公开(公告)号：US20110155223A1

公开(公告)日：2011-06-30

申请号：US12673214

申请日：2009-06-17

申请人： Masahiro Morooka ,  Reiko Yoneya ,  Harumi Takada ,  Masaki Orihashi ,  Cheng Zhu ,  Yusuke Suzuki ,  Kazuhiro Noda ,  Keishi Tada ,  Natsuki Kubo ,  Megumi Miki ,  Mitsuhiro Nakamura

发明人： Masahiro Morooka ,  Reiko Yoneya ,  Harumi Takada ,  Masaki Orihashi ,  Cheng Zhu ,  Yusuke Suzuki ,  Kazuhiro Noda ,  Keishi Tada ,  Natsuki Kubo ,  Megumi Miki ,  Mitsuhiro Nakamura

IPC分类号： H01L31/04 ,  H01L31/02 ,  H01L31/18 ,  B82Y99/00 ,  B82Y40/00

CPC分类号： H01G9/2031 ,  H01G9/2059 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention provides a dye-sensitized solar cell which can obtain a high photoelectric conversion efficiency, which can be manufactured at a low cost, and which is superior in a design property, and a method of manufacturing the same. Dye supporting porous titanium oxide layers 2a to 2d are formed on a transparent conductive substrate 1 so as to display predetermined colors, respectively, and compose predetermined patterns, respectively, in accordance with selection of a thickness, a lamination structure, a particle diameter of titanium oxide fine particles, or a combination ratio of two or more kinds of titanium oxide fine particles when titanium oxide fine particles are composed of the two or more kinds of titanium oxide fine particles different in particle diameter from one another. The transparent conductive substrate 1 having the dye supporting porous titanium oxide layers 2a to 2d formed thereon, and a transparent conductive substrate 3 having a counter electrode 4 formed thereon are stuck to each other through a seal material 5 so that the dye supporting porous titanium oxide layers 2a to 2d, and the counter electrode 4 face each other, and a space defined between the transparent conductive substrate 1 and the transparent conductive substrate 3 is enclosed with an electrolyte layer 6, thereby forming a dye-sensitized solar cell.

摘要翻译： 本发明提供一种能够以低成本制造，且设计性优异的光电转换效率高的染料敏化太阳能电池及其制造方法。 在透明导电性基板1上形成有支撑多孔氧化钛层2a〜2d的分散形状，通过选择厚度，叠层结构，钛粒子的粒径，分别形成规定的颜色，构成规定图案 氧化物微粒，或当氧化钛微粒由两种或更多种粒径不同的氧化钛微粒组成时，两种或更多种氧化钛微粒的组合比。 在其上形成有负载多孔氧化钛层2a〜2d的染料的透明导电性基板1和形成有对置电极4的透明导电性基板3通过密封材料5彼此粘合，使得负载着染料的多孔氧化钛 层2a至2d和对电极4彼此面对，并且在透明导电基板1和透明导电基板3之间限定的空间被电解质层6包围，从而形成染料敏化太阳能电池。

公开(公告)号：US20100144083A1

公开(公告)日：2010-06-10

申请号：US12733093

申请日：2009-06-24

申请人： Yusuke Suzuki ,  Masahiro Morooka ,  Keishi Tada ,  Yasunori Nagano ,  Reiko Yoneya ,  Masaki Orihashi ,  Harumi Takada ,  Cheng Zhu

发明人： Yusuke Suzuki ,  Masahiro Morooka ,  Keishi Tada ,  Yasunori Nagano ,  Reiko Yoneya ,  Masaki Orihashi ,  Harumi Takada ,  Cheng Zhu

