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    Pyrimidyl-thio-carboxanilides
    3.
    发明授权
    Pyrimidyl-thio-carboxanilides 失效

    公开(公告)号：US4765824A

    公开(公告)日：1988-08-23

    申请号：US934064

    申请日：1986-11-21

    申请人： Klaus Sasse ,  Reiner Fischer ,  Hermann Hagemann ,  Hans-Joachim Santel ,  Robert R. Schmidt ,  Robert H. Strang

    发明人： Klaus Sasse ,  Reiner Fischer ,  Hermann Hagemann ,  Hans-Joachim Santel ,  Robert R. Schmidt ,  Robert H. Strang

    IPC分类号： A01N43/54 ,  C07D239/38 ,  C07D401/12 ,  C07D403/12 ,  A01N43/48 ,  C07D239/02

    CPC分类号： C07D401/12 ,  A01N43/54 ,  C07D239/38 ,  C07D403/12

    摘要： A pyrimidyl-thio-carboxanilide of the formula (I), ##STR1## in which R.sup.1 represents hydrogen or halogen, alkyl, alkoxy or alkylthio having 1 to 6 carbon atoms in each case, trifluoromethyl, or phenyl which is unsubstituted or mono- or poly-substituted, identically or differently, by halogen, methyl, ethyl, methoxy or trifluoromethyl,R.sup.2 represents hydrogen, halogen, alkyl having 1 to 6 carbon atoms or trifluoromethyl,R.sup.3 represents halogen, methyl or methoxy,n represents an integer 0, 1 or 2, andZ represents the radical ##STR2## where X represents oxygen or sulphur,R.sup.4 represents hydrogen or hydroxyl, alkyl or alkoxy having 1 to 6 carbon atoms in each case, alkenyl or alkynyl having 3 to 6 carbon atoms in each case, with the proviso that R.sup.4 does not represent hydrogen when X represents oxygen,R.sup.5 represents hydrogen, halogen or alkyl having 1 to 6 carbon atoms which is unsubstituted or mono- or poly-substituted by halogen orR.sup.4 and R.sup.5, together with the carbon atom and the nitrogen atom to which they are bonded, form a 3- to 8-membered heterocyclic ring which is unsubstituted or mono- or poly-substituted, identically or differently, by halogen, methyl or ethyl and which may contain one or more double bonds,R.sup.6 and R.sup.7, independently of one another, represent halogen or alkyl having 1 to 6 carbon atoms which is unsubstituted or mono- or poly-substituted by halogen,R.sup.6 and R.sup.7, together with the carbon atom to which they are bonded, form a 3- to 8-membered ring which may also contain oxygen and/or sulphur atoms as ring members in addition to carbon, and which is unsubstituted or mono- or poly-substituted by halogen, methyl or ethyl and which may contain one or more double bonds, andR.sup.8 represents hydrogen, alkyl having 1 to 6 carbon atoms, which is unsubstituted or mono- or poly-substituted by halogen, alkenyl or alkynyl having 3 to 6 carbon atoms in each case, processes for their preparation, herbicidal compositions and methods for combating weeds using such pyrimidyl-thio-carboxanilides.

    Pyridylthio-acylanilide herbicides
    4.
    发明授权
    Pyridylthio-acylanilide herbicides 失效
    吡啶硫基酰基酰苯胺除草剂

    公开(公告)号：US4898608A

    公开(公告)日：1990-02-06

    申请号：US38700

    申请日：1987-04-15

    申请人： Klaus Sasse ,  Reiner Fischer ,  Hans-Joachim Santel ,  Robert R. Schmidt

    发明人： Klaus Sasse ,  Reiner Fischer ,  Hans-Joachim Santel ,  Robert R. Schmidt

    IPC分类号： C07D213/84 ,  A01N43/40 ,  C07D213/70 ,  C07D213/85 ,  C07D401/12 ,  C07D405/12

    CPC分类号： C07D213/70 ,  A01N43/40 ,  C07D213/85 ,  C07D401/12 ,  C07D405/12

    摘要： Novel herbicidally active pyridylthio-acylanilides of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3, independently of one another, represent hydrogen, halogen, cyano or trifluoromethyl or alkyl, alkoxy and alkylthio having 1 to 4 carbon atoms in each case,R.sup.4 represents halogen, methyl or methoxy,n represents a number 0, 1 or 2,z represents the group (Ia) ##STR2## or the group (Ib) ##STR3## where X represents oxygen, sulphur, an N--R.sup.10 or N--O--R.sup.11 group, or X and R.sup.g tpgether represent the ##STR4## radical, and the other radicals can have various meanings. Intermediates of the formulae ##STR5## are also new.

