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公开(公告)号：US20080210907A1
公开(公告)日：2008-09-04
申请号：US11883462
申请日：2006-01-30
申请人： Masaru Yoshida , Nagatoshi Koumura , Nobuyuki Tamaoki , Hajime Kawanami , Hajime Matsumoto , Said Kazaoui , Nobutsugu Minami
发明人： Masaru Yoshida , Nagatoshi Koumura , Nobuyuki Tamaoki , Hajime Kawanami , Hajime Matsumoto , Said Kazaoui , Nobutsugu Minami
IPC分类号： C09K11/65 , C07D211/56 , C07D217/00 , C07D401/04 , C07D211/84 , C07D265/30 , C07D207/08 , C07D241/02 , C07D251/02 , C07D233/54 , C07D241/36 , C09D1/00
CPC分类号： H01B1/122 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/28 , C07D213/75 , Y02P20/542
摘要： An ionic organic compound having a repeating unit of formula (I) can be synthesized easily from a readily available organic compound through a small number of reaction steps, can be produced without any purification technique such as chromatography, and can be used in a quite small amount for gelation of water or an ionic liquid without any other auxiliary solvent: [-(A-B-C)n-]•m(X) (I) wherein A represents a group having a quaternary ammonium cation which is formed from a heterocyclic compound having at least one nitrogen atom; B represents a functional group, which may have a substituent, selected from amide, urea, urethane and peptide groups; C represents a divalent hydrocarbon group, which may have a substituent, capable of linking between A and B; X represents an anion; n represents the number of repeating units; m represents the total number of anions; and n and m are the same integer. A hydrogel using the compound is stable under acidic conditions, capable of setting a large amount of water with a small amount thereof, and capable of quickly recovering the original elastic modulus against structural disruption caused by mechanical distortion. The hydrogel is capable of directly gelling an ionic liquid without other solvent such as water when causing gelation. Further, the hydrogel is capable of easily dispersing carbon nanotubes in water whose load on the environment is low.
摘要翻译： 具有式（I）重复单元的离子有机化合物可以通过少量的反应步骤从容易获得的有机化合物容易地合成，可以在没有任何纯化技术如色谱法的情况下制备，并且可以用于相当小的 没有任何其他辅助溶剂的水或离子液体的凝胶化量：<？in-line-formula description =“In-line Formulas”end =“lead”？> [ - （ABC）n - ]。m（X）（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A表示具有季铵阳离子的基团，该季铵阳离子由杂环化合物形成， 至少一个氮原子; B表示可以具有选自酰胺，脲，氨基甲酸酯和肽基团的取代基的官能团; C表示能够连接A和B的可具有取代基的二价烃基; X表示阴离子; n表示重复单元的数量; m表示阴离子总数; 并且n和m是相同的整数。 使用该化合物的水凝胶在酸性条件下是稳定的，能够少量地设置大量的水，并且能够快速恢复原始的弹性模量，抵抗由机械变形引起的结构破坏。 当凝胶化时，水凝胶能够直接凝胶化没有其它溶剂如水的离子液体。 此外，水凝胶能够容易地将碳纳米管分散在环境负荷低的水中。
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公开(公告)号：US07858799B2
公开(公告)日：2010-12-28
申请号：US11883462
申请日：2006-01-30
申请人： Masaru Yoshida , Nagatoshi Koumura , Nobuyuki Tamaoki , Hajime Kawanami , Hajime Matsumoto , Said Kazaoui , Nobutsugu Minami
发明人： Masaru Yoshida , Nagatoshi Koumura , Nobuyuki Tamaoki , Hajime Kawanami , Hajime Matsumoto , Said Kazaoui , Nobutsugu Minami
IPC分类号： C07D211/84 , C07D401/04 , C09K11/65
CPC分类号： H01B1/122 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/28 , C07D213/75 , Y02P20/542
摘要： An ionic organic compound having a repeating unit of formula (I) can be synthesized easily from a readily available organic compound through a small number of reaction steps, can be produced without any purification technique such as chromatography, and can be used in a quite small amount for gelation of water or an ionic liquid without any other auxiliary solvent: [-(A-B-C)n-]•m(X) (I) wherein A represents a group having a quaternary ammonium cation which is formed from a heterocyclic compound having at least one nitrogen atom; B represents a functional group, which may have a substituent, selected from amide, urea, urethane and peptide groups; C represents a divalent hydrocarbon group, which may have a substituent, capable of linking between A and B; X represents an anion; n represents the number of repeating units; m represents the total number of anions; and n and m are the same integer. A hydrogel using the compound is stable under acidic conditions, capable of setting a large amount of water with a small amount thereof, and capable of quickly recovering the original elastic modulus against structural disruption caused by mechanical distortion. The hydrogel is capable of directly gelling an ionic liquid without other solvent such as water when causing gelation. Further, the hydrogel is capable of easily dispersing carbon nanotubes in water whose load on the environment is low.
