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1.发明授权Process for transitioning between Ziegler-Natta-based and chromium-based catalysts 有权齐格勒 - 纳塔和铬基催化剂之间的过渡过程公开(公告)号：US07629422B2
公开(公告)日：2009-12-08
申请号：US11312272
申请日：2005-12-20
申请人： Mark G. Goode , Kevin J. Cann , F. David Hussein , Robert L. Santana , David C. Schutz , Agapios K. Agapiou
发明人： Mark G. Goode , Kevin J. Cann , F. David Hussein , Robert L. Santana , David C. Schutz , Agapios K. Agapiou
IPC分类号： C08F2/38 , C08F2/34 , C08F210/08
CPC分类号： C08F10/02 , C08F210/16 , C08F2410/05 , Y10S526/901 , C08F2/34 , C08F2/42 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F210/08
摘要： Embodiments of our invention relate to processes for transitioning among polymerization catalyst systems including processes for transitioning among olefin polymerization reactions using Ziegler-Natta catalysts systems and chromium-based catalyst systems. Among embodiments contemplated are a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor, comprising: adding to the reactor a deactivating agent (DA) selected from one of carbon monoxide, carbon dioxide, or combinations thereof; adding to the reactor a cocatalyst adsorbing agent (CAA), comprising an inorganic oxide selected from one of silica, alumina or combinations thereof; wherein the first catalyst comprises at least one conventional Ziegler-Natta catalyst, and a cocatalyst, wherein the second catalyst comprises at least one chromium-based catalyst, wherein the reactor is a gas-phase, fluidized bed reactor, and wherein the CAA is substantially free of transition metals. In another embodiment a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor is contemplated, comprising: adding a transition aid agent (TAA) wherein the TAA is selected from one of alkoxylated amines, alkoxylated amides, or combinations thereof, wherein the first catalyst comprises at least one Ziegler-Natta catalyst comprising the catalyst, a cocatalyst and optionally a support, and the second catalyst comprises at least one chromium-based catalyst.
摘要翻译： 本发明的实施方案涉及在聚合催化剂体系中过渡的方法，包括使用齐格勒 - 纳塔催化剂体系和铬基催化剂体系在烯烃聚合反应中过渡的方法。 考虑的实施方案是在烯烃聚合反应器中从第一催化剂转变为第二催化剂的方法，包括：向反应器中加入选自一氧化碳，二氧化碳或其组合中的一种失活剂（DA）; 向所述反应器中加入选自二氧化硅，氧化铝或其组合的无机氧化物的助催化剂吸附剂（CAA）; 其中所述第一催化剂包含至少一种常规齐格勒 - 纳塔催化剂和助催化剂，其中所述第二催化剂包含至少一种铬基催化剂，其中所述反应器是气相流化床反应器，并且其中所述CAA基本上 没有过渡金属。 在另一个实施方案中考虑了在烯烃聚合反应器中从第一催化剂转变为第二催化剂的方法，包括：加入转移助剂（TAA），其中TAA选自烷氧基化胺，烷氧基化酰胺或其组合之一 其中所述第一催化剂包含至少一种齐格勒 - 纳塔催化剂，其包含所述催化剂，助催化剂和任选的载体，所述第二催化剂包含至少一种铬基催化剂。
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公开(公告)号：US07985811B2
公开(公告)日：2011-07-26
申请号：US12217945
申请日：2008-07-10
申请人： Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
发明人： Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
CPC分类号： B01J8/1809 , B01J19/002 , B01J2208/00256 , B01J2208/00274 , B01J2208/00734 , B01J2208/00761 , B01J2219/00254 , C08F10/00 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/002 , C08F2/34 , C08F210/14
摘要： Embodiments of the present invention relate to measuring and controlling static in a gas phase reactor polymerization. In particular, embodiments relate to monitoring carryover static in an entrainment zone during gas phase polymerization to determine the onset of reactor discontinuity events such as chunking and sheeting. Embodiments also relate to monitoring carryover static to determine the need for effective additions of continuity additives that minimize reactor static activity and thereby preventing discontinuity events.
摘要翻译： 本发明的实施例涉及测量和控制气相反应器聚合中的静电。 特别地，实施方案涉及在气相聚合期间监测夹带区域中的静态滞留，以确定反应器不连续事件（例如分块和片材）的开始。 实施例还涉及监测携带静电以确定需要有效添加连续性添加剂，其使反应堆静态活性最小化，从而防止不连续事件。
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公开(公告)号：US20090018279A1
公开(公告)日：2009-01-15
申请号：US12217945
申请日：2008-07-10
申请人： Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
发明人： Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
CPC分类号： B01J8/1809 , B01J19/002 , B01J2208/00256 , B01J2208/00274 , B01J2208/00734 , B01J2208/00761 , B01J2219/00254 , C08F10/00 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/002 , C08F2/34 , C08F210/14
摘要： Embodiments of the present invention relate to measuring and controlling static in a gas phase reactor polymerization. In particular, embodiments relate to monitoring carryover static in an entrainment zone during gas phase polymerization to determine the onset of reactor discontinuity events such as chunking and sheeting. Embodiments also relate to monitoring carryover static to determine the need for effective additions of continuity additives that minimize reactor static activity and thereby preventing discontinuity events.
