公开(公告)号：US20070270539A1

公开(公告)日：2007-11-22

申请号：US11793529

申请日：2005-12-13

申请人： Koji Yui ,  Yusuke Aoki ,  Takashi Ueda

发明人： Koji Yui ,  Yusuke Aoki ,  Takashi Ueda

IPC分类号： C08L27/06 ,  C08L53/02

CPC分类号： C08L27/06 ,  C08L51/04 ,  C08L101/00 ,  C08L2666/24

摘要： An object of the present invention is to propose a novel thermoplastic resin composition capable of exhibiting high impact resistance using an impact modifier isolated as a resin powder without coarsening or agglomeration. A thermoplastic resin composition includes 100 parts by weight of a thermoplastic resin (a) and 0.5 to 20 parts by weight of an impact modifier (b) containing a graft copolymer (b-1) containing a butadiene rubber polymer and a rigid shell, a water-soluble polymer compound (b-2) having a physical gel-forming property, and a gelling agent (b-3). In the thermoplastic resin composition, the content of the water-soluble polymer compound (b-2) having the physical gel-forming property is 0.01 to 3.0 parts by weight relative to 100 parts by weight of the graft copolymer (b-1) and the content of the rigid shell in the graft copolymer (b-1) is 1 to 20 percent by weight.

摘要翻译： 本发明的目的是提出一种能够使用分离为抗冲击改性剂作为树脂粉末而显示出高抗冲击性的新型热塑性树脂组合物，而不会粗化或凝聚。 热塑性树脂组合物包含100重量份的热塑性树脂（a）和0.5至20重量份的含有含有丁二烯橡胶聚合物和刚性壳的接枝共聚物（b-1​​）的抗冲改性剂（b）， 具有物理凝胶形成性质的水溶性高分子化合物（b-2）和胶凝剂（b-3）。 在热塑性树脂组合物中，具有物理凝胶形成性的水溶性高分子化合物（b-2）的含量相对于100重量份接枝共聚物（b-1​​）为0.01〜3.0重量份， 接枝共聚物（b-1​​）中的刚性壳的含量为1〜20重量％。

公开(公告)号：US20090137719A1

公开(公告)日：2009-05-28

申请号：US12226563

申请日：2007-04-18

申请人： Toshihiko Kanda ,  Koji Yui ,  Yusuke Aoki

发明人： Toshihiko Kanda ,  Koji Yui ,  Yusuke Aoki

IPC分类号： C08L51/00

CPC分类号： C08L27/06 ,  C08F279/02 ,  C08L5/04 ,  C08L33/06 ,  C08L51/003 ,  C08L51/04 ,  C08L101/00 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

摘要： In order to provide a novel thermoplastic resin composition capable of exhibiting high impact resistance using an impact modifier having good dispersibility and can be isolated as a resin powder without coarsening and agglomeration, and a process for preparing the same, the invention provides a thermoplastic resin composition comprising a thermoplastic resin (a) and 0.5 to 20 parts by weight of a graft copolymer (b) comprising a butadiene-based rubbery polymer and a hard shell based on 100 parts by weight of the thermoplastic resin (a), wherein the composition further comprises 0.01 to 3.0 parts by weight of an aqueous polymer compound (c) having a property to form a physical gel, and 0.01 to 10 parts by weight of a processing aid (d), per 100 parts by weight of the graft copolymer (b), and a process for preparing the thermoplastic resin.

摘要翻译： 为了提供一种能够使用具有良好分散性的抗冲击改性剂表现出高耐冲击性的新型热塑性树脂组合物及其制备方法，并且可以将其分离为树脂粉末而不会粗化和附聚，本发明提供一种热塑性树脂组合物 包含热塑性树脂（a）和基于100重量份热塑性树脂（a）的0.5至20重量份的包含丁二烯基橡胶状聚合物和硬壳的接枝共聚物（b），其中所述组合物进一步 相对于100重量份的接枝共聚物（b），含有0.01〜3.0重量份具有形成物理性凝胶性质的高分子化合物（c）和0.01〜10重量份的加工助剂（d） ）和制备热塑性树脂的方法。

