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    Fluid-bed aromatics alkylation with staged injection of alkylating agents
    2.
    发明授权
    Fluid-bed aromatics alkylation with staged injection of alkylating agents 有权
    流化床芳族化合物烷基化，分期注入烷基化剂

    公开(公告)号：US06642426B1

    公开(公告)日：2003-11-04

    申请号：US09166188

    申请日：1998-10-05

    申请人： David L. Johnson ,  Robert G. Tinger ,  Robert A. Ware ,  Sergei Yurchak

    发明人： David L. Johnson ,  Robert G. Tinger ,  Robert A. Ware ,  Sergei Yurchak

    IPC分类号： C07C15067

    CPC分类号： C07C2/864 ,  C07C15/08

    摘要： A system and process for producing xylene and other alkylated aromatics includes one or more fluidized bed reaction zones that provide contact between the reactants (i.e., an aromatic reactant and an alkylating reagent). Improved conversion and selectivity is realized when the alkylating reagent is stagewise injected into the fluidized bed at one or more locations downstream from the location of aromatic reactant introduction into the fluidized bed. Preferably, the alkylating reagent is introduced at a plurality of locations along the axial direction of the fluidized bed reaction zone, or at plural locations between a plurality of different fluidized bed reaction zones.

    摘要翻译： 用于生产二甲苯和其它烷基化芳族化合物的体系和方法包括提供反应物（即芳族反应物和烷基化试剂）之间的接触的一个或多个流化床反应区。 当将烷基化试剂在芳族反应物引入流化床的位置下游的一个或多个位置分阶段注入流化床时，实现了改进的转化率和选择性。 优选地，烷基化试剂沿着流化床反应区的轴向的多个位置或多个不同的流化床反应区之间的多个位置引入。

    Catalytic production of light olefins from naphtha feed
    5.
    发明授权
    Catalytic production of light olefins from naphtha feed 失效
    从石脑油进料催化生产轻质烯烃

    公开(公告)号：US06835863B2

    公开(公告)日：2004-12-28

    申请号：US09351147

    申请日：1999-07-12

    申请人： Art W. Chester ,  Ke Liu ,  Robert A. Ware

    发明人： Art W. Chester ,  Ke Liu ,  Robert A. Ware

    IPC分类号： C07C406

    CPC分类号： C10G35/095

    摘要： A C4+ naphtha hydrocarbon feed is converted to light olefins and aromatics, by contacting the feed with a catalyst containing ZSM-5 and/or ZSM-11, a substantially inert matrix material such as silica and/or clay, having less than about 20 wt % active matrix material based on total catalyst composition, and phosphorus.

    摘要翻译： 通过使进料与含有ZSM-5和/或ZSM-11的催化剂（基本上惰性的基质材料如二氧化硅和/或粘土）接触，将C4 +石脑油进料转化为轻质烯烃和芳族化合物，其具有小于约20wt 基于总催化剂组成和磷的％活性基质材料。

    Naphtha upgrading
    6.
    发明授权
    Naphtha upgrading 失效
    石脑油升级

    公开(公告)号：US5414172A

    公开(公告)日：1995-05-09

    申请号：US184902

    申请日：1994-01-21

    申请人： Arthur A. Chin ,  Nick A. Collins ,  Mohsen N. Harandi ,  Robert T. Thomson ,  Robert A. Ware

    发明人： Arthur A. Chin ,  Nick A. Collins ,  Mohsen N. Harandi ,  Robert T. Thomson ,  Robert A. Ware

    IPC分类号： C10G59/02 ,  C07C2/66 ,  C07C4/06

    CPC分类号： C10G59/02

    摘要： A process for upgrading low octane naphthas to produce gasoline products with low levels of benzene and aromatics while retaining a high pool octane uses a paraffinic naphtha reformer feed which is dehexanized to provide a C.sub.7 + fraction which is fed to the reformer and a C.sub.6 fraction which is fed together with the C.sub.6 fraction from the reformer effluent to a catalytic upgrading step where the low octane components from the naphtha and the benzene from the reformate are converted to a low benzene, high octane gasoline by alkylation of the benzene and other aromatics present in the reformate. The process has the advantage that benzene make in the reformer is reduced by the partial by-passing of the C.sub.6 benzene precursors around the reformer; in addition, improved benzene alkylation results from the presence of additional light olefins generated by the cracking of paraffins from the paraffinic naphtha. the reaction is preferably carried out in a turbulent fluidized bed reaction zone.

