Abstract:
The present invention relates to a method of preparing an ethylene/alpha-olefin/diene-based elastic copolymer having high viscosity and a high molecular weight, in which energy efficiency of the entire process is optimized. The method of preparing the elastic copolymer includes the steps of: copolymerizing an ethylene/alpha-olefin/diene-based elastic copolymer; and separating and removing the solvent and unreacted monomers from the polymer solution and recovering the elastic copolymer, by sequentially using a gas-liquid separator and a stripper in the purification of the solvent and unreacted monomers.
Abstract:
The present invention is directed to an organometallic complex and a catalyst composition capable of producing polylactide resins with improved properties at a higher conversion rate, a method of producing the organometallic complex, polylactide resins having enhanced hydrolysis resistance and heat resistance together with superior mechanical properties, a preparation process therefor, and polylactide resin compositions including the same.
Abstract:
The present invention relates to an elastic terpolymer which can satisfy excellent processability and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer is a copolymer of 40 to 70 weight % of ethylene, 15 to 55 weight % of a C3-C20 alpha-olefin, and 0.5 to 20 weight % of a diene obtained in the presence of a group 4 transition metal catalyst, of which i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) the Mooney viscosity (ML) and the Mooney relaxation area (MLR) measured by a Mooney viscometer (1+4+2 {circle around (a)}125° C.) can satisfy a specific relation.
Abstract:
The present invention relates to an elastic terpolymer which can satisfy excellent processability and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer is a copolymer of 40 to 70 weight % of ethylene, 15 to 55 weight % of a C3-C20 alpha-olefin, and 0.5 to 20 weight % of a diene obtained in the presence of a group 4 transition metal catalyst, of which i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) Δ tan δ, the difference between the tan δ values at the angular frequencies of 0.2 rad/s and 100.0 rad/s, is 0.5 or less that is measured at 100° C. by using a rubber process analyzer.
Abstract:
The present invention relates to an elastic terpolymer that can acquire good mechanical properties and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer, which is a copolymer comprising 40 to 70 wt % of ethylene, 20 to 50 wt % of a C3-C20 alpha-olefin, and 2 to 20 wt % of a diene as obtained in the presence of a catalyst comprising a vanadium compound, satisfies that: (i) the weight average molecular weight measured by GPC is 100,000 to 500,000; and (ii) in the monomer distribution of the copolymer determined by 13C NMR analysis, K given by a defined Equation 1 is 0.01 or less.
Abstract translation:本发明涉及能够同时获得良好的机械性能和弹性(弹性)的弹性三元共聚物及其制备方法。 弹性三元共聚物,其是包含40至70重量%的乙烯,20至50重量%的C 3 -C 20α-烯烃和2至20重量%的二烯的共聚物,所述共聚物在催化剂存在下获得,所述催化剂包含 钒化合物满足:(i)通过GPC测定的重均分子量为100,000〜500,000; 和(ii)在通过13 C NMR分析测定的共聚物的单体分布中,由定义的等式1给出的K为0.01以下。
Abstract:
The present invention relates to a polylactide resin having excellent heat resistance, a preparation method thereof, and a polylactide resin composition including the same.The polylactide resin is characterized by high polymerization activity owing to an organic coordinated metal catalyst even though it has a low catalyst content, and a molecular weight reduction due to thermal decomposition at high temperature and a rate of thermal decomposition including depolymerization are greatly suppressed by a low catalyst content and a low resin acidity, and thus provided is the polylactide resin having superior heat resistance.
Abstract:
The present invention relates to a polysiloxane-polylactide block copolymer and a preparation method thereof, in which the polysiloxane-polylactide block copolymer has improved impact resistance and flexibility, compared to the conventional polylactide resins and can be prepared by ring-opening polymerization of lactide monomers in the presence of a polymerization initiator of polysiloxane.
Abstract:
The present invention relates to a polysiloxane-polylactide block copolymer and a preparation method thereof, in which the polysiloxane-polylactide block copolymer has improved impact resistance and flexibility, compared to the conventional polylactide resins and can be prepared by ring-opening polymerization of lactide monomers in the presence of a polymerization initiator of polysiloxane.
Abstract:
The present invention relates to an elastic terpolymer that can acquire good mechanical properties and elasticity (flexibility) at the same time, and a preparation method thereof.The elastic terpolymer, which is a copolymer of 40 to 70 wt % of ethylene, 15 to 55 wt % of a C3-C20 alpha-olefin, and 0.5 to 20 wt % of a diene as obtained in the presence of a group 4 transition metal catalyst, satisfies that: (i) the weight average molecular weight measured by GPC is 100,000 to 500,000; and (ii) the ethylene content x (wt %) and the crystallization enthalpy y (ΔHcJ/g) of the copolymer measured by DSC satisfy a defined relational expression.
Abstract:
The present invention relates to a lactide copolymer having good flexibility in addition to excellent properties such as mechanical properties and processability and preferably being applicable as a packaging material, a preparation method thereof, and a resin composition including the same. The lactide copolymer includes two or more specific block copolymerized repeating units that the hard segments of polylactide repeating units are connected to both ends of the soft segments of polyether polyol repeating unit, and the block copolymerized repeating units are connected to each other through the intermediation of urethane connecting groups derived from polyvalent isocyanate compound of which the average equivalent of isocyanate group per a molecule is more than 2 and less than 3.