公开(公告)号：US20080210907A1

公开(公告)日：2008-09-04

申请号：US11883462

申请日：2006-01-30

申请人： Masaru Yoshida ,  Nagatoshi Koumura ,  Nobuyuki Tamaoki ,  Hajime Kawanami ,  Hajime Matsumoto ,  Said Kazaoui ,  Nobutsugu Minami

发明人： Masaru Yoshida ,  Nagatoshi Koumura ,  Nobuyuki Tamaoki ,  Hajime Kawanami ,  Hajime Matsumoto ,  Said Kazaoui ,  Nobutsugu Minami

IPC分类号： C09K11/65 ,  C07D211/56 ,  C07D217/00 ,  C07D401/04 ,  C07D211/84 ,  C07D265/30 ,  C07D207/08 ,  C07D241/02 ,  C07D251/02 ,  C07D233/54 ,  C07D241/36 ,  C09D1/00

CPC分类号： H01B1/122 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/28 ,  C07D213/75 ,  Y02P20/542

摘要： An ionic organic compound having a repeating unit of formula (I) can be synthesized easily from a readily available organic compound through a small number of reaction steps, can be produced without any purification technique such as chromatography, and can be used in a quite small amount for gelation of water or an ionic liquid without any other auxiliary solvent: [-(A-B-C)n-]•m(X)   (I) wherein A represents a group having a quaternary ammonium cation which is formed from a heterocyclic compound having at least one nitrogen atom; B represents a functional group, which may have a substituent, selected from amide, urea, urethane and peptide groups; C represents a divalent hydrocarbon group, which may have a substituent, capable of linking between A and B; X represents an anion; n represents the number of repeating units; m represents the total number of anions; and n and m are the same integer. A hydrogel using the compound is stable under acidic conditions, capable of setting a large amount of water with a small amount thereof, and capable of quickly recovering the original elastic modulus against structural disruption caused by mechanical distortion. The hydrogel is capable of directly gelling an ionic liquid without other solvent such as water when causing gelation. Further, the hydrogel is capable of easily dispersing carbon nanotubes in water whose load on the environment is low.

摘要翻译： 具有式（I）重复单元的离子有机化合物可以通过少量的反应步骤从容易获得的有机化合物容易地合成，可以在没有任何纯化技术如色谱法的情况下制备，并且可以用于相当小的 没有任何其他辅助溶剂的水或离子液体的凝胶化量：<？in-line-formula description =“In-line Formulas”end =“lead”？> [ - （ABC）n - ]。m（X）（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A表示具有季铵阳离子的基团，该季铵阳离子由杂环化合物形成， 至少一个氮原子; B表示可以具有选自酰胺，脲，氨基甲酸酯和肽基团的取代基的官能团; C表示能够连接A和B的可具有取代基的二价烃基; X表示阴离子; n表示重复单元的数量; m表示阴离子总数; 并且n和m是相同的整数。 使用该化合物的水凝胶在酸性条件下是稳定的，能够少量地设置大量的水，并且能够快速恢复原始的弹性模量，抵抗由机械变形引起的结构破坏。 当凝胶化时，水凝胶能够直接凝胶化没有其它溶剂如水的离子液体。 此外，水凝胶能够容易地将碳纳米管分散在环境负荷低的水中。

公开(公告)号：US07858799B2

公开(公告)日：2010-12-28

申请号：US11883462

申请日：2006-01-30

申请人： Masaru Yoshida ,  Nagatoshi Koumura ,  Nobuyuki Tamaoki ,  Hajime Kawanami ,  Hajime Matsumoto ,  Said Kazaoui ,  Nobutsugu Minami

发明人： Masaru Yoshida ,  Nagatoshi Koumura ,  Nobuyuki Tamaoki ,  Hajime Kawanami ,  Hajime Matsumoto ,  Said Kazaoui ,  Nobutsugu Minami