IPC分类号： H01L31/18

CPC分类号： H01M14/005 ,  H01G9/2031 ,  H01G9/2063 ,  H01G9/2068 ,  H01G9/2072 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention relates to a method of manufacturing a photoelectric conversion device in which selective dye adsorption can be performed easily. In the step of a dye adsorbing process, a material unit 21 having partition walls of a predetermined shape is placed over semiconductor electrodes 121 to 123, which are a titanium oxide electrode. The material unit 21 is laminated by a UV cure adhesive. Dye solutions S1 to S3 obtained by dissolving each of three kinds of dyes of N719, Black dye, and D149, for example, into a CH3CN/t-BuOH mixed solution are put in each of sections divided by the partition walls. The material unit 21 is inverted in that state, and left standing still for 24 hours. Then, the adhesive is removed after passage of the 24 hours. Thus, the semiconductor electrodes 121 to 123 having regions corresponding to the sections which regions are colored with the three different kinds of dyes are obtained. The present invention is applicable to a method of manufacturing a dye sensitized solar cell.

摘要翻译： 本发明涉及可以容易地进行选择性染料吸附的光电转换装置的制造方法。 在染料吸附工序中，将具有预定形状的隔壁的材料单元21放置在作为氧化钛电极的半导体电极121〜123上。 材料单元21通过UV固化粘合剂层压。 将通过将N719，黑色染料和D149的三种染料中的每一种例如溶解在CH 3 CN / t-BuOH混合溶液中得到的染料溶液S1至S3放入由分隔壁划分的每个部分中。 材料单元21在该状态下倒置，静置24小时。 然后，在24小时后通过去除粘合剂。 因此，获得具有对应于区域的区域的半导体电极121至123，这些区域用三种不同种类的染料着色。 本发明可应用于染料敏化太阳能电池的制造方法。

公开(公告)号：US20110083719A1

公开(公告)日：2011-04-14

申请号：US12999254

申请日：2009-06-24

申请人： Harumi Takada ,  Masahiro Morooka ,  Reiko Yoneya ,  Masaki Orihashi ,  Cheng Zhu ,  Yusuki Suzuki ,  Kazuhiro Noda

发明人： Harumi Takada ,  Masahiro Morooka ,  Reiko Yoneya ,  Masaki Orihashi ,  Cheng Zhu ,  Yusuki Suzuki ,  Kazuhiro Noda

IPC分类号： H01L31/12

CPC分类号： H01G9/2068 ,  H01G9/2031 ,  H01G9/2059 ,  H01M10/46 ,  H02S40/38 ,  Y02E10/542

摘要： The present invention relates to an electronic device configured to make use of features in terms of design quality and flexibility of a dye-sensitized solar cell. A solar cell-cum-display unit 61 has both a function of a solar cell and a function of a display unit that displays a predetermined display body, allows a predetermined character string such as “PONY” to be indentified, generates electric power from illuminating light or sunlight, and stores the electric power in a storage battery 62. A light source 63 such as a fluorescent lamp radiates light to the solar cell-cum-display unit 61 by the electric power stored in the storage battery 63, whereby the features of the dye-sensitized solar cell can be made use of. The present invention is applicable to a device including a dye-sensitized solar cell.

摘要翻译： 本发明涉及一种电子设备，其被配置为利用染料敏化太阳能电池的设计质量和灵活性方面的特征。 太阳能电池和显示单元61具有太阳能电池的功能和显示预定显示体的显示单元的功能，允许诸如“PONY”之类的预定字符串被识别，从照明中产生电力 光或阳光，并且将电力存储在蓄电池62中。诸如荧光灯的光源63通过存储在蓄电池63中的电力将光辐射到太阳能电池并行显示单元61，由此， 的染料敏化太阳能电池可以使用。 本发明可应用于包括染料敏化太阳能电池的装置。

公开(公告)号：US20120097251A1

公开(公告)日：2012-04-26

申请号：US13061320

申请日：2010-06-25

申请人： Harumi Takada ,  Masaki Orihashi ,  Reiko Yonaya ,  Masahiro Morooka ,  Yusuke Isshiki ,  Yusuke Suzuki

发明人： Harumi Takada ,  Masaki Orihashi ,  Reiko Yonaya ,  Masahiro Morooka ,  Yusuke Isshiki ,  Yusuke Suzuki

