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公开(公告)号：US08852799B2
公开(公告)日：2014-10-07
申请号：US11991558
申请日：2006-09-04
申请人： Masaharu Itaya , Hideyuki Koga , Kumiko Kanai , Takao Inoue , Masahisa Fujimoto
发明人： Masaharu Itaya , Hideyuki Koga , Kumiko Kanai , Takao Inoue , Masahisa Fujimoto
IPC分类号： H01M10/054 , H01M10/052 , H01M4/58 , H01M4/134 , H01M4/02 , H01M10/0566
CPC分类号： H01M4/134 , H01M4/58 , H01M10/052 , H01M10/054 , H01M10/0566 , H01M2004/028 , Y02E60/122
摘要： An object of the invention is to provide an inexpensive non-aqueous electrolyte secondary battery that allows reversible charge and discharge to be carried out and can be used for a long period because of a stable non-aqueous electrolyte used therein. The invention provides a non-aqueous electrolyte secondary battery including a positive electrode including a positive electrode active material and capable of storing and releasing sodium, a negative electrode capable of storing and releasing sodium, and a non-aqueous electrolyte, and the positive electrode active material includes sodium, nickel, manganese, and a transition metal that can exist in a hexavalent state. An example of the transition metal that can exist in a hexavalent state may include tungsten (W). An example of the negative electrode may include a sodium metal capable of storing and releasing sodium ions.
摘要翻译： 本发明的目的是提供一种廉价的非水电解质二次电池，其允许进行可逆的充放电，并且由于其中使用的稳定的非水电解质可长期使用。 本发明提供一种非水电解质二次电池，其包括正极活性物质，能够储存和释放钠，能够储存和释放钠的负极和非水电解质的正极活性物质，正极活性物质 材料包括可以以六价态存在的钠，镍，锰和过渡金属。 可以以六价态存在的过渡金属的实例可以包括钨（W）。 负极的实例可以包括能够储存和释放钠离子的钠金属。
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公开(公告)号：US20100009254A1
公开(公告)日：2010-01-14
申请号：US11991558
申请日：2006-09-04
申请人： Masaharu Itaya , Hideyuki Koga , Kumiko Kanai , Takao Inoue , Masahisa Fujimoto
发明人： Masaharu Itaya , Hideyuki Koga , Kumiko Kanai , Takao Inoue , Masahisa Fujimoto
CPC分类号： H01M4/134 , H01M4/58 , H01M10/052 , H01M10/054 , H01M10/0566 , H01M2004/028 , Y02E60/122
摘要： An object of the invention is to provide an inexpensive non-aqueous electrolyte secondary battery that allows reversible charge and discharge to be carried out and can be used for a long period because of a stable non-aqueous electrolyte used therein. The invention provides a non-aqueous electrolyte secondary battery including a positive electrode including a positive electrode active material and capable of storing and releasing sodium, a negative electrode capable of storing and releasing sodium, and a non-aqueous electrolyte, and the positive electrode active material includes sodium, nickel, manganese, and a transition metal that can exist in a hexavalent state. An example of the transition metal that can exist in a hexavalent state may include tungsten (W). An example of the negative electrode may include a sodium metal capable of storing and releasing sodium ions.
