公开(公告)号：US08574693B2

公开(公告)日：2013-11-05

申请号：US12308946

申请日：2007-05-16

申请人： Masahiro Sugai ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

发明人： Masahiro Sugai ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

IPC分类号： C04B35/113

CPC分类号： B29C47/02 ,  B29B11/08 ,  B29B11/10 ,  B29B11/12 ,  B29C43/52 ,  B29C47/0023 ,  B29C47/06 ,  B29C49/02 ,  B29C2043/522 ,  B29K2003/00 ,  B29K2105/16 ,  B29K2995/006 ,  B29L2031/7158 ,  C08J3/201 ,  C08J2367/04 ,  C08K3/36 ,  C08K9/04 ,  C08K9/06 ,  C08L67/04

摘要： A preform is formed by compounding a resin made from poly-L-lactic acid with a functional filler and subjecting a mouth portion to a heat treatment. Also, a hollow shaped product is produced by blow-molding the preform.

摘要翻译： 通过将由聚-L-乳酸制成的树脂与功能性填料混合并对口部进行热处理而形成预成型体。 此外，通过吹塑预制件来制造中空成型制品。

公开(公告)号：US08343604B2

公开(公告)日：2013-01-01

申请号：US12934748

申请日：2009-02-23

申请人： Masahiro Sugai ,  Hiromi Shimura ,  Masato Suzuki

发明人： Masahiro Sugai ,  Hiromi Shimura ,  Masato Suzuki

IPC分类号： B29D22/00

CPC分类号： B32B27/36 ,  B32B1/02 ,  B32B27/08 ,  B32B27/34 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2307/40 ,  B32B2307/702 ,  B32B2307/714 ,  B32B2307/7242 ,  B32B2439/60 ,  B65D1/0215 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/1393

摘要： A container made of synthetic resin which does not cause whitening or clouding in an unstretched portion even after long-period storage and which has excellent barrier properties. A PET bottle comprising a substrate layer made of PET and a barrier layer having a gas permeability lower than that of the substrate layer, wherein the barrier layer is made of a barrier material prepared by incorporating a polyamide containing m-xylene groups with an amorphous polyamide comprising both m-xylene isophthalamide structures and hexamethylene isophthalamide structures. A copolyamide composed of both a copolymer of m-xylenediamine and isophthalic acid and a copolymer of hexamethylenediamine and isophthalic acid is used as the amorphous polyamide. The content of the amorphous polyamide in the barrier layer is adjusted to 15 to 25 wt %.

摘要翻译： 由合成树脂制成的容器，即使在长期储存后也不会在未拉伸部分中引起白化或混浊，并且具有优异的阻隔性。 一种PET瓶，包括由PET制成的基底层和气体透过率低于基底层的阻挡层，其中阻挡层由通过将含有间二甲苯基团的聚酰胺与非晶形聚酰胺 包括间二甲苯间苯二酰胺结构和六亚甲基间苯二酰胺结构。 使用由间二甲苯二胺和间苯二甲酸的共聚物和六亚甲基二胺和间苯二甲酸的共聚物组成的共聚酰胺作为无定形聚酰胺。 将阻挡层中的无定形聚酰胺的含量调整为15〜25重量％。

公开(公告)号：US20110036850A1

公开(公告)日：2011-02-17

申请号：US12934748

申请日：2009-02-23

申请人： Masahiro Sugai ,  Hiromi Shimura ,  Masato Suzuki

发明人： Masahiro Sugai ,  Hiromi Shimura ,  Masato Suzuki

IPC分类号： B65D90/02

CPC分类号： B32B27/36 ,  B32B1/02 ,  B32B27/08 ,  B32B27/34 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2307/40 ,  B32B2307/702 ,  B32B2307/714 ,  B32B2307/7242 ,  B32B2439/60 ,  B65D1/0215 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/1393

摘要： A container made of synthetic resin which does not cause whitening or clouding in an unstretched portion even after long-period storage and which has excellent barrier properties. A PET bottle comprising a substrate layer made of PET and a barrier layer having a gas permeability lower than that of the substrate layer, wherein the barrier layer is made of a barrier material prepared by incorporating a polyamide containing m-xylene groups with an amorphous polyamide comprising both m-xylene isophthalamide structures and hexamethylene isophthalamide structures. A copolyamide composed of both a copolymer of m-xylenediamine and isophthalic acid and a copolymer of hexamethylenediamine and isophthalic acid is used as the amorphous polyamide. The content of the amorphous polyamide in the barrier layer is adjusted to 15 to 25 wt %.

