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公开(公告)号：US06847699B2
公开(公告)日：2005-01-25
申请号：US10013601
申请日：2001-12-04
申请人： Mark J. Rigali , Manish P. Sutaria , E. Greg Hilmas , Anthony C. Mulligan , Marlene Platero-AllRunner , Mark M. Opeka
发明人： Mark J. Rigali , Manish P. Sutaria , E. Greg Hilmas , Anthony C. Mulligan , Marlene Platero-AllRunner , Mark M. Opeka
IPC分类号： C04B30/02 , C04B35/628 , C04B35/632 , C04B35/645 , C04B41/45 , H01J35/08
CPC分类号： C04B35/5622 , B33Y70/00 , B33Y80/00 , C04B30/02 , C04B35/5607 , C04B35/6261 , C04B35/6263 , C04B35/62855 , C04B35/6286 , C04B35/62865 , C04B35/62868 , C04B35/62873 , C04B35/62876 , C04B35/632 , C04B35/645 , C04B41/009 , C04B41/4584 , C04B2235/3244 , C04B2235/3813 , C04B2235/3817 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3852 , C04B2235/40 , C04B2235/404 , C04B2235/405 , C04B2235/425 , C04B2235/524 , C04B2235/5244 , C04B2235/5252 , C04B2235/526 , C04B2235/5264 , C04B2235/5436 , C04B2235/6021 , C04B2235/77 , H01J35/08 , H01J2235/081 , H01J2235/088 , Y10T428/2916 , Y10T428/2918 , Y10T428/2929 , C04B14/46 , C04B20/1062 , C04B20/1055
摘要： Fibrous monolith composites suitable for use in high temperature environments and/or harsh chemical environments are provided, along with methods of preparation thereof. The fibrous monolith composites exhibit such beneficial properties as enhanced strength, corrosion resistance, thermal shock resistance and thermal cycling tolerance.
摘要翻译： 提供了适用于高温环境和/或恶劣化学环境的纤维整料复合材料及其制备方法。 纤维整体复合材料具有增强强度，耐腐蚀性，耐热冲击性和热循环耐受性等有益特性。
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公开(公告)号：US06355338B1
公开(公告)日：2002-03-12
申请号：US09488868
申请日：2000-01-21
申请人： Gregory E. Hilmas , Dustin R. Beeaff , Anthony C. Mulligan , Mark M. Opeka , Mark J. Rigali , Manish P. Sutaria
发明人： Gregory E. Hilmas , Dustin R. Beeaff , Anthony C. Mulligan , Mark M. Opeka , Mark J. Rigali , Manish P. Sutaria
IPC分类号： B32B2502
CPC分类号： C04B35/622 , C04B35/806 , D01D5/34 , Y10T428/249939 , Y10T428/249945
摘要： A process for continuous composite coextrusion comprising: (a) forming first a material-laden composition comprising a thermoplastic polymer and at least about 40 volume % of a ceramic or metallic particulate in a manner such that the composition has a substantially cylindrical geometry and thus can be used as a substantially cylindrical feed rod; (b) forming a hole down the symmetrical axis of the feed rod; (c) inserting the start of a continuous spool of ceramic fiber, metal fiber or carbon fiber through the hole in the feed rod; (d) extruding the feed rod and spool simultaneously to form a continuous filament consisting of a green matrix material completely surrounding a dense fiber reinforcement and said filament having an average diameter that is less than the average diameter of the feed rod; and (e) arranging the continuous filament into a desired architecture to provide a green fiber reinforced composite.
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3.发明授权Aligned composite structures for mitigation of impact damage and resistance to wear in dynamic environments 失效对齐复合结构，用于减轻动态环境中的冲击损伤和耐磨性公开(公告)号：US07517580B2
公开(公告)日：2009-04-14
申请号：US11298194
申请日：2005-12-09
申请人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Dragan Popovich , Joseph P. Halloran , Michael L. Fulcher , Randy C. Cook
发明人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Dragan Popovich , Joseph P. Halloran , Michael L. Fulcher , Randy C. Cook
CPC分类号： B32B3/26 , B32B18/00 , B32B2315/02 , C04B35/117 , C04B35/62865 , C04B35/62868 , C04B35/645 , C04B35/806 , C04B2235/3843 , C04B2235/524 , C04B2235/5264 , C04B2235/6021 , C04B2235/6567 , C04B2235/658 , C04B2237/34 , C04B2237/341 , C04B2237/343 , C04B2237/363 , C04B2237/368 , C04B2237/38 , C04B2237/704 , C04B2237/76 , C08K3/34 , C08K7/04 , Y10T428/24149 , Y10T428/24926 , Y10T428/249953 , Y10T428/249964 , Y10T428/249965 , Y10T428/24998 , Y10T428/31504 , Y10T442/2615 , Y10T442/2623
摘要： Fibrous monolith composites having architectures that provide increased flaw insensitivity, improved hardness, wear resistance and damage tolerance and methods of manufacture thereof are provided for use in dynamic environments to mitigate impact damage and increase wear resistance.
