Process for the Preparation of Hyperbranched Hollow Fibers
    4.
    发明申请
    Process for the Preparation of Hyperbranched Hollow Fibers 有权
    超支化中空纤维的制备方法

    公开(公告)号:US20120213998A1

    公开(公告)日:2012-08-23

    申请号:US13504717

    申请日:2010-10-26

    IPC分类号: D02G3/22 D01D5/24

    摘要: The invention relates to a process for the preparation of a hollow filament (F) based on one or several molten or dissolved hyperbranched polymers (P) and potentially one or several further polymers (FP), characterized in that the molten or dissolved hyperbranched polymer (P) or the mixture of the hyperbranched polymer (P) with the further polymer (FP) is passed through one or several spinnerets (S), wherein the ratio between the spinneret die-length (L) and the die-channel (Delta-D) is between 0.1 and 9.5. The process can be applied for the preparation of hyperbranched polyethersulfone (HPES) hollow filaments.

    摘要翻译: 本发明涉及一种基于一种或多种熔融或溶解的超支化聚合物(P)和潜在的一种或几种其它聚合物(FP)制备中空丝(F)的方法,其特征在于,熔融或溶解的超支化聚合物 P)或超支化聚合物(P)与其它聚合物(FP)的混合物通过一个或多个喷丝头(S),其中喷丝头长度(L)和模头通道(Delta- D)在0.1和9.5之间。 该方法可用于制备超支化聚醚砜(HPES)中空丝。

    BLENDS FROM BRANCHED POLYARYL ETHERS AND HYDROPHILIC POLYMERS
    5.
    发明申请
    BLENDS FROM BRANCHED POLYARYL ETHERS AND HYDROPHILIC POLYMERS 失效
    分散式聚合物和水解聚合物的共混

    公开(公告)号:US20100197859A1

    公开(公告)日:2010-08-05

    申请号:US12677022

    申请日:2008-08-27

    摘要: The present invention provides polymer blends comprising the components (a) from 40% to 95% by weight of at least one polyaryl ether copolymer constructed of (a1) from 50% to 99.9% by weight of building units of the general formula I and from 0% to 40% by weight of further building units II selected from segments of one or more thermoplastic polymers, and (a2) from 0.1% to 10% by weight of at least one crosslinker V having at least three hydroxyl functionalities, the at least one crosslinker V being present in component (a) in converted form and the sum total of % by weight for (a1) and (a2) being 100% by weight, and (b) from 5% to 60% by weight of at least one hydrophilic polymer selected from polyvinylpyrrolidone, polyvinylpyrrolidone copolymers, polyethylene glycol, polypropylene glycol, copolymers of ethylene glycol and propylene glycol, water-soluble cellulose derivatives, polyamide, polyvinyl acetate and polyvinyl alcohol, where the sum total of % by weight for components (a) and (b) is 100% by weight. The present invention also provides combinations of distinct components (a) and (b) for conjoint use. The invention further provides polymer membranes comprising the aforementioned polymer blends and also a process for their production and the use of the polymer membranes for producing dialysis filters. The present invention also provides dialysis filters comprising the aforementioned hollow fiber membranes.

    摘要翻译: 本发明提供了聚合物共混物,其包含组分(a)40重量%至95重量%的至少一种由(a1)50至99.9重量%的通式I的构建单元构成的至少一种聚芳基醚共聚物, 0%至40%重量的选自一种或多种热塑性聚合物的段的另外的建筑单元II,和(a2)0.1%至10%重量的至少一种具有至少三个羟基官能团的交联剂V,至少 一种交联剂V以转化形式存在于组分(a)中,(a1)和(a2)的重量%的总和为100重量%,和(b)至少5重量%至60重量% 一种选自聚乙烯吡咯烷酮,聚乙烯吡咯烷酮共聚物,聚乙二醇,聚丙二醇,乙二醇和丙二醇的共聚物,水溶性纤维素衍生物,聚酰胺,聚乙酸乙烯酯和聚乙烯醇的亲水性聚合物,其中组分(a )和 (b)为100重量%。 本发明还提供了用于联合使用的不同组分(a)和(b)的组合。 本发明还提供了包含上述聚合物共混物的聚合物膜,以及它们的生产方法和用于生产透析过滤器的聚合物膜的用途。 本发明还提供了包含上述中空纤维膜的透析过滤器。

    Blends from branched polyaryl ethers and hydrophilic polymers
    6.
    发明授权
    Blends from branched polyaryl ethers and hydrophilic polymers 失效
    来自支链聚芳基醚和亲水性聚合物的共混物

    公开(公告)号:US08222342B2

    公开(公告)日:2012-07-17

    申请号:US12677022

    申请日:2008-08-27

    IPC分类号: C08G63/91

    摘要: The present invention provides polymer blends comprising the components (a) from 40% to 95% by weight of at least one polyaryl ether copolymer constructed of (a1) from 50% to 99.9% by weight of building units of the general formula I and from 0% to 40% by weight of further building units II selected from segments of one or more thermoplastic polymers, and (a2) from 0.1% to 10% by weight of at least one crosslinker V having at least three hydroxyl functionalities, the at least one crosslinker V being present in component (a) in converted form and the sum total of % by weight for (a1) and (a2) being 100% by weight, and (b) from 5% to 60% by weight of at least one hydrophilic polymer selected from polyvinylpyrrolidone, polyvinylpyrrolidone copolymers, polyethylene glycol, polypropylene glycol, copolymers of ethylene glycol and propylene glycol, water-soluble cellulose derivatives, polyamide, polyvinyl acetate and polyvinyl alcohol, where the sum total of % by weight for components (a) and (b) is 100% by weight. The present invention also provides combinations of distinct components (a) and (b) for conjoint use. The invention further provides polymer membranes comprising the aforementioned polymer blends and also a process for their production and the use of the polymer membranes for producing dialysis filters. The present invention also provides dialysis filters comprising the aforementioned hollow fiber membranes.