摘要翻译： 由合成树脂制成的容器，即使在长期储存后也不会在未拉伸部分中引起白化或混浊，并且具有优异的阻隔性。 一种PET瓶，包括由PET制成的基底层和气体透过率低于基底层的阻挡层，其中阻挡层由通过将含有间二甲苯基团的聚酰胺与非晶形聚酰胺 包括间二甲苯间苯二酰胺结构和六亚甲基间苯二酰胺结构。 使用由间二甲苯二胺和间苯二甲酸的共聚物和六亚甲基二胺和间苯二甲酸的共聚物组成的共聚酰胺作为无定形聚酰胺。 将阻挡层中的无定形聚酰胺的含量调整为15〜25重量％。

公开(公告)号：US20090226655A1

公开(公告)日：2009-09-10

申请号：US12308946

申请日：2007-05-16

申请人： Masahiro Sugai ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

发明人： Masahiro Sugai ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

IPC分类号： B32B1/00 ,  C08L67/00 ,  C08L5/00 ,  B29C47/88 ,  B29C45/72 ,  B29C43/52

CPC分类号： B29C47/02 ,  B29B11/08 ,  B29B11/10 ,  B29B11/12 ,  B29C43/52 ,  B29C47/0023 ,  B29C47/06 ,  B29C49/02 ,  B29C2043/522 ,  B29K2003/00 ,  B29K2105/16 ,  B29K2995/006 ,  B29L2031/7158 ,  C08J3/201 ,  C08J2367/04 ,  C08K3/36 ,  C08K9/04 ,  C08K9/06 ,  C08L67/04

摘要： A preform is formed by compounding a resin made from poly-L-lactic acid with a functional filler and subjecting a mouth portion to a heat treatment. Also, a hollow shaped product is produced by blow-molding the preform.

摘要翻译： 通过将由聚-L-乳酸制成的树脂与功能性填料混合并对口部进行热处理而形成预成型体。 此外，通过吹塑预制件来制造中空成型制品。

公开(公告)号：US08580365B2

公开(公告)日：2013-11-12

申请号：US11884311

申请日：2006-04-24

申请人： Minoru Abe ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

发明人： Minoru Abe ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

IPC分类号： B32B1/08 ,  B29C41/22 ,  B29C39/12 ,  B29C45/16

CPC分类号： B29B11/08 ,  B29B11/14 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/1404 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/14093 ,  B29B2911/141 ,  B29B2911/1412 ,  B29B2911/14146 ,  B29B2911/14326 ,  B29B2911/1433 ,  B29B2911/14331 ,  B29B2911/14333 ,  B29B2911/14336 ,  B29B2911/14337 ,  B29B2911/1444 ,  B29B2911/14466 ,  B29B2911/14633 ,  B29B2911/14646 ,  B29B2911/14713 ,  B29B2911/14753 ,  B29B2911/14766 ,  B29C45/1642 ,  B29C45/1646 ,  B29C49/06 ,  B29C49/221 ,  B29C2045/1698 ,  B29K2023/12 ,  B29K2067/00 ,  B29K2067/003 ,  B29K2077/00 ,  B29K2105/0032 ,  B29K2105/253 ,  B29K2105/258 ,  B29K2995/0026 ,  B29K2995/0067 ,  B29L2031/7158 ,  B65D1/0215 ,  B65D23/02 ,  Y10T428/1352 ,  Y10T428/139

摘要： The technical problem to be solved by the invention is to change the thickness of the colored resin layer of the preform gradually in the upward or downward direction, by utilizing a tendency of gradual decrease in the thickness of the colored resin layer caused by the flow of the main resin inside the preform mold when the main resin and the colored resin are injected into the mold. The objects of this invention is to provide a biaxially drawn, blow molded bottle having new decorativeness created in which sophisticated color gradations associated with color density are created in the body of this bottle. The means of accomplishing this object involves adjusting the injection pattern including the time of starting and ending the supply of the main resin and the colored resin, and pressure or velocity profiles, reducing the thickness of the colored resin layer in the multi-layered molten resin fluid gradually at an upstream or downstream point of the flow, injection-molding the preform in which a color-gradated portion associated with the thickness of the colored resin layer has been formed, and biaxially drawing and blow molding this preform into a bottle having a color-gradated portion associated with the color density or color shade created on the body of the bottle.

