公开(公告)号：US20140011927A1

公开(公告)日：2014-01-09

申请号：US14001209

申请日：2012-03-01

申请人： Lawrence J. Effler ,  Teresa P. Karjala ,  Mehmet Demirors ,  Nilesh R. Savargaonkar ,  Selim Bensason ,  Zhe Zhou

发明人： Lawrence J. Effler ,  Teresa P. Karjala ,  Mehmet Demirors ,  Nilesh R. Savargaonkar ,  Selim Bensason ,  Zhe Zhou

IPC分类号： C08L23/06 ,  C08K5/524 ,  C08L23/08 ,  C08F10/02

CPC分类号： C08F210/16 ,  C08F2/06 ,  C08F10/02 ,  C08J3/201 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08K5/134 ,  C08K5/52 ,  C08K5/524 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/20 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17

摘要： An ethylene/α-olefin copolymer comprising units derived from ethylene; and units derived from at least one α-olefin; wherein the ethylene/α-olefin copolymer has a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; an Mw/Mn of from 3 to 5; and from 300 to 500 vinyl unsaturations per 1,000,000 carbon atoms in the ethylene/α-olefin copolymer is provided. Also provided is a process for producing an ethylene/α-olefin copolymer comprising: (1) polymerizing ethylene and one or more α-olefins in a polymerization reactor; (2) thereby producing an enhanced melt strength ethylene/α-olefin copolymer having from 300 to 500 vinyl unsaturation units per 1,000,000 carbon atoms, a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; and a Mw/Mn of from 3 to 5.

摘要翻译： 包含衍生自乙烯的单元的乙烯/α-烯烃共聚物; 和衍生自至少一种α-烯烃的单元; 其中所述乙烯/α-烯烃共聚物的密度在0.90至0.94g / cc的范围内; 熔体指数（I 2）在0.05至50dg / min的范围内; Mw / Mn为3至5; 并且提供了乙烯/α-烯烃共聚物中每1,000,000个碳原子的300-500个乙烯基不饱和度。 还提供了一种生产乙烯/α-烯烃共聚物的方法，包括：（1）在聚合反应器中聚合乙烯和一种或多种α-烯烃; （2），从而产生具有每1,000,000个碳原子具有300-500个乙烯基不饱和单元的增强的熔体强度乙烯/α-烯烃共聚物，密度范围为0.90-0.94g / cc; 熔体指数（I 2）在0.05至50dg / min的范围内; Mw / Mn为3〜5。

公开(公告)号：US09428636B2

公开(公告)日：2016-08-30

申请号：US14001209

申请日：2012-03-01

申请人： Lawrence J. Effler ,  Teresa P. Karjala ,  Mehmet Demirors ,  Nilesh R. Savargaonkar ,  Selim Bensason ,  Zhe Zhou

发明人： Lawrence J. Effler ,  Teresa P. Karjala ,  Mehmet Demirors ,  Nilesh R. Savargaonkar ,  Selim Bensason ,  Zhe Zhou

IPC分类号： C08F210/16 ,  C08L23/06 ,  C08J3/20 ,  C08J5/18 ,  C08L23/08 ,  C08K5/524 ,  C08F10/02 ,  C08L23/20 ,  C08F2/06

CPC分类号： C08F210/16 ,  C08F2/06 ,  C08F10/02 ,  C08J3/201 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08K5/134 ,  C08K5/52 ,  C08K5/524 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/20 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17

摘要： An ethylene/α-olefin copolymer comprising units derived from ethylene; and units derived from at least one α-olefin; wherein the ethylene/α-olefin copolymer has a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; an Mw/Mn of from 3 to 5; and from 300 to 500 vinyl unsaturations per 1,000,000 carbon atoms in the ethylene/α-olefin copolymer is provided. Also provided is a process for producing an ethylene/α-olefin copolymer comprising: (1) polymerizing ethylene and one or more α-olefins in a polymerization reactor; (2) thereby producing an enhanced melt strength ethylene/α-olefin copolymer having from 300 to 500 vinyl unsaturation units per 1,000,000 carbon atoms, a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; and a Mw/Mn of from 3 to 5.

