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1.发明申请公开(公告)号：US20120001155A1
公开(公告)日：2012-01-05
申请号：US12985439
申请日：2011-01-06
IPC分类号： H01L51/46 , H01L51/48 , C07D487/22
CPC分类号： H01L51/0092 , C07D487/22 , C07D495/22 , C09B47/00 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/188 , H01L51/0026 , H01L51/0072 , H01L51/0077 , H01L51/442 , H01L2251/308 , H05B33/10 , Y02E10/549
摘要： A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated, heterocyclic rings can be obtained by a thermal fusion process. By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyclic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved, resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.
摘要翻译： 可以通过热熔融方法获得可用作有机光伏器件中的供体材料的化合物，其包含与一种或多种未活化多环芳环或一个或多个未活化杂环稠合的未活化卟啉。 通过将非活化卟啉与非活化多环芳环或杂环的反应混合物加热至融合温度并保持预定时间，将一个或多个多环环或杂环与内消旋的非活化卟啉核心的融合 ，＆bgr 实现了时尚，导致包含具有环状芳环的扭曲的卟啉环的杂化结构。 卟啉核可以是o卟啉。
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2.发明授权公开(公告)号：US09113535B2
公开(公告)日：2015-08-18
申请号：US12985439
申请日：2011-01-06
IPC分类号： C07D487/22 , H05B33/10 , C09B47/00 , H01L51/00
CPC分类号： H01L51/0092 , C07D487/22 , C07D495/22 , C09B47/00 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/188 , H01L51/0026 , H01L51/0072 , H01L51/0077 , H01L51/442 , H01L2251/308 , H05B33/10 , Y02E10/549
摘要： A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. The compounds can include structures of Formula I: By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyclic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.
摘要翻译： 可以通过热熔融方法获得可用作有机光伏器件中的供体材料的化合物，其包含与一种或多种未活化多环芳环或一种或多种未活化杂环稠合的未活化卟啉。 化合物可以包括式I的结构：通过将非活化卟啉与非活化多环芳环或杂环的反应混合物加热至融合温度并保持预定时间，一个或多个多环或杂环的融合 到内消旋的非活化卟啉核心 实现了时尚，导致包含具有环状芳环的失真卟啉环的杂化结构。 卟啉核可以是o卟啉。
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公开(公告)号：US09017826B2
公开(公告)日：2015-04-28
申请号：US12868503
申请日：2010-08-25
CPC分类号： C07D487/22 , C07F3/06 , C07F7/2284 , C07F7/24 , C09B47/045 , H01L27/305 , H01L51/0058 , H01L51/0077 , H01L51/009 , H01L51/42 , Y10S428/917
摘要： Porphyrin compounds are provided. The compounds may further comprise a fused polycyclic aromatic hydrocarbon or a fused heterocyclic aromatic. Fused polycyclic aromatic hydrocarbon s and fused heterocyclic aromatics may extend and broaden absorption, and modify the solubility, crystallinity, and film-forming properties of the porphyrin compounds. Additionally, devices comprising porphyrin compounds are also provided. The porphyrin compounds may be used in a donor/acceptor configuration with compounds, such as C60.
摘要翻译： 提供卟啉化合物。 化合物还可以包含稠合的多环芳族烃或稠合杂环芳族。 稠合多环芳烃和稠合杂环芳族化合物可延长和扩大吸收，并改变卟啉化合物的溶解度，结晶度和成膜性能。 此外，还提供了包含卟啉化合物的装置。 卟啉化合物可以以化合物如C60的供体/受体构型使用。
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公开(公告)号：US20110168984A1
公开(公告)日：2011-07-14
申请号：US12868503
申请日：2010-08-25
IPC分类号： H01L51/46 , C07D487/22
CPC分类号： C07D487/22 , C07F3/06 , C07F7/2284 , C07F7/24 , C09B47/045 , H01L27/305 , H01L51/0058 , H01L51/0077 , H01L51/009 , H01L51/42 , Y10S428/917
摘要： Porphyrin compounds are provided. The compounds may further comprise a fused polycyclic aromatic hydrocarbon or a fused heterocyclic aromatic. Fused polycyclic aromatic hydrocarbon s and fused heterocyclic aromatics may extend and broaden absorption, and modify the solubility, crystallinity, and film-forming properties of the porphyrin compounds. Additionally, devices comprising porphyrin compounds are also provided. The porphyrin compounds may be used in a donor/acceptor configuration with compounds, such as C60.
