公开(公告)号：US07247684B2

公开(公告)日：2007-07-24

申请号：US10489465

申请日：2002-04-11

申请人： Leonardo C. Lopez ,  Jimmy D. Earls ,  Jerry E. White ,  Zenon Lysenko ,  Marvin L. Dettloff

发明人： Leonardo C. Lopez ,  Jimmy D. Earls ,  Jerry E. White ,  Zenon Lysenko ,  Marvin L. Dettloff

IPC分类号： B32B27/38 ,  C08L63/02 ,  C08L63/08

CPC分类号： C08L63/00 ,  C08G59/5006 ,  C08G59/56 ,  C08L27/00 ,  Y10T428/31678 ,  Y10T428/31681 ,  C08L2666/02

摘要： The present invention provides network polymers obtained by curing compositions that comprise an ester with at least two terminal epoxy groups. Preferred esters include those represented by the formula (1), wherein each R1 independently represents a substituted or unsubstituted homoaliphatic or heteroaliphatic group; A represents a substituted or unsubstituted homoalkylene, hetemalkylene, arylene, or heteroarylene segment; and n represents an integer equal to or greater than 2.

摘要翻译： 本发明提供了通过固化包含具有至少两个末端环氧基团的酯的组合物而获得的网状聚合物。 优选的酯包括由式（1）表示的酯，其中每个R 1独立地表示取代或未取代的脂族或杂脂肪族基团; A表示取代或未取代的均亚烷基，亚甲氧基，亚芳基或杂亚芳基链段; n表示2以上的整数。

公开(公告)号：US07279546B2

公开(公告)日：2007-10-09

申请号：US10484419

申请日：2002-07-16

申请人： Jerry E. White ,  Zenon Lysenko ,  Jimmy D. Earls ,  Marvin L. Dettloff ,  James A. Rabon, Jr. ,  Leonardo C. Lopez

发明人： Jerry E. White ,  Zenon Lysenko ,  Jimmy D. Earls ,  Marvin L. Dettloff ,  James A. Rabon, Jr. ,  Leonardo C. Lopez

IPC分类号： C08G63/00 ,  C08L67/00

CPC分类号： C08L67/04 ,  C08G63/06 ,  C08G63/823 ,  C08G63/87 ,  C08L3/04 ,  C08L23/06 ,  C08L23/12 ,  C08L67/02 ,  Y10T428/31786 ,  C08L2666/26 ,  C08L2666/18 ,  C08L23/00 ,  C08L2666/06

摘要： The present invention provides thermoplastic hydroxy-functional polyesters. The polyesters have at least 10 sequential units, wherein the sequential units consist of units selected from units represented by the following formula (1) and units represented by the following formula (2); Wherein each of R1 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R2 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R3 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; Each of R4 independently represents a substituted or unsubstituted homoalkyl or heteroalkyl group; and said moiety having no fewer than 1 unit represented by formula (1) and no fewer than 1 unit represented by formula (2). The present invention further provides processes for making hydroxyfunctional polyesters, such as polymerizing epoxidized fatty acids in the presence of an onium salt, and compositions and articles that include or are derived from the hydroxyfuntional polyesters

摘要翻译： 本发明提供热塑性羟基官能聚酯。 聚酯具有至少10个连续单元，其中顺序单元由选自下式（1）表示的单元和由下式（2）表示的单元组成。 其中R 1和R 2各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 2各自独立地表示氢或取代或未取代的均烷基或杂烷基; R 3各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 4各自独立地表示取代或未取代的均烷基或杂烷基; 并且所述部分具有不少于1个由式（1）表示的单元和不少于1个由式（2）表示的单元。 本发明还提供制备羟基官能聚酯的方法，例如在鎓盐存在下聚合环氧化脂肪酸，以及包含或衍生自羟基官能聚酯的组合物和制品

公开(公告)号：US07745652B2

公开(公告)日：2010-06-29

申请号：US12328868

申请日：2008-12-05

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC分类号： C07C51/43

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US20090143544A1

公开(公告)日：2009-06-04

申请号：US12328868

申请日：2008-12-05

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC分类号： C08L63/08 ,  C07C51/43 ,  C07C59/42 ,  C07C31/18 ,  C07C215/00 ,  C08L79/02 ,  C08L67/04 ,  C07C229/00 ,  C07C69/732 ,  C07C1/00

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US07300986B2

公开(公告)日：2007-11-27

申请号：US10492224

申请日：2002-10-10

申请人： David J. Brennan ,  Jerry E. White ,  Jimmy D. Earls ,  Mary L. Dettloff

发明人： David J. Brennan ,  Jerry E. White ,  Jimmy D. Earls ,  Mary L. Dettloff

IPC分类号： C08L63/02 ,  C08L77/06

CPC分类号： C08G59/1477 ,  C08G59/5033

摘要： The present invention provides compounds that have an amide linkage and at least two epoxy groups. The compounds are preferably aliphatic.

