公开(公告)号：US20240067763A1

公开(公告)日：2024-02-29

申请号：US18022478

申请日：2021-08-26

Applicant: MITSUI CHEMICALS, INC.

Inventor： Takashi KIMURA ,  Makoto ISOGAI ,  Yasushi NAKAYAMA ,  Kenji MICHIUE ,  Takashi JINNAI ,  Wataru YAMADA ,  Shotaro TAKANO ,  Hiroshi TERAO ,  Takaaki YANO ,  Yoshiyuki TOTANI ,  Sunil Krzysztof MOORTHI ,  Takashi NAKANO

IPC: C08F4/16 ,  C08F10/06

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F2410/04

Abstract: The solid titanium catalyst component (I) of the present invention contains titanium, magnesium, halogen, and a cyclic multiple-ester-group-containing compound (a) represented by the following formula (1).

公开(公告)号：US20240067597A1

公开(公告)日：2024-02-29

申请号：US18268090

申请日：2021-12-21

Applicant: MITSUI CHEMICALS, INC.

Inventor： Takaaki YANO ,  Wataru YAMADA ,  Shotaro TAKANO ,  Takashi KIMURA ,  Makoto ISOGAI ,  Takashi NAKANO ,  Sunil Krzysztof MOORTHI

IPC: C07C69/78 ,  C07C35/31 ,  C07C49/553 ,  C07C49/573 ,  C07C49/82 ,  C07C69/76 ,  C07C69/92 ,  C07D317/70

CPC classification number: C07C69/78 ,  C07C35/31 ,  C07C49/553 ,  C07C49/573 ,  C07C49/82 ,  C07C69/76 ,  C07C69/92 ,  C07D317/70 ,  C07C2602/10 ,  C07C2602/44

Abstract: [Problem] To provide an internal donor component capable of producing, with high productivity, a propylene polymer having extremely high stereoregularity when used mainly as a solid titanium catalyst component.
[Solution] A polyol ester compound having a specific polycyclic structure represented by formula (1). This ester compound is characterized in that sites including a C-R3 structure and a C-R4 structure satisfy a specific relationship.

公开(公告)号：US20190062470A1

公开(公告)日：2019-02-28

申请号：US16171192

申请日：2018-10-25

Applicant: MITSUI CHEMICALS, INC.

Inventor： Kou TSURUGI ,  Shiori HANADA ,  Atsushi SHIBAHARA ,  Kazumori KAWAMURA ,  Fumiaki NISHINO ,  Yasuyuki HARADA ,  Wataru YAMADA ,  Akiko MATSUMOTO ,  Isao HARA ,  Tatsuya NAKAMURA ,  Toshihiro MUROTO

IPC: C08F10/02 ,  C08F4/6592 ,  C08F110/02 ,  C08G79/10 ,  C08F4/02

Abstract: An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).

公开(公告)号：US20240067764A1

公开(公告)日：2024-02-29

申请号：US18268074

申请日：2021-12-21

Applicant: MITSUI CHEMICALS, INC.

Inventor： Takashi KIMURA ,  Makoto ISOGAI ,  Yasushi NAKAYAMA ,  Kenji MICHIUE ,  Takashi JINNAI ,  Wataru YAMADA ,  Shotaro TAKANO ,  Hiroshi TERAO ,  Takaaki YANO ,  Yoshiyuki TOTANI ,  Sunil Krzysztof MOORTHI ,  Takashi NAKANO

IPC: C08F4/646 ,  C08F4/649 ,  C08F4/651 ,  C08F4/654 ,  C08F10/06

CPC classification number: C08F4/6465 ,  C08F4/6494 ,  C08F4/651 ,  C08F4/654 ,  C08F10/06

Abstract: A solid titanium catalyst component (I) for olefin polymer production contains titanium, magnesium, halogen, and a cyclic multiple-ester-group-containing compound (a) represented by the formula (1). Preferably, a propylene polymer that is obtained by the olefin polymerization method and has specific thermal properties as determined primarily by differential scanning calorimetry (DSC).

