公开(公告)号：US07749455B2

公开(公告)日：2010-07-06

申请号：US10522604

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

IPC分类号： G05D7/00 ,  B01D53/04 ,  B01D53/34 ,  B01D53/52 ,  B01D53/86 ,  B01J8/02 ,  B01J35/02 ,  C01B17/00 ,  C01B17/16 ,  C01B31/00 ,  C10G17/00 ,  C10G45/00

CPC分类号： B01J23/866 ,  B01D53/885 ,  C10K1/34

摘要： A COS treatment apparatus for a gasified gas includes an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst. Also, a COS treatment apparatus includes a TiO2 catalyst that carries Cr2O3 or NiO. Further, a COS treatment method includes a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.

摘要翻译： 用于气化气体的COS处理装置包括相对于除去氧化催化剂的气化气体流的下游侧的除氧催化剂和COS转化催化剂。 此外，COS处理装置包括载持Cr 2 O 3或NiO的TiO 2催化剂。 此外，COS处理方法包括通过与H 2 S和CO的反应除去O 2的第一步骤和将COS转化为H 2 S的第二步骤。

公开(公告)号：US20060110304A1

公开(公告)日：2006-05-25

申请号：US10523679

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D53/58

CPC分类号： C10K1/101 ,  B01D53/14 ,  B01D2257/406

摘要： The present invention provides a wet gas purification method in which ammonia in the gas is removed, and a system for carrying out said method, characterized in that the method includes a washing step in which ammonia in the gas is absorbed in an absorbent for removal; and an ammonia treating step in which ammonia is stripped from the discharged absorbent at a following stage of the washing step, wherein the absorbent is divided into an off-gas containing ammonia and effluent. In the washing step makeup water is charged continuously or intermittently so that the concentration of ammonia in the gas having passed through the washing step is 10 ppm or lower. According to the present invention, a wet gas purification method can be performed in which the running costs involved in operation is reduced, the manipulation step and system are simple, operation is easy, and the reliability is high.

摘要翻译： 本发明提供一种其中除去气体中的氨的湿气净化方法，以及用于实施所述方法的系统，其特征在于，所述方法包括洗涤步骤，其中所述气体中的氨被吸收剂吸收除去; 以及在洗涤步骤的后续阶段从排出的吸收剂中除去氨的氨处理步骤，其中吸收剂被分成含有氨和废水的废气。 在洗涤步骤中，连续地或间歇地加入水，使得通过洗涤步骤的气体中的氨浓度为10ppm以下。 根据本发明，可以进行操作中涉及的运行成本降低的操作步骤和系统简单，操作容易，可靠性高的湿气净化方法。

公开(公告)号：US07381389B2

公开(公告)日：2008-06-03

申请号：US10523679

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D53/58 ,  B01J10/00

CPC分类号： C10K1/101 ,  B01D53/14 ,  B01D2257/406

摘要： A wet gas purification method is provided for removing ammonia from a heavy oil gasification gas, such as coal. The method principally involves a washing step during which absorbent is charged into the gas to absorb ammonia and an ammonia treating step wherein absorbent discharged from the washing step is separated into an effluent and an off-gas containing ammonia. The amount of absorbent charged during the washing step is controlled such that the ammonia concentration of gas exiting the washing step is 10 ppm or less.

摘要翻译： 提供湿气净化方法，用于从重油气化气体如煤中除去氨。 该方法主要涉及洗涤步骤，在该步骤中将吸收剂装入气体中以吸收氨和氨处理步骤，其中将从洗涤步骤排出的吸收剂分离成流出物和含有氨的废气。 控制在洗涤步骤中加入的吸收剂的量使得离开洗涤步骤的气体的氨浓度为10ppm以下。

公开(公告)号：US20060051263A1

公开(公告)日：2006-03-09

申请号：US10522604

申请日：2003-08-06

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino ,  Kozo Iida ,  Akira Johana

IPC分类号： B01J8/02

CPC分类号： B01J23/866 ,  B01D53/885 ,  C10K1/34

摘要： There is disclosed a COS treatment apparatus for a gasified gas, in which an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst are provided. Also, there is disclosed a COS treatment apparatus containing a TiO2 catalyst that carries Cr2O3 or NiO. Further, there is disclosed a COS treatment method including a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.