摘要翻译： 提供卟啉化合物。 化合物还可以包含稠合的多环芳族烃或稠合杂环芳族。 稠合多环芳烃和稠合杂环芳族化合物可延长和扩大吸收，并改变卟啉化合物的溶解度，结晶度和成膜性能。 此外，还提供了包含卟啉化合物的装置。 卟啉化合物可以以化合物如C60的供体/受体构型使用。
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5.发明申请PHOTOACTIVE DEVICES INCLUDING PORPHYRINOIDS WITH COORDINATING ADDITIVES 有权包括具有协调添加剂的PORPHYRINOID的光学器件公开(公告)号：US20150048314A1
公开(公告)日：2015-02-19
申请号：US13271993
申请日：2011-10-12
申请人： Stephen R. Forrest , Jeramy Zimmerman , Eric K. Yu , Mark E. Thompson , Cong Trinh , Matthew Whited , Viacheslav Diev
发明人： Stephen R. Forrest , Jeramy Zimmerman , Eric K. Yu , Mark E. Thompson , Cong Trinh , Matthew Whited , Viacheslav Diev
CPC分类号： H01L51/0092 , B82Y10/00 , H01L51/0003 , H01L51/001 , H01L51/0046 , H01L51/0047 , H01L51/0077 , H01L51/0078 , H01L51/009 , H01L51/424 , H01L51/4253 , H01L51/5012 , H01L51/5056 , H01L51/5072 , H01L51/56 , Y02E10/549 , Y02P70/521
摘要： Coordinating additives are included in porphyrinoid-based materials to promote intermolecular organization and improve one or more photoelectric characteristics of the materials. The coordinating additives are selected from fullerene compounds and organic compounds having free electron pairs. Combinations of different coordinating additives can be used to tailor the characteristic properties of such porphyrinoid-based materials, including porphyrin oligomers. Bidentate ligands are one type of coordinating additive that can form coordination bonds with a central metal ion of two different porphyrinoid compounds to promote porphyrinoid alignment and/or pi-stacking. The coordinating additives can shift the absorption spectrum of a photoactive material toward higher wavelengths, increase the external quantum efficiency of the material, or both.
摘要翻译： 配合添加剂包括在卟啉类材料中，以促进分子间组织，改善材料的一种或多种光电特性。 配位添加剂选自具有自由电子对的富勒烯化合物和有机化合物。 可以使用不同配位添加剂的组合来定制这种卟啉类物质的特征，包括卟啉低聚物。 二齿配体是可以与两种不同卟啉类化合物的中心金属离子形成配位键的一种配位添加剂，以促进卟啉类比对和/或π-叠层。 配位添加剂可将光活性材料的吸收光谱向较高波长移动，提高材料的外部量子效率，或两者兼有。
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6.发明申请公开(公告)号：US20160254101A1
公开(公告)日：2016-09-01
申请号：US15030881
申请日：2014-10-27
申请人： Stephen R. FORREST , Xin XIAO , Kevin BERGEMANN , Anurag PANDA , Jeramy D. ZIMMERMAN , Brian E. LASSITER , Mark E. THOMPSON , Andrew N. BARTYNSKI , Cong THINH , Xiaozhou CHE
发明人： Stephen R. Forrest , Xin Xiao , Jeramy D. Zimmerman , Kevin Bergemann , Anurag Panda , Brian E. Lassiter , Mark E. Thompson , Andrew N. Bartynski , Cong Trinh , Xiaozhou Che
IPC分类号： H01G9/20 , H01L31/0216
CPC分类号： H01L51/4273 , H01L51/0046 , H01L51/4246 , H01L2251/308 , Y02E10/549
摘要： Disclosed herein are organic photosensitive devices including a first subcell and a second subcell and having at least one exciton-blocking charge carrier filter disposed between the subcells. The filters comprise a mixture of at least one wide energy gap material and at least one electron or hole conducting material. As described herein, the filters simultaneously block excitons and conduct the desired charge carrier (electrons or holes).
摘要翻译： 本文公开了包括第一子电池和第二子电池并且具有设置在子电池之间的至少一个激子阻挡电荷载流子过滤器的有机光敏器件。 过滤器包括至少一个宽能隙材料和至少一个电子或空穴传导材料的混合物。 如本文所述，滤光器同时阻止激子并传导所需的电荷载流子（电子或空穴）。
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公开(公告)号：US08242493B2
公开(公告)日：2012-08-14
申请号：US13150594
申请日：2011-06-01
IPC分类号： H01L51/46
CPC分类号： H01L51/0078 , C09B47/00 , C09B47/04 , H01L51/008 , H01L51/424 , H01L51/4246 , Y02E10/52 , Y02E10/549
摘要： An organic photosensitive optoelectronic device includes an anode, a cathode, and a donor-acceptor heterojunction between the anode and the cathode, the heterojunction including a donor-like material and an acceptor-like material, wherein at least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound, wherein the subporphyrin or subporphyrazine compound includes boron.
