公开(公告)号：US20090143546A1

公开(公告)日：2009-06-04

申请号：US12243346

申请日：2008-10-01

申请人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： C08F2/01 ,  C08F110/02

CPC分类号： B01J8/20 ,  B01J8/0035 ,  B01J19/1837 ,  B01J2208/00548 ,  B01J2208/00752 ,  C08F10/00 ,  C08F210/16 ,  G05D11/132 ,  C08F2/01 ,  C08F2/14 ,  C08F2/06 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/04 ,  C08F2500/23

摘要： A method for controlling the injection of catalyst slurry in a polymerization reactor is described herein. The method includes the preparation of polyethylene with a solid catalyst and a hydrocarbon diluents. The method includes providing solid catalyst and a hydrocarbon diluent in one or more storage vessels such that a catalyst slurry is obtained in said vessel, transferring said catalyst slurry from said storage vessel to a mixing vessel wherein said catalyst slurry is diluted for obtaining a suitable concentration for use in a polymerization reaction, pumping said diluted catalyst slurry at a controlled flow rate from said mixing vessel to said polymerization reactor through one or more conduits, by means of a membrane pump provided in each of said conduits, and the membrane pump is controllable as a function of reactant concentration within the polymerization reactor.

摘要翻译： 本文描述了控制聚合反应器中催化剂浆料注入的方法。 该方法包括用固体催化剂和烃稀释剂制备聚乙烯。 该方法包括在一个或多个储存容器中提供固体催化剂和烃稀释剂，使得在所述容器中获得催化剂浆料，将所述催化剂浆料从所述储存容器转移到混合容器中，其中所述催化剂浆料被稀释以获得合适的浓度 用于聚合反应中，通过设置在每个所述管道中的膜泵将所述稀释的催化剂浆料以受控的流速从所述混合容器泵送到所述聚合反应器，通过一个或多个导管，并且所述膜泵是可控的 作为聚合反应器内反应物浓度的函数。

公开(公告)号：US20130345374A1

公开(公告)日：2013-12-26

申请号：US13917795

申请日：2013-06-14

申请人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： C08F2/01

CPC分类号： C08F110/02 ,  B01J8/0015 ,  B01J2208/00548 ,  C08F2/005 ,  C08F2/01 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/919 ,  Y10T137/85978 ,  Y10T137/86035 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08 ,  C08F2/001

摘要： A method for the copolymerization of ethylene and a C3+ olefin in a loop reactor and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ olefin and a diluent carrier liquid into a loop reactor. A catalyst system can be supplied to said loop reactor. The diluent liquid, ethylene monomer, and C3+ olefin can be circulated through said loop reactor, while copolymerizing said ethylene and C3+ olefin in the presence of said catalyst system to produce a slurry. The slurry can be diverted into a settling leg, and sequentially discharged therefrom and withdrawn from said loop reactor. An ethylene monomer co-feed can be introduced into said loop reactor at spaced locations downstream of the ethylene and diluent. The ethylene co-feed can be introduced in an amount effective to reduce the variation in the ratio of ethylene and C3+ olefin.

摘要翻译： 本文描述了环管式反应器中乙烯与C 3+烯烃的共聚方法及其形成的聚合物。 该方法通常包括将乙烯单体，C 3+烯烃和稀释剂载体液体引入环管反应器。 催化剂体系可以供应到所述环管反应器。 稀释液体，乙烯单体和C3 +烯烃可以在所述环管反应器中循环，同时在所述催化剂体系存在下共聚所述乙烯和C 3+烯烃以产生浆料。 浆料可以转移到沉降腿中，并且顺序地从其中排出并从所述环管反应器中取出。 可以在乙烯和稀释剂下游的间隔位置将乙烯单体共进料引入所述环管反应器。 可以以有效减少乙烯和C 3+烯烃的比例变化的量引入乙烯共进料。

公开(公告)号：US08492489B2

公开(公告)日：2013-07-23

申请号：US12862655

申请日：2010-08-24

申请人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  André Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  André Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： C08F2/12 ,  B01J19/18

CPC分类号： C08F110/02 ,  B01J8/0015 ,  B01J2208/00548 ,  C08F2/005 ,  C08F2/01 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/919 ,  Y10T137/85978 ,  Y10T137/86035 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08 ,  C08F2/001

摘要： A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system comprising at least one loop reactor; supplying at least one polymerization catalyst system to said reactor system; circulating said diluent liquid, ethylene monomer, and alpha olefin copolymer through said loop reactor while copolymerizing said ethylene and said alpha olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particles in said diluent carrier liquid; diverting the flow of said slurry through said loop reactor into at least one settling leg connected to the loop reactor and sequentially discharging the settled polymer slurry from said at least one settling leg to withdraw said polymer slurry from said reactor system; and introducing an ethylene monomer co-feed into said loop reactor at least two spaced locations downstream of the point of introduction of ethylene comonomer and diluent in subparagraph a), said ethylene co-feed being introduced in an amount effective to reduce the variation in the ratio of ethylene monomer and comonomer within said loop reactor.