摘要翻译： 包含衍生自乙烯的单元的乙烯/α-烯烃共聚物; 和衍生自至少一种α-烯烃的单元; 其中所述乙烯/α-烯烃共聚物的密度在0.90至0.94g / cc的范围内; 熔体指数（I 2）在0.05至50dg / min的范围内; Mw / Mn为3至5; 并且提供了乙烯/α-烯烃共聚物中每100万个碳原子的300-500个乙烯基不饱和度。 还提供了一种生产乙烯/α-烯烃共聚物的方法，包括：（1）在聚合反应器中聚合乙烯和一种或多种α-烯烃; （2），由此产生具有每1,000,000个碳原子具有300-500个乙烯基不饱和单元的增强的熔融强度乙烯/α-烯烃共聚物，密度在0.90-0.94g / cc范围内; 熔体指数（I 2）在0.05至50dg / min的范围内; Mw / Mn为3〜5。

公开(公告)号：US20140113090A1

公开(公告)日：2014-04-24

申请号：US14118646

申请日：2012-07-02

申请人： Lawrence J. Effler, JR. ,  Nilesh R. Savargaonkar ,  Mehmet Demirors ,  Selim Bensason ,  Teresa P. Karjala ,  Gregory Bunker ,  Christina Serrat ,  Jian Wang

发明人： Lawrence J. Effler, JR. ,  Nilesh R. Savargaonkar ,  Mehmet Demirors ,  Selim Bensason ,  Teresa P. Karjala ,  Gregory Bunker ,  Christina Serrat ,  Jian Wang

IPC分类号： C08L23/06 ,  B32B1/02

CPC分类号： C08L23/06 ,  B32B1/02 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  Y10T428/1352

摘要： The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film according to the present invention comprises the melt blending product of: (a) less than or equal to 4 percent by weight of a low density polyethylene (LDPE) having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) 90 percent or greater by weight of a heterogenous linear low density polyethylene (hLLDPE) having a density in the range of from 0.917 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; and (e) optionally one or more antioxidants. When the polyethylene blend-composition is formed into a film via blown film process, the output rate is improved at least 6 percent relative to a similar linear low density polyethylene.

摘要翻译： 本发明提供了适用于吹塑薄膜的聚乙烯共混组合物，其制备方法和由其制成的薄膜。 适用于本发明吹塑薄膜的聚乙烯共混组合物包括：（a）小于或等于4重量％的密度范围为0.915至0.915的低密度聚乙烯（LDPE）的熔融共混产物 0.935g / cm 3，熔体指数（I 2）在大于0.8至小于或等于5g / 10分钟的范围内，分子量分布（Mw / Mn）为6至10 ; （b）90重量％以上的密度为0.917〜0.950g / cm3的异质线性低密度聚乙烯（hLLDPE），熔体指数（I 2）为0.1〜 或等于5g / 10分钟; （c）任选的基于水滑石的中和剂; （d）任选的一种或多种成核剂; 和（e）任选的一种或多种抗氧化剂。 当聚乙烯共混物组合物通过吹膜法形成膜时，相对于类似的线性低密度聚乙烯，输出速率提高至少6％。

公开(公告)号：US09284440B2

公开(公告)日：2016-03-15

申请号：US14118646

申请日：2012-07-02

申请人： Lawrence J. Effler, Jr. ,  Nilesh R. Savargaonkar ,  Mehmet Demirors ,  Selim Bensason ,  Teresa P. Karjala ,  Gregory Bunker ,  Cristina Serrat ,  Jian Wang

发明人： Lawrence J. Effler, Jr. ,  Nilesh R. Savargaonkar ,  Mehmet Demirors ,  Selim Bensason ,  Teresa P. Karjala ,  Gregory Bunker ,  Cristina Serrat ,  Jian Wang