摘要翻译： 具有式（I）重复单元的离子有机化合物可以通过少量的反应步骤从容易获得的有机化合物容易地合成，可以在没有任何纯化技术如色谱法的情况下制备，并且可以用于相当小的 不含任何其他辅助溶剂的水或离子液体的凝胶化量：[ - （ABC）n-]•m（X）（I）其中A表示具有季铵阳离子的基团，该季铵阳离子由杂环化合物形成， 至少一个氮原子; B表示可以具有选自酰胺，脲，氨基甲酸酯和肽基团的取代基的官能团; C表示能够连接A和B的可具有取代基的二价烃基; X表示阴离子; n表示重复单元的数量; m表示阴离子总数; 并且n和m是相同的整数。 使用该化合物的水凝胶在酸性条件下是稳定的，能够少量地设置大量的水，并且能够快速恢复原始的弹性模量，抵抗由机械变形引起的结构破坏。 当凝胶化时，水凝胶能够直接凝胶化没有其它溶剂如水的离子液体。 此外，水凝胶能够容易地将碳纳米管分散在环境负荷低的水中。
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3.发明授权Ionic gel electrolyte, dye-sensitized photoelectric conversion device and solar cell 失效离子凝胶电解质，染料敏化光电转换装置和太阳能电池公开(公告)号：US08013241B2
公开(公告)日：2011-09-06
申请号：US12091295
申请日：2006-10-16
IPC分类号： H01L31/00 , C07D213/04 , C07D295/18 , C07D233/00
CPC分类号： H01B1/122 , H01G9/2009 , H01G9/2031 , H01L51/0086 , H01M14/005 , H01M2300/0085 , Y02E10/542
摘要： Disclosed is a novel ionic liquid gel electrolyte having high photoelectric conversion efficiency. Also disclosed are a novel dye-sensitized photoelectric conversion device using such an ionic liquid gel electrolyte, and a solar cell composed of such a dye-sensitized photoelectric conversion device. Specifically disclosed is an ionic liquid gel electrolyte obtained by gelling a liquid electrolyte by using an ionic organic oligomer gelling agent represented by the general formulae (1) and (2) below. Also specifically disclosed are a dye-sensitized photoelectric conversion device, wherein the ionic liquid gel electrolyte is arranged between a counter electrode and a dye-absorbed semiconductor substrate which is arranged in contact with a transparent conductive substrate, and a solar cell.
摘要翻译： 公开了一种具有高光电转换效率的新型离子液体凝胶电解质。 还公开了使用这种离子液体凝胶电解质的新型染料敏化光电转换装置和由这种染料敏化光电转换装置构成的太阳能电池。 具体公开了通过使用下述通式（1）和（2）表示的离子型有机低聚物胶凝剂使液体电解质胶凝而获得的离子液体凝胶电解质。 还公开了一种染料敏化光电转换装置，其中离子液体凝胶电解质被布置在与透明导电基板和太阳能电池接触布置的相对电极和被染料吸收的半导体基板之间。
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4.发明申请IONIC GEL ELECTROLYTE, DYE-SENSITIZED PHOTOELECTRIC CONVERSION DEVICE AND SOLAR CELL 失效离子凝胶电解质，透明光电转换装置和太阳能电池公开(公告)号：US20090266419A1
公开(公告)日：2009-10-29
申请号：US12091295
申请日：2006-10-16
CPC分类号： H01B1/122 , H01G9/2009 , H01G9/2031 , H01L51/0086 , H01M14/005 , H01M2300/0085 , Y02E10/542
摘要： Disclosed is a novel ionic liquid gel electrolyte having high photoelectric conversion efficiency. Also disclosed are a novel dye-sensitized photoelectric conversion device using such an ionic liquid gel electrolyte, and a solar cell composed of such a dye-sensitized photoelectric conversion device. Specifically disclosed is an ionic liquid gel electrolyte obtained by gelling a liquid electrolyte by using an ionic organic oligomer gelling agent represented by the general formulae (1) and (2) below. Also specifically disclosed are a dye-sensitized photoelectric conversion device, wherein the ionic liquid gel electrolyte is arranged between a counter electrode and a dye-absorbed semiconductor substrate which is arranged in contact with a transparent conductive substrate, and a solar cell.