摘要翻译： 本发明的目的是提供一种廉价的非水电解质二次电池，其允许进行可逆的充放电，并且由于其中使用的稳定的非水电解质可长期使用。 本发明提供一种非水电解质二次电池，其包括正极活性物质，能够储存和释放钠，能够储存和释放钠的负极和非水电解质的正极活性物质，正极活性物质 材料包括可以以六价态存在的钠，镍，锰和过渡金属。 可以以六价态存在的过渡金属的实例可以包括钨（W）。 负极的实例可以包括能够储存和释放钠离子的钠金属。
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3.发明申请公开(公告)号：US20100015532A1
公开(公告)日：2010-01-21
申请号：US11883847
申请日：2006-01-20
申请人： Takao Inoue , Kumiko Kanai , Masaharu Itaya , Masahisa Fujimoto
发明人： Takao Inoue , Kumiko Kanai , Masaharu Itaya , Masahisa Fujimoto
CPC分类号： H01M4/136 , H01M4/1397 , H01M4/38 , H01M4/387 , H01M4/70 , H01M10/0587
摘要： A rolled foil of surface roughened copper as thick as 26 μm for example having a surface formed into an irregular shape with copper precipitated thereon by an electrolytic method is prepared as a negative electrode collector. Tin (Sn) or germanium (Ge) is deposited on the rolled foil described above, so that a negative electrode active material layer is formed. Note that the deposited tin or germanium is amorphous. The arithmetic mean roughness Ra in the surface-roughened rolled foil described above is preferably not less than 0.1 μm nor more than 10 μm. A non-aqueous electrolyte is produced by adding sodium hexafluorophosphate as an electrolyte salt in a concentration of 1 mol/l to a non-aqueous solvent produced by mixing ethylene carbonate and diethyl carbonate in the ratio of 50:50 by volume.
摘要翻译： 作为负极集电体，准备例如具有通过电解方法在其上沉积有铜的表面形成为不规则形状的厚度为26μm的表面粗糙化铜的轧制箔。 在上述轧制箔上沉积锡（Sn）或锗（Ge），形成负极活性物质层。 请注意，沉积的锡或锗是无定形的。 上述表面粗糙化的轧制箔中的算术平均粗糙度Ra优选为0.1μm以上10μm以下。 通过将碳酸亚乙酯和碳酸二乙酯以50:50的体积比混合而制备的非水溶剂中加入浓度为1mol / l的电解质盐的六氟磷酸钠制成非水电解质。
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公开(公告)号：US20090053613A1
公开(公告)日：2009-02-26
申请号：US11883815
申请日：2006-01-20
申请人： Takao Inoue , Masahisa Fujimoto , Kumiko Kanai
发明人： Takao Inoue , Masahisa Fujimoto , Kumiko Kanai
IPC分类号： H01M10/00
CPC分类号： H01M4/134 , H01M4/0404 , H01M4/0409 , H01M4/0426 , H01M4/131 , H01M4/1391 , H01M4/1395 , H01M4/505 , H01M4/621 , H01M4/625 , H01M4/661 , H01M4/70 , H01M10/054 , H01M10/0568 , H01M10/0569
摘要： A material (hereinafter referred to as “positive electrode material”) including sodium manganate powder as a positive electrode active material, carbon black powder as a conductive agent, and polytetrafluoroethylene as a binder is prepared. The positive electrode material is mixed in an N-methylpyrrolidone solution to produce slurry as a positive electrode mixture. A working electrode is produced by applying the slurry on a positive electrode collector. A negative electrode containing tin or germanium is produced. The non-aqueous electrolyte is produced by adding sodium hexafluorophosphate as an electrolyte salt in a non-aqueous solvent produced by mixing ethylenecarbonate and diethyl carbonate.
摘要翻译： 制备包含锰酸钠粉末作为正极活性物质的材料（以下称为“正极材料”），作为导电剂的炭黑粉末和作为粘合剂的聚四氟乙烯。 将正极材料混合在N-甲基吡咯烷酮溶液中以产生作为正极混合物的浆料。 通过将浆料涂布在正极集电体上来制造工作电极。 制造含有锡或锗的负极。 非水电解质是通过将六氟磷酸钠作为电解质盐加入到通过混合碳酸亚乙酯和碳酸二乙酯制备的非水溶剂中制备的。
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公开(公告)号：US20070065725A1
公开(公告)日：2007-03-22
申请号：US10576260
申请日：2004-09-15
IPC分类号： H01M4/62
CPC分类号： H01M10/052 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/624 , H01M4/625 , H01M10/0525 , H01M2004/028
摘要： A nonaqueous electrolyte battery wherein the capacity per volume of positive electrode active material layer can be larger than in the use of carbon black only as a conductive material. This nonaqueous electrolyte battery comprises positive electrode (1) having a positive electrode active material layer, negative electrode (2) having a negative electrode active material layer, nonaqueous electrolyte (5) and a conductive material incorporated in the positive electrode active material layer, the conductive material containing carbon black of 1 to less than 800 m2/g specific surface area and at least one material selected from the group consisting of nitrides, carbides and borides.