IPC分类号： C07D211/84 ,  C07D401/04 ,  C09K11/65

CPC分类号： H01B1/122 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/28 ,  C07D213/75 ,  Y02P20/542

摘要： An ionic organic compound having a repeating unit of formula (I) can be synthesized easily from a readily available organic compound through a small number of reaction steps, can be produced without any purification technique such as chromatography, and can be used in a quite small amount for gelation of water or an ionic liquid without any other auxiliary solvent: [-(A-B-C)n-]•m(X)  (I) wherein A represents a group having a quaternary ammonium cation which is formed from a heterocyclic compound having at least one nitrogen atom; B represents a functional group, which may have a substituent, selected from amide, urea, urethane and peptide groups; C represents a divalent hydrocarbon group, which may have a substituent, capable of linking between A and B; X represents an anion; n represents the number of repeating units; m represents the total number of anions; and n and m are the same integer. A hydrogel using the compound is stable under acidic conditions, capable of setting a large amount of water with a small amount thereof, and capable of quickly recovering the original elastic modulus against structural disruption caused by mechanical distortion. The hydrogel is capable of directly gelling an ionic liquid without other solvent such as water when causing gelation. Further, the hydrogel is capable of easily dispersing carbon nanotubes in water whose load on the environment is low.

摘要翻译： 具有式（I）重复单元的离子有机化合物可以通过少量的反应步骤从容易获得的有机化合物容易地合成，可以在没有任何纯化技术如色谱法的情况下制备，并且可以用于相当小的 不含任何其他辅助溶剂的水或离子液体的凝胶化量：[ - （ABC）n-]•m（X）（I）其中A表示具有季铵阳离子的基团，该季铵阳离子由杂环化合物形成， 至少一个氮原子; B表示可以具有选自酰胺，脲，氨基甲酸酯和肽基团的取代基的官能团; C表示能够连接A和B的可具有取代基的二价烃基; X表示阴离子; n表示重复单元的数量; m表示阴离子总数; 并且n和m是相同的整数。 使用该化合物的水凝胶在酸性条件下是稳定的，能够少量地设置大量的水，并且能够快速恢复原始的弹性模量，抵抗由机械变形引起的结构破坏。 当凝胶化时，水凝胶能够直接凝胶化没有其它溶剂如水的离子液体。 此外，水凝胶能够容易地将碳纳米管分散在环境负荷低的水中。

公开(公告)号：US08013241B2

公开(公告)日：2011-09-06

申请号：US12091295

申请日：2006-10-16

申请人： Nagatoshi Koumura ,  Koujirou Hara ,  Zhong-Sheng Wang ,  Masaru Yoshida ,  Nobuyuki Tamaoki

发明人： Nagatoshi Koumura ,  Koujirou Hara ,  Zhong-Sheng Wang ,  Masaru Yoshida ,  Nobuyuki Tamaoki

IPC分类号： H01L31/00 ,  C07D213/04 ,  C07D295/18 ,  C07D233/00

CPC分类号： H01B1/122 ,  H01G9/2009 ,  H01G9/2031 ,  H01L51/0086 ,  H01M14/005 ,  H01M2300/0085 ,  Y02E10/542

摘要： Disclosed is a novel ionic liquid gel electrolyte having high photoelectric conversion efficiency. Also disclosed are a novel dye-sensitized photoelectric conversion device using such an ionic liquid gel electrolyte, and a solar cell composed of such a dye-sensitized photoelectric conversion device. Specifically disclosed is an ionic liquid gel electrolyte obtained by gelling a liquid electrolyte by using an ionic organic oligomer gelling agent represented by the general formulae (1) and (2) below. Also specifically disclosed are a dye-sensitized photoelectric conversion device, wherein the ionic liquid gel electrolyte is arranged between a counter electrode and a dye-absorbed semiconductor substrate which is arranged in contact with a transparent conductive substrate, and a solar cell.

