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公开(公告)号：US4392962A
公开(公告)日：1983-07-12
申请号：US318736
申请日：1981-11-06
申请人： Klaus Lehr , Gero Heymer , Christian May , Hermann Klein
发明人： Klaus Lehr , Gero Heymer , Christian May , Hermann Klein
IPC分类号： B01D15/04 , B01J20/20 , C01B25/08 , C01G5/00 , C01G7/00 , C01G55/00 , C02F1/62 , C22B3/00 , C22B3/24 , C22B3/44 , C22B11/00 , C22B15/00 , C22B43/00
CPC分类号： C22B11/04 , C01G5/003 , C01G55/001 , C01G7/003 , C22B15/0089 , C22B3/24 , C22B43/00 , Y02P10/234 , Y02P10/236 , Y10S210/912 , Y10S210/914
摘要： The invention relates to a process for separating seminoble and/or noble metals from an aqueous solution having compounds of these metals dissolved therein by subjecting the solution to reaction with red phosphorus. More particularly, the solution is conveyed through a zone containing a layer of granular red phosphorus particles with a size of 0.01 to 10 mm, which may be used in admixture with active carbon.
摘要翻译： 本发明涉及一种通过使溶液与红磷反应从其中溶解有这些金属的化合物的水溶液中分离出半金属和/或贵金属的方法。 更具体地说，该溶液被输送通过含有0.01至10mm尺寸的粒状红磷颗粒层的区域，其可与活性炭混合使用。
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公开(公告)号：US4482527A
公开(公告)日：1984-11-13
申请号：US538130
申请日：1983-10-03
申请人： Klaus Lehr , Gero Heymer
发明人： Klaus Lehr , Gero Heymer
摘要： The disclosure relates to a process for removing nitrogen dioxide from off-gas. To this end, the disclosure provides for the off-gas to be intimately contacted with a suspension consisting of red phosphorus and a liquid being inert with respect to red phosphorus, e.g. water.
摘要翻译： 本公开涉及从废气中除去二氧化氮的方法。 为此，本公开内容提供废气与由红磷和相对于红磷惰性的液体组成的悬浮液紧密接触。 水。
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公开(公告)号：US4273752A
公开(公告)日：1981-06-16
申请号：US123106
申请日：1980-02-20
申请人： Klaus Lehr , Gero Heymer , Hans-Werner Stephan , Ursus Thummler
发明人： Klaus Lehr , Gero Heymer , Hans-Werner Stephan , Ursus Thummler
CPC分类号： C01B25/023
摘要： The invention relates to a process for making red phosphorus by subjecting molten yellow phosphorus to a thermal conversion reaction in a closed reaction zone. To this end, a hollow shaft-provided and closed ball mill is preheated to a reaction temperature within the range 280.degree. to 590.degree. C. Yellow phosphorus is continuously introduced into the ball mill through the hollow shaft in quantities per unit time which permit the reaction temperature prevailing inside the ball mill to be maintained without supply of heat from the outside. More particularly, decreasing quantities of yellow phosphorus are introduced per unit time at increasing temperature and increasing quantities of yellow phosphorus are introduced per unit time at decreasing temperature within the limits specified. Red phosphorus is allowed to cool inside the ball mill, water is poured over it and the whole is subjected to wet-grinding. An aqueous suspension of red phosphorus is finally removed from the ball mill.
摘要翻译： 本发明涉及通过使熔融黄磷在封闭反应区中进行热转化反应来制备红磷的方法。 为此，空心轴提供和封闭的球磨机被预热到280℃至590℃的反应温度。黄磷通过空心轴以每单位时间的量连续地引入球磨机，这允许 球磨机内部的反应温度保持不受外界的热量的限制。 更特别地，在增加的温度下每单位时间引入黄磷的减少量，并且在规定的限度内在降低的温度下每单位时间引入增加量的黄磷。 使红磷在球磨机内冷却，将水倒在其上，整体进行湿磨。 最终从球磨机中除去红磷水悬浮液。
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公开(公告)号：US4418043A
公开(公告)日：1983-11-29
申请号：US288667
申请日：1981-07-30
申请人： Klaus Lehr , Gero Heymer
发明人： Klaus Lehr , Gero Heymer
IPC分类号： C22B43/00 , C01G1/00 , C01G3/00 , C01G5/00 , C01G13/00 , C01G55/00 , C02F1/28 , C22B11/00 , C22B15/00 , C01G7/00
CPC分类号： C02F1/288 , C02F1/281 , C22B11/04 , C22B3/24 , Y02P10/234 , Y10S210/912
摘要： The invention relates to a process for separating seminoble metals or noble metals from aqueous solutions having compounds of these metals dissolved therein, by reaction with yellow phosphorus. More particularly the aqueous solutions are contacted with carrier material having a yellow phosphorus coating applied thereto.It is possible for the aqueous solutions to be conveyed through a zone having the yellow phosphorus-coated carrier material placed therein, and for them to be subsequently conveyed through a further zone having uncoated carrier material placed therein.