    摘要翻译： 式（I）的新型除草活性吡啶硫基 - 酰基酰苯胺，其中R 1，R 2和R 3彼此独立地代表氢，卤素，氰基或三氟甲基或每个具有1至4个碳原子的烷基，烷氧基和烷硫基 情况下，R 4表示卤素，甲基或甲氧基，n表示数字0,1或2，z表示基团（Ia）（Ia）或基团（Ib）其中X表示氧， 硫，N-R10或NO-R11基团，或X和Rg共表示基团，其他基团可以具有各种含义。 公式和的中间体也是新的。

    Herbicidal 2-[4-substituted carboxyamino-phenyl mercapto)]-subsituted pyrimidines
    5.
    发明授权
    Herbicidal 2-[4-substituted carboxyamino-phenyl mercapto)]-subsituted pyrimidines 失效
    除草剂2- [4-取代羧基氨基 - 苯基巯基]] - 取代的嘧啶

    公开(公告)号：US4797146A

    公开(公告)日：1989-01-10

    申请号：US937940

    申请日：1986-12-04

    申请人： Klaus Sasse ,  Hermann Hagemann ,  Hans-Joachim Santel ,  Robert R. Schmidt

    发明人： Klaus Sasse ,  Hermann Hagemann ,  Hans-Joachim Santel ,  Robert R. Schmidt

    IPC分类号： A01N43/54 ,  C07D239/38 ,  C07D405/12 ,  C07D239/02 ,  A01N43/48

    CPC分类号： C07D405/12 ,  A01N43/54 ,  C07D239/38

    摘要： Herbicidally, fungicidally and insecticidally active pyrimidylmercapto-acylanilides of the formula ##STR1## in which R.sup.1 represents methyl or ethyl,R.sup.2 represents halogen, methyl or ethyl,R.sup.3 represents hydrogen or methyl,R.sup.4 represents hydrogen, methyl or methoxy,n represents 0, 1 or 2,R.sup.5 represents hydrogen, halogen, cyano, optionally substituted alkyl having 1 to 6 carbon atoms, optionally substituted aryl, optionally substituted aralkyl or the --OR.sup.8 or --SO.sub.m --R.sup.8 radicals, whereR.sup.8 represents optionally substituted alkyl having 1 to 6 carbon atoms or optionally substituted aryl andm represents 0, 1 or 2, andR.sup.6 and R.sup.7, independently of one another, represent halogen or optionally substituted alkyl having 1 to 6 carbon atoms orR.sup.5 and R.sup.6, together with the neighboring carbon atom, represent an optionally substituted, saturated or unsaturated ring, which has 3 to 8 ring members and which can also contain oxygen and sulphur atoms in addition to carbon atoms, orR.sup.6 and R.sup.7, together with the neighboring carbon atom, represent an optionally substituted saturated or unsaturated ring which has 3 to 8 ring carbon atoms.

    摘要翻译： 甲基或乙基，R 3表示氢或甲基，R 4表示氢，甲基或甲氧基，n表示0,1或2，其中R1表示甲基或乙基，R2表示卤素，甲基或乙基，R4表示氢，甲基或甲氧基， 或2，R 5表示氢，卤素，氰基，任选取代的具有1至6个碳原子的烷基，任选取代的芳基，任选取代的芳烷基或-OR 8或-SO m -R 8基团，其中R 8表示任选取代的具有1至6个碳原子的烷基 原子或任选取代的芳基，m表示0,1或2，R 6和R 7彼此独立地表示卤素或任选取代的具有1至6个碳原子的烷基或R 5和R 6与相邻碳原子一起表示 任选取代的，饱和或不饱和的环，其具有3至8个环成员，并且除了碳原子之外还可含有氧和硫原子，或R6和R7以及t 他相邻的碳原子表示任选取代的饱和或不饱和的环，其具有3至8个环碳原子。

    Herbicidal 2-[4-substituted carboxyamino-phenoxy (or phenyl mercapto)]-substituted pyrimidines
    6.
    发明授权
    Herbicidal 2-[4-substituted carboxyamino-phenoxy (or phenyl mercapto)]-substituted pyrimidines 失效
    除草2- [4-取代羧基氨基 - 苯氧基（或苯基巯基）] - 取代的嘧啶

    公开(公告)号：US4627871A

    公开(公告)日：1986-12-09

    申请号：US737977

    申请日：1985-05-24

    申请人： Klaus Sasse ,  Ludwig Eue ,  Hans-Joachim Santel ,  Robert R. Schmidt

    发明人： Klaus Sasse ,  Ludwig Eue ,  Hans-Joachim Santel ,  Robert R. Schmidt

    IPC分类号： A01N43/54 ,  C07D239/34 ,  C07D239/38 ,  C07D239/40 ,  C07D239/52 ,  C07D239/56 ,  C07D239/58 ,  A01N43/48 ,  C07D239/02

