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公开(公告)号:US08637608B2
公开(公告)日:2014-01-28
申请号:US13058063
申请日:2009-08-17
申请人: Klaus Hintzer , Michael Juergens , Harald Kaspar , Kai H. Lochhaas , Oleg Shyshkov , Andre Streiter , Tilman C. Zipplies , Sabine H. G. Beuermann , Muhammad Imran ul-haq
发明人: Klaus Hintzer , Michael Juergens , Harald Kaspar , Kai H. Lochhaas , Oleg Shyshkov , Andre Streiter , Tilman C. Zipplies , Sabine H. G. Beuermann , Muhammad Imran ul-haq
IPC分类号: C08L27/12 , C08F214/26 , C08F12/20 , C08F14/18 , C07C241/00 , B32B1/08 , B32B15/08
CPC分类号: C08F8/30 , C08F4/00 , C08F4/02 , C08F114/20 , C08F114/22 , C08G73/00 , Y10T428/139 , Y10T428/1397 , C08F14/18
摘要: Fluoropolymers containing one or more azide group wherein the azide group is not a sulfonyl-azide group and processes of preparing them.
摘要翻译: 含有一个或多个叠氮基的含氟聚合物及其制备方法,其中叠氮基不是磺酰基叠氮基。
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公开(公告)号:US20130281607A1
公开(公告)日:2013-10-24
申请号:US13995615
申请日:2011-12-21
申请人: Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
发明人: Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
IPC分类号: C25B3/08
CPC分类号: C08F6/003 , C02F1/26 , C02F1/461 , C02F2001/46138 , C02F2001/46147 , C08F2/10 , C08F2/20 , C08F14/08 , C08F14/18 , C08F2800/10 , Y02P20/582 , C08F2/24
摘要: Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [Rf—O-L-COO-]i Xi+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, Rf represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.
摘要翻译: 本文描述的是包含氟化单体的水性聚合反应产物的组合物,其中聚合反应开始于(i)在不存在氟化乳化剂的情况下,并且由此在聚合过程中不加入氟化乳化剂,或(ii)在氟化乳化剂存在下 选自:[Rf-OL-COO-] i Xi +(I)其中L表示直链或支链,非氟化,部分氟化或完全氟化的亚烷基,Rf表示直链或支链部分或完全氟化的脂族基团或 间隔有至少一个氧原子的直链或支链部分或完全氟化的脂肪族基团,X i +表示i为i且i为1,2或3的阳离子; 其中所述反应产物和/或所得水相基本上不含二烷基胺和三烷基胺,并且基本上不含低分子量氟代有机化合物及其方法。
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公开(公告)号:US09453086B2
公开(公告)日:2016-09-27
申请号:US13995615
申请日:2011-12-21
申请人: Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
发明人: Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
CPC分类号: C08F6/003 , C02F1/26 , C02F1/461 , C02F2001/46138 , C02F2001/46147 , C08F2/10 , C08F2/20 , C08F14/08 , C08F14/18 , C08F2800/10 , Y02P20/582 , C08F2/24
摘要: Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [Rf—O-L-COO-]i Xi+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, Rf represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.
摘要翻译: 本文描述的是包含氟化单体的水性聚合反应产物的组合物,其中聚合反应开始于(i)在不存在氟化乳化剂的情况下,并且由此在聚合过程中不加入氟化乳化剂,或(ii)在氟化乳化剂存在下 选自:[Rf-OL-COO-] i Xi +(I)其中L表示直链或支链,非氟化,部分氟化或完全氟化的亚烷基,Rf表示直链或支链部分或完全氟化的脂族基团或 间隔有至少一个氧原子的直链或支链部分或完全氟化的脂肪族基团,X i +表示i为i且i为1,2或3的阳离子; 其中所述反应产物和/或所得水相基本上不含二烷基胺和三烷基胺,并且基本上不含低分子量氟代有机化合物及其方法。
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公开(公告)号:US20110124782A1
公开(公告)日:2011-05-26
申请号:US13054601
申请日:2009-07-15
申请人: Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
发明人: Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号: C08K5/53 , C07F9/28 , C08K5/19 , C08K5/095 , C08K5/06 , C08K5/101 , C08K5/20 , C07C229/04 , C08K5/36 , C07C53/21 , C07C211/02 , C07F9/06 , C09K3/00
CPC分类号: C07C235/10 , C07C69/708 , C07C211/11 , C07C211/14 , C07C291/04 , C07C309/14 , C07F9/091 , C07F9/3808 , C08G65/007
摘要: Compounds represented by formula (Rf-Q-X)s—Z. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r—CHF—(CF2)n—; [Rfb-(O)tC(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)z—; and CF3—O—(CF2)3—O—CF2—. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compounds are also disclosed.