摘要翻译： 公开了一种用于气化气体的COS处理装置，其中位于气化气体的下游侧的O 2 H 2除去催化剂和COS转化催化剂相对于O 2 提供了除去催化剂。

公开(公告)号：US20060141414A1

公开(公告)日：2006-06-29

申请号：US11362148

申请日：2006-02-27

申请人： Masahiro Harada ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Masahiro Hirano ,  Hiroshi Suzumura ,  Shintaro Honjo ,  Yoshinori Koyama ,  Katsuhiko Yokohama ,  Mitsugi Suehiro

发明人： Masahiro Harada ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Masahiro Hirano ,  Hiroshi Suzumura ,  Shintaro Honjo ,  Yoshinori Koyama ,  Katsuhiko Yokohama ,  Mitsugi Suehiro

IPC分类号： F23D14/62

CPC分类号： B01D53/58 ,  B01D53/52 ,  F23G7/065 ,  F23J7/00 ,  F23J15/006 ,  F23J2215/10 ,  Y02P20/129

摘要： A gas combustion treatment method for the combustion treatment of an ammonia-containing gas and a hydrogen sulfide-containing gas, the method comprising a first combustion treatment step in which the ammonia-containing gas, together with a fuel, is introduced and burned; a nitrogen oxide reduction step downstream of the first combustion treatment step, in which a portion of the hydrogen sulfide-containing gas or the ammonia-containing gas is introduced and the nitrogen oxides produced in the first combustion treatment step are reduced in a reducing atmosphere; and a second combustion treatment step downstream of the nitrogen oxide reduction step, in which the remaining hydrogen sulfide-containing gas, together with air, is introduced and burned. The present invention provides a combustion apparatus suitable for use as a combustion furnace for off-gases resulting from the wet purification of coal gasification gas.

公开(公告)号：US07005115B2

公开(公告)日：2006-02-28

申请号：US10245326

申请日：2002-09-18

申请人： Masahiro Harada ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Masahiro Hirano ,  Hiroshi Suzumura ,  Shintaro Honjo ,  Yoshinori Koyama ,  Katsuhiko Yokohama ,  Mitsugi Suehiro

发明人： Masahiro Harada ,  Makoto Susaki ,  Kazuo Ishida ,  Hajime Nagano ,  Masahiro Hirano ,  Hiroshi Suzumura ,  Shintaro Honjo ,  Yoshinori Koyama ,  Katsuhiko Yokohama ,  Mitsugi Suehiro

IPC分类号： C01B17/16 ,  C01B31/20 ,  C01B21/00

CPC分类号： B01D53/58 ,  B01D53/52 ,  F23G7/065 ,  F23J7/00 ,  F23J15/006 ,  F23J2215/10

摘要： A gas combustion treatment method for the combustion treatment of an ammonia-containing gas and a hydrogen sulfide-containing gas, the method comprising a first combustion treatment step in which the ammonia-containing gas, together with a fuel, is introduced and burned; a nitrogen oxide reduction step downstream of the first combustion treatment step, in which a portion of the hydrogen sulfide-containing gas or the ammonia-containing gas is introduced and the nitrogen oxides produced in the first combustion treatment step are reduced in a reducing atmosphere; and a second combustion treatment step downstream of the nitrogen oxide reduction step, in which the remaining hydrogen sulfide-containing gas, together with air, is introduced and burned. The present invention provides a combustion apparatus suitable for use as a combustion furnace for off-gases resulting from the wet purification of coal gasification gas.

公开(公告)号：US06770119B2

公开(公告)日：2004-08-03

申请号：US10233526

申请日：2002-09-04

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Suzaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Suzaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D5314

CPC分类号： C10K1/16 ,  B01D53/14 ,  B01D53/64 ,  B01D2257/602 ,  C10K1/085 ,  C10K1/10

摘要： The present invention provides a mercury removal method which can effectively remove very small amounts of mercury components present in a gas during wet gas purification such as coal or heavy oil gasification gas purification and petroleum refining. A mercury removal method for the removal of mercury present in a gas, the method comprising the steps of bringing a gas containing at least mercury and not less than 10 ppm of hydrogen sulfide into gas-liquid contact with an absorbing fluid under pressurized conditions so as to cause mercury to pass into the absorbing fluid; flashing the mercury-containing absorbing fluid under lower-pressure conditions to separate it into gaseous components and liquid components; and removing the mercury contained in the separated gaseous components by adsorption to an adsorbent.

