Carbon electrode material for a vanadium-based redox-flow battery
    1.
    发明授权
    Carbon electrode material for a vanadium-based redox-flow battery 有权
    用于钒基氧化还原液电池的碳电极材料

    公开(公告)号:US06509119B1

    公开(公告)日:2003-01-21

    申请号:US09590629

    申请日:2000-06-08

    IPC分类号: H01M458

    摘要: The carbon electrode material of the present invention is used for a vanadium redox-flow cell. The carbon electrode material has quasi-graphite crystal structure in which spacing obtained by X-ray wide angle analysis is 3.43 to 3.60 Å, size of a crystallite in c axial direction is 15 to 33 Å and size of crystallite in a axial direction is 30 to 70 Å. In addition, an amount of surface acidic functional groups obtained by XPS surface analysis is 0.1 to 1.2% and total number of surface bound-nitrogen atoms is 5% or smaller relative to total number of surface carbon atoms. The carbon electrode materials formed of a non-woven fabric of a carbonaceouss fiber is preferable.

    摘要翻译: 本发明的碳电极材料用于钒氧化还原液流通池。 碳电极材料具有准石墨晶体结构,其中通过X射线广角分析获得的间距为3.43〜3.60,c轴方向的微晶尺寸为15〜33,轴向尺寸为微晶 方向为30〜70。 此外,通过XPS表面分析获得的表面酸性官能团的量相对于表面碳原子总数为0.1〜1.2%,表面结合氮原子的总数为5%以下。 由碳素纤维的无纺布形成的碳电极材料是优选的。

    Video camera apparatus
    5.
    发明授权
    Video camera apparatus 失效
    摄像机

    公开(公告)号:US5502483A

    公开(公告)日:1996-03-26

    申请号:US171005

    申请日:1993-12-21

    IPC分类号: H04N5/232 H04N5/228 H04N7/01

    摘要: The present invention relates to a video camera apparatus which can automatically correct an image vibration, such as a handling or the like electronically. A control circuit changes an interpolation coefficient .alpha. of an interpolation processing circuit in response to a detected output from a vibration detecting apparatus or an output from a motion vector calculating apparatus that detects a vibration of a video signal. Also, the control circuit controls a scanning pulse generating circuit that derives a scanning pulse for scanning the imager. The scanning pulse generating circuit changes a combination of two scanning lines that are to be interpolated by the interpolation processing circuit using the interpolation coefficient .alpha. by changing the scanning state of the imager when 0.ltoreq..alpha.

    摘要翻译: 本发明涉及一种能够以电子方式自动校正诸如处理等的图像振动的摄像机装置。 控制电路响应于来自振动检测装置的检测到的输出或检测视频信号的振动的运动矢量计算装置的输出,改变内插处理电路的内插系数α。 此外,控制电路控制导出用于扫描成像器的扫描脉冲的扫描脉冲发生电路。 当0≤α

    Proton conducting polymer membrane, method for production thereof and fuel cell therewith
    6.
    发明授权
    Proton conducting polymer membrane, method for production thereof and fuel cell therewith 失效
    质子导电聚合物膜,其制造方法和燃料电池

    公开(公告)号:US08557472B2

    公开(公告)日:2013-10-15

    申请号:US11921455

    申请日:2006-05-31

    IPC分类号: H01M8/10

    摘要: There are provided a novel proton-conducting polymer membrane that shows good workability in a fuel cell assembling process and good proton conductivity and durability even under high-temperature, non-humidified conditions, a method for production thereof, and a fuel cell therewith. The proton-conducting polymer membrane includes: a polymer membrane containing a polybenzimidazole compound having a sulfonic acid group and/or a phosphonic acid group; and vinylphosphonic acid contained in the polymer membrane. The fuel cell uses the proton-conducting polymer membrane. The polybenzimidazole compound preferably includes a sulfonic and/or phosphonic acid group-containing component represented by Structural Formula (1): wherein n represents an integer of 1 to 4, R1 represents a tetravalent aromatic linking unit capable of forming an imidazole ring, R2 represents a bivalent aromatic linking unit, and Z represents a sulfonic acid group and/or a phosphonic acid group.

    摘要翻译: 提供了一种新颖的质子传导性聚合物膜,即使在高温非加湿条件下也能够在燃料电池组装工艺中具有良好的加工性,并且具有良好的质子传导性和耐久性,其制造方法和燃料电池。 质子传导性聚合物膜包括:含有具有磺酸基和/或膦酸基的聚苯并咪唑化合物的聚合物膜; 和聚合物膜中所含的乙烯基膦酸。 燃料电池使用质子传导聚合物膜。 聚苯并咪唑化合物优选包括由结构式(1)表示的含有磺酸和/或膦酸基的组分:其中n表示1至4的整数,R 1表示能够形成咪唑环的四价芳族连接单元,R 2表示 二价芳香族连接单元,Z表示磺酸基和/或膦酸基。

    Proton Conducting Polymer membrane, Method for Production Thereof and Fuel Cell Therewith
    7.
    发明申请
    Proton Conducting Polymer membrane, Method for Production Thereof and Fuel Cell Therewith 失效
    质子传导聚合物膜,其生产方法和燃料电池

