公开(公告)号：US10772322B2

公开(公告)日：2020-09-15

申请号：US13500121

申请日：2010-10-07

申请人： Klaus Reinhard ,  Holger Türk ,  Peter Hahn ,  Tina Schröder-Grimonpont ,  Michael Ishaque ,  Marc Rudolf Jung

发明人： Klaus Reinhard ,  Holger Türk ,  Peter Hahn ,  Tina Schröder-Grimonpont ,  Michael Ishaque ,  Marc Rudolf Jung

IPC分类号： A01N25/04 ,  A01N47/02

摘要： Polymer particles, comprising a) at least one sparingly soluble insecticide from the group consisting of fipronil, allethrin, alpha-cypermethrin, beta-cyfluthrin, bifenthrin, bioallethrin, 4-chloro-2-(2-chloro-2-methylpropyl)-5-[(6-iodo-3-pyridinyl)methoxy]-3(2H)-pyridazinone (CAS-RN: 120955-77-3), chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, etofenprox, fenoxycarb, flufenoxuron, hydramethylnon, imidacloprid, indoxacarb, metaflumizone, permethrin, pyriproxifen, tebufenozide and tralomethrin and b) at least one water-insoluble polymer, are suitable for improving the soil mobility of the sparingly soluble insecticide(s).

公开(公告)号：US20120214857A1

公开(公告)日：2012-08-23

申请号：US13500121

申请日：2010-10-07

申请人： Klaus Reinhard ,  Holger Türk ,  Peter Hahn ,  Tina Schröder-Grimonpont ,  Michael Ishaque ,  Marc Rudolf Jung

发明人： Klaus Reinhard ,  Holger Türk ,  Peter Hahn ,  Tina Schröder-Grimonpont ,  Michael Ishaque ,  Marc Rudolf Jung

IPC分类号： A01N43/56 ,  A01P7/04

摘要： Polymer particles, comprising a) at least one sparingly soluble insecticide from the group consisting of fipronil, allethrin, alpha-cypermethrin, beta-cyfluthrin, bifenthrin, bioallethrin, 4-chloro-2-(2-chloro-2-methylpropyl)-5-[(6-iodo-3-pyridinyl)methoxy]-3(2H)-pyridazinone (CAS-RN: 120955-77-3), chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, etofenprox, fenoxycarb, flufenoxuron, hydramethylnon, imidacloprid, indoxacarb, metaflumizone, permethrin, pyriproxifen, tebufenozide and tralomethrin and b) at least one water-insoluble polymer, are suitable for improving the soil mobility of the sparingly soluble insecticide(s).

摘要翻译： 聚合物颗粒，包含a）至少一种由氟虫腈，丙烯菊酯，α-氯氰菊酯，β-氟氯氰菊酯，联苯菊酯，生物烯丙菊酯，4-氯-2-（2-氯-2-甲基丙基）-5 - [（6-碘-3-吡啶基）甲氧基] -3（2H） - 哒嗪酮（CAS-RN：120955-77-3），氯虫酰胺，chlorfenapyr，cyantraniliprole，cyfluthrin，cyhalothrin，氯氰菊酯，溴氰菊酯，etofenprox， 氟虫腈，氢五甲基，吡虫啉，吲草胺，间氟灭菌素，氯菊酯，吡氯西芬，戊苯酰肼和三氯肾上腺素，和b）至少一种水不溶性聚合物适用于改善微溶性杀虫剂的土壤迁移率。

公开(公告)号：US20120053221A1

公开(公告)日：2012-03-01

申请号：US13319467

申请日：2010-05-10

申请人： Michael Ishaque ,  Marc Rudolf Jung ,  Holger Tuerk ,  Tina Schroeder-Grimonpont ,  Klaus Reinhard ,  Gerhard Schnabel ,  Clark D. Klein ,  Thomas J. Holt ,  Martin P. Mascianica