摘要翻译： 本文描述了环管反应器系统中乙烯与C 3+烯烃共聚物共聚合的方法及由其形成的聚合物。 该方法通常包括将乙烯单体，C 3+α-烯烃共聚单体和稀释剂载体液体引入到包含至少一个环管反应器的反应器系统中; 向所述反应器系统供应至少一种聚合催化剂体系; 在所述催化剂体系的存在下使所述乙烯和所述α-烯烃单体共聚合，从而通过所述环管反应器循环所述稀释液体，乙烯单体和α-烯烃共聚物，以在所述稀释剂载体液体中产生聚合物绒毛颗粒的浆料; 将所述浆料的流动通过所述环管反应器转移到连接到环管反应器的至少一个沉降腿中，并且从所述至少一个沉降腿顺序排出沉降的聚合物浆料以从所述反应器系统中抽出所述聚合物浆料; 并且在乙烯共聚单体和稀释剂在a）部分引入点下游的至少两个间隔位置处将乙烯单体共进料引入所述环管反应器中，所述乙烯共进料以有效减少 乙烯单体和共聚单体在所述环管反应器内的比例。

公开(公告)号：US20120053304A1

公开(公告)日：2012-03-01

申请号：US12862655

申请日：2010-08-24

申请人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  André Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  André Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： C08F2/38

CPC分类号： C08F110/02 ,  B01J8/0015 ,  B01J2208/00548 ,  C08F2/005 ,  C08F2/01 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/919 ,  Y10T137/85978 ,  Y10T137/86035 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08 ,  C08F2/001

摘要： A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system comprising at least one loop reactor; supplying at least one polymerization catalyst system to said reactor system; circulating said diluent liquid, ethylene monomer, and alpha olefin copolymer through said loop reactor while copolymerizing said ethylene and said alpha olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particles in said diluent carrier liquid; diverting the flow of said slurry through said loop reactor into at least one settling leg connected to the loop reactor and sequentially discharging the settled polymer slurry from said at least one settling leg to withdraw said polymer slurry from said reactor system; and introducing an ethylene monomer co-feed into said loop reactor at least two spaced locations downstream of the point of introduction of ethylene comonomer and diluent in subparagraph a), said ethylene co-feed being introduced in an amount effective to reduce the variation in the ratio of ethylene monomer and comonomer within said loop reactor.

摘要翻译： 本文描述了环管反应器系统中乙烯与C 3+烯烃共聚物共聚合的方法及由其形成的聚合物。 该方法通常包括将乙烯单体，C 3+α-烯烃共聚单体和稀释剂载体液体引入到包含至少一个环管反应器的反应器系统中; 向所述反应器系统供应至少一种聚合催化剂体系; 在所述催化剂体系的存在下使所述乙烯和所述α-烯烃单体共聚合，从而通过所述环管反应器循环所述稀释液体，乙烯单体和α-烯烃共聚物，以在所述稀释剂载体液体中产生聚合物绒毛颗粒的浆料; 将所述浆料的流动通过所述环管反应器转移到连接到环管反应器的至少一个沉降腿中，并且从所述至少一个沉降腿顺序排出沉降的聚合物浆料以从所述反应器系统中抽出所述聚合物浆料; 并且在乙烯共聚单体和稀释剂在a）部分引入点下游的至少两个间隔位置将乙烯单体共进料引入所述环管反应器中，所述乙烯共进料以有效减少 乙烯单体和共聚单体在所述环管反应器内的比例。

公开(公告)号：US20050272891A1

公开(公告)日：2005-12-08

申请号：US11057715

申请日：2005-02-14

申请人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Auwera ,  Frans Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Auwera ,  Frans Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： B01J8/00 ,  B01J8/20 ,  B01J19/18 ,  C08F2/00 ,  C08F10/00 ,  C08F210/16 ,  G05B1/00 ,  G05D1/00 ,  G05D11/13

CPC分类号： B01J8/20 ,  B01J8/0035 ,  B01J19/1837 ,  B01J2208/00548 ,  B01J2208/00752 ,  C08F10/00 ,  C08F210/16 ,  G05D11/132 ,  C08F2/01 ,  C08F2/14 ,  C08F2/06 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/04 ,  C08F2500/23

摘要： The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.

