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    PROCESS FOR THE MANUFACTURE FLUOROCARBONS
    1.
    发明申请
    PROCESS FOR THE MANUFACTURE FLUOROCARBONS 失效
    制造氟化物的方法

    公开(公告)号：US20110237847A1

    公开(公告)日：2011-09-29

    申请号：US13153580

    申请日：2011-06-06

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarhjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarhjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    IPC分类号： C07C17/38 ,  C09K3/00

    CPC分类号： C07C17/38 ,  C07C17/206 ,  C07C17/386 ,  C07C19/08 ,  C07C19/10 ,  C09K5/045 ,  C09K2205/126

    摘要： Halocarbons of the structure CF3CF2CH2X, wherein X is either F or Cl or mixtures thereof prepared by: contacting at least one 2-fluorochloropropane with hydrogen fluoride in a first fluorination step in the gas phase or liquid phase under substantially anhydrous conditions, in the absence of added catalyst to partially fluorinate said 2-fluorochloropropane; contacting said partially fluorinated 2-fluorochloropropane with at least the stoichiometric molar equivalent of hydrogen fluoride under substantially anhydrous conditions, in the presence of at least one fluorination catalyst in a second fluorination step; removing said reaction products from contact with said catalyst, and isolating a substantial yield of at least 1,1,1,2,2,3-hexafluoropropane or 1,1,1,2,2, penta-3-chloropropane, or mixtures thereof, respectively.

    摘要翻译： 结构CF 3 CF 2 CH 2 X的卤代烃，其中X是F或Cl或其混合物，其通过以下步骤制备：在基本上无水条件下，在气相或液相中的第一氟化步骤中使至少一种2-氟氯丙烷与氟化氢接触， 加入催化剂部分氟化所述2-氟氯丙烷; 在第二次氟化步骤中，在至少一种氟化催化剂的存在下，在基本无水的条件下使所述部分氟化的2-氟氯丙烷与化学计量摩尔当量的氟化氢接触; 除去所述反应产物不与所述催化剂接触，并分离出至少1,1,1,2,2,3-六氟丙烷或1,1,1,2,2，五-3-氯丙烷或其混合物的实质产率 分别。

    Process for the manufacture fluorocarbons
    2.
    发明授权
    Process for the manufacture fluorocarbons 失效
    制造碳氟化合物的方法

    公开(公告)号：US08354039B2

    公开(公告)日：2013-01-15

    申请号：US13153580

    申请日：2011-06-06

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    IPC分类号： C09K5/04 ,  C07C17/383

    CPC分类号： C07C17/38 ,  C07C17/206 ,  C07C17/386 ,  C07C19/08 ,  C07C19/10 ,  C09K5/045 ,  C09K2205/126

    摘要： Halocarbons of the structure CF3CF2CH2X, wherein X is either F or Cl or mixtures thereof prepared by: contacting at least one 2-fluorochloropropane with hydrogen fluoride in a first fluorination step in the gas phase or liquid phase under substantially anhydrous conditions, in the absence of added catalyst to partially fluorinate said 2-fluorochloropropane; contacting said partially fluorinated 2-fluorochloropropane with at least the stoichiometric molar equivalent of hydrogen fluoride under substantially anhydrous conditions, in the presence of at least one fluorination catalyst in a second fluorination step; removing said reaction products from contact with said catalyst, and isolating a substantial yield of at least 1,1,1,2,2,3-hexafluoropropane or 1,1,1,2,2, penta-3-chloropropane, or mixtures thereof, respectively.

    摘要翻译： 结构CF 3 CF 2 CH 2 X的卤代烃，其中X是F或Cl或其混合物，其通过以下步骤制备：在基本上无水条件下，在气相或液相中的第一氟化步骤中使至少一种2-氟氯丙烷与氟化氢接触， 加入催化剂部分氟化所述2-氟氯丙烷; 在第二次氟化步骤中，在至少一种氟化催化剂的存在下，在基本无水的条件下使所述部分氟化的2-氟氯丙烷与化学计量摩尔当量的氟化氢接触; 除去所述反应产物不与所述催化剂接触，并分离出至少1,1,1,2,2,3-六氟丙烷或1,1,1,2,2，五-3-氯丙烷或其混合物的实质产率 分别。

    Process and methods of purification for the manufacture fluorocarbons
    3.
    发明授权
    Process and methods of purification for the manufacture fluorocarbons 有权
    用于制造碳氟化合物的方法和纯化方法