    摘要翻译： 一种用于升级低辛烷值的石脑油以生产具有低含量苯和芳族化合物的汽油产品同时保留高残留辛烷值的方法使用石蜡石脑油重整器原料，该进料被脱脂以提供进料至重整器的C 7+馏分， 与来自重整器流出物的C6馏分一起进料到催化升级步骤，其中来自石脑油的低辛烷值成分和来自重整产物的苯通过苯和其它芳族化合物的烷基化转化为低苯，高辛烷值汽油 重组。 该方法的优点是在重整器周围的C6苯前体的部分旁路减少了重整器中的苯; 此外，改进的苯烷基化是由于由链烷烃石脑油裂解石蜡产生的另外的轻质烯烃的存在。 该反应优选在湍流流化床反应区中进行。

    Olefin conversion catalyst regeneration
    7.
    发明授权
    Olefin conversion catalyst regeneration 失效
    烯烃转化催化剂再生

    公开(公告)号：US5405814A

    公开(公告)日：1995-04-11

    申请号：US72379

    申请日：1993-06-07

    申请人： James H. Beech, Jr. ,  Weldon K. Bell ,  W. Thomas Mo ,  Hye Kyung C. Timken ,  Robert A. Ware

    发明人： James H. Beech, Jr. ,  Weldon K. Bell ,  W. Thomas Mo ,  Hye Kyung C. Timken ,  Robert A. Ware

    IPC分类号： C07C41/05 ,  B01J29/38 ,  B01J38/06 ,  B01J38/10

    CPC分类号： C07C41/05 ,  C07C41/09 ,  Y02P20/584

    摘要： An olefin hydration catalyst is regenerated with a non-oxidizing light gas, such as hydrogen. Light olefins, especially propylene, are converted to a mixture of alcohol(s), such as isopropanol (IPA) and ether(s), such as diisopropylether (DIPE) by contacting a feed containing the olefin with water and/or alcohol with the olefin hydration catalyst. Regeneration conditions include temperatures of from about 150.degree. C. to about 550.degree. C., pressures below about 1000 psig (6900 kPa). Lower pressures of regeneration unexpectedly demonstrated more effective catalyst regeneration through greater coke removal.

    摘要翻译： 烯烃水合催化剂用非氧化性轻质气体如氢气再生。 通过使含有烯烃的进料与水和/或醇接触，将轻质烯烃，特别是丙烯转化成醇，如异丙醇（IPA）和醚，如二异丙基醚（DIPE））的混合物， 烯烃水合催化剂。 再生条件包括约150℃至约550℃的温度，低于约1000psig（6900kPa）的压力。 更低的再生压力意外地通过更大的焦炭去除表明更有效的催化剂再生。

    Catalytic hydrodesulfurization
    8.
    发明授权
    Catalytic hydrodesulfurization 失效
    催化加氢脱硫