摘要翻译： 本发明要解决的技术问题是通过利用由着色树脂层的流动引起的着色树脂层的厚度逐渐降低的趋势，沿着上下方向逐渐改变预成型体着色树脂层的厚度 当将主树脂和着色树脂注入模具时，预成型模具内的主树脂。 本发明的目的是提供一种双轴拉伸吹塑成型的瓶子，其具有新的装饰性，其中在该瓶子的主体中产生与颜色密度相关的复杂色彩等级。 实现该目的的手段包括调整包括主树脂和着色树脂的供应开始和结束的时间以及压力或速度分布的时间，减少多层熔融树脂中着色树脂层的厚度 流体在流动的上游或下游点逐渐流动，注射成型预成型件，其中已经形成与着色树脂层的厚度相关联的颜色渐变部分，并将该预成型件双轴拉伸和吹塑成具有 与在瓶体上产生的颜色密度或颜色相关联的颜色渐变部分。

公开(公告)号：US09393725B2

公开(公告)日：2016-07-19

申请号：US14084327

申请日：2013-11-19

申请人： Minoru Abe ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

发明人： Minoru Abe ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

IPC分类号： B29C45/16 ,  B29B11/14 ,  B29C49/22 ,  B65D1/02 ,  B65D23/02 ,  B29B11/08 ,  B29C49/06 ,  B29K23/00 ,  B29K67/00 ,  B29K77/00 ,  B29K105/00 ,  B29L31/00

CPC分类号： B29B11/08 ,  B29B11/14 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/1404 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/14093 ,  B29B2911/141 ,  B29B2911/1412 ,  B29B2911/14146 ,  B29B2911/14326 ,  B29B2911/1433 ,  B29B2911/14331 ,  B29B2911/14333 ,  B29B2911/14336 ,  B29B2911/14337 ,  B29B2911/1444 ,  B29B2911/14466 ,  B29B2911/14633 ,  B29B2911/14646 ,  B29B2911/14713 ,  B29B2911/14753 ,  B29B2911/14766 ,  B29C45/1642 ,  B29C45/1646 ,  B29C49/06 ,  B29C49/221 ,  B29C2045/1698 ,  B29K2023/12 ,  B29K2067/00 ,  B29K2067/003 ,  B29K2077/00 ,  B29K2105/0032 ,  B29K2105/253 ,  B29K2105/258 ,  B29K2995/0026 ,  B29K2995/0067 ,  B29L2031/7158 ,  B65D1/0215 ,  B65D23/02 ,  Y10T428/1352 ,  Y10T428/139

摘要： The technical problem to be solved is to change the thickness of the colored resin layer of the preform gradually in the upward or downward direction, by utilizing a tendency of gradual decrease in the thickness of the colored resin layer caused by the flow of the main resin inside the preform mold when the main resin and the colored resin are injected into the mold. This involves adjusting the injection pattern including the time of starting and ending the supply of the main resin and the colored resin, and pressure or velocity profiles, reducing the thickness of the colored resin layer gradually upstream or downstream, injection-molding the preform in which a color-gradated portion associated with the thickness of the colored resin layer has been formed, and biaxially drawing and blow molding this preform into a bottle having a color-gradated portion.

公开(公告)号：US08800794B2

公开(公告)日：2014-08-12

申请号：US12153569

申请日：2008-05-21

申请人： Daisuke Uesugi ,  Akio Hashimoto ,  Masato Suzuki ,  Hiromi Shimura

发明人： Daisuke Uesugi ,  Akio Hashimoto ,  Masato Suzuki ,  Hiromi Shimura

IPC分类号： A47J41/02

CPC分类号： B29C49/0073 ,  B29B2911/1402 ,  B29B2911/1404 ,  B29B2911/14073 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/1412 ,  B29B2911/14126 ,  B29B2911/14146 ,  B29B2911/14326 ,  B29B2911/14328 ,  B29B2911/1433 ,  B29B2911/14331 ,  B29B2911/14332 ,  B29B2911/14333 ,  B29B2911/14335 ,  B29B2911/14336 ,  B29B2911/14337 ,  B29B2911/1444 ,  B29B2911/14466 ,  B29B2911/14646 ,  B29B2911/14713 ,  B29C49/06 ,  B29C49/221 ,  B29C2049/225 ,  B29K2067/00 ,  B29K2995/0067 ,  B65D1/0215 ,  B65D1/023 ,  B65D2501/0036 ,  B65D2501/0081 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1393

摘要： A biaxially drawn, blow-molded bottle and its preform comprise at least a layer of a gas barrier material laminated inside the PET resin layers, a functional portion having a screw thread raised spirally in the upper portion of neck and also having a stop ring disposed under the screw thread, and a neck ring disposed at the lower end of the neck. In these preform and bottle, the leading edge of the gas barrier layer is positioned at a half height of the neck ring where the most advanced front of the leading edge neither reaches a half height of the stop ring nor extends to the functional portion. It is intended here that the neck would not be affected by the shrinking deformation caused by the existence of the gas barrier layer in the functional portion of the neck, which is treated for thermal crystallization.

