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    Method for the production of terylene-3,4:11,12-tetracarboxydiimides by direct synthesis
    2.
    发明申请
    Method for the production of terylene-3,4:11,12-tetracarboxydiimides by direct synthesis 失效
    通过直接合成制备涤纶3,4：11,12-四羧酰亚胺的方法

    公开(公告)号：US20070155968A1

    公开(公告)日：2007-07-05

    申请号：US10586133

    申请日：2005-01-15

    申请人： Martin Konemann ,  Arno Bohm ,  Willi Helfer ,  Jurgen Romeis ,  Jianqiang Qu ,  Klaus Mullen

    发明人： Martin Konemann ,  Arno Bohm ,  Willi Helfer ,  Jurgen Romeis ,  Jianqiang Qu ,  Klaus Mullen

    IPC分类号： C07D471/02

    CPC分类号： C07D221/18 ,  C07D221/14 ,  C07D471/06

    摘要： A process for preparing terylene-3,4:11,12-tetracarboximides I where the variables are each defined as follows: R, R′ are each independently hydrogen; if desired substituted alkyl or cycloalkyl; R1 is hydrogen or alkyl; R2 is hydrogen; alkyl; if desired substituted aryl or hetaryl, by reacting a perylene-3,4-dicarboximide II in the presence of a base-stable, high-boiling organic solvent and of an alkali metal or alkaline earth metal base, with a naphthalene-1,8-dicarboximide III in which X is hydrogen, bromine or chlorine.

    摘要翻译： 制备三苯醚-3,4：11,12-四甲酰亚胺I的方法，其中各变量各自定义如下：R，R'各自独立地为氢; 如果需要，取代的烷基或环烷基; R 1是氢或烷基; R 2是氢; 烷基; 如果需要取代的芳基或杂芳基，通过在碱稳定的高沸点有机溶剂和碱金属或碱土金属碱的存在下使苝-3,4-二甲酰亚胺II与萘-1,8 二甲酰亚胺III，其中X是氢，溴或氯。

    Rylene Tetracarboxylic Acid Diimides Substituted By Cyclic Amino Groups
    3.
    发明申请
    Rylene Tetracarboxylic Acid Diimides Substituted By Cyclic Amino Groups 审中-公开
    由环状氨基取代的亚芳基四羧酸二酰亚胺

    公开(公告)号：US20090124732A1

    公开(公告)日：2009-05-14

    申请号：US11720409

    申请日：2005-11-26

    申请人： Martin Konemann ,  Jianqiang Qu ,  Klaus Mullen

    发明人： Martin Konemann ,  Jianqiang Qu ,  Klaus Mullen

    IPC分类号： C07D471/02 ,  C08K5/34 ,  C08K5/48 ,  C09D11/00

    CPC分类号： C09B5/62

    摘要： Rylenetetracarboximides of the general formula I in which the variables are each defined as follows: R, R′ are each independently hydrogen; optionally substituted C1-C30-alkyl, C3-C8-cycloalkyl, aryl or hetaryl; R1 is hydrogen or C1-C6-alkyl; R2, R3 are each independently hydrogen; optionally substituted C1-C18-alkyl, aryl or hetaryl; A is a 5- to 9-membered ring which is bonded via a nitrogen atom and whose carbon chain may be interrupted by one or more —O—, —S—, —NR1—, —CO— and/or —SO2— moieties, to which one or two unsaturated or saturated 4- to 8-membered rings may be fused, whose carbon chain may likewise be interrupted by these moieties and/or —N═, and the overall ring system may be mono- or polysubstituted, and where the A radicals may be the same or different when m>1; X is chlorine or bromine, and the X radicals may be the same or different when x>1; Z is optionally substituted C3-C20-alkyl, C3-C20-alken-2-yl, C3-C20-alkyn-2-yl, aryloxy, arylthio, hetaryloxy or hetarylthio, where the Z radicals may be the same or different when z>1; m is 1 or 2, n is from 1 to 4 when m=1; is from 1 to 6 when m=2; x is from 0 to 3 when m=1, where n+x+z≦4, is from 0 to 5 when m=2, where n+x+z≦6; z is from 0 to 3 when m=1, where n+x+z≦4, is from 0 to 5 when m=2, where n+x+z≦6.