摘要翻译： 本发明提供具有酰胺键和至少两个环氧基团的化合物。 该化合物优选是脂族的。

公开(公告)号：US06482946B1

公开(公告)日：2002-11-19

申请号：US09705685

申请日：2000-11-03

申请人： Marvin L. Dettloff ,  Jerry E. White ,  Marty J. Null

发明人： Marvin L. Dettloff ,  Jerry E. White ,  Marty J. Null

IPC分类号： C07D26516

CPC分类号： C07D413/04 ,  C07D265/16 ,  C07D413/06 ,  C07D413/14 ,  C08G73/06

摘要： A high char yield polybenzoxazine is formed by mixing (i) a benzoxazine compound, (ii) a furan compound, (iii) a benzoxazine-furan compound or combinations thereof, wherein the mixture has a benzoxazine ring to furan ring ratio from about 0.001 to about 10 and then heating the mixture for a sufficient time to form the polybenzoxazine.

摘要翻译： 通过混合（i）苯并恶嗪化合物，（ii）呋喃化合物，（iii）苯并恶嗪 - 呋喃化合物或其组合，其中所述混合物具有苯并恶嗪环与呋喃环的比例为约0.001至 约10℃，然后将混合物加热足够的时间以形成聚苯并恶嗪。

公开(公告)号：US20100041794A1

公开(公告)日：2010-02-18

申请号：US12522638

申请日：2007-12-11

申请人： Jim D. Earls ,  Jerry E. White ,  Fabio Aguirre Vargas ,  Zenon Lysenko ,  Maurice J. Marks

发明人： Jim D. Earls ,  Jerry E. White ,  Fabio Aguirre Vargas ,  Zenon Lysenko ,  Maurice J. Marks

IPC分类号： C09D7/12 ,  C08G69/00 ,  C08L63/00

CPC分类号： C09D5/03 ,  C07C67/31 ,  C07C235/08 ,  C07C235/28 ,  C11C3/00 ,  C07C69/675

摘要： The present invention relates to new reactive monomer compositions that have a plurality of reactive, functional moieties, such as one or both of a hydroxyl moiety or a carboxylic acid moiety. The present invention also further relates to use of such reactive monomer compositions as a component of curable coating compositions, especially curable powder coating compositions.

摘要翻译： 本发明涉及具有多个反应性功能部分，例如羟基部分或羧酸部分中的一个或两个的新的反应性单体组合物。 本发明还涉及这种反应性单体组合物作为可固化涂料组合物的组分，特别是可固化的粉末涂料组合物的用途。

公开(公告)号：US07576227B2

公开(公告)日：2009-08-18

申请号：US10508805

申请日：2003-04-17

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Josef Bicerano ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettlof ,  Jerry E. White

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Josef Bicerano ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettlof ,  Jerry E. White

IPC分类号： C07C57/00 ,  C07C53/00

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ωpolyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US20100137478A1

公开(公告)日：2010-06-03

申请号：US12623316

申请日：2009-11-20

申请人： Jerry E. White ,  Hari Parvatareddy ,  Felix Achille ,  Leonardo C. Lopez ,  Rudolf J. Koopmans ,  Rene Broos ,  Scott T. Matteucci ,  Steven R. Lakso

发明人： Jerry E. White ,  Hari Parvatareddy ,  Felix Achille ,  Leonardo C. Lopez ,  Rudolf J. Koopmans ,  Rene Broos ,  Scott T. Matteucci ,  Steven R. Lakso

IPC分类号： C08L1/00 ,  C08K3/22

CPC分类号： C08L97/02 ,  Y10T428/31551 ,  C08L77/12

摘要： The instant invention generally provides polymer microfiller composite comprising a molecularly self-assembling material and a microfiller, and a process of making and an article comprising the polymer microfiller composite.

摘要翻译： 本发明通常提供包含分子自组装材料和微细粉碎的聚合物微粉碎复合物，以及制备方法和包含聚合物微粉碎复合材料的制品。

公开(公告)号：US08609751B2

公开(公告)日：2013-12-17

申请号：US12623316

申请日：2009-11-20

申请人： Jerry E. White ,  Hari Parvatareddy ,  Felix Achille ,  Leonardo C. Lopez ,  Rudolf J. Koopmans ,  Rene Broos ,  Steven R. Lakso

发明人： Jerry E. White ,  Hari Parvatareddy ,  Felix Achille ,  Leonardo C. Lopez ,  Rudolf J. Koopmans ,  Rene Broos ,  Steven R. Lakso

IPC分类号： C08L1/00 ,  C08G18/60 ,  B32B27/06

CPC分类号： C08L97/02 ,  Y10T428/31551 ,  C08L77/12

摘要： The instant invention generally provides polymer microfiller composite comprising a molecularly self-assembling material and a microfiller, and a process of making and an article comprising the polymer microfiller composite.

摘要翻译： 本发明通常提供包含分子自组装材料和微细粉碎的聚合物微粉碎复合物，以及制备方法和包含聚合物微粉碎复合材料的制品。