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公开(公告)号：US3676418A
公开(公告)日：1972-07-11
申请号：US3676418D
申请日：1969-07-16
发明人： TASHIRO KIJURO , YOKOYAMA MASUZO
CPC分类号： C08F10/00 , Y10S526/907 , C08F4/636 , C08F4/6378
摘要： A Ziegler-type polymerization catalyst comprising a first catalyst component containing a transition metal compound and a second catalyst component containing an organometallic compound, which first catalyst component contains a silicon compound. Preparation of the first catalyst component and production of olefin polymers are also disclosed.
摘要翻译： 一种齐格勒型聚合催化剂，其包含含有过渡金属化合物的第一催化剂组分和含有有机金属化合物的第二催化剂组分，所述第一催化剂组分含有硅化合物。 还公开了第一催化剂组分的制备和烯烃聚合物的制备。
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公开(公告)号：US3875126A
公开(公告)日：1975-04-01
申请号：US32308073
申请日：1973-01-12
摘要： An Alpha -olefin is polymerized with another monomer through the use of a catalyst system prepared by combining: (I) a solid composition prepared by milling titanium trichloride in the presence of modifier, which is a halohydrocarbon, a silicon compound represented by the general formula SiXm'' Y4 m'' , where X'' is a halogen, Y'' is hydrogen, an alkyl group, an aryl group, an aralkyl group, an alkaryl group, or an alkoxyl group, and m is zero or the integer 1, 2, 3, or 4 (exclusive of SiH4), or a halogen compound of a specific metal; (II) an organoaluminum compound; and (III) a cycloheptatriene compound, including salts of tropylium.
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公开(公告)号：US3457244A
公开(公告)日：1969-07-22
申请号：US3457244D
申请日：1965-04-19
IPC分类号： C08F210/00 , C08F1/42 , C08F15/04 , C08F17/00
CPC分类号： C08F210/00
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公开(公告)号：US3629368A
公开(公告)日：1971-12-21
申请号：US3629368D
申请日：1969-08-18
IPC分类号： C08F2/00 , C08F297/08 , C08F15/04 , C08F1/42
CPC分类号： C08F297/083
摘要： MODIFIED PROPYLENE POLYMER IS PROVIDED HAVING IMPROVED IMPACT RESISTACE AND TOUGHNESS AT LOW TEMPERATURE AS WELL AS HAVING A HIGH SOFTENING POINT AND STIFFNESS. THE MODIFIED PROPYLENE POLYMER IS PRODUCED BY A PROCESS OF POLYMERIZING A MEMBER OF THE GROUP CONSISTING OF PROPYLENE AND ETHYLENE AND SUBSEQUENTLY POLYMERIZING CONTINUOUSLY IN THE SAME SYSTEM THE OTHER MEMBER OF SAID GROUP, SAID POLYMERIZATION BEING EFFECTED AT A TEMPERATURE OF 30-100*C., AT A PRESSURE OF FROM 1-10 ATMOSPHERS AND UTILIZING AS CATALYSTS DIALKYLALUMINUM MONOHALIDE AND TITANIUM TRICHLORIDE, THE POLYMERIZATION OF ETHYLENE BEING EFFECTED IN THE PRESENCE OF AN AVERAGE AMOUNT OF FROM 0-25% BY VOLUME OF PROPYLENE AND THE AMOUNTS OF ETHYLENE AND PROPYLENE FED TO THE REACTION SYSTEM BEING ADJUSTED SO THAT THE RESULTING MODIFIED PROPYLENE POLYMER CONTAINS FROM 5 TO 40% BY WEIGHT ETHYLENE.
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5.发明授权Process for producing crystalline olefin polymers and catalyst compositions therefor 失效生产结晶烯烃聚合物及其催化剂组合物的方法
公开(公告)号：US3622552A
公开(公告)日：1971-11-23
申请号：US3622552D
申请日：1969-10-03
发明人： FUKUDA JUNICHI , TASHIRO KIJURO , KOGA MICHIO , HORI TOSHIO , OGAWA HEIICHIRO , TAKESHITA ELLICHI , AKAIWA KATSUO
CPC分类号： C08F10/00 , C08F4/6094
摘要： Polymerization of olefins and catalyst therefor, said catalyst comprising polymerizing at least one member selected from the group consisting of ethylene, propylene, butene-1 and styrene in the presence of a catalyst composition comprising (1) an organoaluminum compound having the formula, AIR2X wherein R represents a hydrocarbon residue selected from the group consisting of alkyl, aryl, aralkyl, alkaryl and cycloalkyl groups and X represents a halogen atoms selected from the group consisting of chlorine, bromine and iodine, (2) a halide of a transition metal of Groups IV, V and VI of the Periodic Table of the Elements, and (3) an aliphatic carboxylic ester having a side chain on a carbon atom in a Alpha -position to the ester carbon atom, the molar proportion of said organoaluminum compound, said halide of transition metal and said aliphatic carboxylic ester being 10-0.5 : 1 : 0.01-1.
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