    公开(公告)号：US5011593A

    公开(公告)日：1991-04-30

    申请号：US442870

    申请日：1989-11-20

    申请人： Robert A. Ware ,  Stephen S. Wong

    发明人： Robert A. Ware ,  Stephen S. Wong

    IPC分类号： B01J29/78 ,  C10G45/12 ,  C10G45/54 ,  F02B3/06

    CPC分类号： C10G45/12 ,  B01J29/7815 ,  B01J2229/26 ,  B01J2229/42 ,  F02B3/06

    摘要： A hydrodesulfurization process for catalytically hydrosulfurizing highly aromatic feeds, especially catalytically cracked feeds such as light cycle oils from catalytic cracking processes and aromatic extracts, employs a hydrodesulfurization catalyst containing zeolite beta. The zeolite beta based catalyst is more effective for effecting desulfurization than comparable amorphous catalysts or catalysts based on other large pore size zeolite and is capable of achieving a high degree of desulfurization at relatively low levels of conversion. The hydrodesulfurization catalyst comprises a transition metal hydrogenation component, preferably Co/Mo, on zeolite beta together with an inert matrix. The zeolite beta based catalyst may be mixed with amorphous catalyst such as Co/Mo/alumina. The low sulfur products are useful as blending components for road diesel fuels and other distillate fuels.

    摘要翻译： 用于催化加氢硫化高芳族化合物进料，特别是催化裂化进料如来自催化裂化方法的轻质循环油和芳族萃取物的加氢脱硫方法使用含有β沸石的加氢脱硫催化剂。 基于沸石β的催化剂与基于其它大孔径沸石的可比无定形催化剂或催化剂相比，更有效地实现脱硫，并且能够在相当低的转化水平下实现高度脱硫。 加氢脱硫催化剂在沸石β上与惰性基质一起包含过渡金属氢化组分，优选Co / Mo。 沸石β型催化剂可与无定形催化剂如Co / Mo /氧化铝混合。 低硫产品可用作道路柴油燃料和其他馏出燃料的混合组分。

    Process configuration for producing high viscosity lubricating oils
    9.
    发明授权
    Process configuration for producing high viscosity lubricating oils 失效
    生产高粘度润滑油的工艺配置

    公开(公告)号：US4913794A

    公开(公告)日：1990-04-03

    申请号：US379511

    申请日：1989-07-13

    申请人： Quang N. Le ,  Robert A. Ware ,  Stephen S. Wong

    发明人： Quang N. Le ,  Robert A. Ware ,  Stephen S. Wong

    IPC分类号： C10G27/12 ,  C10G71/00

    CPC分类号： C10G71/00 ,  C10G2400/10

    摘要： A process is disclosed for improving the Viscosity Index of a hydrocarbon lubricating oil comprising the steps of providing a flow reactor having separate first and second inlet ports for the separate co-injection of lubricating oil and an organic peroxide, charging said lubricating oil and said organic peroxide of said flow reactor through said first and second inlet ports respectively, controlling the relative flowrates of said lubricating oil and organic peroxide reactants together with the total volumetric flowrate through said flow reactor to maintain a flow regime which favors diffusional mixing between said organic peroxide and said lubricating oil, and maintaining said organic peroxide and said lubricating oil under conversion conditions including temperatures of between about 50.degree. and 300.degree. C. and pressure sufficient to maintain said lubricating oil and said organic peroxide substantially in the liquid phase. Controlling the flow regime to favor diffusional rather than convective mixing between the lubricating oil and the organic peroxide has surprisingly been found to markedly enhance Viscosity Index improvement.

    摘要翻译： 公开了一种用于改进烃类润滑油的粘度指数的方法，该方法包括以下步骤：提供具有单独的第一和第二入口的流动反应器，用于单独共同注入润滑油和有机过氧化物，将所述润滑油和所述有机物 所述流动反应器分别通过所述第一和第二入口过氧化物，控制所述润滑油和有机过氧化物反应物的相对流速以及通过所述流动反应器的总体积流量，以保持有利于所述有机过氧化物和 所述润滑油，并且在包括约50℃至300℃的温度的转化条件下保持所述有机过氧化物和所述润滑油以及足以使所述润滑油和所述有机过氧化物基本上处于液相的压力。 令人惊讶地发现控制流动状态以有利于润滑油和有机过氧化物之间的扩散而不是对流混合，显着提高了粘度指数的改善。