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1.发明授权Hybrid prepreg containing carbon fibers and at least one other reinforcing fiber in specific positions within the prepreg 失效在预浸料坯内的特定位置含有碳纤维和至少一种其它增强纤维的混合预浸料
公开(公告)号：US5279879A
公开(公告)日：1994-01-18
申请号：US634839
申请日：1990-12-27
申请人： Makoto Takezawa , Makiji Miyao , Sadahisa Wada , Hiroshi Inoue
发明人： Makoto Takezawa , Makiji Miyao , Sadahisa Wada , Hiroshi Inoue
CPC分类号： B29C70/504 , B29C70/10 , B29C70/20 , A63B2049/0211 , B29C70/687 , B29L2031/06 , B29L2031/5227 , B29L2031/5245 , B29L2031/7002 , Y10S428/902 , Y10T428/24099 , Y10T428/24124 , Y10T428/24132 , Y10T428/30 , Y10T442/616 , Y10T442/618 , Y10T442/62
摘要： The present invention relates to a hybrid prepreg having reinforcing carbon fibers and foreign fibers. The carbon fibers have a diameter ranging from 5-30 microns and are unidirectionally arranged. The foreign fibers are composed either of single monofilaments having a diameter ranging from between about 50-150 microns or of strands formed by bundling together a plurality of single monofilaments having a diameter ranging from between about 5-50 microns. If strands are employed, they have a conversion diameter (D.sub.0) which is less than about 500 microns. The conversion diameter (D.sub.0) is represented by the following equation: ##EQU1## wherein n is the number of monofilaments used in forming the strand, and wherein d is the diameter of these monofilaments. Examples of foreign fibers which can be used when practicing this invention include boron fibers, metal fibers and organic fibers. These foreign fibers are spaced at fixed intervals, arranged in the same direction as the direction of the reinforcing carbon fibers, and positioned approximately at or near the center of the resulting prepreg. The prepreg prepared in accordance with the present invention also includes a thermosetting matrix resin in which the reinforcing carbon fibers and the foreign fibers are impregnated.
摘要翻译： 本发明涉及具有增强碳纤维和外来纤维的混合预浸料。 碳纤维的直径范围为5-30微米，并且是单向排列的。 外来纤维由直径范围介于约50-150微米之间的单根单丝组成，或者通过将直径范围介于约5-50微米之间的多根单丝共同组成。 如果使用线，则它们的转化直径（D0）小于约500微米。 转化直径（D0）由以下等式表示：（*化学结构*）其中n是用于形成链的单丝数，其中d是这些单丝的直径。 在实施本发明时可以使用的外来纤维的实例包括硼纤维，金属纤维和有机纤维。 这些外来纤维以固定的间隔间隔开，与增强碳纤维的方向相同的方向排列，并且大致位于所得的预浸料坯的中心附近。 根据本发明制备的预浸料还包括其中浸渍增强碳纤维和外来纤维的热固性基质树脂。
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公开(公告)号：US5512119A
公开(公告)日：1996-04-30
申请号：US127928
申请日：1993-09-27
申请人： Makoto Takezawa , Makiji Miyao , Sadahisa Wada , Hiroshi Inoue
发明人： Makoto Takezawa , Makiji Miyao , Sadahisa Wada , Hiroshi Inoue
CPC分类号： B29C70/504 , B29C70/10 , B29C70/20 , A63B2049/0211 , B29C70/687 , B29L2031/06 , B29L2031/5227 , B29L2031/5245 , B29L2031/7002 , Y10S428/902 , Y10T428/24099 , Y10T428/24124 , Y10T428/24132 , Y10T428/30 , Y10T442/616 , Y10T442/618 , Y10T442/62
摘要： The present invention relates to a hybrid prepreg having reinforcing carbon fibers and foreign fibers. The carbon fibers have a diameter ranging from 5-30 microns and are unidirectionally arranged. The foreign fibers are composed either of single monofilaments having a diameter ranging from between about 50-150 microns or of strands formed by bundling together a plurality of single monofilaments having a diameter ranging from between about 5-50 microns. If strands are employed, they have a conversion diameter (D.sub.0) which is less than about 500 microns. The conversion diameter (D.sub.0) is represented by the following equation: ##EQU1## wherein n is the number of monofilaments used in forming the strand, and wherein d is the diameter of these monofilaments. Examples of foreign fibers which can be used when practicing this invention include boron fibers, metal fibers and organic fibers. These foreign fibers are spaced at fixed intervals, arranged in the same direction as the direction of the reinforcing carbon fibers, and positioned approximately at or near the center of the resulting prepreg. The prepreg prepared in accordance with the present invention also includes a thermosetting matrix resin in which the reinforcing carbon fibers and the foreign fibers are impregnated.