IPC分类号： C08L23/06 ,  C08J5/18 ,  C08L23/08 ,  B32B1/02

CPC分类号： C08L23/06 ,  B32B1/02 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  Y10T428/1352

摘要： The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film according to the present invention comprises the melt blending product of: (a) less than or equal to 4 percent by weight of a low density polyethylene (LDPE) having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) 90 percent or greater by weight of a heterogenous linear low density polyethylene (hLLDPE) having a density in the range of from 0.917 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; and (e) optionally one or more antioxidants. When the polyethylene blend-composition is formed into a film via blown film process, the output rate is improved at least 6 percent relative to a similar linear low density polyethylene.

摘要翻译： 本发明提供了适用于吹塑薄膜的聚乙烯共混组合物，其制备方法和由其制成的薄膜。 适用于本发明吹塑薄膜的聚乙烯共混组合物包括：（a）小于或等于4重量％的密度范围为0.915至0.915的低密度聚乙烯（LDPE）的熔融共混产物 0.935g / cm 3，熔体指数（I 2）在大于0.8至小于或等于5g / 10分钟的范围内，分子量分布（Mw / Mn）为6至10 ; （b）90重量％以上的密度为0.917〜0.950g / cm3的异质线性低密度聚乙烯（hLLDPE），熔体指数（I 2）为0.1〜 或等于5g / 10分钟; （c）任选的基于水滑石的中和剂; （d）任选的一种或多种成核剂; 和（e）任选的一种或多种抗氧化剂。 当聚乙烯共混物组合物通过吹膜法形成膜时，相对于类似的线性低密度聚乙烯，输出速率提高至少6％。

公开(公告)号：US08173232B2

公开(公告)日：2012-05-08

申请号：US12781247

申请日：2010-05-17

申请人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

发明人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

IPC分类号： B29D22/00 ,  B29D23/00 ,  B32B1/08

CPC分类号： C08L23/0815 ,  B32B27/08 ,  B32B27/18 ,  B32B27/22 ,  B32B27/302 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/40 ,  B32B2250/24 ,  B32B2262/0261 ,  B32B2262/0276 ,  B32B2262/10 ,  B32B2262/106 ,  B32B2264/10 ,  B32B2270/00 ,  B32B2307/30 ,  B32B2307/31 ,  B32B2307/50 ,  B32B2307/51 ,  B32B2307/54 ,  B32B2307/5825 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/72 ,  B32B2553/00 ,  C08F10/00 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/31855 ,  C08L2666/06 ,  C08F4/64193

摘要： A multi-layer film structure is made from a specific polyethylene copolymer comprising the inner layer and is useful as a stretch hood film structure. The polyethylene copolymer can be characterized by a Comonomer Distribution Constant greater than about 45.

摘要翻译： 多层膜结构由包含内层的特定聚乙烯共聚物制成，并且可用作拉伸罩膜结构。 聚乙烯共聚物可以通过大于约45的共聚单体分布常数来表征。

公开(公告)号：US20110003129A1

公开(公告)日：2011-01-06

申请号：US12781247

申请日：2010-05-17

申请人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

发明人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

IPC分类号： B32B5/00

CPC分类号： C08L23/0815 ,  B32B27/08 ,  B32B27/18 ,  B32B27/22 ,  B32B27/302 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/40 ,  B32B2250/24 ,  B32B2262/0261 ,  B32B2262/0276 ,  B32B2262/10 ,  B32B2262/106 ,  B32B2264/10 ,  B32B2270/00 ,  B32B2307/30 ,  B32B2307/31 ,  B32B2307/50 ,  B32B2307/51 ,  B32B2307/54 ,  B32B2307/5825 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/72 ,  B32B2553/00 ,  C08F10/00 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/31855 ,  C08L2666/06 ,  C08F4/64193

摘要： A multi-layer film structure is made from a specific polyethylene copolymer comprising the inner layer and is useful as a stretch hood film structure. The polyethylene copolymer can be characterized by a Comonomer Distribution Constant greater than about 45.

