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1.发明授权Process for producing thermoplastic molding compositions based on styrene copolymers and polyamide with improved toughness 失效基于苯乙烯共聚物和具有改进韧性的聚酰胺生产热塑性模塑组合物的方法公开(公告)号：US08648143B2
公开(公告)日：2014-02-11
申请号：US13547830
申请日：2012-07-12
摘要： Processes for producing thermoplastic molding compositions, which comprise a) from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units, b) from 15 to 91% by weight of one or more polyamides, c) from 5 to 50% by weight of one or more rubbers, d) from 1 to 25% by weight of one or more compatibilizers, e) from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) from 0 to 40% by weight of further additives, by producing a melt comprising components A, B, and C in a first step and subsequently incorporating D, Also, thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and moldings, fibers, and foils comprising these thermoplastic molding compositions.
摘要翻译： 制备热塑性模塑组合物的方法，其包含a）3至79重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有马来酸酐衍生的单元，b）15至91重量％ 一种或多种聚酰胺，c）5至50重量％的一种或多种橡胶，d）1至25重量％的一种或多种相容剂，e）0至2重量％的一种或多种低聚物， 包含二羧酸酐基团的分子量化合物，f）0至50重量％的一种或多种纤维或颗粒填料，和g）0至40重量％的其它添加剂，通过制备包含组分A ，B和C，并且随后掺入D。此外，可通过这些方法获得的热塑性模塑组合物，这些热塑性模塑组合物的使用以及包含这些热塑性模塑组合物的模制品，纤维和箔。
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2.发明申请PROCESS FOR PRODUCING THERMOPLASTIC MOLDING COMPOSITIONS BASED ON STYRENE COPOLYMERS AND POLYAMIDE WITH IMPROVED TOUGHNESS 失效基于苯乙烯共聚物和具有改善的韧性的聚酰胺制造热塑性成型组合物的方法公开(公告)号：US20130023619A1
公开(公告)日：2013-01-24
申请号：US13547830
申请日：2012-07-12
摘要： Processes for producing thermoplastic molding compositions, which comprise a) from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units, b) from 15 to 91% by weight of one or more polyamides, c) from 5 to 50% by weight of one or more rubbers, d) from 1 to 25% by weight of one or more compatibilizers, e) from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) from 0 to 40% by weight of further additives, by producing a melt comprising components A, B, and C in a first step and subsequently incorporating D, Also, thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and moldings, fibers, and foils comprising these thermoplastic molding compositions.
摘要翻译： 制备热塑性模塑组合物的方法，其包含a）3至79重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有马来酸酐衍生的单元，b）15至91重量％ 一种或多种聚酰胺，c）5至50重量％的一种或多种橡胶，d）1至25重量％的一种或多种相容剂，e）0至2重量％的一种或多种低聚物， 包含二羧酸酐基团的分子量化合物，f）0至50重量％的一种或多种纤维或颗粒填料，和g）0至40重量％的其它添加剂，通过制备包含组分A ，B和C，并且随后掺入D。此外，可通过这些方法获得的热塑性模塑组合物，这些热塑性模塑组合物的使用以及包含这些热塑性模塑组合物的模制品，纤维和箔。
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3.发明申请PROCESS FOR PRODUCING THERMOPLASTIC MOLDING COMPOSITIONS BASED ON STYRENE COPOLYMERS AND POLYAMIDE WITH IMPROVED TOUGHNESS 审中-公开基于苯乙烯共聚物和具有改善的韧性的聚酰胺制造热塑性成型组合物的方法公开(公告)号：US20110178205A1
公开(公告)日：2011-07-21
申请号：US12986718
申请日：2011-01-07
IPC分类号： C08K5/151
摘要： The invention relates to processes for producing thermoplastic molding compositions, where the thermoplastic molding compositions comprise a) as component A, from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units. b) as component B, from 15 to 91% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more rubbers, d) as component D, from 1 to 25% by weight of one or more compatibilizers, e) as component E, from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) as component G, from 0 to 40% by weight of further additives, where each of the % by weight values is based on the total weight of components A to G, and these give a total of 100% by weight, via mixing of components A to G in the melt, which comprises producing a melt comprising components A, B, and C in a first step of the process, in the absence of component D, and delaying the mixing to incorporate component D into this melt until a subsequent second step of the process, and also to thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and also moldings, fibers, and foils comprising these thermoplastic molding compositions.