摘要翻译： 本发明提供了一种除汞方法，其可以有效地去除在湿气净化中例如煤或重油气化气净化和石油精炼中的气体中存在的非常少量的汞成分。 一种用于除去存在于气体中的汞的汞去除方法，该方法包括以下步骤：在加压条件下使至少包含汞和不少于10ppm硫化氢的气体与吸收液体气液接触，以便 使汞进入吸收液; 在低压条件下闪烁含汞吸收液，将其分离成气态组分和液体组分; 并且通过吸附到吸附剂上除去分离的气态组分中所含的汞。

公开(公告)号：US07871586B2

公开(公告)日：2011-01-18

申请号：US11921683

申请日：2006-06-09

申请人： Masahiro Harada ,  Makoto Susaki ,  Shintaro Honjo ,  Shuji Kameyama ,  Masaki Nakahara ,  Akira Kisei

发明人： Masahiro Harada ,  Makoto Susaki ,  Shintaro Honjo ,  Shuji Kameyama ,  Masaki Nakahara ,  Akira Kisei

IPC分类号： B01D53/64 ,  B01D53/74

CPC分类号： C10J3/00 ,  B01D53/64 ,  B01D2251/10 ,  B01D2257/602 ,  C02F1/20 ,  C02F1/26 ,  C02F1/5236 ,  C02F1/683 ,  C02F1/72 ,  C02F9/00 ,  C02F2001/007 ,  C02F2101/20 ,  C02F2103/18 ,  C02F2103/365 ,  C10G31/08 ,  C10G2300/205 ,  C10G2300/207 ,  C10J3/84 ,  C10J2300/169 ,  C10K1/004 ,  C10K1/101 ,  C10K1/143 ,  C10K1/32 ,  Y02E20/16 ,  Y02E20/18

摘要： The present invention provides a mercury removal system and method for effectively removing a mercury component, which is present in a gas stream in an extremely small amount in wet gas cleaning. The mercury removal system in wet gas cleaning includes a water washing tower for introducing therein a target gas containing a mercury component and transferring the mercury component into an absorbing solution, a flash drum (10) for flashing the absorbing solution discharged from the water washing tower to separate the absorbing solution into a gas component and waste water, an oxidation treatment means (1) for adding an oxidizing agent to the absorbing solution at the preceding stage of the flash drum, and a waste water treatment means for subjecting to coagulation sedimentation treatment the separated waste water containing the mercury component at the following stage of the flash drum to dispose of the mercury component as sludge.

摘要翻译： 本发明提供了一种汞去除系统和方法，用于有效地去除在湿气清洁中极少量的气流中存在的汞成分。 湿气清洗中的除汞系统包括用于在其中引入含有汞成分的目标气体并将汞成分转移到吸收溶液中的水洗塔，用于使从水洗塔排出的吸收溶液闪烁的闪蒸筒（10） 将吸收溶液分离成气体成分和废水，将用于在闪蒸鼓的前一阶段向吸收溶液中添加氧化剂的氧化处理装置（1）和用于进行凝结沉淀处理的废水处理装置 分离的废水在闪蒸桶的后续阶段含有汞组分，以处理汞组分作为污泥。

公开(公告)号：US20090304563A1

公开(公告)日：2009-12-10

申请号：US11921683

申请日：2006-06-09

申请人： Masahiro Harada ,  Makoto Susaki ,  Shintaro Honjo ,  Shuji Kameyama ,  Masaki Nakahara ,  Akira Kisei

发明人： Masahiro Harada ,  Makoto Susaki ,  Shintaro Honjo ,  Shuji Kameyama ,  Masaki Nakahara ,  Akira Kisei

IPC分类号： B01D53/64 ,  B01D50/00

CPC分类号： C10J3/00 ,  B01D53/64 ,  B01D2251/10 ,  B01D2257/602 ,  C02F1/20 ,  C02F1/26 ,  C02F1/5236 ,  C02F1/683 ,  C02F1/72 ,  C02F9/00 ,  C02F2001/007 ,  C02F2101/20 ,  C02F2103/18 ,  C02F2103/365 ,  C10G31/08 ,  C10G2300/205 ,  C10G2300/207 ,  C10J3/84 ,  C10J2300/169 ,  C10K1/004 ,  C10K1/101 ,  C10K1/143 ,  C10K1/32 ,  Y02E20/16 ,  Y02E20/18

摘要： The present invention provides a mercury removal system and method for effectively removing a mercury component, which is present in a gas stream in an extremely small amount in wet gas cleaning used for coal or heavy oil gasification, petroleum refining and the like. The mercury removal system in wet gas cleaning comprises a water washing tower for introducing therein a target gas containing a mercury component and transferring the mercury component into an absorbing solution, a flush drum (10) for flushing the absorbing solution discharged from the water washing tower to separate the absorbing solution into a gas component and waste water, an oxidation treatment means (1) for adding an oxidizing agent to the absorbing solution at the preceding stage of the flush drum, and a waste water treatment means for subjecting to coagulation sedimentation treatment the separated waste water containing the mercury component at the following stage of the flush drum to dispose of the mercury component as sludge. The present invention also provides a mercury removal method using the above-described system.