摘要翻译： 本发明的实施例涉及测量和控制气相反应器聚合中的静电。 特别地，实施方案涉及在气相聚合期间监测夹带区域中的静态滞留，以确定反应器不连续事件（例如分块和片材）的开始。 实施例还涉及监测携带静电以确定需要有效添加连续性添加剂，其使反应堆静态活性最小化，从而防止不连续事件。
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公开(公告)号：US20120039755A1
公开(公告)日：2012-02-16
申请号：US13277794
申请日：2011-10-20
申请人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
发明人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
IPC分类号： B01J19/00
CPC分类号： C08F10/00 , Y02P20/582 , C08F2/004 , C08F2500/01
摘要： A method of treating a gas phase fluidized bed reactor and a method of polymerizing olefins in a gas phase fluidized bed reactor in the presence of a catalyst prone to cause sheeting by introducing a chromium-containing compound into the reactor and forming a high molecular weight polymer coating on the walls of the reactor. Furthermore, a device for and method of introducing the chromium-containing compound into the fluidized bed reactor at a plurality of locations in proximity to a lower section of a bed section wall of the fluidized bed reactor, and forming a high molecular weight polymer coating on the bed section wall.
摘要翻译： 一种处理气相流化床反应器的方法和在气相流化床反应器中在催化剂存在下聚合烯烃的方法，其易于通过将含铬化合物引入反应器并形成高分子量聚合物 涂覆在反应器的壁上。 此外，在流化床反应器的床部分壁的下部附近的多个位置处将含铬化合物引入流化床反应器中的装置和方法，并且形成高分子量聚合物涂层 床段墙。
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公开(公告)号：US08084554B2
公开(公告)日：2011-12-27
申请号：US12525202
申请日：2008-02-11
申请人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
发明人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
IPC分类号： C08F2/00 , C08F4/24 , C08F210/00 , B01J19/00
CPC分类号： C08F10/00 , Y02P20/582 , C08F2/004 , C08F2500/01
摘要： A method of treating a gas phase fluidized bed reactor and a method of polymerizing olefins in a gas phase fluidized bed reactor in the presence of a catalyst prone to cause sheeting by introducing a chromium-containing compound into the reactor and forming a high molecular weight polymer coating on the walls of the reactor. Furthermore, a device for and method of introducing the chromium-containing compound into the fluidized bed reactor at a plurality of locations in proximity to a lower section of a bed section wall of the fluidized bed reactor, and forming a high molecular weight polymer coating on the bed section wall.
摘要翻译： 一种处理气相流化床反应器的方法和在气相流化床反应器中在催化剂存在下聚合烯烃的方法，其易于通过将含铬化合物引入反应器并形成高分子量聚合物 涂覆在反应器的壁上。 此外，在流化床反应器的床部分壁的下部附近的多个位置处将含铬化合物引入流化床反应器中的装置和方法，并且形成高分子量聚合物涂层 床段墙。
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公开(公告)号：US08192690B2
公开(公告)日：2012-06-05
申请号：US13277794
申请日：2011-10-20
申请人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
发明人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
IPC分类号： B01J19/00 , C08F2/00 , C08F4/24 , C08F210/00
CPC分类号： C08F10/00 , Y02P20/582 , C08F2/004 , C08F2500/01
摘要： A method of treating a gas phase fluidized bed reactor and a method of polymerizing olefins in a gas phase fluidized bed reactor in the presence of a catalyst prone to cause sheeting by introducing a chromium-containing compound into the reactor and forming a high molecular weight polymer coating on the walls of the reactor. Furthermore, a device for and method of introducing the chromium-containing compound into the fluidized bed reactor at a plurality of locations in proximity to a lower section of a bed section wall of the fluidized bed reactor, and forming a high molecular weight polymer coating on the bed section wall.
摘要翻译： 一种处理气相流化床反应器的方法和在气相流化床反应器中在催化剂存在下聚合烯烃的方法，其易于通过将含铬化合物引入反应器并形成高分子量聚合物 涂覆在反应器的壁上。 此外，在流化床反应器的床部分壁的下部附近的多个位置处将含铬化合物引入流化床反应器中的装置和方法，并且形成高分子量聚合物涂层 床段墙。
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公开(公告)号：US20110184124A1
公开(公告)日：2011-07-28
申请号：US12673561
申请日：2008-08-06
CPC分类号： C08F6/003 , C08F210/16 , C08F2410/02 , C08F2/005 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： A continuity additive according to one general approach includes a substance having an ability to reduce, prevent, or mitigate at least one of fouling, sheeting, and static level of a material present in a polymerization reactor system when added to the reactor system in an effective amount, with the proviso that the substance is not a polysulfone polymer, a polymeric polyamine, or an oil-soluble sulfonic acid; and a scavenger contacted with the substance, optionally, the scavenger neutralizing water coming in contact therewith. Additional continuity additives, methods of making continuity additives, and use of continuity additives are also presented.
