公开(公告)号：US07749455B2

公开(公告)日：2010-07-06

申请号：US10522604

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

IPC分类号： G05D7/00 ,  B01D53/04 ,  B01D53/34 ,  B01D53/52 ,  B01D53/86 ,  B01J8/02 ,  B01J35/02 ,  C01B17/00 ,  C01B17/16 ,  C01B31/00 ,  C10G17/00 ,  C10G45/00

CPC分类号： B01J23/866 ,  B01D53/885 ,  C10K1/34

摘要： A COS treatment apparatus for a gasified gas includes an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst. Also, a COS treatment apparatus includes a TiO2 catalyst that carries Cr2O3 or NiO. Further, a COS treatment method includes a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.

摘要翻译： 用于气化气体的COS处理装置包括相对于除去氧化催化剂的气化气体流的下游侧的除氧催化剂和COS转化催化剂。 此外，COS处理装置包括载持Cr 2 O 3或NiO的TiO 2催化剂。 此外，COS处理方法包括通过与H 2 S和CO的反应除去O 2的第一步骤和将COS转化为H 2 S的第二步骤。

公开(公告)号：US20060051263A1

公开(公告)日：2006-03-09

申请号：US10522604

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

IPC分类号： B01J8/02

CPC分类号： B01J23/866 ,  B01D53/885 ,  C10K1/34

摘要： There is disclosed a COS treatment apparatus for a gasified gas, in which an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst are provided. Also, there is disclosed a COS treatment apparatus containing a TiO2 catalyst that carries Cr2O3 or NiO. Further, there is disclosed a COS treatment method including a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.

摘要翻译： 公开了一种用于气化气体的COS处理装置，其中位于气化气体的下游侧的O 2 H 2除去催化剂和COS转化催化剂相对于O 2 提供了除去催化剂。

公开(公告)号：US20060110304A1

公开(公告)日：2006-05-25

申请号：US10523679

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D53/58

CPC分类号： C10K1/101 ,  B01D53/14 ,  B01D2257/406

摘要： The present invention provides a wet gas purification method in which ammonia in the gas is removed, and a system for carrying out said method, characterized in that the method includes a washing step in which ammonia in the gas is absorbed in an absorbent for removal; and an ammonia treating step in which ammonia is stripped from the discharged absorbent at a following stage of the washing step, wherein the absorbent is divided into an off-gas containing ammonia and effluent. In the washing step makeup water is charged continuously or intermittently so that the concentration of ammonia in the gas having passed through the washing step is 10 ppm or lower. According to the present invention, a wet gas purification method can be performed in which the running costs involved in operation is reduced, the manipulation step and system are simple, operation is easy, and the reliability is high.

摘要翻译： 本发明提供一种其中除去气体中的氨的湿气净化方法，以及用于实施所述方法的系统，其特征在于，所述方法包括洗涤步骤，其中所述气体中的氨被吸收剂吸收除去; 以及在洗涤步骤的后续阶段从排出的吸收剂中除去氨的氨处理步骤，其中吸收剂被分成含有氨和废水的废气。 在洗涤步骤中，连续地或间歇地加入水，使得通过洗涤步骤的气体中的氨浓度为10ppm以下。 根据本发明，可以进行操作中涉及的运行成本降低的操作步骤和系统简单，操作容易，可靠性高的湿气净化方法。

公开(公告)号：US07381389B2

公开(公告)日：2008-06-03

申请号：US10523679

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D53/58 ,  B01J10/00

CPC分类号： C10K1/101 ,  B01D53/14 ,  B01D2257/406

摘要： A wet gas purification method is provided for removing ammonia from a heavy oil gasification gas, such as coal. The method principally involves a washing step during which absorbent is charged into the gas to absorb ammonia and an ammonia treating step wherein absorbent discharged from the washing step is separated into an effluent and an off-gas containing ammonia. The amount of absorbent charged during the washing step is controlled such that the ammonia concentration of gas exiting the washing step is 10 ppm or less.