    CPC分类号： C07D239/58 ,  A01N43/54 ,  C07D239/34 ,  C07D239/38 ,  C07D239/52 ,  C07D239/56

    摘要： The novel substituted carboxylic acid anilides of the formula ##STR1## in which X represents oxygen or sulphur,R.sup.1 represents hydrogen, halogen, alkyl with 1 to 6 carbon atoms, trifluoromethyl, optionally substituted phenyl, alkoxy with 1 to 6 carbon atoms or alkylmercapto with 1 to 6 carbon atoms,R.sup.2 represents halogen or methyl,n represents 0, 1 or 2,R.sup.3 represents hydrogen, halogen, optionally substituted alkyl with 1 to 6 carbon atoms, optionally substituted aryl, optionally substituted aralkyl or the radicals --OR.sup.6 or --SO.sub.m --R.sup.6,whereinR.sup.6 represents optionally substituted alkyl with 1 to 6 carbon atoms or optionally substituted aryl andm represents 0, 1 or 2, andR.sup.4 and R.sup.5 independently of one another represent halogen or optionally substituted alkyl with 1 to 6 carbon atoms, orR.sup.4 and R.sup.5, together with the adjacent carbon atom, represent an optionally substituted, saturated or unsaturated carbocyclic ring with 3 to 8 ring carbon atoms,are very active herbicides.

    摘要翻译： 式（I）的新型取代的羧酸酰苯胺，其中X表示氧或硫，R 1表示氢，卤素，具有1至6个碳原子的烷基，三氟甲基，任选取代的苯基，具有1至6个碳原子的烷氧基 或具有1至6个碳原子的烷基巯基，R 2表示卤素或甲基，n表示0,1或2，R 3表示氢，卤素，任选取代的具有1至6个碳原子的烷基，任选取代的芳基，任选取代的芳烷基或基团 - OR 6或-SO m -R 6，其中R 6表示任选取代的具有1至6个碳原子的烷基或任选取代的芳基，m表示0,1或2，R 4和R 5彼此独立地表示卤素或任选取代的具有1至6个 碳原子或R 4和R 5与相邻的碳原子一起表示任选取代的饱和或不饱和的具有3至8个环碳原子的碳环，是非常活泼的除草剂。

    Process for preparing thiophenols and novel thiophenols
    7.
    发明授权
    Process for preparing thiophenols and novel thiophenols 失效
    制备苯硫酚和新型苯硫酚的方法

    公开(公告)号：US4980510A

    公开(公告)日：1990-12-25

    申请号：US219103

    申请日：1988-07-14

    申请人： Hermann Hagemann ,  Klaus Sasse ,  Reiner Fischer

    发明人： Hermann Hagemann ,  Klaus Sasse ,  Reiner Fischer

    IPC分类号： C07D239/47 ,  A01N43/54 ,  C07B45/06 ,  C07C319/02 ,  C07C323/22 ,  C07C323/62 ,  C07C323/65 ,  C07D213/72 ,  C07D239/38 ,  C07D239/46

    CPC分类号： C07D239/47 ,  A01N43/54 ,  C07B45/06 ,  C07C323/00

    摘要： Thiophenols of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of each other each stand for hydrogen, halogen, nitro, alkyl, alkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl, haloalkyl, haloalkoxy or alkylcarboxyl, optionally substituted aryl or optionally substituted hetaryl,R.sup.5 stands for alkyl, alkoxyalkyl, alkylthioalkyl, haloalkyl, alkenyl, haloalkenyl, optionally substituted aryl or optionally substituted hetaryl, andX stands for carbonyl, sulphinyl or sulphonyl can be obtained by reacting halobenzenes of the formula ##STR2## in which Hal stands for halogen, first with sodium hydrogen sulphide or sodium sulphide in the presence of a diluent to form compounds of the formula ##STR3## and then adding an acid to form the thiophenol, some of the thiophenols are novel and all can be used to form aryethioaminopyridides which are employed as herbicides.

    摘要翻译： 其中R 1，R 2，R 3和R 4各自独立地表示氢，卤素，硝基，烷基，烷氧基，烷硫基，烷氧基烷基，烷硫基烷基，卤代烷基，卤代烷氧基或烷基羧基，任选取代的芳基或任选地 取代的杂芳基，R5代表烷基，烷氧基烷基，烷硫基烷基，卤代烷基，烯基，卤代烯基，任选取代的芳基或任选取代的杂芳基，X代表羰基，亚磺酰基或磺酰基可以通过将式 代表卤素，首先用硫酸氢钠或硫化钠在稀释剂存在下形成式“IMAGE”的化合物，然后加入酸形成苯硫酚，一些苯硫酚是新颖的，都可用于形成 用作除草剂的芳硫氨基吡啶。