摘要翻译： 公开了一种具有高光电转换效率的新型离子液体凝胶电解质。 还公开了使用这种离子液体凝胶电解质的新型染料敏化光电转换装置和由这种染料敏化光电转换装置构成的太阳能电池。 具体公开了通过使用下述通式（1）和（2）表示的离子型有机低聚物胶凝剂使液体电解质胶凝而获得的离子液体凝胶电解质。 还公开了一种染料敏化光电转换装置，其中离子液体凝胶电解质被布置在与透明导电基板和太阳能电池接触布置的相对电极和被染料吸收的半导体基板之间。
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5.发明授权Ionic organic compound, production method thereof, hydrogelling agent composed of the ionic organic compound, hydrogel containing same, methanol gelling agent, methanol gel containing same, and carbon nanotube dispersant 有权离子有机化合物，其制造方法，由离子性有机化合物构成的水凝胶，含有其的水凝胶，甲醇胶凝剂，含有其的甲醇凝胶和碳纳米管分散剂公开(公告)号：US08519040B2
公开(公告)日：2013-08-27
申请号：US13062243
申请日：2009-09-07
CPC分类号： C08G73/0293 , C08J3/075 , C08J3/095 , C08J2377/10 , C08K7/24
摘要： Disclosed are a novel ionic organic compound and a method for producing the ionic organic compound by a simple process. Also disclosed are a hydrogelling agent composed of an ionic organic compound obtained by the method, an alcohol gelling agent, a gel which uses the gelling agent, while using water or methanol as a medium, and a carbon nanotube dispersant composed of the compound. Specifically disclosed is an ionic organic compound represented by general formula (1). The compound is obtained by a condensation reaction of (A) an aromatic diamide compound or cyclohexane diamide compound having a 4-(chloromethyl)benzamide group at both ends, and (B) a compound selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms. The thus-obtained ionic organic compound serves as a gelling agent which is capable of gelling a neutral aqueous solution or an alcohol. The solvent solubility can be changed by substituting the anion of the thus-obtained ionic compound with another anion by anion-exchange. (In the formula, A represents a linking moiety having one or more optionally substituted aromatic rings or a linking moiety composed of a cyclohexane ring; B represents a cationic functional group having a quaternized nitrogen atom, which is selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms; X represents a monovalent anion; and n represents an integer of 1-800.)
摘要翻译： 公开了一种新颖的离子有机化合物和通过简单的方法制备离子有机化合物的方法。 还公开了由使用该方法获得的离子有机化合物，醇胶凝剂，使用胶凝剂的凝胶，同时使用水或甲醇作为介质，以及由该化合物组成的碳纳米管分散剂组成的水凝胶剂。 具体公开的是由通式（1）表示的离子有机化合物。 该化合物通过（A）在两端具有4-（氯甲基）苯甲酰胺基的芳族二酰胺化合物或环己烷二酰胺化合物与（B）选自N，N，N'，N' 可以具有取代基的四甲基亚烷基二胺，其中氮原子之间有1-6个碳原子。 由此获得的离子有机化合物用作能够凝胶化中性水溶液或醇的胶凝剂。 溶剂的溶解度可以通过用阴离子交换用另外的阴离子代替由此得到的离子化合物的阴离子来改变。 （式中，A表示具有一个以上可以具有取代基的芳环或由环己烷环构成的连接部分的连接部分; B表示具有季铵化氮原子的阳离子官能团，其选自N，N，N' 可以具有取代基的N'-四甲基亚烷基二胺，其中氮原子之间具有1-6个碳原子; X表示一价阴离子; n表示1-800的整数。
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6.发明申请IONIC ORGANIC COMPOUND, PRODUCTION METHOD THEREOF, HYDROGELLING AGENT COMPOSED OF THE IONIC ORGANIC COMPOUND, HYDROGEL CONTAINING SAME, METHANOL GELLING AGENT, METHANOL GEL CONTAINING SAME, AND CARBON NANOTUBE DISPERSANT 有权离子有机化合物，其生产方法，由离子有机化合物，含有它们的氢化物，甲醇胶凝剂，含有它们的甲醇凝胶和碳纳米管分散体组成的氢化剂公开(公告)号：US20110178218A1
公开(公告)日：2011-07-21
申请号：US13062243
申请日：2009-09-07
CPC分类号： C08G73/0293 , C08J3/075 , C08J3/095 , C08J2377/10 , C08K7/24
摘要： Disclosed are a novel ionic organic compound and a method for producing the ionic organic compound by a simple process. Also disclosed are a hydrogelling agent composed of an ionic organic compound obtained by the method, an alcohol gelling agent, a gel which uses the gelling agent, while using water or methanol as a medium, and a carbon nanotube dispersant composed of the compound. Specifically disclosed is an ionic organic compound represented by general formula (1). The compound is obtained by a condensation reaction of (A) an aromatic diamide compound or cyclohexane diamide compound having a 4-(chloromethyl)benzamide group at both ends, and (B) a compound selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms. The thus-obtained ionic organic compound serves as a gelling agent which is capable of gelling a neutral aqueous solution or an alcohol. The solvent solubility can be changed by substituting the anion of the thus-obtained ionic compound with another anion by anion-exchange. (In the formula, A represents a linking moiety having one or more optionally substituted aromatic rings or a linking moiety composed of a cyclohexane ring; B represents a cationic functional group having a quaternized nitrogen atom, which is selected from N,N,N′,N′-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms; X represents a monovalent anion; and n represents an integer of 1-800.)