摘要翻译： 本发明涉及通过与黄磷反应从其中溶解有这些金属的化合物的水溶液中分离出含半金属或贵金属的方法。 更具体地，水溶液与其上施加有黄磷涂层的载体材料接触。 水溶液可以通过其中放置有黄磷涂层的载体材料的区域输送，并且随后将其输送通过其中放置有未涂覆的载体材料的另一区域。
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5.发明授权
公开(公告)号：US4600565A
公开(公告)日：1986-07-15
申请号：US708299
申请日：1985-03-05
申请人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
发明人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
摘要： Manganese(II)salt solutions containing ammonium salt are made by subjecting a manganese-containing compound to processing treatment with an ammonium salt solution. A boiling temperature of 57.degree.-68.degree. C. is established in the suspension to be subjected to the processing treatment, by application of a vacuum. The ammonium salt solution used contains 0.5-2.5 mol/l diammonium sulfate or 1.0-5.0 mol/l ammonium nitrate.
摘要翻译： 含有铵盐的锰（II）盐溶液通过使含锰化合物用铵盐溶液进行处理来制备。 通过施加真空在待处理处理的悬浮液中建立沸点为57-68℃的温度。 使用的铵盐溶液含有0.5-2.5mol / l硫酸二铵或1.0-5.0mol / l硝酸铵。
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公开(公告)号：US4330504A
公开(公告)日：1982-05-18
申请号：US226468
申请日：1981-01-19
申请人： Klaus Lehr , Gero Heymer , Hans-Werner Stephan , Ursus Thummler
发明人： Klaus Lehr , Gero Heymer , Hans-Werner Stephan , Ursus Thummler
IPC分类号： B01J8/10 , B01J19/28 , B02C17/00 , C01B25/02 , C01B25/023
CPC分类号： C01B25/023
摘要： The invention relates to an apparatus for making red phosphorus by subjecting molten yellow phosphorus to a thermal conversion reaction in a closed reaction zone. To this end, a hollow shaft-provided and closed ball mill is preheated to a reaction temperature within the range 280.degree. to 590.degree. C. Yellow phosphorus is continuously introduced into the ball mill through the hollow shaft in quantities per unit time which permit the reaction temperature prevailing inside the ball mill to be maintained without supply of heat from the outside. More particularly, decreasing quantities of yellow phosphorous are introduced per unit time at increasing temperature and increasing quantities of yellow phosphorus are introduced per unit time at decreasing temperature within the limits specified. Red phosphorus is allowed to cool inside the ball mill, water is poured over it and the whole is subjected to wet-grinding. An aqueous suspension of red phosphorus is finally removed from the ball mill.
摘要翻译： 本发明涉及一种通过使熔融黄磷在封闭反应区中进行热转化反应来制备红磷的装置。 为此，空心轴提供和封闭的球磨机被预热到280℃至590℃的反应温度。黄磷通过空心轴以每单位时间的量连续地引入球磨机，这允许 球磨机内部的反应温度保持不受外界的热量的限制。 更特别地，在增加的温度下每单位时间引入黄磷的量减少，并且在规定的限度内在逐渐降低的温度下每单位时间引入增加量的黄磷。 使红磷在球磨机内冷却，将水倒在其上，整体进行湿磨。 最终从球磨机中除去红磷水悬浮液。
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公开(公告)号：US4143121A
公开(公告)日：1979-03-06
申请号：US815161
申请日：1977-07-13
申请人： Jurgen Stenzel , Gero Heymer , Christian May
发明人： Jurgen Stenzel , Gero Heymer , Christian May
CPC分类号： C01B25/06
摘要： Phosphine is continuously produced by reacting yellow phosphorus with an aqueous alkali metal hydroxide solution in the presence of an alcohol, with the exclusion of oxygen, at 44 to 90.degree. C. To this end, the reaction is effected in two separate reaction stages. In the first reaction stage, the alkali metal hydroxide solution and phosphorus are reacted with agitation in a molar ratio of 0.7:1 to 0.9:1 and the resulting gaseous phosphine is collected. Resulting liquid phase material containing unreacted phosphorus is delivered to the second reaction stage in which the unreacted phosphorus is reacted with further aqueous alkali metal hydroxide solution. The resulting gaseous reaction products are collected separately from the gaseous phosphine collected in the first reaction stage.