摘要翻译： 本发明涉及生产热塑性模塑组合物的方法，其中热塑性模塑组合物包含a）作为组分A，3至79重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有马来酸酐衍生物 单位。 b）作为组分B，15至91重量％的一种或多种聚酰胺，c）作为组分C，5至50重量％的一种或多种橡胶，d）作为组分D，1至25重量％ 一种或多种增容剂的重量，e）作为组分E，0至2重量％的一种或多种低分子量化合物，其包含二羧酸酐基团，f）作为组分F，0至50重量％ 的一种或多种纤维或颗粒填料，和g）作为组分G，0至40重量％的另外的添加剂，其中每个重量％的值基于组分A至G的总重量，并且这些给出 总共100重量％，通过混合熔体中的组分A至G，其包括在该方法的第一步中产生包含组分A，B和C的熔体，在不存在组分D的情况下，并延迟 混合以将组分D掺入该熔体中，直到该方法的随后的第二步，以及可通过这些方法获得的热塑性模塑组合物 这些热塑性模塑组合物的使用，以及包含这些热塑性模塑组合物的模制品，纤维和箔。
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4.发明申请THERMOPLASTIC MOLDING COMPOUNDS CONTAINING STYRENE COPOLYMERS AND POLYAMIDES 审中-公开含有苯乙烯共聚物和聚酰胺的热塑性成型化合物公开(公告)号：US20110319550A1
公开(公告)日：2011-12-29
申请号：US13148393
申请日：2010-01-29
申请人： Martin Weber , Simone Schillo , Marko Blinzler , Jürgen Deininger
发明人： Martin Weber , Simone Schillo , Marko Blinzler , Jürgen Deininger
CPC分类号： C08L25/08 , C08K7/02 , C08L21/00 , C08L25/04 , C08L25/12 , C08L35/06 , C08L55/02 , C08L77/00 , C08L2666/16 , C08L2666/02 , C08L2666/20 , C08L2666/06
摘要： The thermoplastic molding composition comprises a) as component A, from 3 to 79% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 91% by weight of one or more polyamides having, based on the entire component B, from 0.1 to 0.2% by weight of triacetonediamine (TAD) end groups, c) as component C, from 5 to 50% by weight of one or more impact-modifying rubbers, d) as component D, from 1 to 25% by weight of a styrene copolymer which, based on the entire component D, has from 1.9 to 2.3% by weight of units derived from maleic anhydride, e) as component E, from 0 to 40% by weight of further rubbers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the molding composition comprises less than 0.1% by weight of phthalic anhydride and the total amount of components A to D and, if appropriate, E to G is 100% by weight.
摘要翻译： 热塑性模塑组合物包含a）作为组分A，3至79重量％的一种或多种苯乙烯共聚物，其不具有源自马来酸酐的单元，b）作为组分B，15至91重量％的一种或多种 具有基于整个组分B的0.1至0.2重量％的三丙酮二胺（TAD）端基的聚酰胺，c）作为组分C，5至50重量％的一种或多种冲击改性橡胶，d）为 组分D，1至25重量％的苯乙烯共聚物，其基于整个组分D，具有1.9至2.3重量％的源自马来酸酐的单元，e）作为组分E，0至40重量％ f）作为组分F，0至50重量％的一种或多种纤维或颗粒填料，g）作为组分G，0至40重量％的其它添加剂，其中模塑组合物包含较少的 0.1重量％以上的邻苯二甲酸酐和成分A〜D的总量，如果合适，E〜G为100重量％ 重量。
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5.发明申请公开(公告)号：US20150291793A1
公开(公告)日：2015-10-15
申请号：US14347786
申请日：2012-09-03
申请人： Rolf Minkwitz , Martin Weber , Marko Blinzler , Wenke Wollny
发明人： Rolf Minkwitz , Martin Weber , Marko Blinzler , Wenke Wollny
CPC分类号： C08L77/02 , C08G73/0273 , C08G73/0644 , C08J5/18 , C08J2377/02 , C08J2413/00 , C08J2423/08 , C08J2425/12 , C08K5/3435 , C08K5/34926 , C08K7/02 , C08L35/06 , C08L51/003 , C08L77/06 , C08L2203/12 , C08L2203/16 , C08L2205/025 , C08L2205/035 , C08L2207/04 , D01F6/30 , D01F6/36 , D01F6/42 , C08L77/00 , C08L25/12 , C08L79/04
摘要： Thermoplastic molding compositions comprising: a) 3 to 91.8 wt % of at least one polyamide, as component A, b) 3 to 91.8 wt % of one or more styrene copolymers B without any maleic anhydride-derived units, c) 3 to 91.8 wt % of one or more impact-modifying grafted rubbers C, d) 0.2 to 1.5 wt % of a compound of formula (I), as component D: e) 0 to 0.9 wt % of a mixture of formula (II), as component E: f) 0 to 0.9 wt % of a further stabilizer component F, g) 1 to 25 wt % of one or more styrene copolymers G, h) 1 to 30 wt % of one or more further rubbers, exhibit improved weathering resistance.