    摘要翻译: 本发明提供了聚合物共混物,其包含组分(a)40重量%至95重量%的至少一种由(a1)50至99.9重量%的通式I的构建单元构成的至少一种聚芳基醚共聚物, 0%至40%重量的选自一种或多种热塑性聚合物的段的另外的建筑单元II,和(a2)0.1%至10%重量的至少一种具有至少三个羟基官能团的交联剂V,至少 一种交联剂V以转化形式存在于组分(a)中,(a1)和(a2)的重量%的总和为100重量%,和(b)至少5重量%至60重量% 一种选自聚乙烯吡咯烷酮,聚乙烯吡咯烷酮共聚物,聚乙二醇,聚丙二醇,乙二醇和丙二醇的共聚物,水溶性纤维素衍生物,聚酰胺,聚乙酸乙烯酯和聚乙烯醇的亲水性聚合物,其中组分(a )和 (b)为100重量%。 本发明还提供了用于联合使用的不同组分(a)和(b)的组合。 本发明还提供了包含上述聚合物共混物的聚合物膜,以及它们的生产方法和用于生产透析过滤器的聚合物膜的用途。 本发明还提供了包含上述中空纤维膜的透析过滤器。

    FORWARD OSMOSIS MEMBRANE AND METHOD OF MANUFACTURE
    8.
    发明申请
    FORWARD OSMOSIS MEMBRANE AND METHOD OF MANUFACTURE 审中-公开
    前向OSMOSIS膜及其制造方法

    公开(公告)号:US20130313185A1

    公开(公告)日:2013-11-28

    申请号:US13984454

    申请日:2012-02-13

    摘要: A forward osmosis membrane (10) and method (50) of forming the forward osmosis membrane (10) are provided. The forward osmosis membrane (10) has an integral hydrophilic asymmetric layer (12). The integral hydrophilic asymmetric layer (12) includes a first sublayer (18) having a plurality of first elongated pores (20) extending along a depth of the first sublayer (18) and a second sublayer (22) having a plurality of second elongated pores (24) extending along a thickness of the second sublayer (22). The first elongated pores (20) are dimensionally smaller than the second elongated pores (24). A polyamide layer (14) is formed over a surface of the integral hydrophilic asymmetric layer (12).

    摘要翻译: 提供形成正向渗透膜(10)的正向渗透膜(10)和方法(50)。 正向渗透膜(10)具有整体的亲水不对称层(12)。 积分亲水不对称层(12)包括具有沿着第一子层(18)的深度延伸的多个第一细长孔(20)的第一子层(18)和具有多个第二细长孔 (24)沿第二子层(22)的厚度延伸。 第一细长孔(20)在尺寸上小于第二细长孔(24)。 在整个亲水不对称层(12)的表面上形成聚酰胺层(14)。

    Ultrathin high-performance hollow fiber membranes
    10.
    发明授权
    Ultrathin high-performance hollow fiber membranes 失效
    超薄高性能中空纤维膜

    公开(公告)号:US6015516A

    公开(公告)日:2000-01-18

    申请号:US100094

    申请日:1998-06-19

    IPC分类号: D01D5/24 D01D5/247 D01F6/66

    CPC分类号: D01D5/247 D01D5/24 D01F6/66

    摘要: A process for forming ultrathin dense-layer asymmetric hollow fiber membranes with a dense layer of less than 500 .ANG. from a binary solution system comprising a polymer and a solvent. In this process, the spinning polymeric solution has a high viscosity and exhibits chain entanglement at the spinning temperature. The solubility parameter difference between the bore fluid and the spinning dope is less than 2.5 (cal/cm.sup.3).sup.0.5 and the volume ratio of bore-fluid flow rate to the dope flow rate is between 0.45 to 0.75. The dope is wet-spun into hollow fibers using water as external coagulant. The ultrathin dense-layer asymmetric hollow fiber membranes are suitable for air and other gas separations.

    摘要翻译: 一种从包含聚合物和溶剂的二元溶液体系形成具有小于500安培的致密层的超薄致密层不对称中空纤维膜的方法。 在该方法中,纺丝聚合物溶液具有高粘度并且在纺丝温度下表现出链缠结。 孔流体和纺丝原液之间的溶解度参数差异小于2.5(cal / cm3)0.5,孔流体流速与涂料流速的体积比在0.45至0.75之间。 将涂料用水作为外部凝结剂湿法纺丝成中空纤维。 超薄致密层不对称中空纤维膜适用于空气和其他气体分离。