IPC分类号： H01L51/46 ,  H01L31/18 ,  B82Y99/00

CPC分类号： H01G9/2031 ,  H01G9/2059 ,  H01L51/0086 ,  Y02E10/542 ,  Y02P70/521

摘要： A photoelectric conversion device and a method for making same are provided wherein a porous photoelectrode is prevented from dissolution in an electrolyte, a surface plasmon resonance effect can be well obtained, and a drastic improvement in photoelectric conversion efficiency can be attained.In a photoelectric conversion device having a structure wherein an electrolyte layer (6) is filled between a porous photoelectrode (3) formed on a transparent substrate (1) and a counter electrode (4), the porous photoelectrode (3) is constituted of metal/metal oxide fine particles (7) including a core made of a metal and a shell surrounding the core and made of a metal oxide. In a dye-sensitized photoelectric conversion device, a sensitizing dye (8) is adsorbed on the surface of the porous photoelectrode (3).

摘要翻译： 提供一种光电转换装置及其制造方法，其中防止多孔光电极溶解在电解质中，可以很好地获得表面等离子体共振效应，并且可以实现光电转换效率的急剧提高。 在具有将电解质层（6）填充在形成于透明基板（1）上的多孔光电极（3）和反电极（4）之间的结构的光电转换装置中，多孔光电极（3）由金属 /金属氧化物细颗粒（7），其包括由金属制成的芯和围绕芯并且由金属氧化物制成的壳。 在染料敏化光电转换装置中，敏化染料（8）吸附在多孔光电极（3）的表面上。

公开(公告)号：US20100132785A1

公开(公告)日：2010-06-03

申请号：US12449228

申请日：2008-12-09

申请人： Masahiro Morooka ,  Masaki Orihashi ,  Harumi Takada

发明人： Masahiro Morooka ,  Masaki Orihashi ,  Harumi Takada

IPC分类号： H01L31/00 ,  H01L31/18 ,  H01L31/042

CPC分类号： H01M14/005 ,  H01G9/2013 ,  H01G9/2031 ,  H01G9/2059 ,  H01G9/2077 ,  H01G9/2095 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention provides a dye-sensitized photoelectric conversion element module, such as a dye-sensitized solar cell module, which can be structured so as to be lightweight, thin and flexible, and with which a high electric power generation efficiency can be obtained, and a method of manufacturing the same. In a dye-sensitized photoelectric conversion element module having a plurality of dye-sensitized photoelectric conversion elements on a supporting base material, a filmy glass substrate 1 having a thickness of 0.2 mm or less is used as the supporting base material, and a resin system protective film 9, 11 having a size equal to or larger than that of the filmy glass substrate 1 is bonded to at least one surface of the dye-sensitized photoelectric conversion element module. A dye-sensitized semiconductor layer 3, a porous insulating layer 4, and a counter electrode 5 are laminated in order on a transparent conductive layer 2 formed on the filmy glass substrate 1, thereby structuring a dye-sensitized photoelectric conversion element module. The dye-sensitized semiconductor layer 3 and a porous insulating layer 4 are impregnated with an electrolyte.

摘要翻译： 本发明提供染色敏化的光电转换元件模块，例如染料敏化太阳能电池模块，其可以被构造成轻便，薄且柔性，并且可以获得高的发电效率， 及其制造方法。 在支撑基材上具有多个染料敏化光电转换元件的染料敏化光电转换元件模块中，使用厚度为0.2mm以下的膜状玻璃基板1作为支撑基材，树脂体系 具有等于​​或大于胶片玻璃基板1的尺寸的保护膜9,11被结合到染料敏化光电转换元件模块的至少一个表面上。 染料敏化半导体层3，多孔绝缘层4和对电极5依次层压在形成在胶片玻璃基板1上的透明导电层2上，从而构成染料敏化光电转换元件模块。 染料敏化半导体层3和多孔绝缘层4被电解质浸渍。