摘要翻译： 提供具有提供增加的缺陷不敏感性，改进的硬度，耐磨性和损伤公差的结构的纤维整体复合材料以及其制造方法用于动态环境中以减轻冲击损伤并增加耐磨性。
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4.发明授权Aligned composite structures for mitigation of impact damage and resistance to wear in dynamic environments 失效对齐复合结构，用于减轻动态环境中的冲击损伤和耐磨性公开(公告)号：US06974624B2
公开(公告)日：2005-12-13
申请号：US10310594
申请日：2002-12-04
申请人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Dragan Popovich , Joseph P. Halloran , Michael L. Fulcher , Randy C. Cook
发明人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Dragan Popovich , Joseph P. Halloran , Michael L. Fulcher , Randy C. Cook
CPC分类号： B32B3/26 , B32B18/00 , B32B2315/02 , C04B35/117 , C04B35/62865 , C04B35/62868 , C04B35/645 , C04B35/806 , C04B2235/3843 , C04B2235/524 , C04B2235/5264 , C04B2235/6021 , C04B2235/6567 , C04B2235/658 , C04B2237/34 , C04B2237/341 , C04B2237/343 , C04B2237/363 , C04B2237/368 , C04B2237/38 , C04B2237/704 , C04B2237/76 , C08K3/34 , C08K7/04 , Y10T428/24149 , Y10T428/24926 , Y10T428/249953 , Y10T428/249964 , Y10T428/249965 , Y10T428/24998 , Y10T428/31504 , Y10T442/2615 , Y10T442/2623
摘要： Fibrous monolith composites having architectures that provide increased flaw insensitivity, improved hardness, wear resistance and damage tolerance and methods of manufacture thereof are provided for use in dynamic environments to mitigate impact damage and increase wear resistance.
摘要翻译： 提供具有提供增加的缺陷不敏感性，改进的硬度，耐磨性和损伤公差的结构的纤维整体复合材料以及其制造方法用于动态环境中以减轻冲击损伤并增加耐磨性。
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公开(公告)号：US07704594B2
公开(公告)日：2010-04-27
申请号：US10915923
申请日：2004-08-11
申请人： Anthony C. Mulligan , John Halloran , Dragan Popovich , Mark J. Rigali , Manish P. Sutaria , K. Ranji Vaidyanathan , Michael L. Fulcher , Kenneth L. Knittel
发明人： Anthony C. Mulligan , John Halloran , Dragan Popovich , Mark J. Rigali , Manish P. Sutaria , K. Ranji Vaidyanathan , Michael L. Fulcher , Kenneth L. Knittel
CPC分类号： B29C47/0016 , B29C47/003 , B29C47/128 , H01L41/082 , H01L41/1875 , H01L41/333 , Y10T428/249924 , Y10T428/249925 , Y10T428/249927 , Y10T428/249928 , Y10T428/249929 , Y10T428/2933
摘要： Fibrous monolith processing techniques to fabricate multifunctional structures capable of performing more than one discrete function such as structures capable of bearing structural loads and mechanical stresses in service and also capable of performing at least one additional non-structural function.
