L23/296 ,  H01L33/56 ,  H01L2924/0002 ,  H01L2924/00

摘要： A solution is a liquid organosilicon compound represented by general formula (1) as described below: wherein, X is each independently a group represented by formula (I), formula (II) or formula (III) as described below, and when the number of the group represented by formula (I) per one molecule of the liquid organosilicon compound represented by general formula (1) is defined as a, the number of the group represented by formula (II) per one molecule thereof is defined as b, and the number of the group represented by formula (III) per one molecule thereof is defined as c, 0≦a≦3.5, 0≦b≦3.5, and 0≦c≦1 are obtained, and also a+b+2c=4 is obtained:

公开(公告)号：US20130096249A1

公开(公告)日：2013-04-18

申请号：US13698279

申请日：2011-05-18

申请人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Kiyoshi Sakai ,  Koichi Ayama

发明人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Kiyoshi Sakai ,  Koichi Ayama

IPC分类号： C08F30/08 ,  C09D183/04 ,  C07F7/21

CPC分类号： C08F30/08 ,  C07F7/21 ,  C08G77/045 ,  C08G77/12 ,  C08G77/20 ,  C08G77/50 ,  C08G77/80 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04 ,  C09D183/04 ,  C09K3/1018 ,  H01L23/296 ,  H01L33/56 ,  H01L2924/0002 ,  H01L2924/00

摘要： A solution is a liquid organosilicon compound represented by general formula (1) as described below: wherein, X is each independently a group represented by formula (I), formula (II) or formula (III) as described below, and when the number of the group represented by formula (I) per one molecule of the liquid organosilicon compound represented by general formula (1) is defined as a, the number of the group represented by formula (II) per one molecule thereof is defined as b, and the number of the group represented by formula (III) per one molecule thereof is defined as c, 0≦a≦3.5, 0≦b≦3.5, and 0≦c≦1 are obtained, and also a+b+2c=4 is obtained:

摘要翻译： 溶液是如下所述的由通式（1）表示的液体有机硅化合物：其中，X各自独立地为如下所述的式（I），式（II）或式（III）表示的基团，当数字 由通式（I）表示的基团每一分子由通式（1）表示的液体有机硅化合物表示的基团定义为a，其每一分子中由式（II）表示的基团的数目定义为b，并且 其每一分子由式（III）表示的基团的数目定义为c，0 @ a @ 3.5，0 @ b @ 3.5和0 @ c @ 1，并且a + b + 2c = 4 获得：

公开(公告)号：US20140148536A1

公开(公告)日：2014-05-29

申请号：US14130499

申请日：2012-06-28

申请人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Yoshiko Watanabe ,  Koichi Ayama

发明人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Yoshiko Watanabe ,  Koichi Ayama

IPC分类号： H01L33/56

CPC分类号： H01L33/56 ,  C07F7/21 ,  C08G59/306 ,  C08G77/045 ,  C08G77/12 ,  C08G77/388 ,  C08G77/54 ,  C08K5/1515 ,  C08K5/34924 ,  C09D163/00 ,  H01L2924/0002 ,  H01L2924/00 ,  C08L83/04

摘要： The invention provides an adhesion-imparting agent having heat-resistant transparency and a high refractive index best suited for an addition hardening type composition including a reaction product of silsesquioxane and organopolysiloxane. The invention relates to a compound obtained by allowing a hydrosilylation addition reaction of (A), (B), and when necessary, (C) as described below, and a compound including an organopolysiloxane or silsesquioxane skeleton including as an essential component an isocyanuric ring skeleton and an epoxy group, and having an SiH group residue: (A) a compound including an organopolysiloxane or silsesquioxane skeleton and having three or more SiH groups in one molecule; (B) an epoxy derivative having one aliphatic unsaturated group in one molecule; and (C) organopolysiloxane having two alkenyl groups in one molecule, and having a number average molecular weight of 100 to 500,000, or an isocyanurate compound having two alkenyl groups in one molecule.