公开(公告)号：US20140174524A1

公开(公告)日：2014-06-26

申请号：US14130126

申请日：2012-06-22

申请人： Yoshiaki Obana ,  Keishi Tada ,  Harumi Takada ,  Ryo Sasaki ,  Yusuke Suzuki

发明人： Yoshiaki Obana ,  Keishi Tada ,  Harumi Takada ,  Ryo Sasaki ,  Yusuke Suzuki

IPC分类号： H01G9/20

CPC分类号： H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  Y02B10/10 ,  Y02E10/542 ,  Y02P70/521

摘要： Provided are a counter electrode, which is excellent in electrolytic solution resistance and electrical conductivity, and which is capable of corresponding to an application process carried out by pattern printing during a manufacturing process, a photoelectric conversion element using the counter electrode, and a method for manufacturing the same. A dye-sensitized photoelectric conversion element has a structure in which an electrolyte layer is filled between a porous electrode to which a photosensitizing dye is adsorbed and a counter electrode. The counter electrode includes: a metal counter electrode; a conductive primer layer that contains conductive carbon, and at least one resin selected among a polyamide imide resin, a polyamide resin, and polyimide resin as a binder resin; and a catalyst layer containing conductive carbon and an inorganic binder. The metal counter electrode and the catalyst layer are formed to come into close contact with each other through the conductive primer layer.

摘要翻译： 提供了一种对电极，其电解溶液电阻和电导率优异，并且能够对应于在制造过程中通过图案印刷进行的涂布工艺，使用对电极的光电转换元件，以及用于 制造相同。 染料敏化光电转换元件具有在吸附有感光性染料的多孔电极与对电极之间填充电解质层的结构。 对电极包括：金属对电极; 含有导电性碳的导电性底漆层和选自聚酰胺酰亚胺树脂，聚酰胺树脂和聚酰亚胺树脂中的至少一种树脂作为粘合剂树脂; 以及含有导电性碳和无机粘合剂的催化剂层。 金属对电极和催化剂层形成为通过导电底漆层彼此紧密接触。

公开(公告)号：US20120132280A1

公开(公告)日：2012-05-31

申请号：US13388719

申请日：2010-08-12

申请人： Yasunori Nagano ,  Tetsuya Komine ,  Masahiro Morooka ,  Harumi Takada

发明人： Yasunori Nagano ,  Tetsuya Komine ,  Masahiro Morooka ,  Harumi Takada

IPC分类号： H01L31/0203 ,  H01L31/18

CPC分类号： H01M14/005 ,  H01M2/08 ,  Y02E10/542 ,  Y02P70/521

摘要： The present invention can simplify a process.In the present invention, a transparent conductive layer (5) is provided on an electrode side substrate (12); a porous semiconductor layer (7) is provided on the transparent conductive layer (5); and a counter electrode layer (9) in a state in which it is separated from the porous semiconductor layer (7) is provided. A cell partition wall (6) which is provided on the electrode side substrate (12) and surrounds the periphery of the porous semiconductor layer (7) is provided. In the sensitized solar cell module (11), electrolytic solution (10) is impregnated in the porous semiconductor layer (7) and the counter electrode layer (9), and a sealing material in the form of liquid is disposed in such a manner as to cover an upper portion of the cell partition wall (6) to seal the electrolytic solution (10). Then, the sealing material in the form of liquid is solidified.

摘要翻译： 本发明可以简化过程。 在本发明中，在电极侧基板（12）上设置透明导电层（5）。 在透明导电层（5）上设置多孔半导体层（7）; 和与多孔半导体层（7）分离的状态的对电极层（9）。 提供设置在电极侧基板（12）上且围绕多孔半导体层（7）的周围的电池隔壁（6）。 在敏化太阳能电池模块（11）中，电解液（10）浸渍在多孔半导体层（7）和对电极层（9）中，液体形式的密封材料以 以覆盖电池隔离壁（6）的上部以密封电解液（10）。 然后，液体形式的密封材料被固化。