发明人： Michael Ishaque ,  Marc Rudolf Jung ,  Holger Tuerk ,  Tina Schroeder-Grimonpont ,  Klaus Reinhard ,  Gerhard Schnabel ,  Clark D. Klein ,  Thomas J. Holt ,  Martin P. Mascianica

IPC分类号： A01N43/56 ,  A01P7/04

CPC分类号： A01N25/30 ,  A01N37/28 ,  A01N43/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N47/02 ,  A01N47/34 ,  A01N47/38 ,  A01N51/00 ,  A01N53/00 ,  A01N57/16

摘要： What is described is use of a polymeric solubilizer for increasing the soil mobility of a sparingly soluble insecticide, said polymeric solubilizer having the property that the active insecticidal ingredient in a 1% by weight aqueous solution of the polymeric solubilizer at 25° C. and 1.01325 bar has a solubility at least forty times higher than under the same conditions in pure water, and wherein the active ingredient:solubilizer weight ratio is ≦1.

摘要翻译： 所描述的是使用聚合物增溶剂来增加微溶性杀虫剂的土壤迁移率，所述聚合物增溶剂具有在25℃和1.01325的聚合物增溶剂的1重量％水溶液中的活性杀虫成分的性质 酒精在纯水中的溶解度比相同条件下的溶解度高至少40倍，其中活性成分：增溶剂重量比为1;

公开(公告)号：US09801372B2

公开(公告)日：2017-10-31

申请号：US13319467

申请日：2010-05-10

申请人： Michael Ishaque ,  Marc Rudolf Jung ,  Holger Tuerk ,  Tina Schroeder-Grimonpont ,  Klaus Reinhard ,  Gerhard Schnabel ,  Clark D. Klein ,  Thomas J. Holt ,  Martin P. Mascianica

发明人： Michael Ishaque ,  Marc Rudolf Jung ,  Holger Tuerk ,  Tina Schroeder-Grimonpont ,  Klaus Reinhard ,  Gerhard Schnabel ,  Clark D. Klein ,  Thomas J. Holt ,  Martin P. Mascianica

IPC分类号： A01N43/56 ,  A01P7/04 ,  A01N25/30

CPC分类号： A01N25/30 ,  A01N37/28 ,  A01N43/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N47/02 ,  A01N47/34 ,  A01N47/38 ,  A01N51/00 ,  A01N53/00 ,  A01N57/16

摘要： What is described is use of a polymeric solubilizer for increasing the soil mobility of a sparingly soluble insecticide, said polymeric solubilizer having the property that the active insecticidal ingredient in a 1% by weight aqueous solution of the polymeric solubilizer at 25° C. and 1.01325 bar has a solubility at least forty times higher than under the same conditions in pure water, and wherein the active ingredient:solubilizer weight ratio is ≦1.

公开(公告)号：US08841382B2

公开(公告)日：2014-09-23

申请号：US13222550

申请日：2011-08-31

申请人： Anna Cristadoro ,  Holger Türk ,  Michael Ishaque ,  Rabie Al-Hellani

发明人： Anna Cristadoro ,  Holger Türk ,  Michael Ishaque ,  Rabie Al-Hellani

IPC分类号： C08G65/00 ,  A01N25/04 ,  C07F9/09 ,  A01N25/30 ,  C08G65/34 ,  C08L71/00 ,  A01N25/00 ,  A01N31/00

CPC分类号： C07F9/091 ,  A01N25/04 ,  A01N25/30 ,  C08G81/024 ,  C08G83/004 ,  Y10S424/16 ,  A01N47/02 ,  A01N47/24

摘要： The present invention provides an amphiphile of the formula (I) as described hereinafter. The invention further relates to a process for preparing the amphiphile and to a composition comprising the amphiphile and a sparingly water-soluble active ingredient. It further relates to a process for producing the composition by contacting the amphiphile and the active ingredient, and to the use of the amphiphile for solubilizing a sparingly water-soluble active ingredient in aqueous solutions. The invention also relates to the use of the amphiphile in an agrochemical formulation comprising the amphiphile and a pesticide for controlling phytopathogenic fungi and/or unwanted vegetation and/or unwanted insect or mite infestation and/or for regulating the growth of plants, and finally to plant propagation material comprising the amphiphile.