摘要翻译： 提供湿气净化方法，用于从重油气化气体如煤中除去氨。 该方法主要涉及洗涤步骤，在该步骤中将吸收剂装入气体中以吸收氨和氨处理步骤，其中将从洗涤步骤排出的吸收剂分离成流出物和含有氨的废气。 控制在洗涤步骤中加入的吸收剂的量使得离开洗涤步骤的气体的氨浓度为10ppm以下。

公开(公告)号：US06770119B2

公开(公告)日：2004-08-03

申请号：US10233526

申请日：2002-09-04

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Suzaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Suzaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D5314

CPC分类号： C10K1/16 ,  B01D53/14 ,  B01D53/64 ,  B01D2257/602 ,  C10K1/085 ,  C10K1/10

摘要： The present invention provides a mercury removal method which can effectively remove very small amounts of mercury components present in a gas during wet gas purification such as coal or heavy oil gasification gas purification and petroleum refining. A mercury removal method for the removal of mercury present in a gas, the method comprising the steps of bringing a gas containing at least mercury and not less than 10 ppm of hydrogen sulfide into gas-liquid contact with an absorbing fluid under pressurized conditions so as to cause mercury to pass into the absorbing fluid; flashing the mercury-containing absorbing fluid under lower-pressure conditions to separate it into gaseous components and liquid components; and removing the mercury contained in the separated gaseous components by adsorption to an adsorbent.

摘要翻译： 本发明提供了一种除汞方法，其可以有效地去除在湿气净化中例如煤或重油气化气净化和石油精炼中的气体中存在的非常少量的汞成分。 一种用于除去存在于气体中的汞的汞去除方法，该方法包括以下步骤：在加压条件下使至少包含汞和不少于10ppm硫化氢的气体与吸收液体气液接触，以便 使汞进入吸收液; 在低压条件下闪烁含汞吸收液，将其分离成气态组分和液体组分; 并且通过吸附到吸附剂上除去分离的气态组分中所含的汞。

公开(公告)号：US07572420B2

公开(公告)日：2009-08-11

申请号：US10815419

申请日：2004-04-01

申请人： Shintaro Honjo ,  Toru Takashina ,  Kozo Iida ,  Susumu Okino ,  Yasuhiro Takeuchi

发明人： Shintaro Honjo ,  Toru Takashina ,  Kozo Iida ,  Susumu Okino ,  Yasuhiro Takeuchi

IPC分类号： B01D53/64

CPC分类号： B01D53/501 ,  B01D53/8665 ,  B01D2257/602 ,  F23J15/006 ,  F23J2215/60 ,  F23J2219/40

摘要： The present invention provides a method for removing mercury in exhaust gas, in which mercury in exhaust gas discharged from combustion equipment is removed, characterized by including a mercury oxidation process in which mercury in the exhaust gas is converted to mercury chloride in the presence of a catalyst; a contact process in which the exhaust gas is brought into contact with an absorbing solution in a scrubber to absorb and remove mercury components from the exhaust gas; and a control process in which blowing of air or addition of an oxidizing agent into the scrubber is accomplished, and the amount of blown air or the added amount of oxidizing agent is regulated to control the oxidation-reduction potential of the absorbing agent, and a system for removing mercury in exhaust gas. According to the mercury removing method in accordance with the present invention, a phenomenon that mercury chloride is reduced into metallic mercury by SO2 etc. and the metallic mercury scatters in the exhaust gas can be prevented, and mercury in the exhaust gas can be decreased effectively.

公开(公告)号：US07521032B2

公开(公告)日：2009-04-21

申请号：US10767783

申请日：2004-01-29

申请人： Shintaro Honjo ,  Kozo Iida ,  Susumu Okino ,  Kazuto Kobayashi ,  Kenichi Okada ,  Naoyuki Kamiyama ,  Shigeru Nojima ,  Yasuhiro Takeuchi ,  Tsuyoshi Ohishi

发明人： Shintaro Honjo ,  Kozo Iida ,  Susumu Okino ,  Kazuto Kobayashi ,  Kenichi Okada ,  Naoyuki Kamiyama ,  Shigeru Nojima ,  Yasuhiro Takeuchi ,  Tsuyoshi Ohishi

IPC分类号： B01D53/52

CPC分类号： B01D53/64 ,  B01D2257/406 ,  B01D2257/602 ,  F23J15/006 ,  F23J2215/60 ,  F23J2219/10 ,  F23J2219/40

摘要： The present invention provides a system for removing mercury in exhaust gas, in which mercury is removed from exhaust gas of a boiler, characterized in that between a denitrification apparatus and a wet type desulfurization apparatus, an NH3 decomposition catalyst and a mercury oxidation catalyst are provided, and mercury having been oxidized into mercury chloride is removed by the wet type desulfurization apparatus. Also, it provides a method for removing mercury in exhaust gas, characterized in that the mercury removing method includes an NH3 decomposition process and a mercury oxidation process, which are provided between the denitrification process and a wet desulfurization process, and mercury having been oxidized into mercury chloride is removed in the wet desulfurization process.