摘要翻译： 本发明提供一种具有耐热透明性和高折射率的粘合赋予剂，其最适合于包含倍半硅氧烷和有机聚硅氧烷的反应产物的加成硬化型组合物。 本发明涉及通过如下所述进行（A），（B），必要时的（C）的氢化硅烷化加成反应得到的化合物和包含作为必需成分的有机聚硅氧烷或倍半硅氧烷骨架的化合物的异氰脲酸酯环 骨架和环氧基，并且具有SiH基团残基：（A）包含有机聚硅氧烷或倍半硅氧烷骨架的化合物，并且在一个分子中具有三个或更多个SiH基团; （B）一分子中具有一个脂族不饱和基团的环氧衍生物; 和（C）在一个分子中具有两个烯基的数均分子量为100至500,000的有机聚硅氧烷，或在一个分子中具有两个烯基的异氰脲酸酯化合物。

公开(公告)号：US08987358B2

公开(公告)日：2015-03-24

申请号：US14130499

申请日：2012-06-28

申请人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Yoshiko Watanabe ,  Koichi Ayama

发明人： Kiichi Kawabata ,  Akio Tajima ,  Takashi Matsuo ,  Yoshiko Watanabe ,  Koichi Ayama

IPC分类号： H01L33/56 ,  C07F7/21 ,  C08G77/54 ,  C08G77/388 ,  C08G59/30 ,  C09D163/00

CPC分类号： H01L33/56 ,  C07F7/21 ,  C08G59/306 ,  C08G77/045 ,  C08G77/12 ,  C08G77/388 ,  C08G77/54 ,  C08K5/1515 ,  C08K5/34924 ,  C09D163/00 ,  H01L2924/0002 ,  H01L2924/00 ,  C08L83/04

摘要： The invention provides an adhesion-imparting agent having heat-resistant transparency and a high refractive index best suited for an addition hardening type composition including a reaction product of silsesquioxane and organopolysiloxane. The invention relates to a compound obtained by allowing a hydrosilylation addition reaction of (A), (B), and when necessary, (C) as described below, and a compound including an organopolysiloxane or silsesquioxane skeleton including as an essential component an isocyanuric ring skeleton and an epoxy group, and having an SiH group residue: (A) a compound including an organopolysiloxane or silsesquioxane skeleton and having three or more SiH groups in one molecule; (B) an epoxy derivative having one aliphatic unsaturated group in one molecule; and (C) organopolysiloxane having two alkenyl groups in one molecule, and having a number average molecular weight of 100 to 500,000, or an isocyanurate compound having two alkenyl groups in one molecule.

摘要翻译： 本发明提供一种具有耐热透明性和高折射率的粘合赋予剂，其最适合于包含倍半硅氧烷和有机聚硅氧烷的反应产物的加成硬化型组合物。 本发明涉及通过如下所述进行（A），（B），必要时的（C）的氢化硅烷化加成反应得到的化合物和包含作为必需成分的有机聚硅氧烷或倍半硅氧烷骨架的化合物的异氰脲酸酯环 骨架和环氧基，并且具有SiH基团残基：（A）包含有机聚硅氧烷或倍半硅氧烷骨架的化合物，并且在一个分子中具有三个或更多个SiH基团; （B）一分子中具有一个脂族不饱和基团的环氧衍生物; 和（C）在一个分子中具有两个烯基的数均分子量为100至500,000的有机聚硅氧烷，或在一个分子中具有两个烯基的异氰脲酸酯化合物。

公开(公告)号：US4937304A

公开(公告)日：1990-06-26

申请号：US205278

申请日：1988-06-10

申请人： Koichi Ayama ,  Kaneo Noake ,  Tamio Serita

发明人： Koichi Ayama ,  Kaneo Noake ,  Tamio Serita

IPC分类号： C04B35/571 ,  C04B35/589 ,  C08G77/48 ,  C08G77/62

CPC分类号： C08G77/62 ,  C04B35/571 ,  C04B35/589

摘要： There is provided a new polysilazane product from a specific precursor. Desired molecular weight of the polysilazane can be obtained by selecting proper amount of a silazane or silylamine compound ##STR1## as an additive. The polysilazane is stable during storage without gelation. The polymerization of the precursor can be carried out without gelation even at a high temperature and hence can be completed in a short time. The polysilazane can be made into ceramics fiber by spinning from a solution and subsequent firing.

