SILICA NANOFIBER/METAL OXIDE NANOCRYSTAL COMPOSITE AND METHOD FOR PRODUCING THE SAME
    8.
    发明申请
    SILICA NANOFIBER/METAL OXIDE NANOCRYSTAL COMPOSITE AND METHOD FOR PRODUCING THE SAME 审中-公开
    二氧化硅纳米纤维/金属氧化物纳米复合材料及其制造方法

    公开(公告)号:US20120235094A1

    公开(公告)日:2012-09-20

    申请号:US13512854

    申请日:2010-11-29

    Abstract: A silica nanofiber/metal oxide nanocrystal composite is produced by a method including associating a polymer having a linear polyethyleneimine skeleton in a water-based medium in the presence of ice, adding alkoxysilane to the water-based medium obtained in the above step to form a composite nanofiber including the associate and silica that covers the associate, while the fiber spontaneously forms a disc-shaped network structure, a step of depositing a metal oxide on a surface of the fiber by mixing the disc-shaped structure obtained in the above step with a hydrolyzable metal compound, and a step of calcining the disc-shaped. structure obtained in the step above to form a silica nanofiber through removal of the polymer in the fiber, to convert the metal oxide into a nanocrystal, and to bond the nanocrystal to the fiber. When zinc oxide is used as the metal oxide, the composite functions as a luminous body.

    Abstract translation: 二氧化硅纳米纤维/金属氧化物纳米晶体复合体通过包括在冰存在下将具有线性聚乙烯亚胺骨架的聚合物在水性介质中缔合而制备的方法,在上述步骤中得到的水性介质中加入烷氧基硅烷,形成 复合纳米纤维包括助剂和覆盖助剂的二氧化硅,而纤维自发地形成盘形网状结构,通过将上述步骤获得的盘状结构与 水解性金属化合物,以及煅烧所述盘状的步骤。 在上述步骤中获得的结构,通过除去纤维中的聚合物形成二氧化硅纳米纤维,将金属氧化物转化为纳米晶体,并将纳米晶体结合到纤维上。 当使用氧化锌作为金属氧化物时,复合物起到发光体的作用。

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