Olefin Polymerization Process in the Presence of an Anti-Fouling Agent
    4.
    发明申请
    Olefin Polymerization Process in the Presence of an Anti-Fouling Agent 失效
    抗结垢剂存在下的烯烃聚合方法

    公开(公告)号:US20080119622A1

    公开(公告)日:2008-05-22

    申请号:US10587109

    申请日:2005-02-08

    IPC分类号: C08F2/00

    摘要: An olefin polymerisation process carried out in the presence of an anti-fouling agent and a chromium-type catalyst or Ziegler Natta catalyst; characterised in that the anti-fouling agent comprises an anti-fouling polymer having an average molecular weight (Mw) of greater than 1000 daltons and containing: (1) one or more blocks —(CH2—CH2—O)k— where each k is in the range from 1 to 50; and (2) one or more blocks —(CH2—CH(R)—(O)n where R comprises an alkyl group having from 1 to 6 carbon atoms and each n is in the range from 1 to 50, and terminated by a R′ and a R″ end groups, wherein R′ is OH or an alkoxy having from 1 to 6 carbon atoms and R″ is H or an alkyl having from 1 to 6 carbon atoms.

    摘要翻译: 烯烃聚合方法在防结垢剂和铬型催化剂或齐格勒纳塔催化剂存在下进行; 其特征在于防结垢剂包含平均分子量(Mw)大于1000道尔顿的防污聚合物,其含有:(1)一个或多个嵌段 - (CH 2 CH 2 -CH 其中每个k在1至50的范围内; (2)一个或多个嵌段 - (CH 2 CH 2) - (O)n N,其中R包括具有1至6个碳原子的烷基和 每个n在1至50的范围内,并由R'和R“端基封端,其中R'是OH或具有1至6个碳原子的烷氧基,R”是H或具有 1至6个碳原子。

    Polyolefin production
    6.
    发明授权
    Polyolefin production 失效
    聚烯烃生产

    公开(公告)号:US06407273B1

    公开(公告)日:2002-06-18

    申请号:US09459836

    申请日:1999-12-13

    IPC分类号: C07F1700

    摘要: A metallocene compound having the general formula: CpAXMQ1Q2Cp′A′X′M′Q1′Q2′ wherein Cp and Cp′ are each independently a substituted or unsubstituted cyclopentadienyl moiety; M and M′ are each independently a metal chosen from Group IV B transition metals and vanadium, and coordinate to Cp and Cp′ respectively; X and X′ are each independently a substituted or unsubstituted Group VA or VIA heteroatom and coordinate to M and M′ respectively; A and A′ are bridging groups between Cp and X and between Cp′ and X′ respectively and are independently chosen from —SiR′2—O—SiR′2—, —SinR′m—, —CnR′m— and —CR′2—SiR′2—CR′2—SiR′2—, in which each R′ is independently H or hydrocarbyl having 1 to 20 carbon atoms, n is an integer in the range 1 to 4 and m=2n; each Q1, Q2 and Q1′ and Q2′ is independently a coordinating group which is hydrogen, halogen or hydrocarbyl having 1 to 20 carbon atoms and each of Q1 and Q1′ is coordinated to both M and M′.

    摘要翻译: 具有以下通式的茂金属化合物:CpAXMQ1Q2Cp'A'X'M'Q1'Q2'其中Cp和Cp'各自独立地为取代或未取代的环戊二烯基部分; M和M'各自独立地选自ⅣB族过渡金属和钒,分别与Cp和Cp'配位; X和X'各自独立地为取代或未取代的基团VA或VIA杂原子,分别与M和M'配位; A和A'分别是Cp和X之间以及Cp'和X'之间的桥连基团,独立地选自-SiR'2-O-SiR'2-,-SinR'm-,-CnR'm-和-CR '2-SiR'2-CR'2-SiR'2-,其中每个R'独立地为H或具有1至20个碳原子的烃基,n为1至4的整数,m = 2n; 每个Q1,Q2和Q1'和Q2'独立地是配位基团,其是氢,卤素或具有1至20个碳原子的烃基,并且Q1和Q1'中的每一个与M和M'配位。

    Olefin polymerization process in the presence of an anti-fouling agent
    9.
    发明授权
    Olefin polymerization process in the presence of an anti-fouling agent 失效
    烯烃聚合过程中存在防污垢剂

    公开(公告)号:US07470757B2

    公开(公告)日:2008-12-30

    申请号:US10587109

    申请日:2005-02-08

    IPC分类号: C08F4/69 C08F2/00 C08F10/02

    摘要: An olefin polymerisation process carried out in the presence of an anti-fouling agent and a chromium-type catalyst or Ziegler Natta catalyst; characterised in that the anti-fouling agent comprises an anti-fouling polymer having an average molecular weight (Mw) of greater than 1000 daltons and containing: (1) one or more blocks —(CH2—CH2—O)k— where each k is in the range from 1 to 50; and (2) one or more blocks —(CH2—CH(R)—(O)n− where R comprises an alkyl group having from 1 to 6 carbon atoms and each n is in the range from 1 to 50, and terminated by a R′ and a R″ end groups, wherein R′ is OH or an alkoxy having from 1 to 6 carbon atoms and R″ is H or an alkyl having from 1 to 6 carbon atoms.

    摘要翻译: 烯烃聚合方法在防结垢剂和铬型催化剂或齐格勒纳塔催化剂存在下进行; 其特征在于防污剂包含平均分子量(Mw)大于1000道尔顿的防污聚合物,其含有:(1)一个或多个嵌段 - (CH 2 -CH 2 -O)k - ,其中每个k 在1到50之间; 和(2)一个或多个嵌段 - (CH 2 -CH(R) - (O)n - ,其中R包含具有1至6个碳原子的烷基,并且每个n在1至50的范围内,并且由 R'和R“末端基团,其中R'是OH或具有1至6个碳原子的烷氧基,R”是H或具有1至6个碳原子的烷基。