摘要翻译： 根据一般方法的连续性添加剂包括具有降低，防止或减轻聚合反应器系统中存在的材料的污垢，片材和静态水平中的至少一种的能力的物质，当加入到反应器系统中时， 量，条件是该物质不是聚砜聚合物，聚合多胺或油溶性磺酸; 和与该物质接触的清除剂，任选地，与其接触的清除剂中和水。 还提出了附加的连续性添加剂，制备连续性添加剂的方法和连续性添加剂的使用。
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公开(公告)号：US08420733B2
公开(公告)日：2013-04-16
申请号：US12673561
申请日：2008-08-06
CPC分类号： C08F6/003 , C08F210/16 , C08F2410/02 , C08F2/005 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： A continuity additive according to one general approach includes a substance having an ability to reduce, prevent, or mitigate at least one of fouling, sheeting, and static level of a material present in a polymerization reactor system when added to the reactor system in an effective amount, with the proviso that the substance is not a polysulfone polymer, a polymeric polyamine, or an oil-soluble sulfonic acid; and a scavenger contacted with the substance, optionally, the scavenger neutralizing water coming in contact therewith. Additional continuity additives, methods of making continuity additives, and use of continuity additives are also presented.
摘要翻译： 根据一般方法的连续性添加剂包括具有降低，防止或减轻聚合反应器系统中存在的材料的污垢，片材和静态水平中的至少一种的能力的物质，当加入到反应器系统中时， 量，条件是该物质不是聚砜聚合物，聚合多胺或油溶性磺酸; 和与该物质接触的清除剂，任选地，与其接触的清除剂中和水。 还提出了附加的连续性添加剂，制备连续性添加剂的方法和连续性添加剂的使用。
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公开(公告)号：US20100076164A1
公开(公告)日：2010-03-25
申请号：US12525202
申请日：2008-02-11
申请人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powel , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
发明人： Agapios K. Agapiou , David M. Glowczwski , Zerong Lin , Gary D. Mohr , Ted A. Powel , Michael E. Sieloff , Edward F. Smith , Kevin B. Stavens , Keith W. Trapp , Michael E. Muhle , F. David Hussein
CPC分类号： C08F10/00 , Y02P20/582 , C08F2/004 , C08F2500/01
摘要： A method of treating a gas phase fluidized bed reactor and a method of polymerizing olefins in a gas phase fluidized bed reactor in the presence of a catalyst prone to cause sheeting by introducing a chromium-containing compound into the reactor and forming a high molecular weight polymer coating on the walls of the reactor. Furthermore, a device for and method of introducing the chromium-containing compound into the fluidized bed reactor at a plurality of locations in proximity to a lower section of a bed section wall of the fluidized bed reactor, and forming a high molecular weight polymer coating on the bed section wall.
摘要翻译： 一种处理气相流化床反应器的方法和在气相流化床反应器中在催化剂存在下聚合烯烃的方法，其易于通过将含铬化合物引入反应器并形成高分子量聚合物 涂覆在反应器的壁上。 此外，在流化床反应器的床部分壁的下部附近的多个位置处将含铬化合物引入流化床反应器中的装置和方法，并且形成高分子量聚合物涂层 床段墙。
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公开(公告)号：US07323526B2
公开(公告)日：2008-01-29
申请号：US11192935
申请日：2005-07-29
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , Y02P20/582 , Y10S526/941 , Y10S526/943 , C08F4/65916
摘要： A supported catalyst composition having improved flow properties is disclosed comprising an alkylalumoxane, a metallocene-alkyl an inorganic oxide support having an average particle size of from 0.1 to 50 μm and calcined at a temperature greater than 600° C., and optionally an antifoulant agent and. In one embodiment, the metallocene-alkyl is a Group 4, 5 or 6 metallocene-alkyl, and in another embodiment is a hafnocene-alkyl. Also disclosed is a method of polymerization using such a supported catalyst composition.
摘要翻译： 公开了具有改进的流动性质的负载型催化剂组合物，其包含烷基铝氧烷，茂金属 - 烷基和平均粒度为0.1-50μm的无机氧化物载体，并且在大于600℃的温度下煅烧，以及任选的防污剂 和。 在一个实施方案中，茂金属 - 烷基是第4,5或6族茂金属 - 烷基，在另一个实施方案中是茂金属 - 烷基。 还公开了使用这种负载型催化剂组合物的聚合方法。
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