摘要翻译： 双轴拉伸吹塑成型的瓶子及其预制件至少包含层压在PET树脂层内的气体阻隔材料层，功能部分具有在颈部的上部中螺旋地螺旋形地设置的螺纹，并且还设置有止动环， 在螺纹下方，颈圈设置在颈部的下端。 在这些预成型件和瓶子中，阻气层的前缘位于颈环的一半高度处，其中前缘的最先进的前部既不达到止动环的一半高度也不延伸到功能部分。 这里的目的在于，颈部不会受到在颈部的功能部分中存在阻气层而引起的收缩变形的影响，这被处理为热结晶。

公开(公告)号：US08518504B2

公开(公告)日：2013-08-27

申请号：US13485362

申请日：2012-05-31

申请人： Minoru Abe ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

发明人： Minoru Abe ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

IPC分类号： B32B1/02 ,  B65D1/02 ,  B29C69/00 ,  B29C39/12 ,  B29C45/00

CPC分类号： B29B11/08 ,  B29B11/14 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/1404 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/14093 ,  B29B2911/141 ,  B29B2911/1412 ,  B29B2911/14146 ,  B29B2911/14326 ,  B29B2911/1433 ,  B29B2911/14331 ,  B29B2911/14333 ,  B29B2911/14336 ,  B29B2911/14337 ,  B29B2911/1444 ,  B29B2911/14466 ,  B29B2911/14633 ,  B29B2911/14646 ,  B29B2911/14713 ,  B29B2911/14753 ,  B29B2911/14766 ,  B29C45/1642 ,  B29C45/1646 ,  B29C49/06 ,  B29C49/221 ,  B29C2045/1698 ,  B29K2023/12 ,  B29K2067/00 ,  B29K2067/003 ,  B29K2077/00 ,  B29K2105/0032 ,  B29K2105/253 ,  B29K2105/258 ,  B29K2995/0026 ,  B29K2995/0067 ,  B29L2031/7158 ,  B65D1/0215 ,  B65D23/02 ,  Y10T428/1352 ,  Y10T428/139

摘要： The technical problem to be solved is to change the thickness of the colored resin layer of the preform gradually in the upward or downward direction, by utilizing a tendency of gradual decrease in the thickness of the colored resin layer caused by the flow of the main resin inside the preform mold when the main resin and the colored resin are injected into the mold. This involves adjusting the injection pattern including the time of starting and ending the supply of the main resin and the colored resin, and pressure or velocity profiles, reducing the thickness of the colored resin layer gradually upstream or downstream, injection-molding the preform in which a color-gradated portion associated with the thickness of the colored resin layer has been formed, and biaxially drawing and blow molding this preform into a bottle having a color-gradated portion.

摘要翻译： 要解决的技术问题是通过利用由主树脂的流动引起的着色树脂层的厚度逐渐降低的趋势，在上下方向上逐渐改变预成型体着色树脂层的厚度 当主树脂和着色树脂注入模具时，在预成型模具内部。 这包括调整包括主树脂和着色树脂的供应开始和结束的时间，以及压力或速度分布的时间，逐渐上下游着色树脂层的厚度，注塑成型预成型件，其中 已经形成了与着色树脂层的厚度相关联的颜色渐变部分，并且将该预成型件双轴拉伸和吹塑成具有渐变部分的瓶子。

公开(公告)号：US20110115122A1

公开(公告)日：2011-05-19

申请号：US12977285

申请日：2010-12-23

申请人： Minoru ABE ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

发明人： Minoru ABE ,  Tetsuo Takahashi ,  Masato Suzuki ,  Hiromi Shimura ,  Junichi Chiba

IPC分类号： B29C45/16

CPC分类号： B29B11/08 ,  B29B11/14 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/1404 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/14093 ,  B29B2911/141 ,  B29B2911/1412 ,  B29B2911/14146 ,  B29B2911/14326 ,  B29B2911/1433 ,  B29B2911/14331 ,  B29B2911/14333 ,  B29B2911/14336 ,  B29B2911/14337 ,  B29B2911/1444 ,  B29B2911/14466 ,  B29B2911/14633 ,  B29B2911/14646 ,  B29B2911/14713 ,  B29B2911/14753 ,  B29B2911/14766 ,  B29C45/1642 ,  B29C45/1646 ,  B29C49/06 ,  B29C49/221 ,  B29C2045/1698 ,  B29K2023/12 ,  B29K2067/00 ,  B29K2067/003 ,  B29K2077/00 ,  B29K2105/0032 ,  B29K2105/253 ,  B29K2105/258 ,  B29K2995/0026 ,  B29K2995/0067 ,  B29L2031/7158 ,  B65D1/0215 ,  B65D23/02 ,  Y10T428/1352 ,  Y10T428/139

