Electrolyte process using a hydrogen storing metal member
    5.
    发明授权
    Electrolyte process using a hydrogen storing metal member 失效
    使用储氢金属部件的电解液处理

    公开(公告)号:US06224741B1

    公开(公告)日:2001-05-01

    申请号:US09131677

    申请日:1998-08-10

    IPC分类号: C25B102

    摘要: An electrolytic process which can operate in a hydrogen reaction chamber at a hydrogen reaction rate corresponding to the increase in the rate of production of hydrogen accompanying the increase in the electrolysis rate and maintain the current efficiency at a very high value with respect to the electrolytic current for producing hydrogen and a process for the production of an electrode for this purpose. An electrolytic process is provided which comprises effecting electrolysis of an electrolytic solution in an electrolytic chamber separated from a reaction chamber by a hydrogen-storing metal member with one surface of the hydrogen-storing metal member as a cathode opposing an anode so that hydrogen thus produced is adsorbed by the hydrogen-storing metal member while allowing hydrogen thus adsorbed and a material to be treated to undergo continuous catalytic reaction in the reaction chamber on the other surface of the hydrogen-storing metal member to cause hydrogenation or reduction reaction by hydrogen thus adsorbed.

    摘要翻译: 一种电解方法,其可以在氢反应室中以氢反应速率操作,其伴随着电解速率的增加伴随着氢气生成速率的增加,并且将电流效率保持在相对于电解电流非常高的值 用于生产氢气和用于生产电极的方法。 提供了一种电解方法,其包括通过储氢金属构件在与反应室分离的电解室中电解电解溶液,其中储氢金属构件的一个表面作为与阳极相对的阴极,从而产生氢 被吸氢金属部件吸附,同时允许被吸附的氢,并且被处理材料在储氢金属部件的另一个表面上的反应室中进行连续的催化反应,由此吸附氢气或还原反应 。

    Electrode for electrolysis and electrolytic cell using the electrode
    6.
    发明授权
    Electrode for electrolysis and electrolytic cell using the electrode 失效
    用于电解的电极和使用该电极的电解槽

    公开(公告)号:US5900127A

    公开(公告)日:1999-05-04

    申请号:US825866

    申请日:1997-04-02

    摘要: An electrode for electrolysis comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. The electrode substance having an electrically conductive diamond structure may be a diamond containing an impurity selected from boron, phosphorus and graphite. Alternatively, the electrode substance having an electrically conductive diamond structure may comprise a composite of a diamond and an electrically conductive material. In a preferred embodiment, the electrode further comprises an interlayer comprising at least one of the carbide of a valve metal and silicon carbide disposed between the electrode base material and the electrode substance having an electrically conductive diamond structure. Also disclosed is an electrolytic cell having two chambers including an anode chamber and a cathode chamber partitioned by an ion-exchange membrane. At least one of the anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. An electrolytic cell having three chambers is also disclosed, including an anode chamber, an intermediate chamber and a cathode chamber partitioned by ion-exchange membranes. At least one of an anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material.

    摘要翻译: 一种电解用电极,其特征在于,具有电极基材和覆盖所述电极基材表面的导电性金刚石结构的电极物质。 具有导电金刚石结构的电极物质可以是含有选自硼,磷和石墨的杂质的金刚石。 或者,具有导电金刚石结构的电极物质可以包括金刚石和导电材料的复合物。 在优选实施例中,电极还包括中间层,其包括设置在电极基材和具有导电金刚石结构的电极物质之间的阀金属和碳化硅的碳化物中的至少一种。 还公开了一种具有两个腔室的电解池,该腔室包括由离子交换膜隔开的阳极室和阴极室。 放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材和覆盖电极基材表面的导电金刚石结构的电极物质的电极。 还公开了一种具有三个室的电解池,包括由离子交换膜分隔的阳极室,中间室和阴极室。 放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材的电极和具有覆盖电极母材表面的导电金刚石结构的电极物质。

    Liquid permeation-type gas-diffusion cathode
    7.
    发明授权
    Liquid permeation-type gas-diffusion cathode 失效
    液体渗透型气体扩散阴极

    公开(公告)号:US5827412A

    公开(公告)日:1998-10-27

    申请号:US881361

    申请日:1997-06-24

    CPC分类号: C25B1/46 C25B11/035

    摘要: A liquid-permeable gas-diffusion cathode adapted for caustic soda electrolysis in contact with an ion-exchange membrane partitioning an electrolytic cell into an anode chamber and a cathode gas chamber. Plural horizontal concave grooves and/or convex portions are provided in an interval with one another on the surface of the gas-diffusion cathode facing the gas chamber. Plural vertical concave grooves may also be provided in an interval on the surface of the cathode crossing the horizontal grooves and/or convex portions. Aqueous caustic soda solution thus formed flows downward along the grooves, etc., without covering other portions of the cathode surface, and is easily released therefrom without clogging perforations in the gas-diffusion layer of the cathode.

