摘要:
A proton-conducting polymer composition which contains an aromatic hydrocarbon type of proton-conducting polymer in an amount of 1 to 30 mass %, wherein a component of said proton-conducting polymer having a molecular weight in the range of 2,000 to 230,000 in terms of polyethylene glycol accounts for 10 mass % or more of the total amount of said proton-conducting polymer; a method for preparing the proton-conducting polymer composition, a catalyst ink comprising the proton-conducting polymer composition and a fuel cell including the catalyst ink. The above proton-conducting polymer composition can well exploit the performance capability of a catalyst of a fuel cell, especially when it is allowed to be present with the electrode of a fuel cell.
摘要:
The present invention relates to a sulfonic acid group-containing polymer excellent in ion conductivity and durability, a method for producing the same, a resin composition containing the sulfonic acid group-containing polymer, a polymer electrolyte membrane, a polymer electrolyte membrane/electrode assembly, and a fuel cell. The sulfonic acid group-containing polymer of the present invention, in a first embodiment, includes a constituent represented by the following chemical formula 1: wherein X represents hydrogen or a monovalent cation species; Y represents a sulfone group or a ketone group; and n represents an arbitrary integer not less than 2.
摘要:
Disclosed is an electrolyte membrane-electrode assembly wherein a hydrocarbon-based solid polymer electrolyte membrane is sandwiched between a pair of electrodes. In this electrolyte membrane-electrode assembly, the glass transition temperature of the electrolyte membrane in a dry state is not less than 160° C. and the maximum moisture content of the electrolyte membrane is 10-120%. By using such a hydrocarbon-based solid polymer electrolyte membrane, there can be obtained an electrolyte membrane-electrode assembly which is excellent in reliability and durability. Also disclosed are a fuel cell using such an electrolyte membrane-electrode assembly and a method for producing such an electrolyte membrane-electrode assembly.
摘要:
A polyarylene ether-based compound according to the present invention includes polymer components represented in general formula (1) and general formula (2): wherein Ar indicates a divalent aromatic group, Y indicates a sulfone group or a ketone group, X indicates H or a monovalent cation species, and Ar′ indicates a divalent aromatic group.
摘要:
The present invention relates to a sulfonic acid group-containing polymer excellent in ion conductivity and durability, a method for producing the same, a resin composition containing the sulfonic acid group-containing polymer, a polymer electrolyte membrane, a polymer electrolyte membrane/electrode assembly, and a fuel cell. The sulfonic acid group-containing polymer of the present invention, in a first embodiment, includes a constituent represented by the following chemical formula 1: wherein X represents hydrogen or a monovalent cation species; Y represents a sulfone group or a ketone group; and n represents an arbitrary integer not less than 2.
摘要:
A proton exchange membrane is obtained which can give an excellent power generation characteristic when the membrane is applied to, in particular, a fuel cell wherein high-concentration methanol is used as a fuel. In the aromatic hydrocarbon based proton exchange membrane of the invention, the ion exchange capacity is set into the range of 0.6 to 1.3 meq/g. Moreover, the area swelling rate for a 30% by mass methanol aqueous solution at 40° C. is set into the range of 2 to 30%. Preferably, a sulfonic acid group is bonded to an aromatic ring of the aromatic hydrocarbon based polymer contained in the aromatic hydrocarbon based proton exchange film. Preferably, the aromatic hydrocarbon based polymer is a polyarylene ether based polymer.
摘要:
A proton-conducting polymer composition which contains an aromatic hydrocarbon type of proton-conducting polymer in an amount of 1 to 30 mass %, wherein a component of said proton-conducting polymer having a molecular weight in the range of 2,000 to 230,000 in terms of polyethylene glycol accounts for 10 mass % or more of the total amount of said proton-conducting polymer; a method for preparing the proton-conducting polymer composition, a catalyst ink comprising the proton-conducting polymer composition and a fuel cell including the catalyst ink. The above proton-conducting polymer composition can well exploit the performance capability of a catalyst of a fuel cell, especially when it is allowed to be present with the electrode of a fuel cell.
摘要:
A polyarylene ether-based compound according to the present invention includes polymer components represented in general formula (1) and general formula (2): wherein Ar indicates a divalent aromatic group, Y indicates a sulfone group or a ketone group, X indicates H or a monovalent cation species, and Ar′ indicates a divalent aromatic group.
摘要:
The present invention provides a composite ion exchange membrane which has high mechanical strength and is suitable for use as a solid polymer electrolyte membrane excellent in ionic conductivity and a method for its production. The invention is achieved by a composite ion exchange membrane including a composite layer comprising a support membrane with continuous voids formed of polybenzazole polymer, the support membrane being impregnated with ion exchange resin, and surface layers formed of ion exchange resin free of support membranes, the surface layers being formed on both surfaces of the composite layer so as to sandwich the composite layer therebetween.
摘要:
The present invention provides a composite ion exchange membrane which has high mechanical strength and is suitable for use as a solid polymer electrolyte membrane excellent in ionic conductivity and a method for its production. The invention is achieved by a composite ion exchange membrane including a composite layer comprising a support membrane with continuous voids formed of polybenzazole polymer, the support membrane being impregnated with ion exchange resin, and surface layers formed of ion exchange resin free of support membranes, the surface layers being formed on both surfaces of the composite layer so as to sandwich the composite layer therebetween.