摘要:
A method for manufacturing a crosslinked polyolefin separator, including the steps of: (S1) introducing polyolefin having a weight average molecular weight of 200,000-1,000,000, a first diluting agent, alkoxysilane containing a carbon-carbon double bonded group, an initiator and a crosslinking catalyst to an extruder; (S2) introducing a second diluting agent to the extruder, followed by mixing, to carry out reactive extrusion of a silane-grafted polyolefin composition; (S3) molding and orienting the reactive extruded silane-grafted polyolefin composition in a form of a sheet; (S4) extracting the first diluting agent and the second diluting agent from the oriented sheet to obtain a silane-grafted polyolefin porous membrane; (S5) thermally fixing the porous membrane; and (S6) crosslinking the porous membrane in the presence of water and a crosslinked polyolefin separator are provided. According to the method, it is possible to provide a separator which shows a decrease in intensive silane crosslinking on the surface thereof.
摘要:
A method for manufacturing a crosslinked polyolefin separator, including the steps of: (S1) introducing polyolefin having a weight average molecular weight of 200,000-1,000,000, a first diluting agent, alkoxysilane containing a carbon-carbon double bonded group, an initiator and a crosslinking catalyst to an extruder; (S2) introducing a second diluting agent to the extruder, followed by mixing, to carry out reactive extrusion of a silane-grafted polyolefin composition; (S3) molding and orienting the reactive extruded silane-grafted polyolefin composition in a form of a sheet; (S4) extracting the first diluting agent and the second diluting agent from the oriented sheet to obtain a silane-grafted polyolefin porous membrane; (S5) thermally fixing the porous membrane; and (S6) crosslinking the porous membrane in the presence of water and a crosslinked polyolefin separator are provided. According to the method, it is possible to provide a separator which shows a decrease in intensive silane crosslinking on the surface thereof.
摘要:
A crosslinked polyolefin separator which has gels with a longer side length of 50 μm or more in a number ranging from 0 to 3 per 1 m2 of the separator, and shows a standard deviation of absorbance ratio between the center of the separator and the side thereof ranging from 0.01 to 0.5 is provided. A method for manufacturing the crosslinked polyolefin separator is also provided. The method includes (S1) preparing a polyolefin porous membranes, and (S2) applying a coating solution containing an initiator and alkoxy group-containing vinylsilane onto at least one surface of the porous membrane. The coating solution can permeate even to the inside of exposed pores. Thus, it is possible to provide a crosslinked polyolefin separator in which silane crosslinking occurs uniformly even inside of the pores.
摘要:
The optical film according to the present invention uses polymethylmethacrylate that does not comprise cyclic monomers, but has excellent dimensional stability and optical properties, and thus, can be usefully used as a protection film of a polarization plate.
摘要:
Disclosed is a method of preparing a crosslinked polyolefin separator including preparing a silane grafted polyolefin solution using a polyolefin having a weight average molecular weight higher than or equal to 200,000, a diluent, an alkoxy group containing vinylsilane, and an initiator, forming the silane grafted polyolefin solution in a sheet shape and stretching, extracting the diluent from the stretched sheet to produce a porous membrane, and crosslinking the porous membrane in the presence of water, and a crosslinked polyolefin separator.
摘要:
A crosslinked polyolefin separator which has gels with a longer side length of 50 μm or more in a number ranging from 0 to 3 per 1 m2 of the separator, and shows a standard deviation of absorbance ratio between the center of the separator and the side thereof ranging from 0.01 to 0.5 is provided. A method for manufacturing the crosslinked polyolefin separator is also provided. The method includes (S1) preparing a polyolefin porous membrane, and (S2) applying a coating solution containing an initiator and alkoxy group-containing vinylsilane onto at least one surface of the porous membrane. The coating solution can permeate even to the inside of exposed pores. Thus, it is possible to provide a crosslinked polyolefin separator in which silane crosslinking occurs uniformly even inside of the pores.
摘要:
A method of manufacturing a separator for an electrochemical device according to an exemplary embodiment of the present disclosure includes extruding a resin composition including polyolefin and a diluent, stretching the extruded resin composition to obtain a polyolefin film, extracting the diluent from the obtained polyolefin film to obtain a porous polyolefin film, coating a slurry for forming a porous coating layer on at least one surface of the porous polyolefin film, and heat setting the porous polyolefin film coated with the slurry to obtain a composite separator with a porous coating layer.
摘要:
Disclosed is a separator for an electrochemical device including a porous polymer film, and a porous coating layer including at least one type of particles of inorganic particles and organic particles and binder polymer, the porous coating layer formed on one surface or both surfaces of the porous polymer film, wherein the porous polymer film has a structure in which multiple fibrils arranged parallel to the surface of the film are stacked in layers, and the fibrils are bound to each other to form a lamellar structure with a size from 130 to 200 nm and tortuosity of the porous polymer film is from 1.60 to 1.90, and an electrochemical device comprising the same.
摘要:
The present invention discloses a method for preparing a microporous polyolefin film comprising: a step of injecting a composition comprising polyolefin 30 to 60 wt % and a diluent mixture comprising a diluent, which can make liquid-liquid phase separation with the polyolefin thermodynamically 40 to 70 wt %, into an extruding machine, and melting and kneading thereof to prepare a single phase melt; and a step of extruding the melt while conducting liquid-liquid phase separation by passing through a section having the temperature below the liquid-liquid phase separation temperature and forming thereof in the form of a sheet, and a microporous polyolefin film prepared according to the method.
摘要:
The present invention discloses a method for preparing a microporous polyolefin film comprising: a step of injecting a composition comprising polyolefin 30 to 60 wt % and a diluent, which can make liquid-liquid phase separation with the polyolefin thermodynamically 40 to 70 wt %, into an extruding machine, and melting and kneading thereof to prepare a single phase melt; and a step of extruding the melt while conducting liquid-liquid phase separation by passing through a section having the temperature below the liquid-liquid phase separation temperature and forming thereof in the form of a sheet, and a microporous polyolefin film prepared according to the method.