摘要翻译： 热塑性成型组合物，其包含：a）3至91.8重量％的至少一种作为组分A的聚酰胺，b）3至91.8重量％的一种或多种苯乙烯共聚物B，不含任何马来酸酐衍生的单元，c）3至91.8重量％ ％的一种或多种冲击改性接枝橡胶C，d）0.2-1.5wt％的式（I）化合物作为组分D：e）0-0.9wt％的式（II）的混合物作为组分 E：f）0至0.9重量％的其它稳定剂组分F，g）1至25重量％的一种或多种苯乙烯共聚物G，h）1至30重量％的一种或多种另外的橡胶表现出改善的耐候性。
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公开(公告)号：US20120059109A1
公开(公告)日：2012-03-08
申请号：US13319754
申请日：2010-05-06
CPC分类号： C08L25/12 , C08L25/14 , C08L69/00 , C08L101/005 , C08L2666/02
摘要： The thermoplastic molding composition comprises: a) as component A, from 0 to 97.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which do not have any units derived from maleic anhydride, and which have an intrinsic viscosity smaller than 85 ml/g, b) as component B, from 1 to 98.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which have, based on the entire component B, from 0.5 to 5% by weight of units derived from maleic anhydride, c) as component C, from 1 to 75% by weight of glass fibers, d) from 0.1 to 20% by weight of one or more flow promoters, selected from d1) as component D1, at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), d2) as component D2, at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, d3) as component D3, alkyl acrylate oligomers with a weight-average molar mass in the range from 1200 to 4000 g/mol, e) as component E, from 0 to 40% by weight of further fillers, or rubbers, and/or further additives, where the total amount of components A to D and, if present, E is 100% by weight.
摘要翻译： 热塑性模塑组合物包含：a）作为组分A，0至97.9重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有源自马来酸酐的任何单元，并且其特性粘度小于85 ml / g，b）作为组分B，1至98.9重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其基于整个组分B为0.5至5重量％的衍生自马来酸的单元 酸酐，c）作为组分C，1至75重量％的玻璃纤维，d）0.1至20重量％的一种或多种流动促进剂，选自d1）作为组分D1，至少一种高度支化或超支化 OH值为1至600mg KOH / g聚碳酸酯的聚碳酸酯（根据DIN 53240，第2部分），d2）作为组分D2，至少一种高度支化或超支化的AxBy型聚酯，其中x至少为1.1， y至少为2.1，d3）作为组分D3，具有重均摩尔质量的丙烯酸烷基酯低聚物 范围从1200至4000g / mol，e）作为组分E，0至40重量％的另外的填料或橡胶，和/或其它添加剂，其中组分A至D的总量，如果存在， E为100重量％。
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7.发明申请THERMOPLASTIC MOLDING COMPOUNDS BASED ON STYRENE COPOLYMERS AND POLYAMIDES HAVING IMPROVED WEATHERING RESISTANCE 有权基于苯乙烯共聚物和具有改善耐候性的聚酰胺的热塑性成型化合物公开(公告)号：US20110306701A1
公开(公告)日：2011-12-15
申请号：US13148399
申请日：2010-01-29
CPC分类号： C08F285/00 , C08K7/02 , C08L21/00 , C08L25/04 , C08L25/08 , C08L25/12 , C08L35/06 , C08L55/02 , C08L77/00 , C08F220/44 , C08F212/08 , C08L2666/20 , C08L2666/08 , C08L2666/02
摘要： The thermoplastic molding composition comprises a) as component A, from 3 to 78% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 90% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more impact-modifying graft rubbers without olefinic double bonds in the rubber phase, d) as component D, from 1 to 25% by weight of one or more styrene copolymers which have, based on the entire component D, from 0.5 to 5% by weight of units derived from maleic anhydride, e) as component E, from 1 to 30% by weight of one or more further rubbers based on olefinic monomers without core-shell structure, and having at least 0.1% by weight of functional monomers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the entire amount of components A to E and, if appropriate, F and G is 100% by weight.