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公开(公告)号：US4091078A
公开(公告)日：1978-05-23
申请号：US736556
申请日：1976-10-28
申请人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
发明人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
CPC分类号： C01B25/06
摘要： Phosphine is produced from elementary yellow phosphorus and an aqueous alkali metal hydroxide solution in the presence of an alcohol. The phosphine is more particularly made by using an alcohol having from 5 to 10 carbon atoms and a dissolving power for yellow phosphorus of more than 5 g/l; suspending the phosphorus with agitation in the said alcohol in a reaction zone; reacting the resulting suspension with the alkali metal hydroxide solution at temperatures lower than the boiling point of the alcohol; and collecting the resulting issuing gaseous phosphine.
摘要翻译： 在醇的存在下，由元素黄磷和碱金属氢氧化物水溶液生产磷化氢。 膦更特别地通过使用具有5至10个碳原子的醇和大于5g / l的黄磷的溶解力来制备; 在反应区内搅拌将磷悬浮在所述醇中; 在低于醇的沸点的温度下使得到的悬浮液与碱金属氢氧化物溶液反应; 并收集产生的发出的气态膦。
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公开(公告)号：US4923691A
公开(公告)日：1990-05-08
申请号：US364013
申请日：1989-06-09
申请人： Dieter Peters , Gero Heymer , Christian May
发明人： Dieter Peters , Gero Heymer , Christian May
IPC分类号： C01B21/072
CPC分类号： C01B21/072 , C01P2002/60 , C01P2004/62 , C01P2006/12 , C01P2006/60
摘要： An aluminum nitride powder has a crystallite size of 40 to 150 nm, measured by powder diffractometry and evaluated by the method of Scherrer, a primary particle size of 0.1 to 0.5 .mu.m, a specific surface according to BET of 5 to 50 m.sup.2 /g and a degree of whiteness of more than 91%, measured using light of a 400 to 700 nm wavelength against barium sulfate analytical reagent as standard of whitness.To prepare this aluminum nitride powder, metallic aluminum and monoamminealuminum chloride [AlCl.sub.3 (NH.sub.3)] are first molten together in an inert gas atmosphere at temperatures above 125.degree. C. and allowed to react with one another with evolution of hydrogen. 8 to 20 g of ammonia are then introduced per hour per mol of monoamminealuminum chloride into the aluminum-containing monoamminealuminum chloride melt at temperatures between 250.degree. and 400.degree. C., aluminum nitride being precipitated as a solid until the conversion of the aluminum is complete. The temperature of the melt is finally raised to more than 400.degree. C.
摘要翻译： 氮化铝粉末的微晶尺寸为40〜150nm，用粉末衍射法测定，用Scherrer法评价，一次粒径为0.1〜0.5μm，BET比表面积为5〜50m 2 / g 白度为91％以上，采用400〜700nm波长的光作为白度标准测定硫酸钡分析试剂。 为了制备这种氮化铝粉末，首先在惰性气体气氛中，在高于125℃的温度下将金属铝和一氯化铝[AlCl 3（NH 3）]熔融在一起，并使其彼此发生氢气反应。 然后在250-400℃的温度下将8至20g的氨每小时每摩尔氯化单铝酸铵引入含铝单胺氯化铝熔体中，将氮化铝作为固体沉淀直到铝的转化完全 。 熔体的温度最终升至400℃以上。
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公开(公告)号：US4258022A
公开(公告)日：1981-03-24
申请号：US75001
申请日：1979-09-12
申请人： Georg Elsner , Werner Klose , Christian May , Gero Heymer
发明人： Georg Elsner , Werner Klose , Christian May , Gero Heymer
CPC分类号： C01B25/06
摘要： The invention relates to the continuous production of phosphine. To this end, elemental phosphorus is reacted with an aqueous alkali metal hydroxide solution and at least one alcohol, the reactants being used in admixture with 0.01 to 2 weight % of a surfactant, the percentage being based on the alcohol.
摘要翻译： 本发明涉及磷化氢的连续生产。 为此，元素磷与碱金属氢氧化物水溶液和至少一种醇反应，反应物与0.01至2重量％的表面活性剂混合使用，其百分比基于醇。
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