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    Hydroxy-functional polyesters
    1.
    发明授权
    Hydroxy-functional polyesters 失效
    羟基官能聚酯

    公开(公告)号：US07279546B2

    公开(公告)日：2007-10-09

    申请号：US10484419

    申请日：2002-07-16

    申请人： Jerry E. White ,  Zenon Lysenko ,  Jimmy D. Earls ,  Marvin L. Dettloff ,  James A. Rabon, Jr. ,  Leonardo C. Lopez

    发明人： Jerry E. White ,  Zenon Lysenko ,  Jimmy D. Earls ,  Marvin L. Dettloff ,  James A. Rabon, Jr. ,  Leonardo C. Lopez

    IPC分类号： C08G63/00 ,  C08L67/00

    CPC分类号： C08L67/04 ,  C08G63/06 ,  C08G63/823 ,  C08G63/87 ,  C08L3/04 ,  C08L23/06 ,  C08L23/12 ,  C08L67/02 ,  Y10T428/31786 ,  C08L2666/26 ,  C08L2666/18 ,  C08L23/00 ,  C08L2666/06

    摘要： The present invention provides thermoplastic hydroxy-functional polyesters. The polyesters have at least 10 sequential units, wherein the sequential units consist of units selected from units represented by the following formula (1) and units represented by the following formula (2); Wherein each of R1 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R2 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R3 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; Each of R4 independently represents a substituted or unsubstituted homoalkyl or heteroalkyl group; and said moiety having no fewer than 1 unit represented by formula (1) and no fewer than 1 unit represented by formula (2). The present invention further provides processes for making hydroxyfunctional polyesters, such as polymerizing epoxidized fatty acids in the presence of an onium salt, and compositions and articles that include or are derived from the hydroxyfuntional polyesters

    摘要翻译： 本发明提供热塑性羟基官能聚酯。 聚酯具有至少10个连续单元，其中顺序单元由选自下式（1）表示的单元和由下式（2）表示的单元组成。 其中R 1和R 2各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 2各自独立地表示氢或取代或未取代的均烷基或杂烷基; R 3各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 4各自独立地表示取代或未取代的均烷基或杂烷基; 并且所述部分具有不少于1个由式（1）表示的单元和不少于1个由式（2）表示的单元。 本发明还提供制备羟基官能聚酯的方法，例如在鎓盐存在下聚合环氧化脂肪酸，以及包含或衍生自羟基官能聚酯的组合物和制品

    MOISTURE RESISTANT PHOTOVOLTAIC DEVICES WITH ELASTOMERIC, POLYSILOXANE PROTECTION LAYER
    6.
    发明申请
    MOISTURE RESISTANT PHOTOVOLTAIC DEVICES WITH ELASTOMERIC, POLYSILOXANE PROTECTION LAYER 审中-公开
    具有弹性体，多晶硅保护层的防潮光伏器件

    公开(公告)号：US20110162705A1

    公开(公告)日：2011-07-07

    申请号：US12974643

    申请日：2010-12-21

    申请人： Paul J. Popa ,  Michelle L. Boven ,  Zenon Lysenko ,  Michael E. Mills ,  Leonardo C. Lopez

    发明人： Paul J. Popa ,  Michelle L. Boven ,  Zenon Lysenko ,  Michael E. Mills ,  Leonardo C. Lopez

    IPC分类号： H01L31/0216

    CPC分类号： H01L31/0749 ,  H01L31/048 ,  Y02E10/541

    摘要： Improved protection systems for CIGS-based microelectronic devices of the type incorporating electric conductor(s) such as an electronic collection grid. In one aspect, the present invention relates to a photovoltaic device having a light incident surface and a backside surface. The device includes a chalcogenide-containing photovoltaic layer comprising at least one of copper, indium and/or gallium. A transparent conductive layer is interposed between the photovoltaic layer and the light incident surface, wherein the transparent conductive layer is electrically coupled to the photovoltaic layer. An electronic collection grid is electrically coupled to the transparent conductive layer and overlying at least a portion of the transparent conductive layer. An elastomeric structure having a light incident surface, said structure overlying at least portions of the electronic collection grid and the transparent conductive layer in a manner such that the light incident surface of the elastomeric structure is spaced apart from a major portion of the conductor, and wherein the elastomeric structure comprises an elastomeric siloxane polymer having a WVTR of at least 0.1 g/m2-day. An optional protective barrier overlies the elastomeric structure. The protection systems of the invention incorporate elastomers with water vapor transmission rates that are atypically high in the context of CIGS-based devices.

    摘要翻译： 改进了包含电导体（例如电子收集网格）类型的基于CIGS的微电子器件的保护系统。 一方面，本发明涉及具有光入射面和背面的光电器件。 该装置包括含硫族化物的光伏层，其包含铜，铟和/或镓中的至少一种。 透明导电层介于光伏层和光入射表面之间，其中透明导电层电耦合到光伏层。 电子收集栅格电耦合到透明导电层并且覆盖透明导电层的至少一部分。 具有光入射表面的弹性体结构，所述结构以使得弹性体结构的光入射表面与导体的主要部分间隔开的方式覆盖电子收集栅格和透明导电层的至少一部分，以及 其中所述弹性体结构包含具有至少0.1g / m 2·天的WVTR的弹性体硅氧烷聚合物。 可选的保护屏障覆盖弹性体结构。 本发明的保护系统结合了在基于CIGS的设备的背景下具有非常高的水蒸汽透过率的弹性体。

    Integrate chemical processes for industrial utilization of seed oils
    7.
    发明授权
    Integrate chemical processes for industrial utilization of seed oils 有权
    整合化学工业用于种子油的工业利用

    公开(公告)号：US07576227B2

    公开(公告)日：2009-08-18

    申请号：US10508805

    申请日：2003-04-17

    申请人： Zenon Lysenko ,  Bob R. Maughon ,  Josef Bicerano ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettlof ,  Jerry E. White

    发明人： Zenon Lysenko ,  Bob R. Maughon ,  Josef Bicerano ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettlof ,  Jerry E. White

    IPC分类号： C07C57/00 ,  C07C53/00

    CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

    摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ωpolyester polyamine.

    摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

    PREPOLYMERS AND POLYMERS FOR ELASTOMERS
    9.
    发明申请
    PREPOLYMERS AND POLYMERS FOR ELASTOMERS 审中-公开
    弹性体的制备物和聚合物

    公开(公告)号：US20100266799A1

    公开(公告)日：2010-10-21

    申请号：US12668500

    申请日：2008-07-09

    申请人： William A. Koonce ,  Dwight D. Latham ,  Randall C. Jenkines ,  Debkumar Bhattacharjee ,  Zenon Lysenko ,  Hongyu Chen ,  Mark F. Sonnenschein ,  Klaus Schiller ,  Cora Leibig ,  Alan K. Schrock

    发明人： William A. Koonce ,  Dwight D. Latham ,  Randall C. Jenkines ,  Debkumar Bhattacharjee ,  Zenon Lysenko ,  Hongyu Chen ,  Mark F. Sonnenschein ,  Klaus Schiller ,  Cora Leibig ,  Alan K. Schrock

    IPC分类号： C08G18/10 ,  C08G18/34 ,  B32B1/08

    CPC分类号： C08G18/4288 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/4018 ,  C08G18/4833 ,  C08G18/4841 ,  C08G2101/0008 ,  C08J9/30 ,  C08J2375/04 ,  Y10T428/139 ,  C08G18/3275 ,  C08G18/3206 ,  C08G18/40

    摘要： A prepolymer or elastomer is the reaction product of reactants (a) at least one polyester polyol or fatty acid derived polyol which is the reaction product of at least one initiator and a mixture of fatty acids or derivatives of fatty acids comprising at least about 45 weight percent monounsaturated fatty acids or derivatives thereof, (b) optionally, at least one polyol which is different from the polyol of (a); and (c) at least one isocyanate compound (herein after isocyanate) having an average of at least about 1.8 isocyanate groups per molecule. A process comprises admixing reactants (a) at least one polyol composition comprising the fatty acid derived polyol which is the reaction product of at least one initiator and a mixture of fatty acids or derivatives of fatty acids comprising at least about any of 45 weight percent monounsaturated fatty acids or derivatives thereof; and (b) at least one isocyanate having an average functionality of at least about 1.8 under reaction conditions to form a reaction product which is an elastomer or prepolymer is formed therefrom. An article, coating or thermoplastic polyurethane comprises the elastomer is formed from the prepolymer of or using the process of the invention.

    摘要翻译： 预聚物或弹性体是反应物（a）至少一种聚酯多元醇或脂肪酸衍生多元醇的反应产物，其是至少一种引发剂与脂肪酸或包含至少约45重量％的脂肪酸​​的衍生物的混合物的反应产物 百分比的单不饱和脂肪酸或其衍生物，（b）任选的至少一种不同于（a）的多元醇的多元醇; 和（c）每分子平均具有至少约1.8个异氰酸酯基团的至少一种异氰酸酯化合物（本文中为异氰酸酯）。 一种方法包括混合反应物（a）至少一种多元醇组合物，其包含脂肪酸衍生的多元醇，其是至少一种引发剂的反应产物和脂肪酸或脂肪酸的混合物的混合物，其至少包含约45重量％的单不饱和物 脂肪酸或其衍生物; 和（b）在反应条件下至少一种具有至少约1.8的平均官能度的异氰酸酯形成由弹性体或预聚物形成的反应产物。 一种制品，涂层或热塑性聚氨酯包括弹性体由本发明的预聚物或使用本发明的方法形成。

    Method for preparing poly(dicyclopentadiene)
    10.
    发明申请
    Method for preparing poly(dicyclopentadiene) 审中-公开
    制备聚（二环戊二烯）的方法

    公开(公告)号：US20080023884A1

    公开(公告)日：2008-01-31

    申请号：US11879120

    申请日：2007-07-16

    申请人： Wayde Konze ,  David Bank ,  Martin Cornell ,  Zenon Lysenko ,  Francis Timmers

    发明人： Wayde Konze ,  David Bank ,  Martin Cornell ,  Zenon Lysenko ,  Francis Timmers

    IPC分类号： B29C45/03 ,  C08G61/08

    CPC分类号： C08G61/08 ,  C08F6/006

    摘要： Crosslinked polydicyclopentadiene polymer and copolymer are made by first forming a thermoplastic polymeric intermediate in a ring-opening metathesis polymerization (ROMP), and then crosslinking the intermediate in a melt-processing or solution processing step. The formation of the intermediate permits facile removal of residual monomer, which leads to a reduction in odor and improvement in physical properties. Crosslinking can be achieved using various crosslinking strategies, including further ROMP reactions, addition polymerization of residual double bonds, addition of a crosslinking agent or introduction of functional groups.

    摘要翻译： 交联的聚二聚环戊二烯聚合物和共聚物通过首先在开环易位聚合（ROMP）中形成热塑性聚合物中间体，然后在熔融加工或溶液处理步骤中交联中间体来制备。 中间体的形成允许容易地去除残留的单体，这导致气味的降低和物理性能的改善。 可以使用各种交联策略实现交联，包括进一步的ROMP反应，残余双键的加成聚合，加入交联剂或引入官能团。