摘要翻译： 本发明涉及具有增强碳纤维和外来纤维的混合预浸料。 碳纤维的直径范围为5-30微米，并且是单向排列的。 外来纤维由直径范围介于约50-150微米之间的单根单丝组成，或者通过将直径范围介于约5-50微米之间的多根单丝共同组成。 如果使用线，则它们的转化直径（D0）小于约500微米。 转化直径（D0）由以下等式表示：其中n是形成链中使用的单丝的数量，其中d是这些单丝的直径。 在实施本发明时可以使用的外来纤维的实例包括硼纤维，金属纤维和有机纤维。 这些外来纤维以固定的间隔间隔开，与增强碳纤维的方向相同的方向排列，并且大致位于所得的预浸料坯的中心附近。 根据本发明制备的预浸料还包括其中浸渍增强碳纤维和外来纤维的热固性基质树脂。
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公开(公告)号：US5397636A
公开(公告)日：1995-03-14
申请号：US986815
申请日：1992-12-08
申请人： Makiji Miyao , Osamu Watanabe , Makoto Takezawa , Hiroshi Inoue
发明人： Makiji Miyao , Osamu Watanabe , Makoto Takezawa , Hiroshi Inoue
CPC分类号： B32B27/04 , A63C11/22 , B29C70/086 , B44C5/0469 , B29L2031/5263 , Y10T428/1359 , Y10T428/1369 , Y10T428/139 , Y10T428/239 , Y10T428/24802 , Y10T428/24868 , Y10T428/24884 , Y10T428/2495
摘要： A hybrid laminated prepreg is disclosed, which comprises a resin layer, a decorative layer laminated thereon and having a pattern, and a transparent prepreg layer laminated on the decorative layer. In manufacturing a fiber reinforced composite resin material molding, the hybrid prepreg is laminated in a couple of layers on the outermost one of laminated layers of usual prepreg. Thus, it is possible to easily decorate the obtainable molding to readily provide an aesthetic sense to the appearance of the molding and also dispense with time-consuming operation of coating or the like. Further, unlike the coating or the like, it is possible to stably hold the aesthetic sense of the appearance for long time. The hybrid laminated prepreg can be suitably used for fiber reinforced composite resin material moldings, for instance such sport articles as golf club shafts, tennis rackets, ski pole shafts and fishing rods, fancy articles, briefcases such as attache cases, pipes such as bicycle frames and panels such as fair-faced wall panels.
摘要翻译： 公开了一种混合层压预浸料，其包括层压在其上并具有图案的树脂层，装饰层和层压在装饰层上的透明预浸料层。 在制造纤维增强复合树脂材料成型时，将混合预浸料层叠在通常的预浸料的层压层的最外层上的几层中。 因此，可以容易地装饰所获得的模制品，以便容易地对模制品的外观提供美学意义，并且也省去了涂层等的耗时的操作。 此外，与涂层等不同，可以长时间稳定地保持外观的美感。 混合层压预浸料可以适用于纤维增强复合树脂材料模制品，例如高尔夫球杆杆，网球拍，滑雪杆杆和钓鱼竿，花式物品，公文包如附件箱，诸如自行车架 和面板如平面墙板。
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公开(公告)号：US5188878A
公开(公告)日：1993-02-23
申请号：US876814
申请日：1992-04-29
IPC分类号： B29C70/20
CPC分类号： B29C70/20 , B29K2063/00 , B29K2309/08 , Y10S428/917 , Y10T428/24132 , Y10T428/249946 , Y10T428/31525
摘要： A flexible unidirectional glass prepreg comprising glass rovings having a thickness of 50 to 150 .mu.m and formed of glass fiber monofilaments having a diameter of 10 to 20 .mu.m and a matrix resin impregnated between the fiber monofilaments.