摘要： The technical problem to be solved by the invention is to change the thickness of the colored resin layer of the preform gradually in the upward or downward direction, by utilizing a tendency of gradual decrease in the thickness of the colored resin layer caused by the flow of the main resin inside the preform mold when the main resin and the colored resin are injected into the mold. The objects of this invention is to provide a biaxially drawn, blow molded bottle having new decorativeness created in which sophisticated color gradations associated with color density are created in the body of this bottle. The means of accomplishing this object involves adjusting the injection pattern including the time of starting and ending the supply of the main resin and the colored resin, and pressure or velocity profiles, reducing the thickness of the colored resin layer in the multi-layered molten resin fluid gradually at an upstream or downstream point of the flow, injection-molding the preform in which a color-gradated portion associated with the thickness of the colored resin layer has been formed, and biaxially drawing and blow molding this preform into a bottle having a color-gradated portion associated with the color density or color shade created on the body of the bottle.

摘要翻译： 本发明要解决的技术问题是通过利用由着色树脂层的流动引起的着色树脂层的厚度逐渐降低的趋势，沿着上下方向逐渐改变预成型体着色树脂层的厚度 当将主树脂和着色树脂注入模具时，预成型模具内的主树脂。 本发明的目的是提供一种双轴拉伸吹塑成型的瓶子，其具有新的装饰性，其中在该瓶子的主体中产生与颜色密度相关的复杂色彩等级。 实现该目的的手段包括调整包括主树脂和着色树脂的供应开始和结束的时间以及压力或速度分布的时间，减少多层熔融树脂中着色树脂层的厚度 流体在流动的上游或下游点逐渐流动，注射成型预成型件，其中已经形成与着色树脂层的厚度相关联的颜色渐变部分，并将该预成型件双轴拉伸和吹塑成具有 与在瓶体上产生的颜色密度或颜色相关联的颜色渐变部分。

公开(公告)号：US20080251488A1

公开(公告)日：2008-10-16

申请号：US12153569

申请日：2008-05-21

申请人： Daisuke Uesugi ,  Akio Hashimoto ,  Masato Suzuki ,  Hiromi Shimura

发明人： Daisuke Uesugi ,  Akio Hashimoto ,  Masato Suzuki ,  Hiromi Shimura

IPC分类号： B65D23/02

CPC分类号： B29C49/0073 ,  B29B2911/1402 ,  B29B2911/1404 ,  B29B2911/14073 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/1412 ,  B29B2911/14126 ,  B29B2911/14146 ,  B29B2911/14326 ,  B29B2911/14328 ,  B29B2911/1433 ,  B29B2911/14331 ,  B29B2911/14332 ,  B29B2911/14333 ,  B29B2911/14335 ,  B29B2911/14336 ,  B29B2911/14337 ,  B29B2911/1444 ,  B29B2911/14466 ,  B29B2911/14646 ,  B29B2911/14713 ,  B29C49/06 ,  B29C49/221 ,  B29C2049/225 ,  B29K2067/00 ,  B29K2995/0067 ,  B65D1/0215 ,  B65D1/023 ,  B65D2501/0036 ,  B65D2501/0081 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1393

摘要： A biaxially drawn, blow-molded bottle and its preform comprise at least a layer of a gas barrier material laminated inside the PET resin layers, a functional portion having a screw thread raised spirally in the upper portion of neck and also having a stop ring disposed under the screw thread, and a neck ring disposed at the lower end of the neck. In these preform and bottle, the leading edge of the gas barrier layer is positioned at a half height of the neck ring where the most advanced front of the leading edge neither reaches a half height of the stop ring nor extends to the functional portion. It is intended here that the neck would not be affected by the shrinking deformation caused by the existence of the gas barrier layer in the functional portion of the neck, which is treated for thermal crystallization.

摘要翻译： 双轴拉伸吹塑成型的瓶子及其预制件至少包含层压在PET树脂层内的气体阻隔材料层，功能部分具有在颈部的上部中螺旋地螺旋形地设置的螺纹，并且还设置有止动环， 在螺纹下方，颈圈设置在颈部的下端。 在这些预成型件和瓶子中，阻气层的前缘位于颈环的一半高度处，其中前缘的最先进的前部既不达到止动环的一半高度也不延伸到功能部分。 这里的目的在于，颈部不会受到在颈部的功能部分中存在阻气层而引起的收缩变形的影响，这被处理为热结晶。