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    Bifunctional alkali metal compounds, preparation and use thereof as polymerization initiators
    1.
    发明授权
    Bifunctional alkali metal compounds, preparation and use thereof as polymerization initiators 失效
    双官能碱金属化合物，其制备和用途为聚合引发剂

    公开(公告)号：US4861742A

    公开(公告)日：1989-08-29

    申请号：US238851

    申请日：1988-09-01

    申请人： Klaus Bronstert ,  Siegbert Bohnet ,  Walter Himmele ,  Kaspar Bott

    发明人： Klaus Bronstert ,  Siegbert Bohnet ,  Walter Himmele ,  Kaspar Bott

    IPC分类号： C07F1/00 ,  C07F1/02 ,  C07F1/04 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F12/00 ,  C08F12/08 ,  C08F36/00 ,  C08F36/06

    CPC分类号： C07F1/02 ,  C07F1/04 ,  C08F4/46

    摘要： Bifunctional initiators for anionic polymerization are prepared by reacting an alkenylaromatic compound of the general formula I ##STR1## where Ar is aromatic hydrocarbyl which may be substituted by alkyl or another group inert toward organoalkali metal compounds and may contain nitrogen,R.sup.1 is linear or branched alkyl, cycloalkyl, alkenyl or aralkyl or from 1 to 22 carbon atoms where at least the carbon adjacent to the double bond is saturated and aliphatic,R.sup.2 is hydrogen or is likewise linear or branched alkyl, cycloalkyl, alkenyl or aralkyl or from 1 to 22 carbon atoms where at least the carbon adjacent to the double bond is saturated and aliphatic, and where R.sup.1 and R.sup.2 may be part of a common cycloaliphatic ring, in the presence of one or more ethers and of tertiary amines and in the presence or absence of a further inert aliphatic, alicyclic or aromatic solvent, at from -20.degree. to +70.degree. C. with preferably lithium and with dimerization, with the use in addition of poly-cyclic aromatic hydrocarbons which catalytically promote the dimerization in amount of from 0.001 to 50, preferably 20, mol % and with or without the removal of the ethers and/or tertiary amines after the preparation, and are used for polymerizing anionically polymerizable monomers such as styrene.

    摘要翻译： 用于阴离子聚合的双功能引发剂通过使通式I的链烯基芳族化合物（I）反应来制备，其中Ar是可被烷基取代的芳族烃基或对有机碱金属化合物惰性的另一个基团，并且可以含有氮，R 1是直链的 或支链烷基，环烷基，烯基或芳烷基或1至22个碳原子，其中至少与双键相邻的碳饱和和脂族，R2是氢或同样是直链或支链烷基，环烷基，烯基或芳烷基或1 至少22个碳原子，其中至少邻近双键的碳饱和和脂族，并且其中R1和R2可以是常见的脂环族环的一部分，在一个或多个醚和叔胺的存在下， 不存在另外惰性的脂族，脂环族或芳族溶剂，在-20至+ 70℃，优选锂和二聚作用，同时使用多环 催化促进二聚的量为0.001至50，优选为20摩尔％的芳烃，并且在制备后有或没有除去醚和/或叔胺，并用于聚合阴离子聚合单体如苯乙烯。

    Fungicidal N-substituted 3-arylpyrrolidine derivatives
    4.
    发明授权
    Fungicidal N-substituted 3-arylpyrrolidine derivatives 失效
    杀真菌剂N-取代的3-氨基吡啶衍生物

    公开(公告)号：US5068245A

    公开(公告)日：1991-11-26

    申请号：US251243

    申请日：1988-09-30

    申请人： Matthias Zipplies ,  Hubert Sauter ,  Franz Roehl ,  Walter Himmele ,  Eberhard Ammermann ,  Ernst-Heinrich Pommer

    发明人： Matthias Zipplies ,  Hubert Sauter ,  Franz Roehl ,  Walter Himmele ,  Eberhard Ammermann ,  Ernst-Heinrich Pommer