摘要翻译： 本发明提供了一种用于去除废气中的汞的系统，其中从锅炉废气中除去汞，其特征在于，在脱氮装置和湿式脱硫装置之间，提供NH 3分解催化剂和汞氧化催化剂 并且通过湿式脱硫装置除去氧化成氯化汞的汞。 另外，本发明提供一种除去排气中的汞的方法，其特征在于，除汞方法包括在脱氮工序与湿式脱硫工序之间设置的NH 3分解工序和水银氧化工序，将氧化为 在湿式脱硫工艺中除去氯化汞。

公开(公告)号：US08703080B2

公开(公告)日：2014-04-22

申请号：US12459023

申请日：2009-06-25

申请人： Shintaro Honjo ,  Toru Takashina ,  Kozo Iida ,  Susumu Okino ,  Yasuhiro Takeuchi

发明人： Shintaro Honjo ,  Toru Takashina ,  Kozo Iida ,  Susumu Okino ,  Yasuhiro Takeuchi

IPC分类号： B01D47/00 ,  B01D53/46 ,  B01D53/56 ,  B01D53/86 ,  C01B17/00 ,  C01B17/74 ,  C01B17/48

CPC分类号： B01D53/501 ,  B01D53/8665 ,  B01D2257/602 ,  F23J15/006 ,  F23J2215/60 ,  F23J2219/40

摘要： The present invention provides a method for removing mercury in exhaust gas, in which mercury in exhaust gas discharged from combustion equipment is removed, characterized by including a mercury oxidation process in which mercury in the exhaust gas is converted to mercury chloride in the presence of a catalyst; a contact process in which the exhaust gas is brought into contact with an absorbing solution in a scrubber to absorb and remove mercury components from the exhaust gas; and a control process in which blowing of air or addition of an oxidizing agent into the scrubber is accomplished, and the amount of blown air or the added amount of oxidizing agent is regulated to control the oxidation-reduction potential of the absorbing agent, and a system for removing mercury in exhaust gas. According to the mercury removing method in accordance with the present invention, a phenomenon that mercury chloride is reduced into metallic mercury by SO2 etc. and the metallic mercury scatters in the exhaust gas can be prevented, and mercury in the exhaust gas can be decreased effectively.

摘要翻译： 本发明提供了一种去除废气中排出的废气中的汞的方法，其中废气中排出的废气中的汞被除去，其特征在于包括一种汞氧化法，其中废气中的汞转化为氯化汞， 催化剂; 接触方法，其中废气与洗涤器中的吸收溶液接触以从废气中吸收和去除汞组分; 以及控制方法，其中完成吹入空气或将氧化剂加入到洗涤器中，并且调节吹入空气量或氧化剂的添加量以控制吸收剂的氧化还原电位，并且 废气中汞去除系统。 根据本发明的水银除去方法，可以防止将二氧化氯还原成金属汞，并且可以防止金属汞在排气中飞散的现象，从而可以有效地降低废气中的汞 。

公开(公告)号：US20110044872A1

公开(公告)日：2011-02-24

申请号：US12812866

申请日：2009-01-20

申请人： Nobuyuki Ukai ,  Shintaro Honjo ,  Susumu Okino

发明人： Nobuyuki Ukai ,  Shintaro Honjo ,  Susumu Okino

IPC分类号： B01D53/56 ,  B01D53/50 ,  B01D53/64 ,  B01J19/00

CPC分类号： F23J15/003 ,  B01D53/501 ,  B01D53/64 ,  B01D53/75 ,  B01D53/79 ,  B01D53/8625 ,  B01D2251/10 ,  B01D2251/2062 ,  B01D2251/404 ,  B01D2253/102 ,  B01D2257/602 ,  B01J20/0266 ,  B01J20/0285 ,  B01J20/20 ,  B01J45/00 ,  C02F1/001 ,  C02F1/283 ,  C02F1/42 ,  C02F1/52 ,  C02F1/683 ,  C02F2101/20 ,  C02F2103/18 ,  C02F2209/003 ,  C02F2303/18 ,  F23J15/006 ,  F23J15/025 ,  F23J15/04 ,  F23J2215/20 ,  F23J2215/60 ,  F23J2219/20 ,  F23J2219/30 ,  Y02A50/2348

