摘要:
The present invention is to provide a process for preparing a synthetic intermediate of biotin which is industrially advantageous, and discloses a process for preparing a compound represented by the formula (I): wherein R1 and R2 may be the same or different from each other, and each represents hydrogen atom, a benzyl group which may have a substituent(s) on the benzene ring, a benzhydryl group which may have a substituent(s) on the benzen ring, or a trityl group which may have a substituent(s) on the benzene ring, R3 represents cyano group, carboxyl group, an alkoxycarbonyl group, an alkylthiocarbonyl group, or a carbamoyl group which may have a substituent, or a salt thereof which comprises subjecting a compound represented by the formula (II-a): wherein the symbols have the same meanings as defined above, or a salt thereof to ring transformation.
摘要:
The present invention is to provide a process for preparing a synthetic intermediate of biotin which is industrially advantageous, and discloses a process for preparing a compound represented by the formula (I): 1 wherein R1 and R2 may be the same or different from each other, and each represents hydrogen atom, a benzyl group which may have a substituent(s) on the benzene ring, a benzhydryl group which may have a substituent(s) on the benzen ring, or a trityl group which may have a substituent(s) on the benzene ring, R3 represents cyano group, carboxyl group, an alkoxycarbonyl group, an alkylthiocarbonyl group, or a carbamoyl group which may have a substituent, or a salt thereof which comprises subjecting a compound represented by the formula (II-a): 2 wherein the symbols have the same meanings as defined above, or a salt thereof to ring transformation.
摘要:
The present invention is to provide a process for preparing a synthetic intermediate of biotin which is industrially advantageous, and discloses a process for preparing a compound represented by the formula (I): 1 wherein R1 and R2 may be the same or different from each other, and each represents hydrogen atom, a benzyl group which may have a substituent(s) on the benzene ring, a benzhydryl group which may have a substituent(s) on the benzen ring, or a trityl group which may have a substituent(s) on the benzene ring, R3 represents cyano group, carboxyl group, an alkoxycarbonyl group, an alkylthiocarbonyl group, or a carbamoyl group which may have a substituent, or a salt thereof which comprises subjecting a compound represented by the formula (II-a): 2 wherein the symbols have the same meanings as defined above, or a salt thereof to ring transformation.
摘要:
The present invention is to provide a process for preparing a synthetic intermediate of biotin which is industrially advantageous, and discloses a process for preparing a compound represented by the formula (I): wherein R1 and R2 may be the same or different from each other, and each represents hydrogen atom, a benzyl group which may have a substituent(s) on the benzene ring, a benzhydryl group which may have a substituent(s) on the benzen ring, or a trityl group which may have a substituent(s) on the benzene ring, R3 represents cyano group, carboxyl group, an alkoxycarbonyl group, an alkylthiocarbonyl group, or a carbamoyl group which may have a substituent, or a salt thereof which comprises subjecting a compound represented by the formula (II-a): wherein the symbols have the same meanings as defined above, or a salt thereof to ring transformation.
摘要:
A capacitor has a capacitor element, an electrolyte, a cylindrical case made of metal and having a bottom, a metal terminal plate, and a sealing rubber. The terminal plate has a body portion and a flange portion projected from an outer peripheral surface of the body portion toward the case. The sealing rubber is abutted onto the flange portion of the terminal plate, and is interposed between the outer peripheral surface of the body portion of the terminal plate and a side surface of the case for sealing the case. The case has a drawn and grooved portion formed by being drawn and thus grooved from an outside of the side surface at a place so that the sealing rubber is compressed between the outer peripheral surface of the body portion of the terminal plate and the case. Then, a ring-like groove is provided on the outer peripheral surface of the body portion of the terminal plate at a portion, which is padded with the sealing rubber, the sealing rubber is projected into the groove.
摘要:
A capacitor includes a capacitor element including first and second electrodes, an electrolyte solution, first and second collector plates made of metal and joined to the first and second electrodes of the capacitor element, respectively, a case accommodating the capacitor element, the electrolyte solution, the first and second collector plates, a terminal plate placed at an opening of the case and joined to the second collector plate, and a sealing rubber sealing the terminal plate and the opening of the case. The case has a tubular portion and a bottom plate closing the tubular portion. An inner surface of the bottom plate of the case has a contacting portion contacting the first collector plate and a junction portion facing the first collector plate. The first junction portion of the inner surface of the bottom plate has a joining point joined to the first collector plate and a separation part facing the first collector plate around the first joining point by a first gap between the first junction portion and the first collector plate. The first collector plate is located away from the first contacting portion. The capacitor has a high reliability in connecting the electrodes, preventing an unnecessary resistance or a pin hole produced in the case.
摘要:
The invention provides an oil type release agent die casting containing 70 to 98 parts by weight of a solvent having a specified flash point, 1 to 10 parts by weight of mineral oils and/or synthetic oils having a high viscosity, 15 parts by weight or less of a silicone oil, and 1 to 5 parts by weight of additives having a lubricating function, wherein the flash point of the agent is in the range of 70 to 170° C., and dynamic viscosity of the agent is 2 to 30 mm2/s or higher at 40° C., and a method for setting a mixing ratio of the solvent, a casting method, and a spraying unit for the case of using the release agent.
摘要:
A capacitor has a capacitor element, an electrolyte, a cylindrical case made of metal and having a bottom, a metal terminal plate, and a sealing rubber. The terminal plate has a body portion and a flange portion projected from an outer peripheral surface of the body portion toward the case. The sealing rubber is abutted onto the flange portion of the terminal plate, and is interposed between the outer peripheral surface of the body portion of the terminal plate and a side surface of the case for sealing the case. The case has a drawn and grooved portion formed by being drawn and thus grooved from an outside of the side surface at a place so that the sealing rubber is compressed between the outer peripheral surface of the body portion of the terminal plate and the case. Then, a ring-like groove is provided on the outer peripheral surface of the body portion of the terminal plate at a portion, which is padded with the sealing rubber, the sealing rubber is projected into the groove.
摘要:
A capacitor includes a capacitor element, a bottomed, cylindrical, metallic case, a metallic terminal plate, and a sealing rubber. A flange is provided along the outer circumference of the terminal plate. The flange is brought into contact with the bottom face of the sealing rubber for positioning. The case is wrung from the outside thereof so as to compress the sealing rubber. The sealing rubber has at least one of a ring-shaped top projection wall projecting between the metallic case and the terminal plate on the top face thereof, and a ring-shaped bottom projection wall projecting between the metallic case and the flange on the bottom face thereof.