摘要翻译： 本发明提供如下所述的式（I）的两亲物。 本发明还涉及一种制备两亲物的方法和一种包含两亲物和少量水溶性活性成分的组合物。 本发明还涉及通过使两亲物和活性成分接触来制备组合物的方法，以及使用两亲物将少量水溶性活性成分溶解在水溶液中。 本发明还涉及两亲物在农用化学制剂中的用途，所述农用化学制剂包含用于控制植物病原性真菌和/或不想要的植物和/或不期望的昆虫或螨虫侵染和/或调节植物生长的两亲物和农药， 包含两亲物的植物繁殖材料。

公开(公告)号：US09725554B2

公开(公告)日：2017-08-08

申请号：US13511700

申请日：2010-11-23

申请人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque

发明人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque

IPC分类号： C08G18/32 ,  A01N25/30 ,  C08G18/79 ,  C08G18/28 ,  C08G18/80 ,  C08G18/75 ,  C08G18/22 ,  C08G18/62

CPC分类号： C08G18/3234 ,  A01N25/30 ,  C08G18/222 ,  C08G18/283 ,  C08G18/284 ,  C08G18/62 ,  C08G18/755 ,  C08G18/791 ,  C08G18/792 ,  C08G18/8064 ,  A01N43/50 ,  A01N47/02 ,  A01N47/24

摘要： The present invention provides a composition comprising an amphiphile and an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, wherein the amphiphile comprises a dendritic polyurea which is joined to at least one linear or comb-type polymer, and the joining is effected via a difunctional linker, if the repeat units of the linear polymer are composed of polymerized alkylene oxide. The invention also relates to an amphiphile comprising a dendritic polyurea and a process for preparing the amphiphile.

公开(公告)号：US20120264609A1

公开(公告)日：2012-10-18

申请号：US13515864

申请日：2010-12-15

申请人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque ,  Joachim Clauss

发明人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque ,  Joachim Clauss

IPC分类号： C08G63/91 ,  A01P3/00 ,  A01P21/00 ,  A01P5/00 ,  A01P13/00 ,  A01N25/10 ,  A01P7/04

CPC分类号： A61K9/06 ,  A01N25/02 ,  A61K47/34 ,  C08G18/283 ,  C08G18/4241 ,  C08G18/4277 ,  C08G18/622 ,  C08G18/8016 ,  C08G83/005 ,  A01N47/02 ,  A01N47/24

摘要： The present invention provides a composition comprising an active ingredient with a maximum solubility in water at 20° C. of 10 g/l, and a hyperbranched polyester which is joined to a polar polymer which comprises a polycondensate or a polymer comprising ethylenically unsaturated monomers. The invention further relates to the hyperbranched polyester mentioned and to a process for preparation thereof. It further relates to the use of the hyperbranched polyester for solubilizing the active ingredient in aqueous compositions.

摘要翻译： 本发明提供一种组合物，其包含在20℃下在水中最大溶解度为10g / l的活性成分和与包含缩合物或包含烯键式不饱和单体的聚合物的极性聚合物连接的超支化聚酯。 本发明还涉及所述的超支化聚酯及其制备方法。 它还涉及超支化聚酯用于将活性成分溶解在含水组合物中的用途。

公开(公告)号：US10174156B2

公开(公告)日：2019-01-08

申请号：US13515857

申请日：2010-12-15

申请人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque ,  Ulrike Troppmann ,  Joachim Clauss ,  Chee Chin Liew

发明人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque ,  Ulrike Troppmann ,  Joachim Clauss ,  Chee Chin Liew

IPC分类号： C08G63/12 ,  A01N25/02 ,  A01N25/30 ,  A61K47/34

摘要： The invention provides a composition comprising an active ingredient with a maximum solubility in water at 20° C. of 10 g/l, and a hyperbranched polyester based on a hydrophobic dicarboxylic acid and a trifunctional alcohol. The invention further relates to the hyperbranched polyester mentioned, to a process for preparation thereof and to the use thereof for solubilizing an active ingredient with a maximum solubility in water at 20° C. of 10 g/l in aqueous solutions.