摘要翻译: 由式(Rf-Q-X)s-Z表示的化合物。 每个Rf独立地是选自Rfa-(O)r -CHF-(CF 2)n - 的部分氟化或完全氟化基团; [Rfb-(O)tC(L)H-CF2-O] m -W-; CF 3 CFH-O-(CF 2)p-; CF 3 - (O-CF 2)z - ; 和CF 3 -O-(CF 2)3 -O-CF 2 - 。 还公开了降低液体的表面张力,制造泡沫以及使用该化合物处理表面的方法。
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公开(公告)号:US20110124532A1
公开(公告)日:2011-05-26
申请号:US13054579
申请日:2009-07-16
申请人: Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Michael S. Terrazas , Miguel A. Guerra , Rudolf J. Dams , Tilman C. Zipplies , Zai-Ming Qiu , Klaus Hintzer , Werner Schwertfeger
发明人: Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Michael S. Terrazas , Miguel A. Guerra , Rudolf J. Dams , Tilman C. Zipplies , Zai-Ming Qiu , Klaus Hintzer , Werner Schwertfeger
CPC分类号: C07F7/1804
摘要: Fluorinated compounds represented by formula Rf-Q-X—[Si(R)f(R1)3-f]g. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r-CHF—(CF2)n-; [Rfb-(O)t-C(L)H—CF2—O]m-W—; CF3CFH—O—(CF2)p-; CF3—(O—CF2)z-; and CF3—O—(CF2)3—O—CF2—. Methods of treating a surface or a hydrocarbon-bearing formation using the fluorinated compounds and treated articles and treated hydrocarbon-bearing formations are also disclosed.
摘要翻译: 由式Rf-Q-X- [Si(R)f(R 1)3-f] g表示的氟化合物。 每个Rf独立地是选自Rfa-(O)r -CHF-(CF 2)n - 的部分氟化或完全氟化基团; [Rfb-(O)t -C(L)H-CF 2 -O] m -W-; CF 3 CFH-O-(CF 2)p-; CF 3 - (O-CF 2)z - ; 和CF 3 -O-(CF 2)3 -O-CF 2 - 。 还公开了使用含氟化合物和经处理的制品和经处理的含烃地层处理表面或含烃地层的方法。
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公开(公告)号:US08633288B2
公开(公告)日:2014-01-21
申请号:US13054601
申请日:2009-07-15
申请人: Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
发明人: Rudolf J. Dams , Michael S. Terrazas , Klaus Hintzer , Zai-Ming Qiu , Miguel A. Guerra , Andreas R. Maurer , Harald Kaspar , Kai H. Lochhaas , Michael Juergens , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号: C08F4/44
CPC分类号: C07C235/10 , C07C69/708 , C07C211/11 , C07C211/14 , C07C291/04 , C07C309/14 , C07F9/091 , C07F9/3808 , C08G65/007
摘要: Compounds represented by formula (Rf-Q-X)s—Z. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r—CHF—(CF2)n—; [Rfb-(O)tC(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)z—; and CF3—O—(CF2)3—O—CF2—. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compounds are also disclosed.
