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    Production of Para-Xylene
    3.
    发明申请
    Production of Para-Xylene 有权
    对二甲苯的生产

    公开(公告)号：US20120316375A1

    公开(公告)日：2012-12-13

    申请号：US13487651

    申请日：2012-06-04

    申请人： Xiaobo Zheng ,  Mark P. Hagemeister ,  Timothy P. Bender ,  Robert G. Tinger

    发明人： Xiaobo Zheng ,  Mark P. Hagemeister ,  Timothy P. Bender ,  Robert G. Tinger

    IPC分类号： C07C1/22 ,  B01J19/00

    CPC分类号： B01J8/18 ,  B01J8/1827 ,  B01J2219/00006 ,  C07C2/864 ,  C07C5/2729 ,  C07C7/12 ,  C07C7/14 ,  C07C7/1485 ,  C07C2523/04 ,  C07C2529/40 ,  C07C2529/65 ,  C07C15/08

    摘要： The invention is a process for producing paraxylene, benzene and/or toluene is alkylated with methanol in the presence of a catalyst under conditions effective to convert said benzene and/or toluene to xylene and produce a product stream containing water, xylene and one or more phenolic impurities. The said product stream is separated into a water-rich stream and a xylene-rich stream containing one or more phenolic impurities and at least a portion of the xylene-rich stream is contacted with an aqueous solution of a base under conditions to remove at least some of the phenolic impurities from the xylene-rich stream portion.

    摘要翻译： 本发明是在有效将所述苯和/或甲苯转化为二甲苯的条件下，在催化剂存在下用甲醇烷基化的对二甲苯，苯和/或甲苯的方法，并产生含有水，二甲苯和一种或多种 酚类杂质。 将所述产物流分离成富含水的物流和含有一种或多种酚类杂质的富含二甲苯的物流，并且至少部分富含二甲苯的物流与碱的水溶液接触，以至少除去 一些来自富含二甲苯的料流部分的酚类杂质。

    PROCESS AND APPARATUS FOR THE CONVERSION OF HYDROCARBONS
    5.
    发明申请
    PROCESS AND APPARATUS FOR THE CONVERSION OF HYDROCARBONS 有权
    转化烃类的方法和装置

    公开(公告)号：US20160115094A1

    公开(公告)日：2016-04-28

    申请号：US14872388

    申请日：2015-10-01

    申请人： Jihad M. Dakka ,  Robert G. Tinger

    发明人： Jihad M. Dakka ,  Robert G. Tinger

    IPC分类号： C07C2/86 ,  C07C51/265 ,  C07C5/27

    CPC分类号： C07C2/864 ,  C07C2/865 ,  C07C5/2702 ,  C07C5/2732 ,  C07C7/12 ,  C07C7/163 ,  C07C45/006 ,  C07C51/265 ,  C07C15/08 ,  C07C63/26 ,  C07C49/303

    摘要： A hydrocarbon conversion process is described. The process includes contacting in a reactor an inert gas with one or more catalyst compositions suitable for methylation of toluene and hydrogenation of phenol; contacting a reducing agent with the one or more catalyst compositions under conditions suitable for reducing metal oxide content of the catalyst composition; contacting at least part of toluene and/or benzene-containing with a oxygenate in the presence of the one or more catalyst compositions and under conditions effective to convert toluene to xylenes and produce a reactor effluent stream comprising para-xylene and having a lower concentration of phenol than the toluene-containing stream; separating at least one para-xylene-enriched stream from the reactor effluent stream; and separating from the at least one para-xylene enriched stream at least one toluene-enriched stream and at least one para-xylene-product stream. An apparatus for carrying out such a process is also described.

    摘要翻译： 描述烃转化方法。 该方法包括在反应器中使惰性气体与一种或多种适用于甲苯甲苯化和苯酚氢化的催化剂组合物接触; 在适于降低催化剂组合物的金属氧化物含量的条件下使还原剂与一种或多种催化剂组合物接触; 在一种或多种催化剂组合物的存在下和在有效将甲苯转化为二甲苯的条件下，使至少部分甲苯和/或苯与含氧化合物接触，并产生包含对二甲苯并且具有较低浓度的 苯酚比含甲苯流; 从反应器流出物流中分离出至少一种富含对二甲苯的物流; 以及从所述至少一种对二甲苯富集流中分离出至少一种富甲苯流和至少一种对二甲苯产物流。 还描述了用于执行这种处理的装置。

    Fluid-bed aromatics alkylation with staged injection of alkylating agents
    6.
    发明授权
    Fluid-bed aromatics alkylation with staged injection of alkylating agents 有权
    流化床芳族化合物烷基化，分期注入烷基化剂

    公开(公告)号：US06642426B1

    公开(公告)日：2003-11-04

    申请号：US09166188

    申请日：1998-10-05

    申请人： David L. Johnson ,  Robert G. Tinger ,  Robert A. Ware ,  Sergei Yurchak

    发明人： David L. Johnson ,  Robert G. Tinger ,  Robert A. Ware ,  Sergei Yurchak

    IPC分类号： C07C15067

    CPC分类号： C07C2/864 ,  C07C15/08

    摘要： A system and process for producing xylene and other alkylated aromatics includes one or more fluidized bed reaction zones that provide contact between the reactants (i.e., an aromatic reactant and an alkylating reagent). Improved conversion and selectivity is realized when the alkylating reagent is stagewise injected into the fluidized bed at one or more locations downstream from the location of aromatic reactant introduction into the fluidized bed. Preferably, the alkylating reagent is introduced at a plurality of locations along the axial direction of the fluidized bed reaction zone, or at plural locations between a plurality of different fluidized bed reaction zones.

    摘要翻译： 用于生产二甲苯和其它烷基化芳族化合物的体系和方法包括提供反应物（即芳族反应物和烷基化试剂）之间的接触的一个或多个流化床反应区。 当将烷基化试剂在芳族反应物引入流化床的位置下游的一个或多个位置分阶段注入流化床时，实现了改进的转化率和选择性。 优选地，烷基化试剂沿着流化床反应区的轴向的多个位置或多个不同的流化床反应区之间的多个位置引入。