摘要翻译： 本发明涉及一种聚合烯烃的装置和方法。 一个实施方案包括在催化剂存在下在第一环管反应器中聚合至少一种单体以产生第一聚烯烃级分。 将第一聚烯烃部分的一部分转移到与第一回路反应器串联连接的第二回路反应器。 该方法还包括在催化剂存在下在第二环管反应器中聚合至少一种单体，以产生除第一聚烯烃级分之外的第二聚烯烃级分。 第一和第二聚烯烃级分的组合可产生具有双峰分子量分布的聚合物树脂绒毛。

公开(公告)号：US07902306B2

公开(公告)日：2011-03-08

申请号：US12605614

申请日：2009-10-26

申请人： Giacomo Conti

发明人： Giacomo Conti

IPC分类号： C08F2/00 ,  G05D16/00 ,  G01N7/00

CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2400/02 ,  C08F2/00 ,  C08F210/14

摘要： Methods for polymerization of an olefin monomer and polymers formed therefrom are described herein. The methods generally include introducing an olefin monomer and a diluent carrier liquid into a polymerization reactor, supplying at least one polymerization catalyst system to said polymerization reactor, circulating said diluent liquid in said olefin monomer within said reactor while polymerizing said olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particle in said diluent carrier liquid, recovering polymer particles from said polymerization reactor, initiating a localized pressure drop in said reactor to produce a pressure wave in which the pressure varies with time, measuring said pressure wave and characterizing said pressure wave as either a hydraulic pressure curve or a non-hydraulic pressure curve, which is characteristic of a gas being present in said slurry and in response to the characteristic of said pressure curve as being a non-hydraulic pressure curve, reducing the olefin monomer concentration in said reactor.

摘要翻译： 本文描述了烯烃单体和由其形成的聚合物的聚合方法。 所述方法通常包括将烯烃单体和稀释剂载体液体引入聚合反应器，向所述聚合反应器供应至少一种聚合催化剂体系，在所述反应器内循环所述烯烃单体中的稀释液体，同时在所述烯烃单体存在下聚合所述烯烃单体 所述催化剂体系在所述稀释剂载体液体中产生聚合物绒毛颗粒的浆料，从所述聚合反应器中回收聚合物颗粒，在所述反应器中引发局部压降，产生压力随时间变化的压力波，测量所述压力波 并且将所述压力波表征为作为存在于所述浆料中的气体的特征的液压曲线或非液压曲线，并且响应于作为非液压压力曲线的所述压力曲线的特性，减小 所述反应器中的烯烃单体浓度。

公开(公告)号：US20070060723A1

公开(公告)日：2007-03-15

申请号：US11499042

申请日：2006-08-01

申请人： Giacomo Conti

发明人： Giacomo Conti

IPC分类号： C08F2/00

CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2400/02 ,  C08F2/00 ,  C08F210/14

摘要： Provided is an apparatus for polymerising an olefin monomer, which apparatus comprises the following: (a) a reactor for polymerising the olefin monomer; (b) a means for measuring the presence of gas in the reactor; and (c) a means for controlling the concentration of olefin monomer in the reactor; wherein, the means for measuring the presence of gas in the reactor is a means capable of measuring a pressure curve in the reactor to determine whether the pressure curve is characteristic of a hydraulic system or a non-hydraulic system.

摘要翻译： 提供了一种用于聚合烯烃单体的装置，该装置包括以下步骤：（a）用于聚合烯烃单体的反应器; （b）测量反应器中气体的存在的装置; 和（c）控制反应器中烯烃单体浓度的方法; 其中，用于测量反应器中气体存在的装置是能够测量反应器中的压力曲线以确定压力曲线是液压系统还是非液压系统的特征的装置。

公开(公告)号：US20100144982A1

公开(公告)日：2010-06-10

申请号：US12605614

申请日：2009-10-26

申请人： Giacomo Conti

发明人： Giacomo Conti

IPC分类号： C08F2/04

CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2400/02 ,  C08F2/00 ,  C08F210/14

摘要： Methods for polymerization of an olefin monomer and polymers formed therefrom are described herein. The methods generally include introducing an olefin monomer and a diluent carrier liquid into a polymerization reactor, supplying at least one polymerization catalyst system to said polymerization reactor circulating said diluent liquid in said olefin monomer within said reactor while polymerizing said olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particle in said diluent carrier liquid, recovering polymer particles from said polymerization reactor, initiating a localized pressure drop in said reactor to produce a pressure wave in which the pressure varies with time, measuring said pressure wave and characterizing said pressure wave as either a hydraulic pressure curve or a non-hydraulic pressure curve which is characteristic of a gas being present in said slurry and in response to the characteristic of said pressure curve as being a non-hydraulic pressure curve reducing the olefin monomer concentration in said reactor.

摘要翻译： 本文描述了烯烃单体和由其形成的聚合物的聚合方法。 所述方法通常包括将烯烃单体和稀释剂载体液体引入聚合反应器中，在所述聚合反应器中向所述聚合反应器供应所述聚合反应器，所述聚合反应器在所述反应器中循环所述烯烃单体中的稀释液体，同时在所述烯烃单体存在下聚合所述烯烃单体 催化剂体系以在所述稀释剂载体液体中产生聚合物绒毛颗粒的浆料，从所述聚合反应器回收聚合物颗粒，引发所述反应器中的局部压降，产生压力随时间变化的压力波，测量所述压力波， 将所述压力波表征为作为存在于所述浆料中的气体的特征的液压曲线或非液压曲线，并且响应于所述压力曲线的特性作为减少烯烃单体的非液压压力曲线 浓度在所述反应器中。