公开(公告)号：US09434840B2

公开(公告)日：2016-09-06

申请号：US13702858

申请日：2011-06-07

申请人： Yusuke Aoki

发明人： Yusuke Aoki

IPC分类号： C08L83/06 ,  C08L69/00 ,  C08L83/10 ,  C08G77/448 ,  C08K5/42 ,  C08L27/12

CPC分类号： C08L83/06 ,  C08G77/448 ,  C08K5/42 ,  C08L27/12 ,  C08L69/00 ,  C08L83/10 ,  C08L2666/02 ,  C08L83/00

摘要： Provided are a polycarbonate-based resin composition that brings together an excellent impact strength and excellent flame retardancy and a molded article thereof. The polycarbonate-based resin composition is a polycarbonate-based resin composition, including, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of (A-1) a polycarbonate-polyorganosiloxane copolymer which has a constituent unit represented by a general formula (I) and a constituent unit represented by a general formula (II), and in which an average number of repetitions of the constituent unit represented by the general formula (II) is 30 to 500, and 70 to 0 mass % of (A-2) an aromatic polycarbonate resin except the polycarbonate-polyorganosiloxane copolymer, 0.01 to 0.15 part by mass of (B) an alkali metal salt and/or alkaline earth metal salt of an organosulfonic acid, and 0.1 to 1 part by mass of (C) a mixed powder formed of polytetrafluoroethylene particles and organic polymer particles, in which: a content of a polyorganosiloxane block moiety formed of the constituent unit represented by the general formula (II) in the resin mixture (A) is 2 to 30 mass %; and the composition is free of an organohalogen-based flame retardant and an organophosphate-based flame retardant.

摘要翻译： 提供将聚合物具有优异的冲击强度和优异的阻燃性的聚碳酸酯类树脂组合物及其成型体。 聚碳酸酯类树脂组合物是聚碳酸酯系树脂组合物，其中，相对于100质量份（A）由（A-1）30〜100质量％的聚碳酸酯 - 聚有机硅氧烷共聚物形成的树脂混合物100质量份， 由通式（I）表示的结构单元和由通式（II）表示的结构单元，其中由通式（II）表示的构成单元的平均重复数为30〜500，并且 （A-2）除了聚碳酸酯 - 聚有机硅氧烷共聚物以外的芳香族聚碳酸酯树脂为70〜0质量％，（B）有机磺酸的碱金属盐和/或碱土金属盐，0.1〜 （C）由聚四氟乙烯粒子和有机聚合物粒子形成的混合粉末1质量份，其中由树脂混合物（A）中由通式（II）表示的构成单元形成的聚有机硅氧烷嵌段部分的含量 ）是2到 30质量％ 并且组合物不含有机卤素类阻燃剂和有机磷酸酯类阻燃剂。

公开(公告)号：US20130303672A1

公开(公告)日：2013-11-14

申请号：US13883663

申请日：2011-10-27

申请人： Yusuke Aoki

发明人： Yusuke Aoki

IPC分类号： C08L83/06

CPC分类号： C08L83/06 ,  C08G77/448 ,  C08K3/22 ,  C08K5/42 ,  C08K5/52 ,  C08K9/04 ,  C08K2003/2241 ,  C08K2201/005 ,  C08L27/00 ,  C08L27/18 ,  C08L69/00 ,  C08L83/10 ,  H02S40/34 ,  Y02E10/50

摘要： Provided are: a polycarbonate-based resin composition, including: (A) 100 parts by mass of a resin mixture formed of: 30 to 100 mass % of a PC-POS copolymer (A-1) which has constituent units represented by a general formula (I) and a general formula (II), and in which an average repetition number n of organosiloxane constituent units in the general formula (II) is 70 to 500; and 70 to 0 mass % of an aromatic polycarbonate resin (A-2) except the PC-POS copolymer (A-1); (B) 0.01 to 0.15 part by mass of an alkaline (earth) metal salt of an organic sulfonic acid; (C) 0.1 to 1 part by mass of a polytetrafluoroethylene having a fibril-forming ability; and (D) 2 to 15 parts by mass of titanium dioxide particles each having, on an outermost surface thereof, a coating layer formed of a polyol free of a nitrogen atom; a molded article obtained by molding the resin composition; and a structure member for solar photovoltaic power generation formed of the molded article. The polycarbonate-based resin composition, molded article, and structure member for solar photovoltaic power generation each have excellent flame retardancy and excellent tracking resistance without impairing a low-temperature impact characteristic which a PC-POS copolymer has.

