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公开(公告)号：US20090143544A1
公开(公告)日：2009-06-04
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C08L63/08 , C07C51/43 , C07C59/42 , C07C31/18 , C07C215/00 , C08L79/02 , C08L67/04 , C07C229/00 , C07C69/732 , C07C1/00
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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公开(公告)号：US07745652B2
公开(公告)日：2010-06-29
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C07C51/43
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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公开(公告)号：US07247684B2
公开(公告)日：2007-07-24
申请号：US10489465
申请日：2002-04-11
CPC分类号： C08L63/00 , C08G59/5006 , C08G59/56 , C08L27/00 , Y10T428/31678 , Y10T428/31681 , C08L2666/02
摘要： The present invention provides network polymers obtained by curing compositions that comprise an ester with at least two terminal epoxy groups. Preferred esters include those represented by the formula (1), wherein each R1 independently represents a substituted or unsubstituted homoaliphatic or heteroaliphatic group; A represents a substituted or unsubstituted homoalkylene, hetemalkylene, arylene, or heteroarylene segment; and n represents an integer equal to or greater than 2.
摘要翻译： 本发明提供了通过固化包含具有至少两个末端环氧基团的酯的组合物而获得的网状聚合物。 优选的酯包括由式（1）表示的酯，其中每个R 1独立地表示取代或未取代的脂族或杂脂肪族基团; A表示取代或未取代的均亚烷基，亚甲氧基，亚芳基或杂亚芳基链段; n表示2以上的整数。
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公开(公告)号：US07279546B2
公开(公告)日：2007-10-09
申请号：US10484419
申请日：2002-07-16
申请人： Jerry E. White , Zenon Lysenko , Jimmy D. Earls , Marvin L. Dettloff , James A. Rabon, Jr. , Leonardo C. Lopez
发明人： Jerry E. White , Zenon Lysenko , Jimmy D. Earls , Marvin L. Dettloff , James A. Rabon, Jr. , Leonardo C. Lopez
CPC分类号： C08L67/04 , C08G63/06 , C08G63/823 , C08G63/87 , C08L3/04 , C08L23/06 , C08L23/12 , C08L67/02 , Y10T428/31786 , C08L2666/26 , C08L2666/18 , C08L23/00 , C08L2666/06
摘要： The present invention provides thermoplastic hydroxy-functional polyesters. The polyesters have at least 10 sequential units, wherein the sequential units consist of units selected from units represented by the following formula (1) and units represented by the following formula (2); Wherein each of R1 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R2 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R3 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; Each of R4 independently represents a substituted or unsubstituted homoalkyl or heteroalkyl group; and said moiety having no fewer than 1 unit represented by formula (1) and no fewer than 1 unit represented by formula (2). The present invention further provides processes for making hydroxyfunctional polyesters, such as polymerizing epoxidized fatty acids in the presence of an onium salt, and compositions and articles that include or are derived from the hydroxyfuntional polyesters
摘要翻译： 本发明提供热塑性羟基官能聚酯。 聚酯具有至少10个连续单元，其中顺序单元由选自下式（1）表示的单元和由下式（2）表示的单元组成。 其中R 1和R 2各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 2各自独立地表示氢或取代或未取代的均烷基或杂烷基; R 3各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 4各自独立地表示取代或未取代的均烷基或杂烷基; 并且所述部分具有不少于1个由式（1）表示的单元和不少于1个由式（2）表示的单元。 本发明还提供制备羟基官能聚酯的方法，例如在鎓盐存在下聚合环氧化脂肪酸，以及包含或衍生自羟基官能聚酯的组合物和制品
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公开(公告)号：US06482946B1
公开(公告)日：2002-11-19
申请号：US09705685
申请日：2000-11-03
IPC分类号： C07D26516
CPC分类号： C07D413/04 , C07D265/16 , C07D413/06 , C07D413/14 , C08G73/06
摘要： A high char yield polybenzoxazine is formed by mixing (i) a benzoxazine compound, (ii) a furan compound, (iii) a benzoxazine-furan compound or combinations thereof, wherein the mixture has a benzoxazine ring to furan ring ratio from about 0.001 to about 10 and then heating the mixture for a sufficient time to form the polybenzoxazine.
摘要翻译： 通过混合（i）苯并恶嗪化合物，（ii）呋喃化合物，（iii）苯并恶嗪 - 呋喃化合物或其组合，其中所述混合物具有苯并恶嗪环与呋喃环的比例为约0.001至 约10℃，然后将混合物加热足够的时间以形成聚苯并恶嗪。
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公开(公告)号：US20120172493A1
公开(公告)日：2012-07-05
申请号：US13389028
申请日：2010-09-21
申请人： Marvin L. Dettloff , Gary A. Hunter , Susan K. Falcone-Potts , Ha Q. Pham , Martine Rousse , Bernd Hoevel
发明人： Marvin L. Dettloff , Gary A. Hunter , Susan K. Falcone-Potts , Ha Q. Pham , Martine Rousse , Bernd Hoevel
CPC分类号： C08G59/64 , C08G59/621 , C08J5/24 , C08J2363/02
摘要： A curable epoxy resin composite composition including a reinforcing material and an epoxy resin composition, and a process for preparing a composite from such composition; wherein a combination of at least one alkanolamine and at least one styrenated phenol are present in the epoxy resin composition in a sufficient amount to increase the rate of reaction of the at least one epoxy resin and the at least one alkanolamine curing agent while maintaining the thermal and mechanical properties of the composite upon curing of the epoxy resin composition.