摘要翻译： 公开了一种具有高光电转换效率的新型离子液体凝胶电解质。 还公开了使用这种离子液体凝胶电解质的新型染料敏化光电转换装置和由这种染料敏化光电转换装置构成的太阳能电池。 具体公开了通过使用下述通式（1）和（2）表示的离子型有机低聚物胶凝剂使液体电解质胶凝而获得的离子液体凝胶电解质。 还公开了一种染料敏化光电转换装置，其中离子液体凝胶电解质被布置在与透明导电基板和太阳能电池接触布置的相对电极和被染料吸收的半导体基板之间。

公开(公告)号：US08519040B2

公开(公告)日：2013-08-27

申请号：US13062243

申请日：2009-09-07

申请人： Masaru Yoshida ,  Nagatoshi Koumura ,  Harumi Ohyama ,  Nobuyuki Tamaoki

发明人： Masaru Yoshida ,  Nagatoshi Koumura ,  Harumi Ohyama ,  Nobuyuki Tamaoki

IPC分类号： C08G69/00 ,  C08G73/02 ,  C08G73/06

CPC分类号： C08G73/0293 ,  C08J3/075 ,  C08J3/095 ,  C08J2377/10 ,  C08K7/24

摘要： Disclosed are a novel ionic organic compound and a method for producing the ionic organic compound by a simple process. Also disclosed are a hydrogelling agent composed of an ionic organic compound obtained by the method, an alcohol gelling agent, a gel which uses the gelling agent, while using water or methanol as a medium, and a carbon nanotube dispersant composed of the compound. Specifically disclosed is an ionic organic compound represented by general formula (1). The compound is obtained by a condensation reaction of (A) an aromatic diamide compound or cyclohexane diamide compound having a 4-(chloromethyl)benzamide group at both ends, and (B) a compound selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms. The thus-obtained ionic organic compound serves as a gelling agent which is capable of gelling a neutral aqueous solution or an alcohol. The solvent solubility can be changed by substituting the anion of the thus-obtained ionic compound with another anion by anion-exchange. (In the formula, A represents a linking moiety having one or more optionally substituted aromatic rings or a linking moiety composed of a cyclohexane ring; B represents a cationic functional group having a quaternized nitrogen atom, which is selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms; X represents a monovalent anion; and n represents an integer of 1-800.)

摘要翻译： 公开了一种新颖的离子有机化合物和通过简单的方法制备离子有机化合物的方法。 还公开了由使用该方法获得的离子有机化合物，醇胶凝剂，使用胶凝剂的凝胶，同时使用水或甲醇作为介质，以及由该化合物组成的碳纳米管分散剂组成的水凝胶剂。 具体公开的是由通式（1）表示的离子有机化合物。 该化合物通过（A）在两端具有4-（氯甲基）苯甲酰胺基的芳族二酰胺化合物或环己烷二酰胺化合物与（B）选自N，N，N'，N' 可以具有取代基的四甲基亚烷基二胺，其中氮原子之间有1-6个碳原子。 由此获得的离子有机化合物用作能够凝胶化中性水溶液或醇的胶凝剂。 溶剂的溶解度可以通过用阴离子交换用另外的阴离子代替由此得到的离子化合物的阴离子来改变。 （式中，A表示具有一个以上可以具有取代基的芳环或由环己烷环构成的连接部分的连接部分; B表示具有季铵化氮原子的阳离子官能团，其选自N，N，N' 可以具有取代基的N'-四甲基亚烷基二胺，其中氮原子之间具有1-6个碳原子; X表示一价阴离子; n表示1-800的整数。