摘要翻译： 提供：聚碳酸酯类树脂组合物，其包含：（A）100质量份由以下组成的树脂混合物形成：30〜100质量％的PC-POS共聚物（A-1），其具有由通式 式（I）和通式（II）表示，通式（II）中的有机硅氧烷构成单元的平均重复数n为70〜500。 和70〜0质量％的除PC-POS共聚物（A-1）以外的芳香族聚碳酸酯树脂（A-2）。 （B）0.01〜0.15质量份的有机磺酸的碱土金属盐; （C）0.1〜1质量份具有原纤维形成能力的聚四氟乙烯; 和（D）2〜15质量份的二氧化钛粒子，其最外表面具有由不含氮原子的多元醇形成的涂层; 通过模塑树脂组合物获得的模制品; 以及由该模制品形成的用于太阳能光伏发电的结构件。 用于太阳能光伏发电的聚碳酸酯类树脂组合物，模制品和结构件各自具有优异的阻燃性和优异的耐追踪性，而不损害PC-POS共聚物具有的低温冲击特性。

公开(公告)号：US08871836B2

公开(公告)日：2014-10-28

申请号：US13883663

申请日：2011-10-27

申请人： Yusuke Aoki

发明人： Yusuke Aoki

IPC分类号： C08K9/10 ,  C08L83/06 ,  C08K3/22 ,  C08L69/00 ,  H01L31/048 ,  C08K9/04

CPC分类号： C08L83/06 ,  C08G77/448 ,  C08K3/22 ,  C08K5/42 ,  C08K5/52 ,  C08K9/04 ,  C08K2003/2241 ,  C08K2201/005 ,  C08L27/00 ,  C08L27/18 ,  C08L69/00 ,  C08L83/10 ,  H02S40/34 ,  Y02E10/50

摘要： Provided are: a polycarbonate-based resin composition, including: (A) 100 parts by mass of a resin mixture formed of: 30 to 100 mass % of a PC-POS copolymer (A-1) which has constituent units represented by a general formula (I) and a general formula (II), and in which an average repetition number n of organosiloxane constituent units in the general formula (II) is 70 to 500; and 70 to 0 mass % of an aromatic polycarbonate resin (A-2) except the PC-POS copolymer (A-1); (B) 0.01 to 0.15 part by mass of an alkaline (earth) metal salt of an organic sulfonic acid; (C) 0.1 to 1 part by mass of a polytetrafluoroethylene having a fibril-forming ability; and (D) 2 to 15 parts by mass of titanium dioxide particles each having, on an outermost surface thereof, a coating layer formed of a polyol free of a nitrogen atom; a molded article obtained by molding the resin composition; and a structure member for solar photovoltaic power generation formed of the molded article. The polycarbonate-based resin composition, molded article, and structure member for solar photovoltaic power generation each have excellent flame retardancy and excellent tracking resistance without impairing a low-temperature impact characteristic which a PC-POS copolymer has.

摘要翻译： 提供：聚碳酸酯类树脂组合物，其包含：（A）100质量份由以下组成的树脂混合物形成：30〜100质量％的PC-POS共聚物（A-1），其具有由通式 式（I）和通式（II）表示，通式（II）中的有机硅氧烷构成单元的平均重复数n为70〜500。 和70〜0质量％的除PC-POS共聚物（A-1）以外的芳香族聚碳酸酯树脂（A-2）。 （B）0.01〜0.15质量份的有机磺酸的碱土金属盐; （C）0.1〜1质量份具有原纤维形成能力的聚四氟乙烯; 和（D）2〜15质量份的二氧化钛粒子，其最外表面具有由不含氮原子的多元醇形成的涂层; 通过模塑树脂组合物获得的模制品; 以及由该模制品形成的用于太阳能光伏发电的结构件。 用于太阳能光伏发电的聚碳酸酯类树脂组合物，模制品和结构件各自具有优异的阻燃性和优异的耐追踪性，而不损害PC-POS共聚物具有的低温冲击特性。

公开(公告)号：US20140106208A1

公开(公告)日：2014-04-17

申请号：US14123179

申请日：2012-05-28

申请人： Yasuhiro Ishikawa ,  Yusuke Aoki ,  Takayoshi Tanaka

发明人： Yasuhiro Ishikawa ,  Yusuke Aoki ,  Takayoshi Tanaka

IPC分类号： H01M2/02 ,  C08L83/04 ,  C08K5/52

CPC分类号： H01M2/026 ,  C08G77/448 ,  C08K3/04 ,  C08K5/42 ,  C08K5/52 ,  C08K5/526 ,  C08K2201/011 ,  C08L27/18 ,  C08L69/00 ,  C08L83/10 ,  H01M2/0262 ,  H01M2/1094

摘要： A polycarbonate resin composition for a battery pack, which comprises: 100 parts by mass of (A) a polycarbonate-based resin composed of 5 to 100 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1) whose main chain is formed of a structural unit represented by the general formula (I) and a structural unit represented by the general formula (II), and that contains 2 to 10 mass % of a polyorganosiloxane block, and 0 to 95 mass % of an aromatic polycarbonate (A-2) except the copolymer (A-1); and 0.01 to 1 parts by mass of (B) a phosphorus-based antioxidant; and a battery pack formed by using the resin composition.

