Cross-linked polyolefin separator and manufacturing method for same

    公开(公告)号:US11355814B2

    公开(公告)日:2022-06-07

    申请号:US16755444

    申请日:2019-06-11

    申请人: LG Chem, Ltd.

    摘要: A method for manufacturing a crosslinked polyolefin separator, including the steps of: (S1) introducing polyolefin having a weight average molecular weight of 200,000-1,000,000, a first diluting agent, alkoxysilane containing a carbon-carbon double bonded group, an initiator and a crosslinking catalyst to an extruder; (S2) introducing a second diluting agent to the extruder, followed by mixing, to carry out reactive extrusion of a silane-grafted polyolefin composition; (S3) molding and orienting the reactive extruded silane-grafted polyolefin composition in a form of a sheet; (S4) extracting the first diluting agent and the second diluting agent from the oriented sheet to obtain a silane-grafted polyolefin porous membrane; (S5) thermally fixing the porous membrane; and (S6) crosslinking the porous membrane in the presence of water and a crosslinked polyolefin separator are provided. According to the method, it is possible to provide a separator which shows a decrease in intensive silane crosslinking on the surface thereof.

    Cross-Linked Polyolefin Separator and Manufacturing Method for Same

    公开(公告)号:US20200266411A1

    公开(公告)日:2020-08-20

    申请号:US16755444

    申请日:2019-06-11

    申请人: LG Chem, Ltd.

    IPC分类号: H01M2/16 H01M2/14 C08K5/01

    摘要: A method for manufacturing a crosslinked polyolefin separator, including the steps of: (S1) introducing polyolefin having a weight average molecular weight of 200,000-1,000,000, a first diluting agent, alkoxysilane containing a carbon-carbon double bonded group, an initiator and a crosslinking catalyst to an extruder; (S2) introducing a second diluting agent to the extruder, followed by mixing, to carry out reactive extrusion of a silane-grafted polyolefin composition; (S3) molding and orienting the reactive extruded silane-grafted polyolefin composition in a form of a sheet; (S4) extracting the first diluting agent and the second diluting agent from the oriented sheet to obtain a silane-grafted polyolefin porous membrane; (S5) thermally fixing the porous membrane; and (S6) crosslinking the porous membrane in the presence of water and a crosslinked polyolefin separator are provided. According to the method, it is possible to provide a separator which shows a decrease in intensive silane crosslinking on the surface thereof.

    Crosslinked Polyolefin Separator and Manufacturing Method Therefor

    公开(公告)号:US20200220139A1

    公开(公告)日:2020-07-09

    申请号:US16648562

    申请日:2019-07-26

    申请人: LG Chem, Ltd.

    IPC分类号: H01M2/16 H01M2/14 C08J7/16

    摘要: A crosslinked polyolefin separator which has gels with a longer side length of 50 μm or more in a number ranging from 0 to 3 per 1 m2 of the separator, and shows a standard deviation of absorbance ratio between the center of the separator and the side thereof ranging from 0.01 to 0.5 is provided. A method for manufacturing the crosslinked polyolefin separator is also provided. The method includes (S1) preparing a polyolefin porous membranes, and (S2) applying a coating solution containing an initiator and alkoxy group-containing vinylsilane onto at least one surface of the porous membrane. The coating solution can permeate even to the inside of exposed pores. Thus, it is possible to provide a crosslinked polyolefin separator in which silane crosslinking occurs uniformly even inside of the pores.

    Method for preparing microporous polyolefin film by thermally-induced phase separation method
    10.
    发明授权
    Method for preparing microporous polyolefin film by thermally-induced phase separation method 有权
    通过热诱导相分离法制备微孔聚烯烃膜的方法

    公开(公告)号:US09505899B2

    公开(公告)日:2016-11-29

    申请号:US14444419

    申请日:2014-07-28

    申请人: LG CHEM, LTD.

    摘要: The present invention discloses a method for preparing a microporous polyolefin film comprising: a step of injecting a composition comprising polyolefin 30 to 60 wt % and a diluent, which can make liquid-liquid phase separation with the polyolefin thermodynamically 40 to 70 wt %, into an extruding machine, and melting and kneading thereof to prepare a single phase melt; and a step of extruding the melt while conducting liquid-liquid phase separation by passing through a section having the temperature below the liquid-liquid phase separation temperature and forming thereof in the form of a sheet, and a microporous polyolefin film prepared according to the method.

    摘要翻译: 本发明公开了一种微孔聚烯烃薄膜的制造方法,其特征在于,包括以下步骤:将含有聚烯烃30〜60重量%的组合物和稀释剂进行注入,所述稀释剂能够将聚烯烃与动力学上的液 - 液相分离为40〜70重量% 挤出机,并将其熔融和捏合以制备单相熔体; 以及通过使液体 - 液相分离温度低于液 - 液相分离温度的部分进行液 - 液相分离而挤出熔融物的步骤,并将其形成为片状,以及根据该方法制备的微孔聚烯烃膜 。