摘要： A flue gas control system of a coal combustion boiler according to the present invention includes: an HCI atomizer (32) that sprays hydrogen chloride (33) to flue gas from a coal combustion boiler (11) that uses coal as a fuel (F); NOx removing apparatus (13) that removes nitrogen oxides by ammonia denitration by adding ammonia (12) to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater (14) that recovers heat in the gas after removal of nitrogen oxides; a precipitator (15) that removes particulates in the gas; an activated carbon atomizer (22) that sprays activated carbon (22a) into the gas after particulate collection; a bag filter (21) that collects activated carbon having adsorbed mercury; a desulfurizer (16) that removes sulfur oxides in the flue gas after removal of activated carbon; a stack (17) that discharges the gas which has undergone desulfurization to outside; and an ORP meter (19) that measures an oxidation reduction potential for feeding air to a slurry absorbent in the desulfurizer (16).

摘要翻译： 根据本发明的燃煤锅炉的烟气控制系统包括：将来自使用煤作为燃料（F）的煤燃烧锅炉（11）的烟道气喷射氯化氢（33）的HCl喷雾器（32） ; NO x除去装置（13），其通过在喷射氯化氢之后向烟道气中加入氨（12）而通过氨脱硝除去氮氧化物并氧化汞; 一种空气预热器（14），其在去除氮氧化物之后回收气体中的热量; 除尘器（15），其去除气体中的微粒; 在颗粒收集之后将活性炭（22a）喷射到气体中的活性碳雾化器（22）; 收集具有吸附的汞的活性炭的袋式过滤器（21） 去除活性炭后除去烟道气中的硫氧化物的脱硫剂（16）; 将已进行脱硫的气体排出到外部的堆（17） 以及测量用于将空气供给到脱硫器（16）中的浆料吸收剂的氧化还原电位的ORP计（19）。

公开(公告)号：US08071060B2

公开(公告)日：2011-12-06

申请号：US12812866

申请日：2009-01-20

申请人： Nobuyuki Ukai ,  Shintaro Honjo ,  Susumu Okino

发明人： Nobuyuki Ukai ,  Shintaro Honjo ,  Susumu Okino

IPC分类号： B01D53/34 ,  B01D53/50 ,  B01D53/56 ,  B01D53/64 ,  B01D53/74

CPC分类号： F23J15/003 ,  B01D53/501 ,  B01D53/64 ,  B01D53/75 ,  B01D53/79 ,  B01D53/8625 ,  B01D2251/10 ,  B01D2251/2062 ,  B01D2251/404 ,  B01D2253/102 ,  B01D2257/602 ,  B01J20/0266 ,  B01J20/0285 ,  B01J20/20 ,  B01J45/00 ,  C02F1/001 ,  C02F1/283 ,  C02F1/42 ,  C02F1/52 ,  C02F1/683 ,  C02F2101/20 ,  C02F2103/18 ,  C02F2209/003 ,  C02F2303/18 ,  F23J15/006 ,  F23J15/025 ,  F23J15/04 ,  F23J2215/20 ,  F23J2215/60 ,  F23J2219/20 ,  F23J2219/30 ,  Y02A50/2348

摘要： A flue gas control system of a coal combustion boiler comprises an HCl atomizer that sprays hydrogen chloride to flue gas from a coal combustion boiler that uses coal as a fuel; NOx removing apparatus that removes nitrogen oxides by ammonia denitration by adding ammonia to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater that recovers heat in the gas after removal of nitrogen oxides; a precipitator that removes particulates in the gas; an activated carbon atomizer that sprays activated carbon into the gas after particulate collection; a bag filter that collects activated carbon having adsorbed mercury; a desulfurizer that removes sulfur oxides in the flue gas after removal of activated carbon; a stack that discharges the gas which has undergone desulfurization to outside; and an ORP meter that measures an oxidation reduction potential for feeding air to a slurry absorbent in the desulfurizer.

摘要翻译： 煤燃烧锅炉的烟气控制系统包括将氯化氢喷射到使用煤作为燃料的燃煤锅炉的烟道气中的HCl雾化器; NOx去除装置，其通过在喷洒氯化氢之后向废气中加入氨并通过氨脱硝来氧化汞; 一个空气预热器，在除去氮氧化物之后回收气体中的热量; 除尘器，用于除去气体中的微粒; 一种在颗粒物收集之后将活性炭喷射到气体中的活性炭雾器; 收集具有吸附汞的活性炭的袋式过滤器; 去除活性炭后除去烟道气中的硫氧化物的脱硫剂; 将经过脱硫的气体排出到外部的叠层; 以及测量用于将空气送入脱硫器中的浆料吸收剂的氧化还原电位的ORP计量器。