    IPC分类号： C07D207/06 ,  C07D207/08 ,  C07D405/04 ,  C07D405/08

    CPC分类号： C07D405/08 ,  C07D207/06 ,  C07D207/08

    摘要： N-Substituted 3-arylpyrrolidine derivatives of the formula ##STR1## where R.sup.1 is 2,2-dimethylpropyl, 3,3-dimethylbutyl, 4,4-dimethylpentyl, 2,4,4-trimethylpentyl, 6-methylhept-2-yl, 3,5,5-trimethylhexyl, 6,10-dimethylundec-2-yl, 3-methylcyclohexyl, 3,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, 3,3,5,5-tetramethylcyclohexyl, 4-methylcyclohexyl, 4-ethylcyclohexyl, 4-propylcyclohexyl, 4-isopropylcyclohexyl, 4-tert.-butylcyclohexyl, trans-4-tert.-butylcyclohexyl, 4(2-methylbut-2-yl)cyclohexyl, 4(2,4,4-trimethylpent-2-yl)-cyclohexyl, cyclododecanyl, C.sub.3 -C.sub.9 -trialkylsilyl-substituted C.sub.4 -C.sub.12 -cycloalkyl, 4-hydroxycyclohexyl, 4-hydroxy-3-methylcyclohexyl, 4-hydroxy-3,5-dimethylcyclohexyl, 4-hydroxy-3,3-dimethylcyclohexyl, 4-hydroxy-3,3,5-trimethylcyclohexyl, unsubstituted or hydroxy-, C.sub.1 -C.sub.9 -alkyl-, C.sub.1 -C.sub.5 -alkoxy- or C.sub.3 -C.sub.9 -trialkylsilyl-substituted C.sub.5 -C.sub.12 -cycloalkenyl,R.sup.1 is further bicycloalkyl,R.sup.1 is further 4-tert.-butyl-benzyl, 4-chlorobenzyl, 4-tert.-butoxybenzyl, 1,4-dioxaspiro[4,5]decan-8-yl,5 to 7-membered heterocycloalkyl,5 to 7-membered heterocycloalkylmethyl,R.sup.2 is alkyl, alkoxy or trialkylsilyl,R.sup.3 is alkyl, alkenyl, alkynyl or arylalkyl,X- is a plant-tolerated anion,n is 0 or 1,and plant-tolerated salts thereof, and fungicides containing these compounds.

    摘要翻译： 其中R 1是2,2-二甲基丙基，3,3-二甲基丁基，4,4-二甲基戊基，2,4,4-三甲基戊基，6-甲基庚-2-基， 3,5,5-三甲基己基，6,10-二甲基十一烷基-2-基，3-甲基环己基，3,3-二甲基环己基，3,3,5-三甲基环己基，3,3,5,5-四甲基环己基，4-甲基环己基， 4-乙基环己基，4-丙基环己基，4-异丙基环己基，4-叔丁基环己基，反式-4-叔丁基环己基，4（2-甲基丁-2-基）环己基，4（2,4,4-三甲基 - 2-环己基，环十二烷基，C 3 -C 9 - 三烷基甲硅烷基取代的C 4 -C 12环烷基，4-羟基环己基，4-羟基-3-甲基环己基，4-羟基-3,5-二甲基环己基，4-羟基-3， 4-羟基-3,3,5-三甲基环己基，未取代或羟基 - ，C 1 -C 9 - 烷基 - ，C 1 -C 5 - 烷氧基 - 或C 3 -C 9 - 三烷基甲硅烷基取代的C 5 -C 12 - 环烯基，R 1是 进一步的双环烷基，R 1还是4-叔丁基 - 苄基，4-氯苄基，4-叔丁氧基苄基，1,4-二氧杂螺[4,5]癸烷-8- 芳基，5至7元杂环烷基，5至7元杂环烷基甲基，R2为烷基，烷氧基或三烷基甲硅烷基，R3为烷基，烯基，炔基或芳烷基，X为植物耐受阴离子，n为0或1， 及其耐受植物的盐，以及含有这些化合物的杀真菌剂。

    Method of continuously producing .gamma.-butyrolactams
    7.
    发明授权
    Method of continuously producing .gamma.-butyrolactams 失效
    连续生产{65-丁内酰胺的方法

    公开(公告)号：US3975400A

    公开(公告)日：1976-08-17

    申请号：US334398

    申请日：1973-02-21

    申请人： Walter Himmele ,  Ernst Hofmann ,  Herwig Hoffmann ,  Reinhold Plass

    发明人： Walter Himmele ,  Ernst Hofmann ,  Herwig Hoffmann ,  Reinhold Plass

    IPC分类号： C07D207/26 ,  C07D207/267

    CPC分类号： C07D207/267

    摘要： Method of producing .gamma.-butyrolactams by reacting .gamma.-butyrolactones with ammonia in the presence or absence of water at elevated temperatures and pressures. The reaction is carried out continuously at temperatures ranging from 180.degree. to 340.degree.C whilst maintaining pressures which are at least 10 percent higher than the pressure equal to the sum of the partial pressures of the reactants at the temperature used. .gamma.-Butyrolactams are valuable intermediates, for example in the manufacture of polymers, pharmaceuticals and solvents.

    摘要翻译： 在高温和高压下，在存在或不存在水的情况下，使γ-丁内酯与氨反应制备γ-丁内酰胺的方法。 反应在180℃至340℃的温度下连续进行，同时保持比在所用温度下等于反应物分压之和的压力至少高10％的压力。 γ-丁内酰胺是有价值的中间体，例如在聚合物，药物和溶剂的制备中。