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公开(公告)号：US20160075825A1
公开(公告)日：2016-03-17
申请号：US14786986
申请日：2014-04-22
发明人： Martin Roos , Jürgen Herwig , Kévin Micoine , Frank Weinelt
CPC分类号： C08G65/46 , B01D61/027 , B01D2311/04 , B01D2311/12 , C08G65/40 , C08G65/44 , C08G65/485
摘要： The invention relates to a method for the purification of poly(arylene ethers) of formula (I) in which m=0 to 1.0, n=1.0-m, and Ar1, Ar2, Ar3 and Ar4 independently represent divalent arylene groups. The compound of formula (I) is produced in a first step 1, with a raw product being obtained by bringing a metal or ammonium salt of divalent dihydroxy derivatives of Ar1 or Ar3 into contact with one or more dihalogenated derivatives of Ar2 and/or Ar4, in the presence of a solvent LM1. A precipitate that is present, if appropriate, is separated (step B) so as to obtain a solution L which then undergoes a membrane filtration (step C).
摘要翻译： 本发明涉及一种纯化式（I）的聚（亚芳基醚）的方法，其中m = 0至1.0，n = 1.0-m，Ar1，Ar2，Ar3和Ar4独立地表示二价亚芳基。 在第一步骤1中制备式（I）化合物，其中通过使Ar1或Ar3的二价二羟基衍生物的金属或铵盐与一种或多种Ar 2和/或Ar 4的二卤代衍生物接触而得到 ，在溶剂LM1存在下。 如果合适，存在沉淀物（步骤B），得到溶液L，然后进行膜过滤（步骤C）。
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公开(公告)号：US09598537B2
公开(公告)日：2017-03-21
申请号：US14786986
申请日：2014-04-22
申请人： Martin Roos , Jürgen Herwig , Kévin Micoine , Frank Weinelt
发明人： Martin Roos , Jürgen Herwig , Kévin Micoine , Frank Weinelt
CPC分类号： C08G65/46 , B01D61/027 , B01D2311/04 , B01D2311/12 , C08G65/40 , C08G65/44 , C08G65/485
摘要： The invention relates to a method for the purification of poly(arylene ethers) of formula (I) in which m=0 to 1.0, n=1.0-m, and Ar1, Ar2, Ar3 and Ar4 independently represent divalent arylene groups. The compound of formula (I) is produced in a first step 1, with a raw product being obtained by bringing a metal or ammonium salt of divalent dihydroxy derivatives of Ar1 or Ar3 into contact with one or more dihalogenated derivatives of Ar2 and/or Ar4, in the presence of a solvent LM1. A precipitate that is present, if appropriate, is separated (step B) so as to obtain a solution L which then undergoes a membrane filtration (step C).
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公开(公告)号：US09637436B2
公开(公告)日：2017-05-02
申请号：US14873827
申请日：2015-10-02
申请人： Kévin Micoine , Ralf Meier , Jürgen Herwig , Angélique Bétard , Thomas Quandt
发明人： Kévin Micoine , Ralf Meier , Jürgen Herwig , Angélique Bétard , Thomas Quandt
IPC分类号： B01J21/12 , B01J23/42 , B01J37/12 , C07C45/58 , B01J35/00 , B01J21/06 , B01J21/08 , B01J23/38 , B01J23/40 , B01J23/44 , B01J35/10 , B01J37/00 , B01J37/02 , B01J35/02 , B01J37/08 , C07D225/02
CPC分类号： C07C45/58 , B01J21/066 , B01J21/08 , B01J23/38 , B01J23/40 , B01J23/44 , B01J35/0006 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1085 , B01J37/0009 , B01J37/0201 , B01J37/0207 , B01J37/08 , C07C2601/20 , C07D225/02 , C07C49/307
摘要： A catalyst composition is useful for producing a ketone from a compound containing at least one epoxide group, and the catalyst composition contains at least one precious metal; and at least one mixed oxide; wherein the mixed oxide contains zirconium dioxide and silicon dioxide; wherein the precious metal is supported and the support is not entirely made of the mixed oxide; and wherein a mass ratio of zirconium dioxide to silicon dioxide in the mixed oxide is 86:14 to 99.9:0.1.