摘要翻译： 非水电解质电池，其中正极活性物质层的体积容量可以比仅使用炭黑作为导电材料大。 这种非水电解质电池包括具有正极活性物质层的正极（1），具有负极活性物质层的负极（2），非水电解质（5）和掺入到正极活性物质层中的导电材料， 含有1至小于800m 2 / g比表面积的炭黑的导电材料和选自氮化物，碳化物和硼化物的至少一种材料。
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公开(公告)号：US20060222953A1
公开(公告)日：2006-10-05
申请号：US10568805
申请日：2004-08-11
申请人： Takao Inoue , Kumiko Kanai , Kazunori Donoue , Masahisa Fujimoto
发明人： Takao Inoue , Kumiko Kanai , Kazunori Donoue , Masahisa Fujimoto
IPC分类号： H01M4/62
CPC分类号： H01M4/624 , H01M4/131 , H01M4/623 , H01M10/052
摘要： A nonaqueous electrolyte battery wherein the per-volume capacity of positive electrode active material layer can be increased over that exhibited in the use of carbon as a conducting material. This nonaqueous electrolyte battery comprises positive electrode (1) containing a positive electrode active material layer, negative electrode (2) containing a negative electrode active material layer, nonaqueous electrolyte (5) and a conducting material contained in the positive electrode active material layer and constituted of at least one non-carbon material selected from the group consisting of nitrides, carbides and borides, which conducting material is in the form of particles of 0.2 to 5 μm average diameter easily dispersed in the positive electrode active material layer.
摘要翻译： 一种非水电解质电池，其中正极活性物质层的每体积容量可以比使用碳作为导电材料时显示的容量增加。 该非水电解质电池包括含有正极活性物质层的正极（1），含有负极活性物质层的负极（2），非水电解质（5）和包含在正极活性物质层中的导电材料， 的至少一种选自氮化物，碳化物和硼化物的非碳材料，其导电材料是平均直径为0.2至5μm的颗粒形式，容易分散在正极活性物质层中。
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公开(公告)号：US08815449B2
公开(公告)日：2014-08-26
申请号：US11883815
申请日：2006-01-20
申请人： Takao Inoue , Masahisa Fujimoto , Kumiko Kanai
发明人： Takao Inoue , Masahisa Fujimoto , Kumiko Kanai
IPC分类号： H01M4/505 , H01M4/64 , H01M10/056
CPC分类号： H01M4/134 , H01M4/0404 , H01M4/0409 , H01M4/0426 , H01M4/131 , H01M4/1391 , H01M4/1395 , H01M4/505 , H01M4/621 , H01M4/625 , H01M4/661 , H01M4/70 , H01M10/054 , H01M10/0568 , H01M10/0569
摘要： A material (hereinafter referred to as “positive electrode material”) including sodium manganate powder as a positive electrode active material, carbon black powder as a conductive agent, and polytetrafluoroethylene as a binder is prepared. The positive electrode material is mixed in an N-methylpyrrolidone solution to produce slurry as a positive electrode mixture. A working electrode is produced by applying the slurry on a positive electrode collector. A negative electrode containing tin or germanium is produced. The non-aqueous electrolyte is produced by adding sodium hexafluorophosphate as an electrolyte salt in a non-aqueous solvent produced by mixing ethylenecarbonate and diethyl carbonate.