公开(公告)号：US6107504A

公开(公告)日：2000-08-22

申请号：US181608

申请日：1998-10-28

申请人： Yuuichi Yamamoto ,  Koichi Ayama

发明人： Yuuichi Yamamoto ,  Koichi Ayama

IPC分类号： C07B61/00 ,  C07F7/08 ,  C08G77/12 ,  C08G77/38 ,  C08G77/385 ,  C08G77/46

CPC分类号： C07F7/0852 ,  C08G77/38 ,  C08G77/46

摘要： There are herein disclosed a siloxane compound represented by the formula (1) ##STR1## wherein R.sup.2 is a methyl group or a phenyl group; R.sup.3 is an alkyl group having 1 to 6 carbon atoms or A; l is an integer of 0 to 500; m is an integer of 0 to 1,000; n is an integer of 0 to 500; p is an integer of 0 to 2; and A is an ester group represented by the formula (2) ##STR2## wherein R.sup.6 is hydrogen or the methyl group; s is an integer of 0 to 100; and R.sup.1 is a branched or a straight-chain alkyl group having 1 to 30 carbon atoms, a cyclohexyl group, a phenyl group, a benzyl group, a glycidyl group, or a fluorine-containing organic group represented by the formula (3) ##STR3## wherein R.sup.4 is a saturated hydrocarbon having 0 to 6 carbon atoms, and when 0 is selected, R.sup.4 is not present; R.sup.5 is hydrogen or fluorine; a is 0 or 1; and b and c are each an integer of 0 to 20, but for a, b and c, 0 is not simultaneously selected, and a preparation method of the above siloxane compound.

摘要翻译： 本文公开了式（1）表示的硅氧烷化合物，其中R 2为甲基或苯基; R3是具有1至6个碳原子的烷基或A; l为0〜500的整数; m为0〜1000的整数; n为0〜500的整数， p为0〜2的整数。 和A是由式（2）表示的酯基，其中R 6是氢或甲基; s为0〜100的整数; R1为碳原子数1〜30的支链或直链烷基，由式（3）表示的环己基，苯基，苄基，缩水甘油基或含氟有机基，式 R4是具有0至6个碳原子的饱和烃，当选择0时，不存在R4; R5是氢或氟; a是0或1; b和c各自为0〜20的整数，但对于a，b和c，不同时选择0，也可以是上述硅氧烷化合物的制备方法。

公开(公告)号：US6107505A

公开(公告)日：2000-08-22

申请号：US203401

申请日：1998-12-02

申请人： Kazuhiro Yoshida ,  Koichi Ayama ,  Nobumasa Ootake

发明人： Kazuhiro Yoshida ,  Koichi Ayama ,  Nobumasa Ootake

IPC分类号： C07F7/08 ,  C08G77/04 ,  C08G77/06 ,  C08G77/20

CPC分类号： C08G77/06 ,  C07F7/0874 ,  C08G77/04 ,  C08G77/20

摘要： The present invention discloses a process for producing a polyorganosiloxane, which comprises adding an organochlorosilane to a uniform mixture comprising water and at least one kind of alcohol, to subject the organochlorosilane to a hydrolysis and condensation reaction. The organochlorosilane is preferably one represented by the following formula (1):R.sup.1 --Si(Cl).sub.3 (1)wherein R.sup.1 is a C.sub.1-30 straight chain saturated or unsaturated hydrocarbon group, a C.sub.1-30 branched chain saturated or unsaturated hydrocarbon group, a phenyl group, a cyclohexyl group, a C.sub.3-15 halogenated hydrocarbon group, an acryloxypropyl group or a methacryloxypropyl group.