摘要翻译: 由式(Rf-Q-X)s-Z表示的化合物。 每个Rf独立地是选自Rfa-(O)r -CHF-(CF 2)n - 的部分氟化或完全氟化基团; [Rfb-(O)tC(L)H-CF2-O] m -W-; CF 3 CFH-O-(CF 2)p-; CF 3 - (O-CF 2)z - ; 和CF 3 -O-(CF 2)3 -O-CF 2 - 。 还公开了降低液体的表面张力,制造泡沫以及使用该化合物处理表面的方法。
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7.
公开(公告)号:US08404790B2
公开(公告)日:2013-03-26
申请号:US13403724
申请日:2012-02-23
申请人: Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman C. Zipplies
发明人: Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman C. Zipplies
IPC分类号: C08F14/18
摘要: A method of making a fluoropolymer in the presence of a fluorinated surfactant.
摘要翻译: 在氟化表面活性剂存在下制备含氟聚合物的方法。
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公开(公告)号:US08476385B2
公开(公告)日:2013-07-02
申请号:US12602877
申请日:2008-06-06
申请人: Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Werner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
发明人: Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Werner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
IPC分类号: C08F18/20
CPC分类号: C08F220/24 , C08F220/28 , C08F220/36 , C08F230/08 , C08G65/007 , C08L33/08 , C08L35/06 , C09D133/08 , C09D133/14 , C09D135/06 , C08L2666/04
摘要: A composition including at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHF—(CF2)n—; [Rfa—(O)t—C(L)H—CF2—O]m—W—; Rfb-O—(CF2)p-; F(CkF2k)—(O—CkF2k)P—O—CF2—; and CF3—O—(CF2)3—(OCF(CF3)—CF2)Z—O-L1-. Each Q is independently selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. Each X is independently selected from the group consisting of alkylene and arylalkylene, wherein alkylene and arylalkylene are each optionally interrupted by at least one ether linkage and optionally terminated by —N(R1)—C(O)— or —O—C(O)—. R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Rfa represents a partially or fully fluorinated alkyl group having from 1 to 10 carbon atoms and optionally interrupted with at least one oxygen atom. Rfb is selected from the group consisting of CF3CFH— and F(CjF2j)-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compositions are also disclosed.
摘要翻译: 包含至少一个由式表示的第一二价单元的组合物:每个Rf独立地选自Rfa-(O)t-CHF-(CF 2)n - ; [Rfa-(O)t -C(L)H-CF 2 -O] m -W-; Rfb-O-(CF2)p-; F(CkF2k) - (O-CkF2k)P-O-CF2-; 和CF 3 -O-(CF 2)3 - (OCF(CF 3)-CF 2)Z-O-L 1。 每个Q独立地选自由键,-C(O)-N(R 1) - 和-C(O)-O-组成的组。 每个X独立地选自亚烷基和芳基亚烷基,其中亚烷基和芳基亚烷基各自任选地被至少一个醚键中断,并且任选地被-N(R 1)-C(O) - 或-OC(O) - 。 R和R 1各自独立地选自氢和具有1至4个碳原子的烷基。 Rfa表示具有1至10个碳原子并且任选被至少一个氧原子中断的部分或完全氟化的烷基。 Rfb选自CF 3 CFH-和F(C 1 F 2)) - 。 还公开了降低液体的表面张力,制造泡沫和使用组合物处理表面的方法。
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公开(公告)号:US20100179262A1
公开(公告)日:2010-07-15
申请号:US12602877
申请日:2008-06-06
申请人: Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Worner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
发明人: Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Worner Schwertfeger , Michael S. Terrazas , Tilman C. Zipplies
CPC分类号: C08F220/24 , C08F220/28 , C08F220/36 , C08F230/08 , C08G65/007 , C08L33/08 , C08L35/06 , C09D133/08 , C09D133/14 , C09D135/06 , C08L2666/04
摘要: A composition including at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHF—(CF2)n—; [Rfa—(O)t—C(L)H—CF2—O]m—W—; Rfb-O—(CF2)p-; F(CkF2k)—(O—CkF2k)P—O—CF2—; and CF3—O—(CF2)3—(OCF(CF3)—CF2)Z—O-L1-. Each Q is independently selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. Each X is independently selected from the group consisting of alkylene and arylalkylene, wherein alkylene and arylalkylene are each optionally interrupted by at least one ether linkage and optionally terminated by —N(R1)—C(O)— or —O—C(O)—. R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Rfa represents a partially or fully fluorinated alkyl group having from 1 to 10 carbon atoms and optionally interrupted with at least one oxygen atom. Rfb is selected from the group consisting of CF3CFH— and F(CjF2j)-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compositions are also disclosed.