摘要翻译： 制备包含锰酸钠粉末作为正极活性物质的材料（以下称为“正极材料”），作为导电剂的炭黑粉末和作为粘合剂的聚四氟乙烯。 将正极材料混合在N-甲基吡咯烷酮溶液中以产生作为正极混合物的浆料。 通过将浆料涂布在正极集电体上来制造工作电极。 制造含有锡或锗的负极。 非水电解质是通过将六氟磷酸钠作为电解质盐加入到通过混合碳酸亚乙酯和碳酸二乙酯制备的非水溶剂中制备的。
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公开(公告)号：US20080026289A1
公开(公告)日：2008-01-31
申请号：US11819151
申请日：2007-06-25
申请人： Koh Masahara , Kumiko Kanai , Takao Inoue , Masahisa Fujimoto
发明人： Koh Masahara , Kumiko Kanai , Takao Inoue , Masahisa Fujimoto
CPC分类号： H01M4/0426 , H01M4/1395 , H01M4/38 , H01M4/661 , H01M4/70 , H01M10/054 , H01M10/0568
摘要： A low-cost, high-discharge capacity density non-aqueous electrolyte secondary battery is provided. The battery includes a positive electrode, a non-aqueous electrolyte containing sodium ions, and a negative electrode having a thin-film negative electrode active material containing germanium (Ge) as its main active material or a negative electrode active material comprising particles containing germanium as its main active material.
摘要翻译： 提供了一种低成本，高放电容量密度的非水电解质二次电池。 该电池包括正极，含有钠离子的非水电解质和具有含有锗（Ge）作为其主要活性物质的薄膜负极活性物质的负极或含有锗的粒子的负极活性物质 其主要活性物质。
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公开(公告)号：US07247405B2
公开(公告)日：2007-07-24
申请号：US10786594
申请日：2004-02-26
CPC分类号： H01M4/38 , H01M4/133 , H01M4/136 , H01M4/1393 , H01M4/1397 , H01M4/381 , H01M4/581 , H01M4/5815 , H01M4/583 , H01M4/5835 , H01M10/054 , H01M10/0568
摘要： A nonaqueous electrolyte battery which comprises a positive electrode including carbon fluoride or sulfur as an active material, a negative electrode including calcium as an active material, and an electrolyte including an imide salt of calcium or a sulfonic acid salt of calcium.
摘要翻译： 一种非水电解质电池，包括含有作为活性物质的氟化碳或硫的正极，包含钙作为活性物质的负极，以及包含钙的酰亚胺盐或钙的磺酸盐的电解质。
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10.发明授权公开(公告)号：US07709151B2
公开(公告)日：2010-05-04
申请号：US12205270
申请日：2008-09-05
申请人： Takao Inoue , Masahisa Fujimoto , Masaharu Itaya
发明人： Takao Inoue , Masahisa Fujimoto , Masaharu Itaya
IPC分类号： H01M4/26
CPC分类号： H01M4/525 , C01G45/1228 , C01G49/009 , C01G51/42 , C01G51/66 , C01G53/42 , C01G53/66 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2006/40 , H01M4/0438 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M10/0525
摘要： As a positive electrode active material, a lithium transition metal complex oxide having a layered rock-salt structure containing lithium (Li) and containing magnesium atoms (Mg) substituted for part of lithium atoms (Li) is used. The lithium transition metal complex oxide is formed by chemical or electrochemical substitution of Mg atoms for part of Li atoms in LiCoO2, LiMnO2, LiFeO2, LiNiO2, or the like. A cell is prepared in which a negative electrode 2 and a positive electrode 1 including the lithium transition metal complex oxide (positive electrode active material) are disposed in a non-aqueous electrolyte 5 including a lithium salt, and part of Li in the lithium transition metal complex oxide is extracted by discharging the cell. Then, the electrolyte including Li is replaced with an electrolyte including Mg, and the cell is discharged, so that Mg atoms are substituted for the part of Li atoms in the lithium transition metal complex oxide.
摘要翻译： 作为正极活性物质，使用具有锂（Li）层状岩盐结构并含有镁原子（Mg）取代部分锂原子（Li）的锂过渡金属络合物氧化物。 锂过渡金属复合氧化物通过Mg原子在LiCoO 2，LiMnO 2，LiFeO 2，LiNiO 2等中的部分Li原子的化学或电化学取代而形成。 制备电池，其中将包含锂过渡金属络合物（正极活性物质）的负极2和正极1设置在包含锂盐的非水电解质5中，并且在锂转变中的一部分Li 通过排出电池提取金属复合氧化物。 然后，将包含Li的电解质替换为包含Mg的电解质，并且电池被排出，使得Mg原子被锂过渡金属复合氧化物中的Li原子的一部分代替。
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