    摘要翻译: 一种液体可渗透的气体扩散阴极,其适于与将电解槽分隔成阳极室和阴极气体室的离子交换膜接触的苛性钠电解。 在面对气室的气体扩散阴极的表面上,间隔地设有多个水平凹槽和/或凸部。 也可以在与水平槽和/或凸部交叉的阴极表面上的间隔内设置多个垂直凹槽。 这样形成的碱性苛性钠溶液不会覆盖阴极表面的其它部分而沿着凹槽等向下流动,并且容易地从阴极的气体扩散层中堵塞穿孔而释放。

    Production method of acid water and alkaline water
    8.
    发明授权
    Production method of acid water and alkaline water 失效
    酸性水和碱性水的生产方法

    公开(公告)号:US06527940B1

    公开(公告)日:2003-03-04

    申请号:US08818447

    申请日:1997-03-17

    IPC分类号: C02F1461

    摘要: Electrolysis is carried out while supplying an aqueous sodium chloride solution having a weak acidic property to the anode chamber of a water electrolytic cell. The electrolytic cell is partitioned with a cation-exchange membrane into an anode chamber and a cathode chamber. Furthermore, because the pH of the anolyte is sufficiently reduced due to the acid content and pH of the liquid supplied to the anode chamber from the start of electrolysis, which is different from a conventional electrolytic method, the electrolysis of the present invention may be carried out for a time needed to obtain a sufficiently high oxidation reduction potential. Thus, acid water almost the same as that obtained in a conventional method is obtained in the present invention by consuming about {fraction (1/10)} the electric power that is used in a conventional method.

    摘要翻译: 在向水电解槽的阳极室供给具有弱酸性的氯化钠水溶液的同时进行电解。 将电解槽用阳离子交换膜分隔成阳极室和阴极室。 此外,由于不同于以往的电解方法,由于从电解开始供给到阳极室的液体的酸含量和pH值充分降低了阳极电解液的pH,所以可以承载本发明的电解 需要一段时间才能获得足够高的氧化还原电位。 因此,在本发明中通过消耗常规方法中使用的电力的大约1/10,获得与常规方法中获得的酸水几乎相同的酸水。

    Electrolytic cell and method for the production of acid water
    9.
    发明授权
    Electrolytic cell and method for the production of acid water 失效
    电解池及酸水生产方法

    公开(公告)号:US6126796A

    公开(公告)日:2000-10-03

    申请号:US81059

    申请日:1998-05-19

    IPC分类号: C02F1/46 C02F1/461 C02F1/467

    摘要: An electrolytic cell for the production of acid water which performs simple operation to produce acid water without complicated control over the concentration of hydrochloric acid to be added or precipitation of alkaline earth metal salts, which are disadvantages of the prior art electrolysis for the production of acid water. An electrolytic cell for the production of acid water, which comprises a power supply for applying a voltage across an anode chamber and a cathode chamber partitioned by an ion-exchange membrane. The anode in the anode chamber is disposed in close contact with the ion-exchange membrane. The electrolytic cell further comprises means for supplying an aqueous solution of hydrochloric acid and water to the cathode chamber and the anode chamber, respectively. Hydrochloric acid is not directly added to the anode chamber but indirectly added to the anode chamber by diffusing through the ion-exchange membrane. In this manner, hydrochloric acid is uniformly dispersed into the anode chamber by diffusing through the ion-exchange membrane. Thus, the need for controlling concentration is eliminated. Furthermore, because both the catholyte and anolyte are kept acidic, no precipitation of metal salts occurs.

    摘要翻译: 一种用于生产酸水的电解池,其操作简便,不需要对添加的盐酸的浓度进行复杂控制,或者沉淀碱土金属盐,这是现有技术电解生产酸的缺点 水。 一种用于生产酸水的电解池,包括用于施加跨越阳极室的电压的电源和由离子交换膜分隔的阴极室。 阳极室中的阳极设置成与离子交换膜紧密接触。 电解槽还包括用于将盐酸和水的水溶液分别供应到阴极室和阳极室的装置。 盐酸不直接添加到阳极室,而是通过离子交换膜扩散而间接添加到阳极室。 以这种方式,盐酸通过离子交换膜扩散而均匀地分散到阳极室中。 因此,消除了控制浓度的需要。 此外,由于阴极电解液和阳极电解液都保持酸性,因此不会发生金属盐沉淀。

    Liquid permeation-type gas-diffusion electrode
    10.
    发明授权
    Liquid permeation-type gas-diffusion electrode 失效
    液体渗透型气体扩散电极

    公开(公告)号:US5938901A

    公开(公告)日:1999-08-17

    申请号:US890667

    申请日:1997-07-09

    CPC分类号: H01M4/8626 C25B11/035

    摘要: A gas-diffusion electrode (cathode) in contact with an ion-exchange membrane partitioning an electrolytic cell for producing caustic soda, etc., by electrolysis into an anode chamber and a cathode chamber (gas chamber). The gas-diffusion electrode is divided into plural electrode members in the horizontal direction with an interval provided between adjacent electrode members. Electrolyte guide plates may be disposed on the electrode members or between the adjacent electrode members. An aqueous caustic soda solution formed in the electrolysis smoothly is removed from the gas-diffusion electrode without clogging the electrode.

    摘要翻译: 与通过电解进入阳极室和阴极室(气室)而分离用于生产苛性钠的电解池的离子交换膜接触的气体扩散电极(阴极)。 气体扩散电极在水平方向上被分成多个电极部件,间隔设置在相邻的电极部件之间。 电解质引导板可以设置在电极构件上或相邻的电极构件之间。 在电解中形成的电解中的苛性钠水溶液从气体扩散电极中除去而不堵塞电极。