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公开(公告)号：US06294616B1
公开(公告)日：2001-09-25
申请号：US08450648
申请日：1995-05-25
申请人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
发明人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
IPC分类号： C08F1014
CPC分类号： C08G77/442 , C08F232/08 , C08F277/00 , C08L53/025 , C08L2666/04
摘要： Polycyclic addition polymers derived from norbornene-type monomers are mixed with a variety of other polymers to generate families of new blends, alloys, and block copolymers.
摘要翻译： 衍生自降冰片烯型单体的多环加成聚合物与各种其它聚合物混合以产生新的共混物，合金和嵌段共聚物的族。
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公开(公告)号：US06649707B1
公开(公告)日：2003-11-18
申请号：US09679001
申请日：2000-10-04
申请人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
发明人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
IPC分类号： C08G7704
CPC分类号： C08G77/442 , C08F232/08 , C08F277/00 , C08L53/025 , C08L2666/04
摘要： Polycyclic addition polymers derived from norbornene-type monomers are mixed with a variety of other polymers to generate families of new blends, alloys, and block copolymers.
摘要翻译： 衍生自降冰片烯型单体的多环加成聚合物与各种其它聚合物混合以产生新的共混物，合金和嵌段共聚物的族。
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公开(公告)号：US5571881A
公开(公告)日：1996-11-05
申请号：US476810
申请日：1995-06-07
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F4/76 , C08F4/78
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.
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4.发明授权Addition polymers derived from norbornene-functional monomers and process therefor 失效衍生自降冰片烯官能单体的加成聚合物及其工艺
公开(公告)号：US5569730A
公开(公告)日：1996-10-29
申请号：US339863
申请日：1994-11-15
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F10/00 , C08F32/02 , C08F34/00
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.
摘要翻译： 衍生自降冰片烯官能单体的加成聚合物由衍生自链转移剂的烯烃部分封端，所述链转移剂选自相邻碳原子之间具有末端烯属双键的化合物，不包括苯乙烯，乙烯基醚和共轭二烯，并且所述 碳原子上连有两个氢原子。 本发明的加成聚合物由包含VIII族金属离子源的单组分或多组分催化剂体系制备。 催化剂体系是独特的，因为它们催化仅在聚合物链的末端插入链转移剂。
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公开(公告)号：US07422836B2
公开(公告)日：2008-09-09
申请号：US10783386
申请日：2004-02-20
IPC分类号： G03F7/00 , G03F7/004 , C08F136/00
CPC分类号： C08F232/08 , G03F7/0045 , G03F7/0046 , G03F7/038 , G03F7/0382 , G03F7/0392 , G03F7/0395 , G03F7/0397
摘要： Oligomers of polycyclic olefin monomers, and optionally allylic or olefinic monomers, and a method of making such oligomers that includes reacting polycyclic olefin monomers in the presence of a Ni or Pd containing catalyst, or in the case of allylic monomers in the presence of a free radical initiator. The oligomers can be included in photoresist compositions as dissolution rate modifiers. The photoresist compositions can further include a polymeric binder resin, a photoacid generator, and solvents.
摘要翻译： 多环烯烃单体和任选的烯丙基或烯属单体的低聚物，以及制备这样的低聚物的方法，其包括在含有Ni或Pd的催化剂存在下使多环烯烃单体反应，或者在烯丙基单体的情况下， 自由基引发剂。 低聚物可以包含在光致抗蚀剂组合物中作为溶解速率改性剂。 光致抗蚀剂组合物还可以包括聚合物粘合剂树脂，光致酸产生剂和溶剂。
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公开(公告)号：US06790579B1
公开(公告)日：2004-09-14
申请号：US09630894
申请日：2000-08-02
IPC分类号： G03F7039
CPC分类号： C08G61/08 , G03F7/0045 , G03F7/038 , G03F7/039 , Y10S430/106
摘要： The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source.