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公开(公告)号：US20160096794A1
公开(公告)日：2016-04-07
申请号：US14873827
申请日：2015-10-02
申请人： Kévin Micoine , Ralf Meier , Juergen Herwig , Angélique Bétard , Thomas Quandt
发明人： Kévin Micoine , Ralf Meier , Juergen Herwig , Angélique Bétard , Thomas Quandt
IPC分类号： C07C45/58 , B01J21/08 , C07D225/02 , B01J37/02 , B01J35/02 , B01J35/10 , B01J23/44 , B01J37/08
CPC分类号： C07C45/58 , B01J21/066 , B01J21/08 , B01J23/38 , B01J23/40 , B01J23/44 , B01J35/0006 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1085 , B01J37/0009 , B01J37/0201 , B01J37/0207 , B01J37/08 , C07C2601/20 , C07D225/02 , C07C49/307
摘要： A catalyst composition is useful for producing a ketone from a compound containing at least one epoxide group, and the catalyst composition contains at least one precious metal; and at least one mixed oxide; wherein the mixed oxide contains zirconium dioxide and silicon dioxide; wherein the precious metal is supported and the support is not entirely made of the mixed oxide; and wherein a mass ratio of zirconium dioxide to silicon dioxide in the mixed oxide is 86:14 to 99.9:0.1.
摘要翻译： 催化剂组合物可用于从含有至少一个环氧基的化合物制备酮，并且催化剂组合物含有至少一种贵金属; 和至少一种混合氧化物; 其中所述混合氧化物含有二氧化锆和二氧化硅; 其中所述贵金属被支撑并且所述支撑体不完全由所述混合氧化物制成; 并且其中所述混合氧化物中二氧化锆与二氧化硅的质量比为86:14至99.9:0.1。
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公开(公告)号：US09643153B2
公开(公告)日：2017-05-09
申请号：US14714985
申请日：2015-05-18
申请人： Ralf Meier , Kévin Micoine , Peter Kreis , Frederik Gluth , Markus Priske
发明人： Ralf Meier , Kévin Micoine , Peter Kreis , Frederik Gluth , Markus Priske
IPC分类号： C07D301/32 , B01J19/24 , C07D225/02 , B01D61/02 , B01J31/40 , C07D301/12
CPC分类号： B01J19/2475 , B01D61/027 , B01D2311/02 , B01J31/4061 , B01J2219/24 , B01J2231/72 , B01J2531/56 , B01J2531/64 , B01J2531/66 , B01J2531/985 , B01J2540/42 , C07D201/02 , C07D225/02 , C07D301/12 , C07D301/32 , Y02P20/584
摘要： A homogeneous catalyst system is removed from a reaction mixture of two liquid phases by separating the two liquid phases with a membrane having at least one separation-active layer in such a way that the homogeneous catalyst system is at least partially concentrated in a membrane retentate; wherein the reaction mixture contains at least one partially epoxidized cyclic unsaturated compound having twelve carbon atoms; and wherein the membrane separation-active layer contains crosslinked a silicone acrylate and/or polydimethylsiloxane and/or polyimide.
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6.发明申请公开(公告)号：US20170095789A1
公开(公告)日：2017-04-06
申请号：US15382991
申请日：2016-12-19
申请人： Ralf MEIER , Kévin Micoine , Peter Kreis , Frederik Gluth , Markus Priske
发明人： Ralf MEIER , Kévin Micoine , Peter Kreis , Frederik Gluth , Markus Priske
IPC分类号： B01J19/24 , B01D61/02 , C07D301/32 , C07D201/02 , C07D225/02 , C07D301/12
摘要： An apparatus for the epoxidation of a cyclic unsaturated C12 compound with hydrogen peroxide is provided. The apparatus includes a reactor for carrying out the reaction, wherein the walls of the reactor are at least partially furnished with a separation-active layer of crosslinked silicone acrylates and/or polydimethylsiloxane.
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