摘要翻译： 有机光敏光电子器件包括在阳极和阴极之间的阳极，阴极和供体 - 受体异质结，异质结包括施主样材料和受体样材料，其中至少一个供体样材料 并且受体样材料包括亚酞菁，卟啉和/或子卟吩化合物，其中卟啉或子卟吩化合物包括硼。
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公开(公告)号：US20110285280A1
公开(公告)日：2011-11-24
申请号：US13205290
申请日：2011-08-08
申请人： Mark E. THOMPSON , Peter Djurovich , Sergey Lamansky , Drew Murphy , Raymond Kwong , Feras Abdel-Razzaq , Stephen R. Forrest , Mare A. Baldo , Paul E. Burrows
发明人： Mark E. THOMPSON , Peter Djurovich , Sergey Lamansky , Drew Murphy , Raymond Kwong , Feras Abdel-Razzaq , Stephen R. Forrest , Mare A. Baldo , Paul E. Burrows
IPC分类号： H01J1/63
CPC分类号： H01L51/0085 , C07D209/86 , C09K11/06 , C09K2211/1007 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1092 , C09K2211/185 , C09K2211/186 , H01L51/0042 , H01L51/0059 , H01L51/006 , H01L51/0062 , H01L51/0065 , H01L51/0067 , H01L51/0068 , H01L51/0071 , H01L51/0072 , H01L51/0077 , H01L51/0081 , H01L51/0087 , H01L51/0088 , H01L51/5016 , H01L51/5096 , H01L2251/308 , Y10S428/917
摘要： Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.
摘要翻译： 描述了有机发光器件，其中发射层包含含有发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，并且发射分子选自磷光有机金属络合物，包括环金属化 铂，铱和锇络合物。 有机发光器件任选地包含激子阻挡层。 此外，通过具有式L2MX的过渡金属的有机金属络合物的发射极层获得有机发光器件的改善的电致发光效率，其中L和X是不同的二齿配体。 该配方的化合物可以比先前的方法更容易合成，并且合成选项允许将荧光分子插入磷光复合物，配体以微调发光的颜色，以及配体捕获载体。
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公开(公告)号：US20090209760A1
公开(公告)日：2009-08-20
申请号：US12434259
申请日：2009-05-01
申请人： Mark E. Thompson , Peter Djurovich , Sergey Lamansky , Drew Murphy , Raymond Kwong , Feras Abdel-Razzaq , Stephen R. Forrest , Mare A. Baldo , Paul E. Burrows
发明人： Mark E. Thompson , Peter Djurovich , Sergey Lamansky , Drew Murphy , Raymond Kwong , Feras Abdel-Razzaq , Stephen R. Forrest , Mare A. Baldo , Paul E. Burrows
IPC分类号： C07F17/00
CPC分类号： H01L51/0085 , C07D209/86 , C09K11/06 , C09K2211/1007 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1092 , C09K2211/185 , C09K2211/186 , H01L51/0042 , H01L51/0059 , H01L51/006 , H01L51/0062 , H01L51/0065 , H01L51/0067 , H01L51/0068 , H01L51/0071 , H01L51/0072 , H01L51/0077 , H01L51/0081 , H01L51/0087 , H01L51/0088 , H01L51/5016 , H01L51/5096 , H01L2251/308 , Y10S428/917
摘要： Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.
摘要翻译： 描述了有机发光器件，其中发射层包含含有发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，并且发射分子选自磷光有机金属络合物，包括环金属化 铂，铱和锇络合物。 有机发光器件任选地包含激子阻挡层。 此外，通过具有式L2MX的过渡金属的有机金属络合物的发射极层获得有机发光器件的改善的电致发光效率，其中L和X是不同的二齿配体。 该配方的化合物可以比先前的方法更容易合成，并且合成选项允许将荧光分子插入磷光复合物，配体以微调发光的颜色，以及配体捕获载体。
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公开(公告)号：US07279235B2
公开(公告)日：2007-10-09
申请号：US11061832
申请日：2005-02-18
申请人： Mark E. Thompson , Yujian You , Andrei Shoustikov , Scott Sibley , Paul E. Burrows , Stephen R. Forrest
发明人： Mark E. Thompson , Yujian You , Andrei Shoustikov , Scott Sibley , Paul E. Burrows , Stephen R. Forrest
IPC分类号： H01L51/54
CPC分类号： H01L51/0084 , C07D487/22 , C09K11/06 , C09K2211/10 , C09K2211/1003 , C09K2211/1007 , C09K2211/1018 , C09K2211/1029 , C09K2211/1033 , C09K2211/1074 , C09K2211/18 , C09K2211/185 , C09K2211/186 , H01L51/0053 , H01L51/0067 , H01L51/0077 , H01L51/0081 , H01L51/0087 , H01L51/5016 , H01L51/5221 , H01L51/5234 , H01L2251/308 , H01L2251/5323 , H05B33/14 , H05B33/28 , Y10S428/917 , Y10T428/24942
摘要： Organic light emitting devices are Disclosed which are comprised of a heterostructure for producing electroluminescence wherein the heterostructure is comprised of an emissive layer containing a phosphorescent dopant compound. For example, the phosphorescent dopant compound may be comprised of platinum octaethylporphine (PtOEP), which is a compound having the chemical structure with the formula:
摘要翻译： 公开了由用于产生电致发光的异质结构组成的有机发光器件，其中异质结构由含有磷光掺杂剂化合物的发射层组成。 例如，磷光掺杂剂化合物可以由具有以下化学结构的化合物的铂八乙基卟吩（PtOEP）组成：
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