摘要翻译： 本发明公开了一种聚有机硅氧烷的制造方法，其包括向含有水和至少一种醇的均匀混合物中加入有机氯硅烷，使有机氯硅烷进行水解和缩合反应。 有机氯硅烷优选为下式（1）表示的化合物：R1-Si（C1）3（1）其中R1为C1-30直链饱和或不饱和烃基，C1-30支链饱和或不饱和烃基 苯基，环己基，C3-15卤代烃基，丙烯酰氧基丙基或甲基丙烯酰氧基丙基。

公开(公告)号：US5831110A

公开(公告)日：1998-11-03

申请号：US42737

申请日：1998-03-17

申请人： Yuichi Isoda ,  Koichi Ayama

发明人： Yuichi Isoda ,  Koichi Ayama

IPC分类号： C07F7/08 ,  C07F7/10

CPC分类号： C07F7/0852 ,  C07F7/0874

摘要： According to the present invention there is disclosed a process for producing a fluorine-containing siloxane compound represented by the formula (3): ##STR1## �wherein A is a fluorine-containing organic group represented by the formula (4): ##STR2## (wherein R.sup.1 and R.sup.2 are each independently a fluorine atom or a trifluoromethyl group, R.sup.3 is a hydrogen atom or a straight chain or branched chain hydrocarbon group having 1 to 8 carbon atoms, k is an integer of 0 to 16, m is an integer of 0 to 30, n is 0 or 1, and p is an integer of 0 to 9); r is an integer of 1 to 3; R.sup.4 is a monovalent hydrocarbon group having 1 to 6 carbon atoms; and B.sup.1 is a hydrogen atom, a methacryloxypropyl group or a vinyl group!, which process comprises reacting a fluorine-containing silane represented by the formula (1): ##STR3## (wherein R.sup.1, R.sup.2, R.sup.3, k, m, n and p have the same definitions as given above) with a chlorosilane represented by the formula (2): ##STR4## (wherein R.sup.4, B.sup.1 and r have the same definitions as given above). There is also disclosed a fluorine-containing siloxane compound of the formula (3) wherein B.sup.1 is an isocyanate-containing group.

摘要翻译： 根据本发明，公开了由式（3）表示的含氟硅氧烷化合物的制造方法：由式（4）表示的有机基团：tly为氟原子或三氟甲基，R3为氢 原子或碳原子数为1〜8的直链或支链烃基，k为0〜16的整数，m为0〜30的整数，n为0或1，p为0〜9的整数。 ）; r为1〜3的整数， R4是具有1-6个碳原子的一价烃基; 和B1是氢原子，甲基丙烯酰氧基丙基或乙烯基]，该方法包括使由式（1）表示的含氟硅烷：其中R1，R2，R3，k，m ，n和p具有与上述相同的定义）与式（2）表示的氯代硅烷：其中R4，B1和r具有与上述相同的定义。 还公开了式（3）的含氟硅氧烷化合物，其中B1是含异氰酸酯的基团。

公开(公告)号：US5952444A

公开(公告)日：1999-09-14

申请号：US925183

申请日：1997-09-08

申请人： Koichi Ayama

发明人： Koichi Ayama

IPC分类号： C08G18/61 ,  C08G18/80 ,  C09D175/04 ,  C08G77/04

CPC分类号： C08G18/61 ,  C08G18/8025 ,  C09D175/04

摘要： According to the present invention, there are here disclosed a polyurethane resin derivative having a polydimethylsiloxane side chain and an isocyanate group in a main chain of a polyurethane molecule which is obtainable by reacting (A) a polydimethylsiloxane having an alkyl group on one terminal and 2 hydroxyl groups in the vicinity of the other terminal with (B) a polyisocyanate having 2 or more isocyanate groups in one molecule; a coating resin composition which is obtainable by reacting a polyurethane resin derivative having a polydimethylsiloxane side chain and an isocyanate group in a main chain of a polyurethane molecule with a hydroxyl group-containing resin; and a method for curing the coating resin composition.

摘要翻译： 根据本发明，这里公开了在聚氨酯分子的主链中具有聚二甲基硅氧烷侧链和异氰酸酯基的聚氨酯树脂衍生物，其通过（A）在一个末端具有烷基的聚二甲基硅氧烷和2 （B）在一个分子中具有2个以上异氰酸酯基团的多异氰酸酯的另一个末端附近的羟基; 通过使聚氨酯分子的主链中具有聚二甲基硅氧烷侧链和异氰酸酯基的聚氨酯树脂衍生物与含羟基的树脂反应得到的涂料树脂组合物; 以及固化涂料树脂组合物的方法。