公开(公告)号：US20120309626A1

公开(公告)日：2012-12-06

申请号：US13515857

申请日：2010-12-15

申请人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque ,  Ulrike Troppmann ,  Joachim Clauss ,  Chee Chin Liew

发明人： Holger Türk ,  Monika Haberecht ,  Hiroe Yamada ,  Bernd Bruchmann ,  Daniel Schönfelder ,  Michael Ishaque ,  Ulrike Troppmann ,  Joachim Clauss ,  Chee Chin Liew

IPC分类号： A01N25/28 ,  A61K31/5415 ,  A61K31/55 ,  A61K31/565 ,  C08G63/91 ,  A01N43/72 ,  A01N43/46 ,  A01N31/16 ,  A01N43/50 ,  A61K47/34 ,  A61K31/4174

CPC分类号： C08G63/12 ,  A01N25/02 ,  A01N25/30 ,  A61K47/34 ,  A01N43/50 ,  A01N47/02 ,  A01N47/24

摘要： The invention provides a composition comprising an active ingredient with a maximum solubility in water at 20° C. of 10 g/l, and a hyperbranched polyester based on a hydrophobic dicarboxylic acid and a trifunctional alcohol. The invention further relates to the hyperbranched polyester mentioned, to a process for preparation thereof and to the use thereof for solubilizing an active ingredient with a maximum solubility in water at 20° C. of 10 g/l in aqueous solutions.

摘要翻译： 本发明提供了包含在20℃下在水中最大溶解度为10g / l的活性成分和基于疏水性二羧酸和三官能醇的超支化聚酯的组合物。 本发明还涉及提及的超支化聚酯，其制备方法及其用于在20℃下在水溶液中溶解最大溶解度为20克/升的水的活性成分的用途。

公开(公告)号：US20120309629A1

公开(公告)日：2012-12-06

申请号：US13514332

申请日：2010-12-03

申请人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

发明人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

IPC分类号： A01N25/02 ,  A61K8/85 ,  A01P13/00 ,  C07C69/96 ,  A01P3/00 ,  A01P7/04 ,  A01P7/02 ,  A61K47/34 ,  A01P21/00

CPC分类号： A01N25/30 ,  C08G64/0216 ,  A01N47/24

摘要： The present invention provides a composition comprising an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, and an amphiphile comprising an alkoxylated hyperbranched polycarbonate, wherein the polycarbonate comprises an alcohol which is a trifunctional or higher polyfunctional polyetherol based on a C3-C12 alkylene oxide and an alcohol which has at least three OH groups. Likewise provided is an amphiphile comprising the polycarbonate, and a process for preparing the amphiphile. The invention further relates to the use of the amphiphile for solubilizing an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, in aqueous solutions, and a method of controlling phytopathogenic fungi and/or unwanted plant growth and/or unwanted insect or mite infestation and/or of regulating the growth of plants.

摘要翻译： 本发明提供一种组合物，其包含其在20℃下在水中的溶解度不超过10g / L的活性成分和包含烷氧基化超支化聚碳酸酯的两亲物，其中所述聚碳酸酯包含三官能或更高官能度的醇 基于C3-C12环氧烷的聚醚类和具有至少三个OH基的醇。 同样提供包含聚碳酸酯的两亲物和制备两亲物的方法。 本发明还涉及两亲物在水溶液中溶解在20℃下在水中的溶解度不超过10g / L的活性成分的用途，以及控制植物病原真菌和/或不需要的植物生长的方法 和/或不期望的昆虫或螨虫侵袭和/或调节植物的生长。