摘要翻译： 一种电池组用聚碳酸酯树脂组合物，其包含：（A）由5〜100质量％的聚碳酸酯 - 聚有机硅氧烷共聚物（A-1）构成的聚碳酸酯类树脂100质量份，其主链由 由通式（I）表示的结构单元和由通式（II）表示的结构单元，含有2〜10质量％的聚有机硅氧烷嵌段和0〜95质量％的芳香族聚碳酸酯（A-2） ）除了共聚物（A-1）外; 和（B）磷系抗氧化剂0.01〜1质量份; 以及通过使用该树脂组合物形成的电池组。

公开(公告)号：US20130082222A1

公开(公告)日：2013-04-04

申请号：US13702858

申请日：2011-06-07

申请人： Yusuke Aoki

发明人： Yusuke Aoki

IPC分类号： C08L83/06

CPC分类号： C08L83/06 ,  C08G77/448 ,  C08K5/42 ,  C08L27/12 ,  C08L69/00 ,  C08L83/10 ,  C08L2666/02 ,  C08L83/00

摘要： Provided are a polycarbonate-based resin composition that brings together an excellent impact strength and excellent flame retardancy and a molded article thereof. The polycarbonate-based resin composition is a polycarbonate-based resin composition, including, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of (A-1) a polycarbonate-polyorganosiloxane copolymer which has a constituent unit represented by a general formula (I) and a constituent unit represented by a general formula (II), and in which an average number of repetitions of the constituent unit represented by the general formula (II) is 30 to 500, and 70 to 0 mass % of (A-2) an aromatic polycarbonate resin except the polycarbonate-polyorganosiloxane copolymer, 0.01 to 0.15 part by mass of (B) an alkali metal salt and/or alkaline earth metal salt of an organosulfonic acid, and 0.1 to 1 part by mass of (C) a mixed powder formed of polytetrafluoroethylene particles and organic polymer particles, in which: a content of a polyorganosiloxane block moiety formed of the constituent unit represented by the general formula (II) in the resin mixture (A) is 2 to 30 mass %; and the composition is free of an organohalogen-based flame retardant and an organophosphate-based flame retardant.

摘要翻译： 提供将聚合物具有优异的冲击强度和优异的阻燃性的聚碳酸酯类树脂组合物及其成型体。 聚碳酸酯类树脂组合物是聚碳酸酯系树脂组合物，其中，相对于100质量份（A）由（A-1）30〜100质量％的聚碳酸酯 - 聚有机硅氧烷共聚物形成的树脂混合物100质量份， 由通式（I）表示的结构单元和由通式（II）表示的结构单元，其中由通式（II）表示的构成单元的平均重复数为30〜500，并且 （A-2）除了聚碳酸酯 - 聚有机硅氧烷共聚物以外的芳香族聚碳酸酯树脂为70〜0质量％，（B）有机磺酸的碱金属盐和/或碱土金属盐，0.1〜 （C）由聚四氟乙烯粒子和有机聚合物粒子形成的混合粉末1质量份，其中由树脂混合物（A）中由通式（II）表示的构成单元形成的聚有机硅氧烷嵌段部分的含量 ）是2到 30质量％ 并且组合物不含有机卤素类阻燃剂和有机磷酸酯类阻燃剂。

公开(公告)号：US4604418A

公开(公告)日：1986-08-05

申请号：US640119

申请日：1984-08-13

申请人： Masanori Shindo ,  Yusuke Aoki ,  Yosizumi Kataoka ,  Susumu Enomoto ,  Minoru Nakamura

发明人： Masanori Shindo ,  Yusuke Aoki ,  Yosizumi Kataoka ,  Susumu Enomoto ,  Minoru Nakamura

IPC分类号： B01J31/04 ,  C07B61/00 ,  C07D251/34 ,  C08G18/00 ,  C08G18/79 ,  C08G18/80 ,  C09D175/00 ,  C08L75/04

CPC分类号： C07D251/34 ,  C08G18/792 ,  C08G18/8016

摘要： The invention relates to a process for isocyanurating hexamethylene-diisocyanate containing polyol adduct thereof using a novel catalyst and to a paint composition formed from of the product of the above mentioned process and polyol, and to the composition yielding a paint film showing an excellent light resistance and weather resistance, especially high yellowing resistance.

摘要翻译： 本发明涉及一种使用新型催化剂将含六亚甲基二异氰酸酯的多元醇加合物异氰脲酸化的方法和由上述方法和多元醇的产物形成的涂料组合物以及产生显示出优异耐光性的漆膜的组合物 耐候性，特别是耐黄变性高。