公开(公告)号：US20110315213A1

公开(公告)日：2011-12-29

申请号：US13161577

申请日：2011-06-16

申请人： Harumi Takada ,  Masahiro Morooka

发明人： Harumi Takada ,  Masahiro Morooka

IPC分类号： H01L31/0224

CPC分类号： H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  H01G9/2068 ,  H01G9/2081 ,  H01L51/0024 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

摘要： Disclosed herein is a method of manufacturing a photoelectric conversion element, including adhering a counter electrode having a current collector onto a porous photoelectrode and a porous insulating layer which are sequentially layered over a substrate; and bending the current collector and joining the current collector to the substrate.

摘要翻译： 本文公开了一种制造光电转换元件的方法，包括将具有集电器的对电极粘附到在基板上依次层叠的多孔光电极和多孔绝缘层; 并弯曲集电体并将集电体接合到基板。

公开(公告)号：US20110159425A1

公开(公告)日：2011-06-30

申请号：US12973739

申请日：2010-12-20

申请人： Hitoshi Itabashi ,  Takashi Kenmoku ,  Harumi Takada

发明人： Hitoshi Itabashi ,  Takashi Kenmoku ,  Harumi Takada

IPC分类号： G03G9/097

CPC分类号： G03G9/08791 ,  G03G9/08706 ,  G03G9/08708 ,  G03G9/08722 ,  G03G9/08724 ,  G03G9/08726

摘要： To obtain a toner which has excellent charge rise and stability, tends to have a sharp charge distribution, has excellent pigment dispersion properties, exhibits no disarray in an image even during a high-speed copying operation, and can stably output high-resolution images. A toner comprising toner particle containing a binder resin, a colorant, resin PA, and resin PB, wherein the resin PA has unit A represented by Formula (1), the resin PB has unit B represented by Formula (2), a content “a” of the unit A in the toner particle is 2.00 μmol/g or more, and a molar ratio b/a of the content “a” and a content “b” of the unit B in the toner particle is 0.10 or more and 10.00 or less.

摘要翻译： 为了获得具有优异的电荷上升和稳定性的调色剂，倾向于具有尖锐的电荷分布，具有优异的颜料分散性能，即使在高速复印操作期间也不会在图像中混乱，并且可以稳定地输出高分辨率图像。 包含粘合剂树脂，着色剂，树脂PA和树脂PB的调色剂颗粒的调色剂，其中树脂PA具有由式（1）表示的单元A，树脂PB具有由式（2）表示的单元B，含量“ 调色剂颗粒中的单元A“为2.00μmol/ g以上，调色剂颗粒中单元B的含量”a“和含量”b“的摩尔比b / a为0.10以上， 10.00以下。

公开(公告)号：US5942431A

公开(公告)日：1999-08-24

申请号：US875062

申请日：1997-07-10

申请人： Tadashi Yoneda ,  Harumi Takada ,  Kei Ohno ,  Junji Sasuga

发明人： Tadashi Yoneda ,  Harumi Takada ,  Kei Ohno ,  Junji Sasuga

IPC分类号： C12N15/09 ,  C12N1/21 ,  C12N9/20 ,  C12N15/55 ,  C12R1/07 ,  C12R1/19 ,  C12R1/38 ,  C07H21/04 ,  C12N1/20 ,  C12N15/00

CPC分类号： C12N9/20

摘要： DNA sequences encoding lipases and method for producing the lipases. The disclosed lipases are industrially useful in, for example, detergents, food processing, paper making, oil manufacturing.

摘要翻译： PCT No.PCT / JP96 / 00426 Sec。 371日期1997年7月10日 102（e）日期1997年7月10日PCT提交1996年2月23日PCT公布。 WO96 / 27002 PCT出版物 日期1996年9月6日编码脂肪酶的DNA序列和生产脂肪酶的方法。 所公开的脂肪酶在工业上可用于例如洗涤剂，食品加工，造纸，油制造。