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15 条记录 (耗时 0.017 秒)

    Polyethylene polypiperazine compositions
    1.
    发明授权
    Polyethylene polypiperazine compositions 失效
    聚乙烯聚哌嗪组合物

    公开(公告)号：US4684729A

    公开(公告)日：1987-08-04

    申请号：US861018

    申请日：1986-05-07

    申请人： Lawrence G. Duquette ,  Philip E. Garrou

    发明人： Lawrence G. Duquette ,  Philip E. Garrou

    IPC分类号： C07D295/13 ,  C08G73/02 ,  C07D403/12 ,  C08G73/06

    CPC分类号： C07D295/13 ,  C08G73/0273

    摘要： The invention is the process which comprises contacting a reaction mixture comprising between about 1 and 100 percent by weight of a polyethylene-substituted piperazine, a piperazine or mixtures thereof, wherein such compounds contain a primary or secondary nitrogen wherein one of the carbons adjacent to the nitrogen has a hydrogen atom bonded to the carbon atom, and between about 1 and 99 percent of a solvent, with a catalytic amount of palladium on a support, at a temperature of between about 150.degree. C. and 300.degree. C., under condition such that the product so prepared contains polyethylene polypiperazines.

    摘要翻译： 本发明是包括使包含约1至100重量％的聚乙烯取代的哌嗪，哌嗪或其混合物的反应混合物接触的方法，其中所述化合物含有伯或次氮，其中邻近 在约150℃至300℃的温度下，在条件下，氮气具有与碳原子键合的氢原子和约1至99％的溶剂与催化量的载体上的钯 使得如此制备的产品含有聚乙烯多哌嗪。

    Process for preparing tetrahydrocarbylphosphonium bicarbonate salts
    2.
    发明授权
    Process for preparing tetrahydrocarbylphosphonium bicarbonate salts 失效
    四烃基碳酸氢盐的制备方法

    公开(公告)号：US4266079A

    公开(公告)日：1981-05-05

    申请号：US91280

    申请日：1979-11-05

    申请人： George A. Doorakian ,  Lawrence G. Duquette ,  John F. Arnett

    发明人： George A. Doorakian ,  Lawrence G. Duquette ,  John F. Arnett

    IPC分类号： C07F9/54

    CPC分类号： C07F9/5442 ,  C07F9/5407

    摘要： Certain tetrahydrocarbylphosphonium bicarbonate salts are produced by reacting a trihydrocarbyl(hydrocarbylcarboxymethyl)phosphonium hydroxide inner salt with water. For example, methyl tri-n-butylphosphonium bicarbonate salt was prepared in quantitative yields by heating tri-n-butylcarboxymethylphosphonium hydroxide inner salt in an aqueous methanol solution at 100.degree. C. for 3 hours.

    摘要翻译： 通过使氢氧化三烃基（烃基羧甲基）磷酸氢盐与水反应制备某些烃基碳酸氢盐。 例如，通过在100℃的甲醇水溶液中加热三正丁基羧甲基鏻氢氧化物内盐3小时，以定量的产率制备甲基三正丁基鏻碳酸氢盐。

    Catalyst for making polyurethanes
    3.
    发明授权
    Catalyst for making polyurethanes 失效
    制备聚氨酯的催化剂

    公开(公告)号：US4189543A

    公开(公告)日：1980-02-19

    申请号：US935233

    申请日：1978-08-21

    申请人： George A. Doorakian ,  Lawrence G. Duquette ,  Philip W. McGraw

    发明人： George A. Doorakian ,  Lawrence G. Duquette ,  Philip W. McGraw

    IPC分类号： C08G18/16 ,  C08G18/20

    CPC分类号： C08G18/2027 ,  C08G18/168

    摘要： Compounds of formulas I and II are heat-activated catalysts used in making polyurethanes. ##STR1## wherein R, R.sub.1, and R.sub.2 are each independently H, hydrocarbyl or an inertly-substituted hydrocarbyl; R.sub.3 and R.sub.4 are each independently hydrocarbyl or an inertly-substituted hydrocarbyl; and X is an anion. Upon heating, Compounds I and II catalyze the reaction and may release gaseous by-products which cause the resulting polyurethane compound to foam. For example, the catalyst, t-butyl imidazole-N-carboxylate, when heated to 120.degree. C., catalyzes the reaction between a polyol and a polyisocyanate to give a foamed polyurethane which cured in 16 minutes.

    摘要翻译： 式I和II的化合物是用于制备聚氨酯的热活化催化剂。 其中R，R 1和R 2各自独立地为H，烃基或惰性取代的烃基; R 3和R 4各自独立地为烃基或惰性取代的烃基; X为阴离子。 加热时，化合物I和II催化反应，并可能释放导致所得聚氨酯化合物发泡的气态副产物。 例如，催化剂叔丁基咪唑-N-羧酸酯在加热至120℃时催化多元醇与多异氰酸酯之间的反应，得到在16分钟内固化的发泡聚氨酯。

    Preparation of ABO.sub.3 compounds from mixed metal aromatic coordination complexes
    4.
    发明授权
    Preparation of ABO.sub.3 compounds from mixed metal aromatic coordination complexes 失效
    从混合金属芳族配位络合物制备ABO3化合物

    公开(公告)号：US4880758A

    公开(公告)日：1989-11-14

    申请号：US088460

    申请日：1987-08-24

    申请人： Robert H. Heistand, II ,  Lawrence G. Duquette

    发明人： Robert H. Heistand, II ,  Lawrence G. Duquette

    IPC分类号： C01B13/18 ,  C01G1/02 ,  C01G23/00 ,  C01G25/00 ,  C04B35/465 ,  C04B35/468 ,  C07F7/28

    CPC分类号： C04B35/4682 ,  C01B13/185 ,  C01G1/02 ,  C01G23/006 ,  C04B35/465 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2002/88 ,  C01P2004/51