摘要翻译： 纤维整料加工技术来制造能够执行多于一个离散功能的多功能结构，例如能够承受结构载荷和使用中的机械应力的结构，并且还能够执行至少一个附加的非结构功能。
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公开(公告)号：US07063812B2
公开(公告)日：2006-06-20
申请号：US10852326
申请日：2004-05-24
申请人： Manish P. Sutaria , Mark J. Rigali , Ronald A. Cipriani , Gregory J. Artz , Anthony C. Mulligan
发明人： Manish P. Sutaria , Mark J. Rigali , Ronald A. Cipriani , Gregory J. Artz , Anthony C. Mulligan
CPC分类号： C04B35/6455 , B22F3/1017 , B22F2998/00 , B22F2998/10 , C04B35/56 , C04B35/5607 , C04B35/5622 , C04B35/583 , C04B35/593 , C04B35/5935 , C04B35/62272 , C04B35/62277 , C04B35/6286 , C04B35/62868 , C04B35/62894 , C04B35/63416 , C04B35/63488 , C04B35/64 , C04B35/645 , C04B35/803 , C04B35/806 , C04B2235/3217 , C04B2235/3225 , C04B2235/3418 , C04B2235/365 , C04B2235/386 , C04B2235/3873 , C04B2235/524 , C04B2235/5268 , C04B2235/6021 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/661 , C04B2235/668 , C04B2235/77 , B22F2201/02 , B22F3/20 , B22F3/02 , B22F2003/145
摘要： Methods for consolidation and densification of fibrous monolith composite structures are provided. Consolidation and densification of two- and three-dimensional fibrous monolith components having complex geometries can be achieved by pressureless sintering. The fibrous monolith composites are formed from filaments having at least a first material composition generally surrounded by a second material composition. The composites are sintered at a pressure of no more than about 30 psi to provide consolidated and densified fibrous monolith composites.
摘要翻译： 提供了纤维整体复合结构的固结和致密化方法。 具有复杂几何形状的二维和三维纤维整体组件的固化和致密化可以通过无压烧结实现。 纤维整体复合材料由具有至少第一材料组合物的长丝形成，该第一材料组合物通常被第二材料组合物包围。 复合材料在不超过约30psi的压力下烧结以提供固结和致密化的纤维整料复合材料。
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公开(公告)号：US06740286B2
公开(公告)日：2004-05-25
申请号：US10005241
申请日：2001-12-04
申请人： Manish P. Sutaria , Mark J. Rigali , Ronald A. Cipriani , Gregory J. Artz , Anthony C. Mulligan
发明人： Manish P. Sutaria , Mark J. Rigali , Ronald A. Cipriani , Gregory J. Artz , Anthony C. Mulligan
IPC分类号： B28B320
CPC分类号： C04B35/6455 , B22F3/1017 , B22F2998/00 , B22F2998/10 , C04B35/56 , C04B35/5607 , C04B35/5622 , C04B35/583 , C04B35/593 , C04B35/5935 , C04B35/62272 , C04B35/62277 , C04B35/6286 , C04B35/62868 , C04B35/62894 , C04B35/63416 , C04B35/63488 , C04B35/64 , C04B35/645 , C04B35/803 , C04B35/806 , C04B2235/3217 , C04B2235/3225 , C04B2235/3418 , C04B2235/365 , C04B2235/386 , C04B2235/3873 , C04B2235/524 , C04B2235/5268 , C04B2235/6021 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/661 , C04B2235/668 , C04B2235/77 , B22F2201/02 , B22F3/20 , B22F3/02 , B22F2003/145
摘要： Methods for consolidation and densification of fibrous monolith composite structures are provided. Consolidation and densification of two- and three-dimensional fibrous monolith components having complex geometries can be achieved by pressureless sintering. The fibrous monolith composites are formed from filaments having at least a first material composition generally surrounded by a second material composition. The composites are sintered in an inert gas or nitrogen gas at a pressure of no more than about 30 psi to provide consolidated and densified fibrous monolith composites.
摘要翻译： 提供了纤维整体复合结构的固结和致密化方法。 具有复杂几何形状的二维和三维纤维整体组件的固化和致密化可以通过无压烧结实现。 纤维整体复合材料由具有至少第一材料组合物的长丝形成，该第一材料组合物通常被第二材料组合物包围。 复合材料在不大于约30psi的压力下在惰性气体或氮气中烧结，以提供固结和致密的纤维整体复合材料。
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公开(公告)号：US06805946B2
公开(公告)日：2004-10-19
申请号：US10005085
申请日：2001-12-04
申请人： Anthony C. Mulligan , John Halloran , Dragan Popovich , Mark J. Rigali , Manish P. Sutaria , K. Ranji Vaidyanathan , Michael L. Fulcher , Kenneth L. Knittel
发明人： Anthony C. Mulligan , John Halloran , Dragan Popovich , Mark J. Rigali , Manish P. Sutaria , K. Ranji Vaidyanathan , Michael L. Fulcher , Kenneth L. Knittel
IPC分类号： B32B502
CPC分类号： B29C47/0016 , B29C47/003 , B29C47/128 , H01L41/082 , H01L41/1875 , H01L41/333 , Y10T428/249924 , Y10T428/249925 , Y10T428/249927 , Y10T428/249928 , Y10T428/249929 , Y10T428/2933
摘要： Fibrous monolith processing techniques to fabricate multifunctional structures capable of performing more than one discrete function such as structures capable of bearing structural loads and mechanical stresses in service and also capable of performing at least one additional non-structural function.