摘要翻译： 所述热塑性模塑组合物包含a）作为组分A，3至78重量％的一种或多种苯乙烯共聚物，其不具有源自马来酸酐的单元，b）作为组分B，15至90重量％的一种或多种 聚酰胺，c）作为组分C，5-50重量％的橡胶相中没有烯属双键的一种或多种冲击改性接枝橡胶，d）作为组分D，1至25重量％的一种或多种 苯乙烯共聚物，其基于整个组分D，0.5-5重量％的源自马来酸酐的单元，e）作为组分E，1-30重量％的一种或多种基于烯烃单体的另外的橡胶，没有 核 - 壳结构，并且具有至少0.1重量％的官能单体，f）作为组分F，0至50重量％的一种或多种纤维或颗粒填料，g）作为组分G，0至40重量％ 的其他添加剂，其中组分A至E的总量和如果合适的话，F和G为100％ 重量。
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8.发明授权Thermoplastic molding compounds based on styrene copolymers and polyamides having improved weathering resistance 有权基于苯乙烯共聚物和具有改善耐候性的聚酰胺的热塑性模塑料公开(公告)号：US08889767B2
公开(公告)日：2014-11-18
申请号：US13148399
申请日：2010-01-29
IPC分类号： C08J3/20 , C08K5/15 , C08L25/08 , C08L77/00 , C08L25/04 , C08F285/00 , C08L21/00 , C08L35/06 , C08L25/12 , C08K7/02 , C08L55/02
CPC分类号： C08F285/00 , C08K7/02 , C08L21/00 , C08L25/04 , C08L25/08 , C08L25/12 , C08L35/06 , C08L55/02 , C08L77/00 , C08F220/44 , C08F212/08 , C08L2666/20 , C08L2666/08 , C08L2666/02
摘要： The thermoplastic molding composition comprises a) as component A, from 3 to 78% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 90% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more impact-modifying graft rubbers without olefinic double bonds in the rubber phase, d) as component D, from 1 to 25% by weight of one or more styrene copolymers which have, based on the entire component D, from 0.5 to 5% by weight of units derived from maleic anhydride, e) as component E, from 1 to 30% by weight of one or more further rubbers based on olefinic monomers without core-shell structure, and having at least 0.1% by weight of functional monomers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the entire amount of components A to E and, if appropriate, F and G is 100% by weight.