    摘要： Methods of producing ABO.sub.3 compounds in which A represents a first metal ion and B represents a second metal ion from mixed metal coordination complexes are disclosed. The methods involve reacting compounds serving as a source of the B metal ion with a substituted aromatic compound, in solution, and thereafter reacting the metal coordination complex formed with a compound serving as a source of the A metal, in solution. An example is the reaction of titanium tetraisopropoxide with catechol to form a titanium catecholate coordination complex which is thereafter reacted with barium hydroxide octahydrate to form a pentamethanol barium triscatecholatotitanate mixed metal coordination complex which can be calcined at elevated temperatures to produce the ABO.sub.3 compound, barium titanate (BaTiO.sub.3), which is known to have outstanding dielectric, ferroelectric and piezoelectric properties. Portions of the A and/or B ions can be substituted with other metals.

    摘要翻译： 公开了生产ABO3化合物的方法，其中A代表第一金属离子，B代表来自混合金属配位络合物的第二金属离子。 所述方法包括将作为B金属离子源的化合物与取代的芳族化合物在溶液中反应，然后使与形成的作为A金属源的化合物形成的金属配位络合物在溶液中反应。 一个例子是四异丙醇钛与儿茶酚的反应形成儿茶酚酸钛配位络合物，然后与氢氧化钡八水合物反应，形成五甲醇钡三邻氨基苯甲酸钛酸盐混合金属配位络合物，其可以在高温下煅烧以产生ABO 3化合物，钛酸钡 （BaTiO 3），其已知具有优异的介电，铁电和压电性能。 A和/或B离子的一部分可以被其它金属取代。

    Ar-cyclic sulfonium arenethiol salts and their zwitterions
    7.
    发明授权
    Ar-cyclic sulfonium arenethiol salts and their zwitterions 失效
    Ar-环锍异戊二烯盐及其两性离子

    公开(公告)号：US4130543A

    公开(公告)日：1978-12-19

    申请号：US673579

    申请日：1976-04-05

    申请人： George A. Doorakian ,  Lawrence G. Duquette

    发明人： George A. Doorakian ,  Lawrence G. Duquette

    IPC分类号： C07D333/46 ,  C08G65/44

    CPC分类号： C07C321/00 ,  C07D333/46

    摘要： Ar-cyclic sulfonium arenethiol salts exemplified by the formula: ##STR1## may be converted to their corresponding zwitterion, exemplified by the formula: ##STR2## The latter polymerize very readily upon exposure to mild conditions of heat or radiative energy. The resultant polymers are water-insoluble resins useful as adhesives, coatings, films and the like. The zwitterions containing more than one arenesulfide and cyclic sulfonium group per molecule, crosslink upon exposure to heat to form thermoset resins.

    摘要翻译： 以下式示出的Ar-环状锍异戊二烯盐：可将“IMAGE”转化成其相应的两性离子，其例子如下：

    Preparation of ABO.sub.3 compounds from mixed metal aromatic coordination complexes
    8.
    发明授权
    Preparation of ABO.sub.3 compounds from mixed metal aromatic coordination complexes 失效
    从混合金属芳族配位络合物制备ABO3化合物

    公开(公告)号：US4946810A

    公开(公告)日：1990-08-07

    申请号：US405335

    申请日：1989-09-11

    申请人： Robert H. Heistand, II ,  Lawrence G. Duquette

    发明人： Robert H. Heistand, II ,  Lawrence G. Duquette

    IPC分类号： C01B13/18 ,  C01G1/02 ,  C01G23/00 ,  C04B35/465 ,  C04B35/468

    CPC分类号： C01B13/185 ,  C01G1/02 ,  C01G23/006 ,  C04B35/465 ,  C04B35/4682 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2002/88 ,  C01P2004/51

    摘要： Methods of producing ABO.sub.3 compounds in which A represents a first metal ion and B represents a second metal ion from mixed metal coordination complexes are disclosed. The methods involve reacting compounds serving as a source of the B metal ion with a substituted aromatic compound, in solution, and thereafter reacting the metal coordination complex formed with a compound serving as a source of the A metal, in solution. An example is the reaction of titanium tetraisopropoxide with catechol to form a titanium catecholate coordination complex which is thereafter reacted with barium hydroxide octahydrate to form a pentamethanol barium triscatecholatotitanate mixed metal coordination complex which can be calcined at elevated temperatures to produce the ABO.sub.3 compound, barium titanate (BaTiO.sub.3), which is known to have outstanding dielectric, ferroelectric and piezoelectric properties. Portions of the A and/or B ions can be substituted with other metals.

    摘要翻译： 公开了生产ABO3化合物的方法，其中A代表第一金属离子，B代表来自混合金属配位络合物的第二金属离子。 所述方法包括将作为B金属离子源的化合物与取代的芳族化合物在溶液中反应，然后使与形成的作为A金属源的化合物形成的金属配位络合物在溶液中反应。 一个例子是四异丙醇钛与儿茶酚的反应形成儿茶酚酸钛配位络合物，然后与氢氧化钡八水合物反应，形成五甲醇钡三邻氨基苯甲酸钛酸盐混合金属配位络合物，其可以在高温下煅烧以产生ABO 3化合物，钛酸钡 （BaTiO 3），其已知具有优异的介电，铁电和压电性能。 A和/或B离子的一部分可以被其它金属取代。