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7.发明授权Photoresist compositions comprising polycyclic polymers with acid labile pendant groups 有权包含具有酸不稳定侧基的多环聚合物的光致抗蚀剂组合物公开(公告)号：US06723486B2
公开(公告)日：2004-04-20
申请号：US09850915
申请日：2001-05-08
申请人： Brian L. Goodall , Saikumar Jayaraman , Robert A. Shick , Larry F. Rhodes , Robert David Allen , Richard Anthony DiPietro , Thomas Wallow
发明人： Brian L. Goodall , Saikumar Jayaraman , Robert A. Shick , Larry F. Rhodes , Robert David Allen , Richard Anthony DiPietro , Thomas Wallow
IPC分类号： G03F7004
CPC分类号： G03F7/0045 , C08G61/08 , G03F7/038 , G03F7/039 , Y10S430/109 , Y10S430/111 , Y10S430/115
摘要： The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source.
摘要翻译： 本发明涉及包含光酸引发剂和包含含有酸不稳定基团的重复单元的多环聚合物的辐射敏感性光致抗蚀剂组合物。 在暴露于成像辐射源时，光酸引发剂产生酸，该酸切割引起聚合物极性变化的侧链酸不稳定基团。 聚合物在暴露于成像源的区域中变得可溶于碱性水溶液。
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公开(公告)号：US6136499A
公开(公告)日：2000-10-24
申请号：US812418
申请日：1997-03-06
IPC分类号： H01L21/027 , C08F4/80 , C08F32/00 , C08F32/08 , C08G61/08 , C08L45/00 , C08L65/00 , G03F7/004 , G03F7/038 , G03F7/039 , G03C1/73
CPC分类号： C08G61/08 , G03F7/0045 , G03F7/039 , G03F7/038 , Y10S430/106
摘要： The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source.
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9.发明授权Mold addition polymerization of norbornene-type monomers using group 10 metal complexes 有权使用第10族金属络合物对降冰片烯型单体进行加模聚合公开(公告)号：US06936672B2
公开(公告)日：2005-08-30
申请号：US09921051
申请日：2001-08-02
申请人： Andrew Bell , Larry F. Rhodes , Brian L. Goodall , John C. Fondran , Lester H. Mclntosh, III , Dennis A. Barnes
发明人： Andrew Bell , Larry F. Rhodes , Brian L. Goodall , John C. Fondran , Lester H. Mclntosh, III , Dennis A. Barnes
IPC分类号： B29C45/00 , B29K45/00 , C08F4/70 , C08F4/80 , C08F32/00 , C08F232/00 , C08F232/08 , C08F4/44 , C08F132/08
CPC分类号： C08F232/08 , C08F32/00 , C08F232/00
摘要： A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5′-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.
摘要翻译： 催化剂体系和本体加成聚合方法或降冰片烯，甲基降冰片烯，乙基降冰片烯，丁基降冰片烯或己基降冰片烯等多环烯烃，1,2,3,4,4a，5,8,8a-八氢-1,4： 5,8-二甲基萘，5,5' - （1,2-乙二基）双双环[2.2.1]庚-2-烯和1,4,4a，4b，5,8,8a，8b-八氢-1 ，4：5,8-二甲基亚二苯基。 催化剂包括有机金属或有机钯过渡金属前催化剂和活化剂化合物。 可以在反应注射成型工艺中进行聚合以产生具有高玻璃化转变温度的热塑性和热固性模塑聚合物制品。
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公开(公告)号：US06455650B1
公开(公告)日：2002-09-24
申请号：US09412935
申请日：1999-10-05
申请人： John-Henry Lipian , Larry F. Rhodes , Brian L. Goodall , Andrew Bell , Richard A. Mimna , John C. Fondran , Saikumar Jayaraman , April D. Hennis , Christine N. Elia , Jennifer D. Polley , Ayusman Sen
发明人： John-Henry Lipian , Larry F. Rhodes , Brian L. Goodall , Andrew Bell , Richard A. Mimna , John C. Fondran , Saikumar Jayaraman , April D. Hennis , Christine N. Elia , Jennifer D. Polley , Ayusman Sen
IPC分类号： C08F480
CPC分类号： C08F32/08 , C08F32/00 , Y02P20/582
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译： 使用阳离子10族金属络合物和下式的弱配位阴离子进行环烯加成聚合的方法：其中[（R'）z M（L'）x（L“）y]是阳离子络合物，其中M表示 第10组过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。
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