摘要翻译： 纤维整料加工技术来制造能够执行多于一个离散功能的多功能结构，例如能够承受结构载荷和使用中的机械应力的结构，并且还能够执行至少一个附加的非结构功能。
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公开(公告)号：US07387757B2
公开(公告)日：2008-06-17
申请号：US10880189
申请日：2004-06-29
申请人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Gregory J. Artz , Felix H. Gafner , K. Ranji Vaidyanathan
发明人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Gregory J. Artz , Felix H. Gafner , K. Ranji Vaidyanathan
IPC分类号： B28B5/00
CPC分类号： C08K3/18 , B22F3/008 , B22F2998/00 , B22F2999/00 , B28B3/20 , B28B17/0081 , B29C43/006 , B29C47/0016 , B29C47/54 , B29K2105/06 , B33Y10/00 , C04B35/5622 , C04B35/6286 , C04B35/6303 , C04B35/632 , C04B35/634 , C04B35/638 , C04B35/645 , C04B35/6455 , C04B35/806 , C04B2235/3826 , C04B2235/3839 , C04B2235/524 , C04B2235/6021 , C04B2235/77 , C04B2235/96 , Y10T428/2929 , B22F3/10 , B22F3/14 , B22F3/15 , B22F1/004 , B22F1/025 , B22F3/20 , B22F2203/01 , B22F3/004
摘要： Processes for mechanically fabricating two and three-dimensional fibrous monolith composites include preparing a fibrous monolith filament from a core composition of a first powder material and a boundary material of a second powder material. The filament includes a first portion of the core composition surrounded by a second portion of the boundary composition. One or more filaments are extruded through a mechanically-controlled deposition nozzle onto a working surface to create a fibrous monolith composite object. The objects may be formed directly from computer models and have complex geometries.
摘要翻译： 用于机械制造二维和三维纤维整体复合材料的方法包括从第一粉末材料的芯组合物和第二粉末材料的边界材料制备纤维整料长丝。 细丝包括由边界组合物的第二部分包围的芯组合物的第一部分。 将一根或多根细丝通过机械控制的沉积喷嘴挤出到工作表面上以产生纤维整体复合物体。 物体可以直接从计算机模型形成并且具有复杂的几何形状。
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公开(公告)号：US06797220B2
公开(公告)日：2004-09-28
申请号：US10005656
申请日：2001-12-04
申请人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Gregory J. Artz , Felix H. Gafner , K. Ranji Vaidyanathan
发明人： Anthony C. Mulligan , Mark J. Rigali , Manish P. Sutaria , Gregory J. Artz , Felix H. Gafner , K. Ranji Vaidyanathan
IPC分类号： B28B500
CPC分类号： C08K3/18 , B22F3/008 , B22F2998/00 , B22F2999/00 , B28B3/20 , B28B17/0081 , B29C43/006 , B29C47/0016 , B29C47/54 , B29K2105/06 , B33Y10/00 , C04B35/5622 , C04B35/6286 , C04B35/6303 , C04B35/632 , C04B35/634 , C04B35/638 , C04B35/645 , C04B35/6455 , C04B35/806 , C04B2235/3826 , C04B2235/3839 , C04B2235/524 , C04B2235/6021 , C04B2235/77 , C04B2235/96 , Y10T428/2929 , B22F3/10 , B22F3/14 , B22F3/15 , B22F1/004 , B22F1/025 , B22F3/20 , B22F2203/01 , B22F3/004
摘要： Processes for mechanically fabricating two and three-dimensional fibrous monolith composites include preparing a fibrous monolith filament from a core composition of a first powder material and a boundary material of a second powder material. The filament includes a first portion of the core composition surrounded by a second portion of the boundary composition. One or more filaments are extruded through a mechanically-controlled deposition nozzle onto a working surface to create a fibrous monolith composite object. The objects may be formed directly from computer models and have complex geometries.
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