摘要翻译： 本发明提供一种汞清除系统和方法，用于有效地除去在用于煤或重油气化，石油精炼等的湿气清洗中以极小量存在于气流中的汞成分。 湿气清洗中的除汞系统包括：水洗塔，用于在其中引入含有汞成分的目标气体并将汞成分转移到吸收溶液中;冲洗桶（10），用于冲洗从水洗塔排出的吸收溶液 将吸收溶液分离成气体成分和废水，在冲洗鼓前段向吸收液中添加氧化剂的氧化处理装置（1）和进行凝结沉淀处理的废水处理装置 在冲洗桶的后续阶段将含有汞组分的分离废水作为污泥处理。 本发明还提供一种使用上述系统的汞去除方法。

公开(公告)号：US20110044872A1

公开(公告)日：2011-02-24

申请号：US12812866

申请日：2009-01-20

申请人： Nobuyuki Ukai ,  Shintaro Honjo ,  Susumu Okino

发明人： Nobuyuki Ukai ,  Shintaro Honjo ,  Susumu Okino

IPC分类号： B01D53/56 ,  B01D53/50 ,  B01D53/64 ,  B01J19/00

CPC分类号： F23J15/003 ,  B01D53/501 ,  B01D53/64 ,  B01D53/75 ,  B01D53/79 ,  B01D53/8625 ,  B01D2251/10 ,  B01D2251/2062 ,  B01D2251/404 ,  B01D2253/102 ,  B01D2257/602 ,  B01J20/0266 ,  B01J20/0285 ,  B01J20/20 ,  B01J45/00 ,  C02F1/001 ,  C02F1/283 ,  C02F1/42 ,  C02F1/52 ,  C02F1/683 ,  C02F2101/20 ,  C02F2103/18 ,  C02F2209/003 ,  C02F2303/18 ,  F23J15/006 ,  F23J15/025 ,  F23J15/04 ,  F23J2215/20 ,  F23J2215/60 ,  F23J2219/20 ,  F23J2219/30 ,  Y02A50/2348

摘要： A flue gas control system of a coal combustion boiler according to the present invention includes: an HCI atomizer (32) that sprays hydrogen chloride (33) to flue gas from a coal combustion boiler (11) that uses coal as a fuel (F); NOx removing apparatus (13) that removes nitrogen oxides by ammonia denitration by adding ammonia (12) to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater (14) that recovers heat in the gas after removal of nitrogen oxides; a precipitator (15) that removes particulates in the gas; an activated carbon atomizer (22) that sprays activated carbon (22a) into the gas after particulate collection; a bag filter (21) that collects activated carbon having adsorbed mercury; a desulfurizer (16) that removes sulfur oxides in the flue gas after removal of activated carbon; a stack (17) that discharges the gas which has undergone desulfurization to outside; and an ORP meter (19) that measures an oxidation reduction potential for feeding air to a slurry absorbent in the desulfurizer (16).

摘要翻译： 根据本发明的燃煤锅炉的烟气控制系统包括：将来自使用煤作为燃料（F）的煤燃烧锅炉（11）的烟道气喷射氯化氢（33）的HCl喷雾器（32） ; NO x除去装置（13），其通过在喷射氯化氢之后向烟道气中加入氨（12）而通过氨脱硝除去氮氧化物并氧化汞; 一种空气预热器（14），其在去除氮氧化物之后回收气体中的热量; 除尘器（15），其去除气体中的微粒; 在颗粒收集之后将活性炭（22a）喷射到气体中的活性碳雾化器（22）; 收集具有吸附的汞的活性炭的袋式过滤器（21） 去除活性炭后除去烟道气中的硫氧化物的脱硫剂（16）; 将已进行脱硫的气体排出到外部的堆（17） 以及测量用于将空气供给到脱硫器（16）中的浆料吸收剂的氧化还原电位的ORP计（19）。