公开(公告)号：US20110178218A1

公开(公告)日：2011-07-21

申请号：US13062243

申请日：2009-09-07

申请人： Masaru Yoshida ,  Nagatoshi Koumura ,  Harumi Ohyama ,  Nobuyuki Tamaoki

发明人： Masaru Yoshida ,  Nagatoshi Koumura ,  Harumi Ohyama ,  Nobuyuki Tamaoki

IPC分类号： C08L77/04 ,  C08G69/26 ,  C08G69/28 ,  C08K5/05 ,  B82Y30/00

CPC分类号： C08G73/0293 ,  C08J3/075 ,  C08J3/095 ,  C08J2377/10 ,  C08K7/24

摘要： Disclosed are a novel ionic organic compound and a method for producing the ionic organic compound by a simple process. Also disclosed are a hydrogelling agent composed of an ionic organic compound obtained by the method, an alcohol gelling agent, a gel which uses the gelling agent, while using water or methanol as a medium, and a carbon nanotube dispersant composed of the compound. Specifically disclosed is an ionic organic compound represented by general formula (1). The compound is obtained by a condensation reaction of (A) an aromatic diamide compound or cyclohexane diamide compound having a 4-(chloromethyl)benzamide group at both ends, and (B) a compound selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms. The thus-obtained ionic organic compound serves as a gelling agent which is capable of gelling a neutral aqueous solution or an alcohol. The solvent solubility can be changed by substituting the anion of the thus-obtained ionic compound with another anion by anion-exchange. (In the formula, A represents a linking moiety having one or more optionally substituted aromatic rings or a linking moiety composed of a cyclohexane ring; B represents a cationic functional group having a quaternized nitrogen atom, which is selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms; X represents a monovalent anion; and n represents an integer of 1-800.)

摘要翻译： 公开了一种新颖的离子有机化合物和通过简单的方法制备离子有机化合物的方法。 还公开了由使用该方法获得的离子有机化合物，醇胶凝剂，使用胶凝剂的凝胶，同时使用水或甲醇作为介质，以及由该化合物组成的碳纳米管分散剂组成的水凝胶剂。 具体公开的是由通式（1）表示的离子有机化合物。 该化合物通过（A）在两端具有4-（氯甲基）苯甲酰胺基的芳族二酰胺化合物或环己烷二酰胺化合物与（B）选自N，N，N'，N' 可以具有取代基的四甲基亚烷基二胺，其中氮原子之间有1-6个碳原子。 由此获得的离子有机化合物用作能够凝胶化中性水溶液或醇的胶凝剂。 溶剂的溶解度可以通过用阴离子交换用另外的阴离子代替由此得到的离子化合物的阴离子来改变。 （式中，A表示具有一个以上可以具有取代基的芳环或由环己烷环构成的连接部分的连接部分; B表示具有季铵化氮原子的阳离子官能团，其选自N，N，N' 可以具有取代基的N'-四甲基亚烷基二胺，其中氮原子之间具有1-6个碳原子; X表示一价阴离子; n表示1-800的整数。

公开(公告)号：US20090266419A1

公开(公告)日：2009-10-29

申请号：US12091295

申请日：2006-10-16

申请人： Nagatoshi Koumura ,  Koujirou Hara ,  Zhong-Sheng Wang ,  Masaru Yoshida ,  Nobuyuki Tamaoki

发明人： Nagatoshi Koumura ,  Koujirou Hara ,  Zhong-Sheng Wang ,  Masaru Yoshida ,  Nobuyuki Tamaoki

IPC分类号： H01L31/00 ,  H01G9/022

CPC分类号： H01B1/122 ,  H01G9/2009 ,  H01G9/2031 ,  H01L51/0086 ,  H01M14/005 ,  H01M2300/0085 ,  Y02E10/542

摘要： Disclosed is a novel ionic liquid gel electrolyte having high photoelectric conversion efficiency. Also disclosed are a novel dye-sensitized photoelectric conversion device using such an ionic liquid gel electrolyte, and a solar cell composed of such a dye-sensitized photoelectric conversion device. Specifically disclosed is an ionic liquid gel electrolyte obtained by gelling a liquid electrolyte by using an ionic organic oligomer gelling agent represented by the general formulae (1) and (2) below. Also specifically disclosed are a dye-sensitized photoelectric conversion device, wherein the ionic liquid gel electrolyte is arranged between a counter electrode and a dye-absorbed semiconductor substrate which is arranged in contact with a transparent conductive substrate, and a solar cell.

