摘要:
The invention relates to pre-impregnating agents for high-resistant and elastic composite fibres having 50-85 mass % textile surface components and 15-50 mass % polyaminotriazine ether containing carbamide acid ester groups. The invention also relates to methods for making the pre-impregnating agents. The pre-impregnating agents can be used for heat-protecting cloths, flameproof covers, electric insulating papers, construction parts and for vehicle equipment.
摘要:
The invention relates to products, especially moulding materials of polymers containing triazine segments and consisting of mixtures of meltable 4-18 ring oligotriazine ethers which are soluble in highly polar solvents, and in which the triazine rings are predominantly linked by alkylene diamiino groups. Said moulding materials can contain up to 50 mass % of other reactive polymers such as ethylene copolymers, maleic acid anhydride copolymers, modified maleic acid anhydride copolymers, poly(meth)acrylates, polyamides, polyester and/or polyurethanes, up to 75 mass % of filling materials and/or reinforcing fibres, and up to 2 mass % of stabilisers, UV absorbers and/or auxiliary agents. The moulding materials of polymers containing triazine segments can be processed by means of conventional fusion methods and can be used as hot-melt adhesives and for producing plates, tubes, profiles, injection moulded parts, fibres, coatings and foamed material.
摘要:
A method for curing aminoplasts, during which layers having layer thicknesses of up to 300 um or filaments and fiber fibrids having a diameter of up to 300 um, which consist of: i) 95 to 99.95% by mass of solvent-free meltable aminoplast polycondensates with molar masses ranging from 1000 to 300000; j) 5 to 0.05% by mass of curing agents, which can be activated by actinic light and which are comprised of acidifiers of the blocked sulfonic acid and/or halogen-substituted triazine derivative and/or onium salt type, and optionally; k) 1 to 20% by mass, with regard to the meltable aminoplast polycondensates, of unmodified and/or modified maleic anhydride copolymers, and/or; i) 0.1 to 5% by mass, with regard to the meltable aminoplast polycondensates, of nanoparticles. The aminoplasts are cured by irradiating them with actinic light at a temperature between the melting point of the aminoplast polycondensate and the thermoinduced decomposition temperature of the light-activatable curing agents. This method enables the production of, preferably, textile fabrics or coatings.
摘要:
Compositions for producing aminoplast products by means of melt processing consisting of: A) 95 to 99.9% by mass of solvent-free meltable polycondensates of melamine resins having molar masses ranging from 300 to 300 000; A) from 0.1 to 5% by mass of weak acids serving as thermoinducible curing agents consisting of: acidifiers of the blocked sulfonic acid type; aliphatic C4-C18 carboxylic acids; aromatic C7-C18 carboxylic acids; alkali salts or ammonium salts of phosphoric acid; C1-C12-alkyl esters or C2-C8-hydroxyalkyl esters of C7-C14 aromatic carboxylic acids or of inorganic acids; salts of melamine or of guanamines having C1-18 aliphatic carboxylic acids; anhydrides, half-esters or half-amides of C4-C20 dicarboxylic acids; half-esters or half-amides of copolymers consisting of ethylenically unsaturated C4-C20 dicarboxylic acid anhydrides and ethylenically unsaturated monomers of the C2-C20 olefin type and/or C8-C20 vinyl aromatic compounds; and/or salts of C1-C12-alkyl amines or alkanolamines having C1-C18 aliphatic, C7-C14 aromatic or alkylaromatic carboxylic acids and inorganic acids of the hydrochloric acid, sulphuric acid or phosphoric acid type, and; B) optionally up to 400% by mass of fillers and or reinforcing fibers, up to 30% by mass of additional reactive polymers of the ethylene copolymer, maleic anhyudride copolymer, modified maleic anhydride copolymer, poly(meth)acrylate, polyamide, polyester and/or polyurethane type, and up to 4% by mass, each time with regard to the polycondensates of melamine resins, of stabilizes, UV absorbers and/or auxiliary agents. These inventive compositions can be processed by means of melt processing into products such as panels, coated supporting materials, profiled pieces, pipes, injection-molded articles, fibrous products and laminates.
摘要:
The invention relates to a method for producing a compound having at least one mono substituted amino group. According to the invention, a starting substance supporting at least one amino group as reacted with a reagent supporting a first functional group and at least one other functional group in a reaction mixture. The first functional group is a hydroxyl group and the at least one other functional group is selected from hydroxyl groups, mercapto groups, carboxylic acid groups, carboxylic acid ester groups, carboxylic acid amide groups, keto groups, carbonate groups, halogens, epoxy groups and carbamate groups. If several other functional groups are present, the groups are selected independently of one another from the aforementioned class. Melamine, urea and guanamine are, in particular, reacted with glycol, glycerine and hydroxyl acetic acid derivatives.
摘要:
The invention relates to a method for producing at least one compound having at least one at least monosubstituted amino group. According to the invention, a starting substance having at least one amino group is reacted with an alcohol in a reaction mixture in the presence of ammonia.
摘要:
The invention relates to a method for producing at least one compound having at least one at least monosubstituted amino group. According to the invention, a starting substance having at least one amino group is reacted with an alcohol in a reaction mixture in the presence of ammonia.
摘要:
The present invention relates to Melamine based Mannich compounds of the general formulae (1)-(12) and a process for synthesizing melamine based Mannich-products comprising the steps of a) reacting at least one substituted melamine with at least one aldehyde, in particular formaldehyde, under basic conditions to form at least one OH-containing compound, b) reacting the at least one OH-containing compound in the presence of a catalyst to form at least one mannich-base, c1) reacting the at least one mannich-base with at least one enol-forming carbonyl compound, or c2) reacting the at least one mannich-base with at least one aromatic compound, and d) working up the reaction mixture. The invention relates further to precondensates obtainable from these products.