摘要翻译： 多层膜结构由包含内层的特定聚乙烯共聚物制成，可用作拉伸罩膜结构。 聚乙烯共聚物可以通过大于约45的共聚单体分布常数来表征。

公开(公告)号：US10131114B2

公开(公告)日：2018-11-20

申请号：US14349789

申请日：2012-10-04

申请人： Jacquelyn A Degroot ,  Gert J. Claasen ,  Selim Bensason ,  Mehmet Demirors ,  Thor Gudmundsson ,  Jason C. Brodil

发明人： Jacquelyn A Degroot ,  Gert J. Claasen ,  Selim Bensason ,  Mehmet Demirors ,  Thor Gudmundsson ,  Jason C. Brodil

IPC分类号： D01H1/00 ,  B32B5/26 ,  B32B5/24 ,  D01F6/04 ,  D01F8/06 ,  B32B5/02 ,  D04H1/4291 ,  D04H3/007 ,  D04H3/16 ,  D04H13/00

摘要： The instant invention provides nonwoven fabrics and staple or binder fibers prepared from an ethylene-based polymer having a Comonomer Distribution Constant in the range of from greater than from 100 to 400, a vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range from 1 to less than 2; a density in the range of 0.930 to 0.970 g/cm3, a melt index (12) in the range of from 15 to 30 or from 10 to 50 g/10 minutes, a molecular weight distribution (Mw/Mn) in the range of from 2 to 3.5, and a molecular weight distribution (Mz/Mw) in the range of from less than 2.

公开(公告)号：US20120237741A1

公开(公告)日：2012-09-20

申请号：US13424978

申请日：2012-03-20

申请人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

发明人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

IPC分类号： B32B27/32

CPC分类号： B32B27/32 ,  B32B1/08 ,  C08F10/00 ,  C08L23/0815 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/24942 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/31855 ,  C08L2666/06 ,  C08F4/64193 ,  C08L23/04 ,  C08F4/64137

摘要： The instant invention provides a composition suitable for stretch hood, method of producing the same, and articles made therefrom. The article according to the present invention comprises a multi-layer film according to the present invention has a thickness of at least 3 mils comprising at least one inner layer and two exterior layers, wherein the inner layer comprises at least 50 weight percent polyethylene copolymer having a melt index less than 2 grams/10 minutes, a density less than or equal to 0.910 g/cm3, a total heat of fusion less than 120 Joules/gram and a heat of fusion above 115° C. of less than 5 Joules/gram, the total heat of fusion of the inner layer less than the heat of fusion of either of the two exterior layers, and wherein the multi-layer film has an elastic recovery of at least 40% when stretched to 100% elongation.

摘要翻译： 本发明提供了适用于拉伸罩的组合物，其制造方法以及由其制成的制品。 根据本发明的制品包括根据本发明的多层膜具有至少3密耳的厚度，其包含至少一个内层和两个外层，其中所述内层包含至少50重量％的聚乙烯共聚物，其具有 小于2克/ 10分钟的熔体指数，小于或等于0.910克/厘米3的密度，小于120焦耳/克的熔融热总和小于5焦耳/克的熔点在115℃以上， 克，内层的总熔化热小于两个外层之一的熔化热，并且其中当拉伸至100％伸长时，多层膜具有至少40％的弹性回复率。

公开(公告)号：US08389086B2

公开(公告)日：2013-03-05

申请号：US13424978

申请日：2012-03-20

申请人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

发明人： Prashant Mandare ,  Gregory Bunker ,  Rajen M. Patel ,  Yi Jin ,  Selim Bensason ,  Mehmet Demirors ,  Theresa J. Hermel-Davidock ,  Sarah M. Hayne ,  Jose E. Ruiz