公开(公告)号：US20170240664A1

公开(公告)日：2017-08-24

申请号：US15588358

申请日：2017-05-05

Applicant: MITSUI CHEMICALS, INC.

Inventor： Kou TSURUGI ,  Shiori HANADA ,  Atsushi SHIBAHARA ,  Kazumori KAWAMURA ,  Fumiaki NISHINO ,  Yasuyuki HARADA ,  Wataru YAMADA ,  Akiko MATSUMOTO ,  Isao HARA ,  Tatsuya NAKAMURA ,  Toshihiro MUROTO

IPC: C08F10/02

CPC classification number: C08F10/02 ,  C08F4/02 ,  C08F4/027 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65922 ,  C08F110/02 ,  C08G79/10 ,  C08F210/16 ,  C08F4/65927

Abstract: An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).

公开(公告)号：US20150376306A1

公开(公告)日：2015-12-31

申请号：US14766396

申请日：2014-02-07

Applicant: Mitsui Chemicals, Inc.

Inventor： Kou TSURUGI ,  Siori HANADA ,  Atsushi SHIBAHARA ,  Kazumori KAWAMURA ,  Fumiaki NISHINO ,  Yasuyuki HARADA ,  Wataru YAMADA ,  Akiko MATSUMOTO ,  Isao HARA ,  Tatsuya NAKAMURA ,  Toshihiro MUROTO

IPC: C08F110/02

CPC classification number: C08F10/02 ,  C08F4/02 ,  C08F4/027 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65922 ,  C08F110/02 ,  C08G79/10 ,  C08F210/16 ,  C08F4/65927

Abstract: An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).

Abstract translation: 本发明的目的是提供一种适合用作助催化剂的固体聚铝氧烷组合物和与烯烃低聚或聚合催化剂组合的催化剂载体，而不使用固体无机载体如二氧化硅。 本发明的固体聚铝氧烷组合物包括聚烷基铝氧烷和三烷基铝，并且通过特定方法（i）测量，在25℃下在正己烷中的溶解度小于0.50mol％，在25℃下在甲苯中的溶解度 通过特定方法（ii）测量的小于1.0摩尔％的C，并且相对于衍生自多烷基铝氧烷部分的烷基的总摩尔数，衍生自三烷基铝部分的烷基的摩尔分数为13摩尔％以上 和通过特定方法（iii）测量的相对于四氢呋喃-d8可溶性成分测得的来自三烷基铝部分的烷基。

公开(公告)号：US20240025838A1

公开(公告)日：2024-01-25

申请号：US18022470

申请日：2021-08-26

Applicant: MITSUI CHEMICALS, INC.

Inventor： Wataru YAMADA ,  Takaaki YANO ,  Shotaro TAKANO ,  Takashi KIMURA ,  Makoto ISOGAI ,  Takashi NAKANO ,  Sunil Krzysztof MOORTHI

IPC: C07C69/78 ,  C07D307/77 ,  C07C229/64 ,  C07C69/75 ,  C07C69/34 ,  C07D209/02 ,  C07D413/12 ,  C07D409/12

CPC classification number: C07C69/78 ,  C07D307/77 ,  C07C229/64 ,  C07D409/12 ,  C07C69/34 ,  C07D209/02 ,  C07D413/12 ,  C07C69/75

Abstract: The ester compound of the present invention is represented by the following formula (1), wherein R1 to R24 are each independently a hydrogen atom, a halogen atom, a hydrocarbon group, or a hetero atom-containing hydrocarbon group; R1 to R10, R23, and R24 may be bonded to one another to form a ring or may form a multiple bond at which adjacent substituents are directly bonded; R11 to R24 may be bonded to one another to form a ring, or adjacent substituents may be bonded to one another to form a multiple bond; at least one set in R1 to R24 is bonded to one another to form a ring structure; n2 to n5 each independently represent an integer of 0 to 2; n1 and n6 each independently represent an integer of 0 or 1; and L1 and L2 are each independently a hydrocarbon group or a hetero atom-containing hydrocarbon group.