摘要翻译： 所述热塑性模塑组合物包含a）作为组分A，3至78重量％的一种或多种苯乙烯共聚物，其不具有源自马来酸酐的单元，b）作为组分B，15至90重量％的一种或多种 聚酰胺，c）作为组分C，5-50重量％的橡胶相中没有烯属双键的一种或多种冲击改性接枝橡胶，d）作为组分D，1至25重量％的一种或多种 苯乙烯共聚物，其基于整个组分D，0.5-5重量％的源自马来酸酐的单元，e）作为组分E，1-30重量％的一种或多种基于烯烃单体的另外的橡胶，没有 核 - 壳结构，并且具有至少0.1重量％的官能单体，f）作为组分F，0至50重量％的一种或多种纤维或颗粒填料，g）作为组分G，0至40重量％ 的其他添加剂，其中组分A至E的总量和如果合适的话，F和G为100％ 重量。
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公开(公告)号：US08853319B2
公开(公告)日：2014-10-07
申请号：US13319754
申请日：2010-05-06
IPC分类号： C08G18/08 , C08L25/12 , C08L25/14 , C08L69/00 , C08L101/00
CPC分类号： C08L25/12 , C08L25/14 , C08L69/00 , C08L101/005 , C08L2666/02
摘要： The thermoplastic molding composition comprises: a) as component A, from 0 to 97.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which do not have any units derived from maleic anhydride, and which have an intrinsic viscosity smaller than 85 ml/g, b) as component B, from 1 to 98.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which have, based on the entire component B, from 0.5 to 5% by weight of units derived from maleic anhydride, c) as component C, from 1 to 75% by weight of glass fibers, d) from 0.1 to 20% by weight of one or more flow promoters, selected from d1) as component D1, at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), d2) as component D2, at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, d3) as component D3, alkyl acrylate oligomers with a weight-average molar mass in the range from 1200 to 4000 g/mol, e) as component E, from 0 to 40% by weight of further fillers, or rubbers, and/or further additives, where the total amount of components A to D and, if present, E is 100% by weight.
摘要翻译： 热塑性模塑组合物包含：a）作为组分A，0至97.9重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有源自马来酸酐的任何单元，并且其特性粘度小于85 ml / g，b）作为组分B，1至98.9重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其基于整个组分B为0.5至5重量％的衍生自马来酸的单元 酸酐，c）作为组分C，1至75重量％的玻璃纤维，d）0.1至20重量％的一种或多种流动促进剂，选自d1）作为组分D1，至少一种高度支化或超支化 OH值为1至600mg KOH / g聚碳酸酯的聚碳酸酯（根据DIN 53240，第2部分），d2）作为组分D2，至少一种高度支化或超支化的AxBy型聚酯，其中x至少为1.1， y至少为2.1，d3）作为组分D3，具有重均摩尔质量的丙烯酸烷基酯低聚物 范围从1200至4000g / mol，e）作为组分E，0至40重量％的另外的填料或橡胶，和/或其它添加剂，其中组分A至D的总量，如果存在， E为100重量％。
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10.发明申请THERMOPLASTIC MOLDING COMPOUNDS ON THE BASIS OF STYRENE COPOLYMERS AND POLYAMIDES HAVING IMPROVED LOW-TEMPERATURE TOUGHNESS 审中-公开基于苯乙烯共聚物和具有改善的低温韧性的聚酰胺的热塑性模塑化合物公开(公告)号：US20130345353A1
公开(公告)日：2013-12-26
申请号：US13992852
申请日：2011-12-19
申请人： Martin Weber , Marko Blinzler
发明人： Martin Weber , Marko Blinzler
IPC分类号： C08L33/20
CPC分类号： C08L33/20 , C08K5/1539 , C08L25/08 , C08L25/12 , C08L51/06 , C08L55/02 , C08L77/00 , C08L77/02 , C08L2666/02
摘要： The invention relates to thermoplastic molding compounds, containing a) 3 to 91.9 wt % of one or more styrene copolymers as component A, b) 3 to 91 wt % of one or more polyamides as component B, c) 3 to 50 wt % of one or more graft natural rubbers as component C, d) 0.1 to 25 wt % of one or more compatibilizers as component D, and e) 2 to 30 wt % of ethylene-1-octene copolymer having functional groups as component E, said thermoplastic molding compounds having improved low-temperature toughness.
摘要翻译： 本发明涉及热塑性模塑料，其包含：a）3至91.9重量％的一种或多种苯乙烯共聚物作为组分A，b）3至91重量％的一种或多种作为组分B的聚酰胺，c）3至50重量％ 作为组分C的一种或多种接枝天然橡胶，d）作为组分D的0.1至25重量％的一种或多种相容剂，和e）2至30重量％的具有官能团作为组分E的乙烯-1-辛烯共聚物，所述热塑性 具有改善的低温韧性的成型化合物。
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