    4,5-Dichloro-imidazole-1-carboxylic acid aryl esters and their use as plant protection agents
    8.
    发明授权
    4,5-Dichloro-imidazole-1-carboxylic acid aryl esters and their use as plant protection agents 失效
    4,5-二氯 - 咪唑-1-羧酸芳基酯及其作为植物保护剂的用途

    公开(公告)号：US4183742A

    公开(公告)日：1980-01-15

    申请号：US835092

    申请日：1977-09-21

    申请人： Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    发明人： Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    IPC分类号： A01N43/36 ,  A01N47/16 ,  A01N47/22 ,  A01P13/00 ,  C07D233/68 ,  C07D233/90 ,  C07D487/14 ,  C07D233/28 ,  A01N9/22

    CPC分类号： C07D487/14 ,  A01N47/22 ,  C07D233/68 ,  C07D233/90

    摘要： A 4,5-dichloro-imidazole-1-carboxylic acid aryl ester of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents an optionally substituted saturated or unsaturated aliphatic radical, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents, or R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5- to 7-membered heterocyclic radical in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, Y represents halogen, alkyl with 1 to 6 carbon atoms, trifluoromethyl, alkoxy with 1 to 6 carbon atoms, nitro, cyano or a ##STR3## group, in which R.sup.4 represents alkyl with 1 to 6 carbon atoms and n represents 0, 1, 2, 3, 4, or 5, which possesses plant protection properties especially herbicidal and plant growth regulant properties.

    摘要翻译： 其中X表示三氟甲基，氰基或其中R 1表示任选取代的饱和或不饱和脂族基团的基团的4,5-二氯 - 咪唑-1-羧酸芳基酯，其中X表示三氟甲基， R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基，R 3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的链烯基或炔基，每个 的这些烷基，烯基和炔基，以携带一个或多个取代基，或表示环中具有5至7个碳原子的环烷基，其任选被具有1至6个碳原子的烷基取代，或表示可以任选携带一个或多个 取代基，或R2和R3与相邻的氮原子结合形成任选取代的5至7元杂环基，其中1至3个环成员可以选自氧，硫和氮，Y代表卤素，烷基与1至 6个碳原子，三氟甲基，具有1至6个碳原子的烷氧基，硝基，氰基或者IMAGE基团，其中R 4表示具有1至6个碳原子的烷基，n表示0,1,2,3,4或5个 具有植物保护性，特别是除草和植物生长调节性。

    4,5-Dichloro-imidazole derivatives and their use as plant protection agents
    9.
    发明授权
    4,5-Dichloro-imidazole derivatives and their use as plant protection agents 失效
    4,5-二氯咪唑衍生物及其作为植物保护剂的用途

    公开(公告)号：US4178166A

    公开(公告)日：1979-12-11

    申请号：US835095

    申请日：1977-09-21

    申请人： Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    发明人： Klaus Sasse ,  Gunther Beck ,  Ludwig Eue ,  Robert R. Schmidt

    IPC分类号： A01N43/50 ,  A01P13/00 ,  C07D233/68 ,  C07D233/90 ,  C07D487/14 ,  A01N9/22

    CPC分类号： C07D487/14 ,  A01N43/50 ,  C07D233/68 ,  C07D233/90

    摘要： A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents trifluoromethyl, cyano or a ##STR2## in which R.sup.1 represents an optionally saturated or unsaturated aliphatic radical,R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents hydrogen, alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents, orR.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom for an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulphur and nitrogen, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted;and the use of such novel 4,5-dichloro-imidazole derivatives as plant protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.

    摘要翻译： 式（I）的4,5-二氯 - 咪唑衍生物，其中X表示三氟甲基，氰基或者其中R 1表示任选饱和或不饱和的脂族基团，R 2表示氢，烷基与1至 8个碳原子，具有至多8个碳原子的烯基或甲酰基，R3表示氢，具有1至8个碳原子的烷基或具有至多8个碳原子的链烯基或炔基，这些烷基，烯基和炔基中的每一个都是可能的 自由基携带一个或多个取代基，或表示环中具有5至7个碳原子的环烷基，其任选被具有1至6个碳原子的烷基取代，或表示可任选地携带一个或多个取代基的苯基，或者R 2和R 3连接 与相邻的氮原子一起用于任选取代的5元至7元杂环，其中1至3个环成员可以选自氧，硫和氮，R表示具有1至12个碳原子的烷基或烯基或 炔基各自具有至多12个碳原子，这些烷基，烯基和炔基中的每一个可以携带一个或多个取代基，或代表环中具有5至7个碳原子的环烷基或代表至少为 二取代; 以及这种新型的4,5-二氯 - 咪唑衍生物作为植物保护剂，特别是作为除草剂，植物生长调节剂，杀虫剂或杀螨剂的用途。