Elastic terpolymer including diene group and preparation method thereof

    公开(公告)号:US09376522B2

    公开(公告)日:2016-06-28

    申请号:US14437419

    申请日:2013-10-14

    Applicant: LG CHEM, LTD.

    Abstract: The present invention relates to an elastic terpolymer which can satisfy excellent processability and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer is a copolymer of 40 to 70 weight % of ethylene, 15 to 55 weight % of a C3-C20 alpha-olefin, and 0.5 to 20 weight % of a diene obtained in the presence of a group 4 transition metal catalyst, of which i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) the Mooney viscosity (ML) and the Mooney relaxation area (MLR) measured by a Mooney viscometer (1+4+2 {circle around (a)}125° C.) can satisfy a specific relation.

    Elastic terpolymer and preparation method thereof
    5.
    发明授权
    Elastic terpolymer and preparation method thereof 有权
    弹性三元共聚物及其制备方法

    公开(公告)号:US09382360B2

    公开(公告)日:2016-07-05

    申请号:US14441072

    申请日:2012-11-15

    Applicant: LG CHEM, LTD.

    Abstract: The present invention relates to an elastic terpolymer that can acquire good mechanical properties and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer, which is a copolymer comprising 40 to 70 wt % of ethylene, 20 to 50 wt % of a C3-C20 alpha-olefin, and 2 to 20 wt % of a diene as obtained in the presence of a catalyst comprising a vanadium compound, satisfies that: (i) the weight average molecular weight measured by GPC is 100,000 to 500,000; and (ii) in the monomer distribution of the copolymer determined by 13C NMR analysis, K given by a defined Equation 1 is 0.01 or less.

    Abstract translation: 本发明涉及能够同时获得良好的机械性能和弹性(弹性)的弹性三元共聚物及其制备方法。 弹性三元共聚物,其是包含40至70重量%的乙烯,20至50重量%的C 3 -C 20α-烯烃和2至20重量%的二烯的共聚物,所述共聚物在催化剂存在下获得,所述催化剂包含 钒化合物满足:(i)通过GPC测定的重均分子量为100,000〜500,000; 和(ii)在通过13 C NMR分析测定的共聚物的单体分布中,由定义的等式1给出的K为0.01以下。

    Polylactide resin having excellent heat resistance and preparation method thereof
    6.
    发明授权
    Polylactide resin having excellent heat resistance and preparation method thereof 有权
    具有优异耐热性的聚丙交酯树脂及其制备方法

    公开(公告)号:US09115248B2

    公开(公告)日:2015-08-25

    申请号:US14219848

    申请日:2014-03-19

    Applicant: LG CHEM, LTD.

    CPC classification number: C08G63/85 C08G63/08 C08G63/823

    Abstract: The present invention relates to a polylactide resin having excellent heat resistance, a preparation method thereof, and a polylactide resin composition including the same.The polylactide resin is characterized by high polymerization activity owing to an organic coordinated metal catalyst even though it has a low catalyst content, and a molecular weight reduction due to thermal decomposition at high temperature and a rate of thermal decomposition including depolymerization are greatly suppressed by a low catalyst content and a low resin acidity, and thus provided is the polylactide resin having superior heat resistance.

    Abstract translation: 本发明涉及耐热性优异的聚丙交酯树脂及其制备方法以及包含其的聚交酯树脂组合物。 聚丙交酯树脂的特征在于由于有机配位金属催化剂而具有高聚合活性,即使其催化剂含量低,并且由于高温下的热分解和包括解聚在内的热分解速率引起的分子量降低被 低催化剂含量和低树脂酸度,因此提供了具有优异耐热性的聚丙交酯树脂。

    Elastic terpolymer and preparation method thereof
    9.
    发明授权
    Elastic terpolymer and preparation method thereof 有权
    弹性三元共聚物及其制备方法

    公开(公告)号:US09458276B2

    公开(公告)日:2016-10-04

    申请号:US14440563

    申请日:2012-11-15

    Applicant: LG CHEM, LTD.

    Abstract: The present invention relates to an elastic terpolymer that can acquire good mechanical properties and elasticity (flexibility) at the same time, and a preparation method thereof.The elastic terpolymer, which is a copolymer of 40 to 70 wt % of ethylene, 15 to 55 wt % of a C3-C20 alpha-olefin, and 0.5 to 20 wt % of a diene as obtained in the presence of a group 4 transition metal catalyst, satisfies that: (i) the weight average molecular weight measured by GPC is 100,000 to 500,000; and (ii) the ethylene content x (wt %) and the crystallization enthalpy y (ΔHcJ/g) of the copolymer measured by DSC satisfy a defined relational expression.

    Abstract translation: 弹性三元共聚物,其为40至70重量%的乙烯,15至55重量%的C 3 -C 20α-烯烃和0.5至20重量%的二烯的共聚物, 金属催化剂满足:(i)通过GPC测定的重均分子量为100,000〜500,000; 和(ii)通过DSC测量的共聚物的乙烯含量x(wt%)和结晶焓y(ΔHcJ/ g)满足规定的关系式。

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