IPC分类号： B29D22/00 ,  B29D23/00 ,  B32B1/08

CPC分类号： B32B27/32 ,  B32B1/08 ,  C08F10/00 ,  C08L23/0815 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/24942 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/31855 ,  C08L2666/06 ,  C08F4/64193 ,  C08L23/04 ,  C08F4/64137

摘要： The instant invention provides a composition suitable for stretch hood, method of producing the same, and articles made therefrom. The article according to the present invention comprises a multi-layer film according to the present invention has a thickness of at least 3 mils comprising at least one inner layer and two exterior layers, wherein the inner layer comprises at least 50 weight percent polyethylene copolymer having a melt index less than 2 grams/10 minutes, a density less than or equal to 0.910 g/cm3, a total heat of fusion less than 120 Joules/gram and a heat of fusion above 115° C. of less than 5 Joules/gram, the total heat of fusion of the inner layer less than the heat of fusion of either of the two exterior layers, and wherein the multi-layer film has an elastic recovery of at least 40% when stretched to 100% elongation.

摘要翻译： 本发明提供了适用于拉伸罩的组合物，其制造方法以及由其制成的制品。 根据本发明的制品包括根据本发明的多层膜具有至少3密耳的厚度，其包含至少一个内层和两个外层，其中所述内层包含至少50重量％的聚乙烯共聚物，其具有 小于2克/ 10分钟的熔体指数，小于或等于0.910克/厘米3的密度，小于120焦耳/克的熔融热总和小于5焦耳/克的熔点在115℃以上， 克，内层的总熔化热小于两个外层之一的熔化热，并且其中当拉伸至100％伸长时，多层膜具有至少40％的弹性回复率。

公开(公告)号：US20150225520A1

公开(公告)日：2015-08-13

申请号：US14411565

申请日：2012-07-20

申请人： Selim Bensason ,  Mehmet Demirors ,  Xiao Bing Yun

发明人： Selim Bensason ,  Mehmet Demirors ,  Xiao Bing Yun

IPC分类号： C08J5/18 ,  B29C55/02

CPC分类号： C08J5/18 ,  B29C55/02 ,  B29K2023/0625 ,  B29L2009/00 ,  B32B27/205 ,  B32B27/32 ,  B32B2307/31 ,  B32B2307/542 ,  B32B2307/558 ,  B32B2307/5825 ,  B32B2439/70 ,  B32B2555/00 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08J2301/00 ,  C08J2323/08 ,  C08L23/06 ,  C08L23/0815 ,  C08L2203/16 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26 ,  C08F2/001 ,  C08F4/64193

摘要： The instant invention provides a linear low density polyethylene composition suitable for cast film, films made therefrom, and packaging devices comprising one or more such film layers. The linear low density polyethylene composition suitable for cast film according to the present invention comprises an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 200, for example from 40 to 150, a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range from 1.2 to 5, for example from 1.5 to 4; a density in the range of from 0.910 to 0.935, for example from 0.915 to 0.925, g/cm3, a melt index (I2) in a range of from 1 to 10, for example from 2 to 6 g/10 minutes, a molecular weight distribution (Mw/Mn) in the range of from 2 to 3.5.

摘要翻译： 本发明提供一种适用于流延薄膜，由其制成的薄膜的线性低密度聚乙烯组合物和包括一种或多种这样的薄膜层的包装装置。 适用于本发明的流延膜的线性低密度聚乙烯组合物包含乙烯/α-烯烃互聚物组合物，其共聚单体分布常数（CDC）为40-200，例如40-150，乙烯基 存在于乙烯基聚合物组合物的骨架中的每1000个碳原子上少于0.12个乙烯基的不饱和度; 零剪切粘度比（ZSVR）在1.2至5，例如1.5至4的范围内; 在0.910至0.935范围内的密度，例如0.915至0.925g / cm 3，熔体指数（I 2）在1至10，例如2至6g / 10分钟的范围内，分子 重量分布（Mw / Mn）在2至3.5的范围内。