    公开(公告)号：US07981311B2

    公开(公告)日：2011-07-19

    申请号：US12440040

    申请日：2007-09-05

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    IPC分类号： C09K5/04 ,  C11D7/30

    CPC分类号： C07C17/38 ,  C07C17/206 ,  C07C17/386 ,  C07C19/08 ,  C07C19/10 ,  C09K5/045 ,  C09K2205/126

    摘要： Halocarbons of the structure CF3CF2CH2X, wherein X is either F or Cl or mixtures thereof prepared by: contacting at least one 2-fluorochloropropane with hydrogen fluoride in a first fluorination step in the gas phase or liquid phase under substantially anhydrous conditions, in the absence of added catalyst to partially fluorinate said 2-fluorochloropropane; contacting said partially fluorinated 2-fluorochloropropane with at least the stoichiometric molar equivalent of hydrogen fluoride under substantially anhydrous conditions, in the presence of at least one fluorination catalyst in a second fluorination step; removing said reaction products from contact with said catalyst, and isolating a substantial yield of at least 1,1,1,2,2,3-hexafluoropropane or 1,1,1,2,2,penta-3-chloropropane, or mixtures thereof, respectively.

    摘要翻译： 结构CF 3 CF 2 CH 2 X的卤代烃，其中X是F或Cl或其混合物，其通过以下步骤制备：在基本上无水条件下，在气相或液相中的第一氟化步骤中使至少一种2-氟氯丙烷与氟化氢接触， 加入催化剂部分氟化所述2-氟氯丙烷; 在第二次氟化步骤中，在至少一种氟化催化剂的存在下，在基本无水的条件下使所述部分氟化的2-氟氯丙烷与化学计量摩尔当量的氟化氢接触; 除去所述反应产物不与所述催化剂接触，并分离出至少1,1,1,2,2,3-六氟丙烷或1,1,1,2,2，五-3-氯丙烷或其混合物的实质产率 分别。

    Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF
    8.
    发明授权
    Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF 有权

    公开(公告)号：US07906693B2

    公开(公告)日：2011-03-15

    申请号：US12442955

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/00 ,  C07C19/08

    CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C17/278 ,  C07C21/18 ,  C07C19/08 ,  C07C19/10

    摘要： A process is disclosed for making CH2═CFCF3. The process involves contacting CH2ClCF2CF3 with H2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH2═CFCF3. The mole ratio of H2 to the CH2ClCF2CF3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH2═CFCF3 that involves (a) reacting CH2ClCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH3CF2CF3; and (b) dehydrofluorinating CH3CF2CF3 from (a) to form CH2═CFCF3; and another process for making CH2═CFCF3 that involves (1) dehydrofluorinating CH2ClCF2CF3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF3; and (2) hydrogenating CHCl═CFCF3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH2═CFCF3. Also disclosed is a process for making CH2ClCF2CF5. This process involves reacting CH2ClF with CF2═CF2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF3CF═CHCl and HF.

    PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE, A PROCESS FOR PRODUCING 1-CHLORO-2,3,3,3-PENTAFLUOROPROPANE AND AZEOTROPIC COMPOSITIONS OF 1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE WITH HF
    10.
    发明申请
    PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE, A PROCESS FOR PRODUCING 1-CHLORO-2,3,3,3-PENTAFLUOROPROPANE AND AZEOTROPIC COMPOSITIONS OF 1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE WITH HF 有权

    公开(公告)号：US20100076231A1

    公开(公告)日：2010-03-25

    申请号：US12442955

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/25 ,  C07C17/278

    CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C17/278 ,  C07C21/18 ,  C07C19/08 ,  C07C19/10

    摘要： A process is disclosed for making CH2═CFCF3. The process involves contacting CH2ClCF2CF3 with H2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH2═CFCF3. The mole ratio of H2 to the CH2ClCF2CF3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH2═CFCF3 that involves (a) reacting CH2ClCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH3CF2CF3; and (b) dehydrofluorinating CH3CF2CF3 from (a) to form CH2═CFCF3; and another process for making CH2═CFCF3 that involves (1) dehydrofluorinating CH2ClCF2CF3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF3; and (2) hydrogenating CHCl═CFCF3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH2═CFCF3. Also disclosed is a process for making CH2ClCF2CF5. This process involves reacting CH2ClF with CF2═CF2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF3CF═CHCl and HF.