    摘要翻译： 其中各个变量各自定义如下：通式I的四环四甲酰亚胺化物：R，R'各自独立地为氢; 任选取代的C 1 -C 30 - 烷基，C 3 -C 8 - 环烷基，芳基或杂芳基; R1是氢或C1-C6-烷基; R2，R3各自独立地为氢; 任选取代的C 1 -C 18 - 烷基，芳基或杂芳基; A是通过氮原子键合并且其碳链可以被一个或多个-O - ， - S - ， - NR 1 - ， - CO - 和/或-SO 2 - 部分间隔的5至9元环 可以将一个或两个不饱和或饱和的4至8元环稠合，其碳链同样可被这些部分和/或-N-间隔，并且整个环系统可以是单取代或多取代的，以及 当m> 1时，A基团可以相同或不同; X是氯或溴，当x> 1时X基团可以相同或不同; Z是任选取代的C 3 -C 20 - 烷基，C 3 -C 20 - 烯-2-基，C 3 -C 20 - 炔-2-基，芳氧基，芳硫基，杂芳氧基或杂芳硫基，其中Z基可以相同或不同，当z > 1; m为1或2，当m = 1时，n为1至4; 当m = 2时为1〜6; 当m = 1时，x为0至3，其中n + x + z <= 4，当m = 2时为0至5，其中n + x + z <= 6; 当m = 1时，z为0至3，其中n + x + z <= 4，当m = 2时为0至5，其中n + x + z <= 6。

    Terrylene and Quaterrylene Derivatives
    4.
    发明申请
    Terrylene and Quaterrylene Derivatives 有权

    公开(公告)号：US20080255357A1

    公开(公告)日：2008-10-16

    申请号：US11913333

    申请日：2006-05-03

    申请人： Neil Gregory Pschirer ,  Jianqiang Qu ,  Martin Konemann

    发明人： Neil Gregory Pschirer ,  Jianqiang Qu ,  Martin Konemann

    IPC分类号： C07D221/18 ,  C07D487/06 ,  C07D235/02

    CPC分类号： C07D493/06 ,  C07C1/2078 ,  C07D221/18 ,  C07D311/78 ,  C07D491/06 ,  C07F5/025 ,  C09B3/14 ,  C09B5/62 ,  C07C13/62

    摘要： Rylene derivatives of the general formula I in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (a), (b) or (c) are both a —COOM radical; are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) Y are joined to one another with formation of a six-membered ring to give a radical of the formula (a) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or together are a radical of the formula (a), (b) or (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (b) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (c) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c) which may be arranged in the cis or trans position to the other (c) radical; are both a —COOM radical when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical, M being different from hydrogen in the case that one X radical is a radical of the formula (d); are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) when both X radicals are hydrogen or one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d); R are identical or different radicals: substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio; R′ is hydrogen; substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl; A are each independently substituted or unsubstituted phenylene, naphthylene or pyridylene; M is hydrogen, ammonium or alkali metal cation; R″ are each independently hydrogen, alkyl, cycloalkyl, aryl or hetaryl, or are joined together with formation of a 5- to 7-membered, fused or unfused and substituted or unsubstituted ring comprising the two oxygen atoms and also the boron atom; R1 is hydrogen or alkyl, where the R1 radicals may be the same or different when they occur more than once; R2, R3 are each independently hydrogen; substituted or unsubstituted alkyl, aryl or hetaryl; m is 1 or 2; n is from 3 to 6 where m=1; is from 2 to 8 where m=2, and mixtures thereof.

    Substituted Rylene Derivatives
    5.
    发明申请
    Substituted Rylene Derivatives 有权
    取代的Rylene衍生物

    公开(公告)号：US20080167467A1

    公开(公告)日：2008-07-10

    申请号：US11994719

    申请日：2006-07-06

    申请人： Martin Konemann ,  Arno Bohm ,  Neil Gregory Pschirer ,  Jianqiang Qu ,  Gabriele Mattern

    发明人： Martin Konemann ,  Arno Bohm ,  Neil Gregory Pschirer ,  Jianqiang Qu ,  Gabriele Mattern

    IPC分类号： C07D221/18

    CPC分类号： C07D493/06 ,  C07D471/06 ,  C08K5/0041 ,  C08K5/3437

    摘要： Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.

    摘要翻译： 通式I的亚芳基衍生物各自定义如下：Rylene是多环共轭环系，其包含至少一个苝单元可以包含杂原子作为环原子，可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团：任选取代的烷基，环烷基，芳基，杂芳基，-U-芳基，其中U是-O - ， - S - ， - NR 2 - ， - CO-， - SO - 或-SO 2 - 部分，或C 1 -C 12 - 烷氧基，C 1 -C -C≡CR2，-CR 2 -CR 2，2 - ， - 羟基，巯基，卤素，氰基，硝基，-NR 3，R 4，-NR 3，COR 4， SO 2，SO 2，SO 2，SO 2，SO 3，SO 4，SO 2， >，-COOR 3或-SO 3 R 3; R'是相同或不同的基团：氢或R基团之一; R 2是氢或烷基，其中R 2个基团当它们不止一次出现时可以相同或不同; R 3，R 4各自独立地为氢; 任选取代的烷基，芳基或杂芳基; n为1至8。