摘要翻译: 包含至少一个由式表示的第一二价单元的组合物:每个Rf独立地选自Rfa-(O)t-CHF-(CF 2)n - ; [Rfa-(O)t -C(L)H-CF 2 -O] m -W-; Rfb-O-(CF2)p-; F(CkF2k) - (O-CkF2k)P-O-CF2-; 和CF 3 -O-(CF 2)3 - (OCF(CF 3)-CF 2)Z-O-L 1。 每个Q独立地选自由键,-C(O)-N(R 1) - 和-C(O)-O-组成的组。 每个X独立地选自亚烷基和芳基亚烷基,其中亚烷基和芳基亚烷基各自任选地被至少一个醚键中断,并且任选被-N(R 1)-C(O) - 或-O-C(O ) - 。 R和R 1各自独立地选自氢和具有1至4个碳原子的烷基。 Rfa表示具有1至10个碳原子并且任选被至少一个氧原子中断的部分或完全氟化的烷基。 Rfb选自CF 3 CFH-和F(C 1 F 2)) - 。 还公开了降低液体的表面张力,制造泡沫和使用组合物处理表面的方法。
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10.
公开(公告)号:US20080015304A1
公开(公告)日:2008-01-17
申请号:US11457239
申请日:2006-07-13
申请人: Klaus Hintzer , Michael Jurgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman C. Zipplies
发明人: Klaus Hintzer , Michael Jurgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman C. Zipplies
IPC分类号: D06M15/277
摘要: The present invention provides a method of making a fluoropolymer comprising polymerizing one or more fluorinated monomers in an aqueous emulsion polymerization in the presence of a fluorinated surfactant selected from fluorinated surfactants of formula (I): [RfO-L-CO2−]iXi+ (I) wherein Rf is selected from a partially fluorinated alkyl group, a fully fluorinated alkyl group, a partially fluorinated alkyl group that is interrupted with one or more oxygen atoms, and a fully fluorinated alkyl group that is interrupted with one or more oxygen atoms; L is selected from a partially fluorinated alkylene group, a fully fluorinated alkylene group, a partially fluorinated alkylene group that is interrupted with one or more oxygen atoms, and a fully fluorinated alkylene group that is interrupted with one or more oxygen atoms; Xi+ represents a cation having the valence i; and i is 1, 2, or 3; further wherein at least part of the fluorinated surfactant is added to the aqueous phase as an aqueous mixture with at least one fluorinated liquid, and further wherein when the fluorinated surfactant is a perfluorinated polyethercarboxylic acid, the fluorinated liquid is not a perfluoropolyether.
摘要翻译: 本发明提供一种制备含氟聚合物的方法,其包括在含氟表面活性剂存在下在水乳液聚合中聚合一种或多种氟化单体,所述氟化表面活性剂选自式(I)的氟化表面活性剂:<?in-line-formula description =“In 线公式“end =”lead“?> [R&lt;&lt; /&gt;&lt; /&gt; (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R f选自部分氟化烷基 基团,完全氟化的烷基,被一个或多个氧原子间隔的部分氟化的烷基和被一个或多个氧原子间隔的完全氟化的烷基; L选自部分氟化的亚烷基,完全氟化的亚烷基,被一个或多个氧原子间隔的部分氟化的亚烷基和被一个或多个氧原子间隔的完全氟化的亚烷基; X i + +表示具有i价的阳离子; 我是1,2或3; 其中至少部分氟化表面活性剂与至少一种氟化液体作为含水混合物加入到水相中,并且其中当氟化表面活性剂是全氟化聚醚羧酸时,氟化液体不是全氟聚醚。
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