摘要翻译： 公开了一种新颖的离子有机化合物和通过简单的方法制备离子有机化合物的方法。 还公开了由使用该方法获得的离子有机化合物，醇胶凝剂，使用胶凝剂的凝胶，同时使用水或甲醇作为介质，以及由该化合物组成的碳纳米管分散剂组成的水凝胶剂。 具体公开的是由通式（1）表示的离子有机化合物。 该化合物通过（A）在两端具有4-（氯甲基）苯甲酰胺基的芳族二酰胺化合物或环己烷二酰胺化合物与（B）选自N，N，N'，N' 可以具有取代基的四甲基亚烷基二胺，其中氮原子之间有1-6个碳原子。 由此获得的离子有机化合物用作能够凝胶化中性水溶液或醇的胶凝剂。 溶剂的溶解度可以通过用阴离子交换用另外的阴离子代替由此得到的离子化合物的阴离子来改变。 （式中，A表示具有一个以上可以具有取代基的芳环或由环己烷环构成的连接部分的连接部分; B表示具有季铵化氮原子的阳离子官能团，其选自N，N，N' 可以具有取代基的N'-四甲基亚烷基二胺，其中氮原子之间具有1-6个碳原子; X表示一价阴离子; n表示1-800的整数。
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7.发明授权公开(公告)号：US08372558B2
公开(公告)日：2013-02-12
申请号：US12230103
申请日：2008-08-22
申请人： Jinhua Chen , Yasunari Maekawa , Masaharu Asano , Masaru Yoshida
发明人： Jinhua Chen , Yasunari Maekawa , Masaharu Asano , Masaru Yoshida
IPC分类号： H01M8/10
CPC分类号： H01M8/1025 , C08F8/12 , C08F2810/20 , C08J3/28 , C08J2351/08 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1067 , H01M8/1072 , H01M2008/1095 , H01M2300/0082 , Y02P70/56 , C08F285/00
摘要： A vinyl monomer is graft polymerized on an aromatic hydrocarbon-based polymer film substrate to introduce graft chains into the substrate and thereafter a functional monomer represented by the following formula and having sulfonic acid groups or functional groups capable of conversion to sulfonic acid groups is graft polymerized to introduce the sulfonic acid groups or the functional groups capable of conversion to sulfonic acid groups: where R is an aromatic ring or an aliphatic chain; X is (1) —OH, (2) —OLi, —ONa or —OK, (3) —F or —Cl, or (4) —OCnH2n+1 where n is an integer of 1 to 7. Since the graft chains obtained by graft polymerization of the vinyl monomer can also be utilized as scaffold polymers, the graft polymerizability of the functional monomer to the aromatic hydrocarbon-based polymer film substrate is sufficiently improved to enable the preparation of a polymer electrolyte membrane that excels not only in proton conductivity and mechanical strength but also in dimensional stability.