摘要翻译： 公开了一种具有高光电转换效率的新型离子液体凝胶电解质。 还公开了使用这种离子液体凝胶电解质的新型染料敏化光电转换装置和由这种染料敏化光电转换装置构成的太阳能电池。 具体公开了通过使用下述通式（1）和（2）表示的离子型有机低聚物胶凝剂使液体电解质胶凝而获得的离子液体凝胶电解质。 还公开了一种染料敏化光电转换装置，其中离子液体凝胶电解质被布置在与透明导电基板和太阳能电池接触布置的相对电极和被染料吸收的半导体基板之间。

公开(公告)号：US06183666B2

公开(公告)日：2001-02-06

申请号：US09363646

申请日：1999-07-30

申请人： Nobuyuki Tamaoki ,  Hiroo Matsuda ,  Yoshishige Kida

发明人： Nobuyuki Tamaoki ,  Hiroo Matsuda ,  Yoshishige Kida

IPC分类号： C09K1936

CPC分类号： G11B7/25 ,  B41M5/28 ,  B41M5/284 ,  C07J9/00 ,  C09K19/36 ,  G11B7/244 ,  G11B7/2531

摘要： A cholesteryl compound has formula (1), and a rewritable full-color thermosensitive recording material contains the above-mentioned cholesteryl compound of formula (1): YO—CO(CH2)n—A—(CH2)nCO—OY  (1) wherein A is a 1,5-hexadienylene group represented by the formula —C(R)═CHCH2CH2CH═C(R)-, in which R is a hydrogen atom or methyl group; Y is a cholesterol residue obtained by removing a hydroxyl group from cholesterol; and n is an integer of 5 to 7.

摘要翻译： 胆固醇基化合物具有式（1），可重写全色热敏记录材料含有上述式（1）的胆固醇基化合物：其中A是由式-C（R）表示的1,5-己二亚乙基， = CHCH 2 CH 2 CH = C（R） - ，其中R是氢原子或甲基; Y是通过从胆固醇中除去羟基获得的胆固醇残基; n为5〜7的整数。

公开(公告)号：US20100237327A1

公开(公告)日：2010-09-23

申请号：US12303751

申请日：2007-06-05

申请人： Masahiro Funahashi ,  Fuxapei Chan ,  Nobuyuki Tamaoki

发明人： Masahiro Funahashi ,  Fuxapei Chan ,  Nobuyuki Tamaoki

IPC分类号： H01L51/30 ,  H01L51/40 ,  C07D409/14

CPC分类号： H01L51/0076 ,  C09K19/3491 ,  H01L51/0068 ,  H01L51/5048

摘要： According to the present invention, a liquid crystal semiconductor capable of exhibiting a highly ordered smectic phase at approximately room temperature, being used for formation of a smectic liquid crystal thin film that is stable at room temperature by a solution process, and showing excellent ambipolar charge-transporting properties, a thin film transistor comprising the same, and the like are provided.Also, the following are provided: a smectic liquid crystal compound represented by the following general formula (1) wherein R1 represents a straight-chain alkyl group having 1 to 8 carbon atoms, R2 represents an alkyl or alkoxy group having 1 to 8 carbon atoms, and “n” is an integer of 0 to 3; an ambipolar charge-transporting material comprising the smectic liquid crystal compound; an organic semiconductor thin film having a thin film layer comprising the smectic liquid crystal compound; and a thin film transistor comprising the organic semiconductor thin film.