    公开(公告)号:US20090136818A1

    公开(公告)日:2009-05-28

    申请号:US11921455

    申请日:2006-05-31

    IPC分类号: H01M8/10 H01M8/02 C08J5/22

    摘要: There are provided a novel proton-conducting polymer membrane that shows good workability in a fuel cell assembling process and good proton conductivity and durability even under high-temperature, non-humidified conditions, a method for production thereof, and a fuel cell therewith. The proton-conducting polymer membrane includes: a polymer membrane containing a polybenzimidazole compound having a sulfonic acid group and/or a phosphonic acid group; and vinylphosphonic acid contained in the polymer membrane. The fuel cell uses the proton-conducting polymer membrane. The polybenzimidazole compound preferably includes a sulfonic and/or phosphonic acid group-containing component represented by Structural Formula (1): wherein n represents an integer of 1 to 4, R1 represents a tetravalent aromatic linking unit capable of forming an imidazole ring, R2 represents a bivalent aromatic linking unit, and Z represents a sulfonic acid group and/or a phosphonic acid group.

    摘要翻译: 提供了一种新颖的质子传导性聚合物膜,即使在高温,非加湿条件下,燃料电池组装工艺中的加工性能也良好,甚至具有良好的质子传导性和耐久性,其制造方法和燃料电池。 质子传导性聚合物膜包括:含有具有磺酸基和/或膦酸基的聚苯并咪唑化合物的聚合物膜; 和聚合物膜中所含的乙烯基膦酸。 燃料电池使用质子传导聚合物膜。 聚苯并咪唑化合物优选包括由结构式(1)表示的含有磺酸和/或膦酸基的组分:其中n表示1至4的整数,R 1表示能够形成咪唑环的四价芳族连接单元,R 2表示 二价芳香族连接单元,Z表示磺酸基和/或膦酸基。

    Electrolyte Membrane-Electrode Assembly, Fuel Cell Using The Same, And Method For Producing Electrolyte Membrane-Electrode Assembly
    9.
    发明申请
    Electrolyte Membrane-Electrode Assembly, Fuel Cell Using The Same, And Method For Producing Electrolyte Membrane-Electrode Assembly 审中-公开
    电解质膜电极组件,使用其的燃料电池,以及用于制造电解质膜 - 电极组件的方法

    公开(公告)号:US20080063917A1

    公开(公告)日:2008-03-13

    申请号:US10566218

    申请日:2004-07-29

    IPC分类号: H01M8/10 B29C65/02

    摘要: Disclosed is an electrolyte membrane-electrode assembly wherein a hydrocarbon-based solid polymer electrolyte membrane is sandwiched between a pair of electrodes. In this electrolyte membrane-electrode assembly, the glass transition temperature of the electrolyte membrane in a dry state is not less than 160° C. and the maximum moisture content of the electrolyte membrane is 10-120%. By using such a hydrocarbon-based solid polymer electrolyte membrane, there can be obtained an electrolyte membrane-electrode assembly which is excellent in reliability and durability. Also disclosed are a fuel cell using such an electrolyte membrane-electrode assembly and a method for producing such an electrolyte membrane-electrode assembly.

    摘要翻译: 公开了一种电解质膜 - 电极组件,其中烃基固体聚合物电解质膜夹在一对电极之间。 在该电解质膜 - 电极组件中,干燥状态的电解质膜的玻璃化转变温度为160℃以上,电解质膜的最高含水量为10〜120%。 通过使用这种烃基固体高分子电解质膜,可以获得可靠性和耐久性优异的电解质膜 - 电极组件。 还公开了使用这种电解质膜 - 电极组件的燃料电池和这种电解质膜 - 电极组件的制造方法。

    Composite ion-exchange membrane
    10.
    发明授权
    Composite ion-exchange membrane 失效
    复合离子交换膜

    公开(公告)号:US07649025B2

    公开(公告)日:2010-01-19

    申请号:US10530965

    申请日:2003-10-16

    IPC分类号: C08J5/20 H01M4/00 H01M8/08

    摘要: A composite ion exchange membrane having a high swelling resistance and being superior in mechanical strength and ion conductivity can be provided by means of an composite ion exchange membrane including an ion exchange resin composition and a support membrane having a continuous pore penetrating the support membrane, wherein the support membrane is one which accepts the ion exchange resin composition within the pore, and wherein the ion exchange resin composition is one which contains an ion exchange resin containing, as a main component, an aromatic polyether and/or its derivative, the aromatic polyether being obtained by mixing a compound having a specific structure, an aromatic dihalogenated compound and a bisphenol compound with a carbonate and/or a bicarbonate of an alkali metal and polymerizing the mixture in an organic solvent.

    摘要翻译: 具有高抗溶胀性和机械强度和离子传导性优异的复合离子交换膜可以通过包括离子交换树脂组合物的复合离子交换膜和穿透支撑膜的连续孔的支撑膜来提供,其中 支撑膜是在孔内接受离子交换树脂组合物的离子交换树脂组合物,其中离子交换树脂组合物是含有作为主要成分的芳族聚醚和/或其衍生物的离子交换树脂, 通过将具有特定结构的化合物,芳族二卤化合物和双酚化合物与碱金属的碳酸盐和/或碳酸氢盐混合并将该混合物在有机溶剂中聚合而获得。