摘要翻译： 乙烯基单体在芳烃类聚合物膜基材上接枝聚合以将接枝链引入基材中，然后将由下式表示的具有磺酸基或能够转化为磺酸基的官能团的官能单体接枝聚合 引入磺酸基团或能够转化为磺酸基团的官能团：其中R是芳环或脂族链; X是（1）-OH，（2）-OLi，-ONa或-OK，（3）-F或-Cl或（4）-OCnH 2 + 1，其中n是1至7的整数。 通过乙烯基单体的接枝聚合获得的链也可以用作支架聚合物，功能性单体对芳族烃类聚合物膜基材的接枝聚合性得到充分改善，能够制备高分子电解质膜， 质子传导性和机械强度，而且尺寸稳定性。
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8.发明授权Process or producing hybrid ion-exchange membranes comprising functional inorganics and graft polymer and electrolyte membranes for use in fuel cells comprising the hybrid ion-exchange membranes 失效用于生产包含功能性无机物和用于燃料电池的接枝聚合物和电解质膜的混合离子交换膜的方法，所述燃料电池包括所述混合离子交换膜公开(公告)号：US08241770B2
公开(公告)日：2012-08-14
申请号：US12805513
申请日：2010-08-03
申请人： Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano , Yousuke Morita , Soji Nishiyama , Toshimitsu Tachibana , Yozo Nagai
发明人： Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano , Yousuke Morita , Soji Nishiyama , Toshimitsu Tachibana , Yozo Nagai
IPC分类号： H01M8/10
CPC分类号： C08J5/2281 , C08J2323/06 , C08J2327/18
摘要： Polymer ion-exchange membranes having outstanding electrical conductivity, water retention and oxidation resistance are produced by the steps of uniformly mixing an organic high-molecular weight resin with functional inorganics having the abilities to promote graft polymerization of polymerizable monomers, adsorb water and conduct protons, irradiating the resulting functional inorganics/polymer membrane to initiate graft polymerization or graft copolymerization of polymerizable monomers having functional groups, and then introducing sulfonic acid groups into the graft chains.
摘要翻译： 具有优异的导电性，保水性和抗氧化性的聚合物离子交换膜通过以下步骤产生：将有机高分子量树脂与具有促进可聚合单体的接枝聚合，吸附水和导电质子的能力的功能性无机物均匀混合， 照射所得到的功能性无机/聚合物膜以引发具有官能团的可聚合单体的接枝聚合或接枝共聚，然后将磺酸基团引入接枝链。
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9.发明授权公开(公告)号：US08232353B2
公开(公告)日：2012-07-31
申请号：US11892304
申请日：2007-08-21
申请人： Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano , Yosuke Morita
发明人： Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano , Yosuke Morita
IPC分类号： C08F2/46
CPC分类号： C08J5/225 , C08J2327/16 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1065 , H01M8/1076 , H01M8/1079 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： A polymer film substrate is irradiated with ions to make a large number of nano-sized through-holes and the substrate may be further irradiated with ionizing radiation so that a functional monomer may be grafted or co-grafted onto a surface of the film and within the holes; in addition, sulfonic acid group(s) may be introduced into the graft chains to produce a polymer ion-exchange membrane that may have high oxidation resistance, dimensional stability, electrical conductivity and/or methanol resistance, as well as may have an ion-exchange capacity controlled over a wide range.
摘要翻译： 用离子照射聚合物膜基板以制造大量的纳米尺寸的通孔，并且可以进一步用电离辐射照射基底，使得官能单体可以接枝或共嫁接到膜的表面上 孔; 此外，可以将磺酸基团引入到接枝链中以产生可以具有高抗氧化性，尺寸稳定性，导电性和/或耐甲醇性的聚合物离子交换膜，并且可以具有离子交换膜， 交换能力在很大范围内受到控制。
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公开(公告)号：US20100233425A1
公开(公告)日：2010-09-16
申请号：US12680556
申请日：2008-09-19
CPC分类号： C04B35/478 , C04B35/62665 , C04B38/0006 , C04B2111/00793 , C04B2235/3418 , C04B2235/3463 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , Y10T428/24149 , C04B35/185 , C04B38/0054 , C04B38/0074 , C04B38/067 , C04B38/0675 , C04B38/068 , C04B38/10
摘要： A honeycomb structure having a crystal phase composed of aluminum titanate and mullite, which is obtained by sintering a honeycomb molding made of a mixture comprising titania powder, alumina powder, silica powder and mullite powder, the mixture containing 1-10 parts by mass of silica powder and 5-30 parts by mass of mullite powder per the total amount (100 parts by mass) of the titania powder and the alumina powder, and the mullite powder containing 40-60% by mass of particles having particle sizes of 10-50 μm and 5-30% by mass of particles having particle sizes of 3 μm or less, and its production method.
摘要翻译： 具有由钛酸铝和莫来石组成的结晶相的蜂窝结构体，其通过烧结由包含二氧化钛粉末，氧化铝粉末，二氧化硅粉末和莫来石粉末的混合物制成的蜂窝模塑而获得，所述混合物含有1-10质量份的二氧化硅 粉末和总计30质量份莫来石粉末（100质量份）的二氧化钛粉末和氧化铝粉末，并且含有40〜60质量％的粒径为10〜50质量％的莫来石粉末 μm和5〜30质量％的粒径为3μm以下的粒子及其制造方法。
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