摘要翻译： 根据本发明，能够在大约室温下表现出高度顺序的近晶相的液晶半导体用于通过溶液法在室温下稳定的近晶液晶薄膜的形成，并且显示优异的双极电荷 - 输送性质，包含该薄膜晶体管的薄膜晶体管等。 另外，提供以下通式（1）表示的近晶型液晶化合物，其中R1表示碳原子数1〜8的直链烷基，R2表示碳原子数1〜8的烷基或烷氧基 ，“n”为0〜3的整数。 包含近晶液晶化合物的双极电荷输送材料; 具有由层状液晶性化合物构成的薄膜层的有机半导体薄膜; 以及包含有机半导体薄膜的薄膜晶体管。

公开(公告)号：US06537711B1

公开(公告)日：2003-03-25

申请号：US09669596

申请日：2000-09-26

申请人： Shigeaki Nimura ,  Hiroyuki Sugimoto ,  Nobuyuki Tamaoki ,  Hiroo Matsuda ,  Yoshishige Kida

发明人： Shigeaki Nimura ,  Hiroyuki Sugimoto ,  Nobuyuki Tamaoki ,  Hiroo Matsuda ,  Yoshishige Kida

IPC分类号： B41M526

CPC分类号： B41M5/28 ,  C09K19/36 ,  C09K19/50 ,  Y10S430/165

摘要： There is disclosed a reversible recording material having a liquid crystal mixture comprising at least two cholesteric liquid crystal compounds. The cholesteric liquid crystal compounds which are contained in the reversible recording material has a molecular weight of less than 2000 and a grass transition temperature equal to or more than 30° C. The two cholesteric liquid crystal compounds are compatible each other. After at least a part of the reversible recording material is heated to a temperature where the part of the reversible recording material becomes a cholesteric liquid crystal phase, the part of the reversible recording material is rapidly cooled down to below the glass transition temperature thereof, so that a reflecting color from the reversible recording material can be fixed to achieve a recording.

摘要翻译： 公开了具有包含至少两种胆甾型液晶化合物的液晶混合物的可逆记录材料。 包含在可逆记录材料中的胆甾型液晶化合物的分子量小于2000，草转变温度等于或大于30℃。两种胆甾型液晶化合物彼此相容。 在可逆记录材料的至少一部分被加热到可逆记录材料的一部分变为胆甾型液晶相的温度之后，可逆记录材料的一部分被快速冷却到其玻璃化转变温度以下，因此 来自可逆记录材料的反射颜色可以被固定以实现记录。

公开(公告)号：US06524759B1

公开(公告)日：2003-02-25

申请号：US09513083

申请日：2000-02-25

申请人： Hiroyuki Sugimoto ,  Shigeaki Nimura ,  Kyohji Tsutsui ,  Nobuyuki Tamaoki ,  Hiroo Matsuda

发明人： Hiroyuki Sugimoto ,  Shigeaki Nimura ,  Kyohji Tsutsui ,  Nobuyuki Tamaoki ,  Hiroo Matsuda

IPC分类号： G02F1133

CPC分类号： B41M5/46 ,  B41M5/281 ,  G02F1/132 ,  G02F1/133365 ,  G02F1/13718

摘要： A reversible recording medium has a support, a reversible light absorbing layer formed on the support, and, a reversible cholesteric reflection layer formed on the reversible light absorbing layer, containing a cholesteric liquid crystalline compound capable of assuming a cholesteric liquid crystalline phase reversibly showing iridescent colors by selective reflection. A method for reversibly recording an image in the above-mentioned recording medium, and a reversible recording apparatus using the above-mentioned recording medium are also disclosed.

摘要翻译： 可逆记录介质具有支撑体，形成在支撑体上的可逆光吸收层，以及形成在可逆光吸收层上的可逆胆甾型反射层，其包含胆甾型液晶化合物，其能够呈现可逆地显示虹彩色的胆甾型液晶相 颜色通过选择性反射。 还公开了一种用于在上述记录介质中可逆地记录图像的方法，以及使用上述记录介质的可逆记录装置。