摘要翻译： 一种柔性单向玻璃预浸料，其包括厚度为50-150μm的玻璃粗纱，由直径为10至20μm的玻璃纤维单丝和浸渍在纤维单丝之间的基质树脂形成。
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公开(公告)号：US5387301A
公开(公告)日：1995-02-07
申请号：US157596
申请日：1993-11-29
申请人： Makiji Miyao , Makoto Takezawa
发明人： Makiji Miyao , Makoto Takezawa
IPC分类号： B05D7/24 , B29B11/16 , B29B15/10 , B29C70/50 , B29K105/06 , C08J3/24 , C08J5/24 , C09J5/02 , B29B15/08 , B29K105/08
摘要： In the prepreg manufacuturing method according to the present invention, at least one of a first and second release papers is coated with a matrix resin having a low viscosity. Reinforcing fibers are supplied in between the release papers and arranged on the matrix resin layer. Then, the reinforcing fibers are impregnated with the matrix resin by heating and pressing the release papers. After separating one of the papers, a room-temperature curing type hardener is applied onto the matrix resin layer to form a high viscosity layer on a surface layer of the matrix resin layer. Thereafter, a cover film is laid over the surface layer to make a prepreg.
摘要翻译： 在根据本发明的预浸料制造方法中，第一和第二剥离纸中的至少一种涂布有具有低粘度的基质树脂。 增强纤维被提供在隔离纸之间并且布置在基质树脂层上。 然后，通过加热和压制剥离纸，用基体树脂浸渍增强纤维。 分离纸张之后，将一种室温固化型固化剂施加到基体树脂层上，以在基体树脂层的表面层上形成高粘度层。 此后，将覆盖膜放置在表面层上以制成预浸料。
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6.发明授权
公开(公告)号：US5122417A
公开(公告)日：1992-06-16
申请号：US246127
申请日：1988-09-16
申请人： Shinkichi Murakami , Keijiro Manabe , Makiji Miyao , Mamoru Enomoto , Yuji Ishida , Hiroshi Inoue
发明人： Shinkichi Murakami , Keijiro Manabe , Makiji Miyao , Mamoru Enomoto , Yuji Ishida , Hiroshi Inoue
CPC分类号： B29D99/0003 , B29C70/207 , B29C70/525 , B29K2101/10 , B29K2101/12 , B29K2105/0809 , B29K2105/108 , Y10S428/902 , Y10T428/249943 , Y10T428/249948 , Y10T428/2925 , Y10T428/2936 , Y10T428/30
摘要： This invention relates to fiber-reinforced composite resin pultrusion products of circular and noncircular cross-sectional contours, manufactured by impregnating fiber tows or rovings with a resin, drawing them into a die, and forming them into an article of predetermined size and shape, and then curing it, and relates also to a method for manufacturing the same.
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公开(公告)号：US06808796B1
公开(公告)日：2004-10-26
申请号：US09713000
申请日：2000-11-17
IPC分类号： D04H500
CPC分类号： B29C70/504 , B29C70/202 , B29C70/226 , Y10T428/24124 , Y10T428/249921 , Y10T428/249924 , Y10T428/249945 , Y10T428/249946 , Y10T428/249947 , Y10T428/24995 , Y10T428/249952
摘要： A continuous reinforcing fiber sheet in which reinforcing fibers are arranged at an arbitrary angle to the main axis. The continuous reinforcing fiber sheet is well applicable to pultrusion forming without the risk of the reinforcing fibers being dispersed. This permits use of the continuous reinforcing fiber sheet in a long fiber-reinforced plastic structural member having remarkably improved torsional rigidity. The continuous reinforcing fiber sheet 1 has a continuous resin-penetrable support sheet 2 and a reinforcing fiber layer 3 held by the resin-penetrable support sheet 2. Long reinforcing fibers 4 in the reinforcing fiber layer 3 have substantially a certain length (F) and are arranged in the longitudinal direction of the resin-penetrable support sheet 2 at a prescribed angle (&agr;) to the longitudinal direction of the resin-penetrable support sheet 2.
摘要翻译： 一种连续增强纤维片，其中增强纤维与主轴成任意角度。 连续增强纤维片材很好地适用于拉挤成型，而不会增强纤维分散的风险。 这允许在具有显着提高的扭转刚度的长纤维增强塑料结构构件中使用连续增强纤维片。 连续的增强纤维片1具有由可树脂穿透的支撑片2保持的连续的树脂穿透性支撑片2和增强纤维层3。增强纤维层3中的长增强纤维4具有一定长度（F）和 沿树脂可穿透支撑片2的纵向方向以与树脂可穿透支撑片2的纵向方向成规定角度（α）布置。
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