摘要翻译： 包含增强材料和环氧树脂组合物的可固化环氧树脂复合组合物及其制备方法。 其中至少一种链烷醇胺和至少一种苯乙烯化酚的组合以足够的量存在于环氧树脂组合物中以提高至少一种环氧树脂和至少一种链烷醇胺固化剂的反应速率同时保持热 以及环氧树脂组合物固化时复合材料的机械性能。
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7.发明申请公开(公告)号：US20120010330A1
公开(公告)日：2012-01-12
申请号：US13254180
申请日：2010-02-16
CPC分类号： C08G59/56 , C08G59/621 , C08L63/00
摘要： A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.
摘要翻译： 一种可固化组合物，其包含（a）至少一种环状二胺，（b）至少一种在25℃下对于非杂环中最碱性的胺基具有约9.5至约12的pKa值的非杂环胺 胺分子，（c）至少一种环氧树脂，和（d）至少一种烷基化苯酚; （i）其中来自环二胺的胺氢的当量与组合物中来自环二胺和非杂环胺的总胺氢相比大于约5％; （ii）其中组合物中总胺氢的当量与组合物中总环氧化物的当量的比例大于或等于约1; 和（iii）其中烷基化苯酚的量大于可固化组合物的约10重量％。
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公开(公告)号：US5633020A
公开(公告)日：1997-05-27
申请号：US539138
申请日：1995-10-04
IPC分类号： B05D7/24 , B05D7/00 , C08G59/42 , C08G67/00 , C08G67/04 , C08L57/00 , C08L63/00 , C08L73/00 , C08L73/02 , C09D5/03 , C09D133/06 , C09D163/00 , C09D173/00 , C09D173/02 , C08L33/14
CPC分类号： B05D7/53 , C08G59/42 , C08L63/00 , C08L73/02 , C09D133/068 , C09D163/00 , C09D173/02 , C08L57/00 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31692
摘要： A coating composition with a solids content of at least about 65% by weight comprises a polyanhydride having more than one non-cyclic anhydride moiety, a co-reactant resin such as a glycidyl (meth)acrylate-containing polymer and a latent catalyst wherein the equivalent ratio of epoxy to anhydride is from about 0.8:1 to 1.3:1.
摘要翻译： 固体含量为至少约65重量％的涂料组合物包含具有多于一个非环酸酐部分的聚酐，共反应物树脂如含（甲基）丙烯酸酯缩水甘油酯聚合物和潜催化剂，其中， 环氧与酸酐的当量比为约0.8:1至1.3:1。
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公开(公告)号：US5602274A
公开(公告)日：1997-02-11
申请号：US396458
申请日：1995-02-28
IPC分类号： B05D7/24 , B05D7/00 , C08G59/42 , C08G67/00 , C08G67/04 , C08L57/00 , C08L63/00 , C08L73/00 , C08L73/02 , C09D5/03 , C09D133/06 , C09D163/00 , C09D173/00 , C09D173/02 , C07C69/75
CPC分类号： B05D7/53 , C08G59/42 , C08L63/00 , C08L73/02 , C09D133/068 , C09D163/00 , C09D173/02 , C08L57/00 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31692
摘要： A polyanhydride having a molecular weight of no more than about 2000 is useful in a coating composition with a coreactant resin such as an epoxy resin and comprises:(a) a polyvalent organic moiety;(b) a plurality of ester linkages bonded to the polyvalent organic moiety;(c) divalent organic moieties bonded to the ester linkages; and(d) non-cyclic anhydride moleties bonded to the divalent organic moleties.
摘要翻译： 分子量不大于约2000的聚酐可用于具有共反应树脂如环氧树脂的涂料组合物，并且包含：（a）多价有机部分; （b）与多价有机部分结合的多个酯键; （c）键合到酯键的二价有机基团; 和（d）与二价有机游动物结合的非环状酸酐摩尔。
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10.发明授权公开(公告)号：US08980979B2
公开(公告)日：2015-03-17
申请号：US13254180
申请日：2010-02-16
CPC分类号： C08G59/56 , C08G59/621 , C08L63/00
摘要： A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.
摘要翻译： 一种可固化组合物，其包含（a）至少一种环状二胺，（b）至少一种在25℃下对于非杂环中最碱性的胺基具有约9.5至约12的pKa值的非杂环胺 胺分子，（c）至少一种环氧树脂，和（d）至少一种烷基化苯酚; （i）其中来自环二胺的胺氢的当量与组合物中来自环二胺和非杂环胺的总胺氢相比大于约5％; （ii）其中组合物中总胺氢的当量与组合物中总环氧化物的当量的比例大于或等于约1; 和（iii）其中烷基化苯酚的量大于可固化组合物的约10重量％。
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