公开(公告)号：US08202360B2

公开(公告)日：2012-06-19

申请号：US13060384

申请日：2009-09-02

申请人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Keiichi Inukai ,  Natsuko Kozuka ,  Masaki Maeda

发明人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Keiichi Inukai ,  Natsuko Kozuka ,  Masaki Maeda

IPC分类号： C01B33/26 ,  B01J20/16 ,  F24F3/14 ,  B01D53/28

CPC分类号： B01D53/02 ,  B01D53/28 ,  B01D2253/106 ,  B01D2253/1085 ,  B01J20/16 ,  C01B33/26

摘要： The present invention aims to provide an adsorbent with superior adsorption performance of 20 wt % or more in a humidity range of 5 to 60 wt % by using a low-cost reagent as the raw material. Aluminum sulfate is used as the Al source, the respective aqueous solutions are mixed to achieve a Si/Al molar ratio of 0.70 to 1.0 in the mixed solution, the pH is adjusted to be 6 to 9 with acid or alkali, the solution is heated at 90 to 110° C. and subsequently subject to desalination treatment in order to synthesize an amorphous aluminum silicate. The obtained amorphous aluminum silicate yields a superior water vapor adsorption performance of 20 wt % or more in a relative humidity of 60%, and can be used as an adsorbent for desiccant air conditioning and as other adsorbents.

摘要翻译： 本发明旨在通过使用低成本试剂作为原料，提供在5〜60重量％的湿度范围内具有20重量％以上的优异吸附性能的吸附剂。 使用硫酸铝作为Al源，将各水溶液混合以在混合溶液中达到0.70至1.0的Si / Al摩尔比，用酸或碱将pH调节至6至9，将溶液加热 在90至110℃下进行脱盐处理，然后进行脱盐处理以合成无定形硅酸铝。 所获得的无定形硅酸铝在相对湿度为60％时获得优异的20重量％以上的水蒸汽吸附性能，并且可以用作干燥剂空调的吸附剂和其它吸附剂。

公开(公告)号：US20110189070A1

公开(公告)日：2011-08-04

申请号：US13060384

申请日：2009-09-02

申请人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Keiichi Inukai ,  Natsuko Kozuka ,  Masaki Maeda

发明人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Keiichi Inukai ,  Natsuko Kozuka ,  Masaki Maeda

IPC分类号： C01B33/26

CPC分类号： B01D53/02 ,  B01D53/28 ,  B01D2253/106 ,  B01D2253/1085 ,  B01J20/16 ,  C01B33/26

摘要： The present invention aims to provide an adsorbent with superior adsorption performance of 20 wt % or more in a humidity range of 5 to 60 wt % by using a low-cost reagent as the raw material. Aluminum sulfate is used as the Al source, the respective aqueous solutions are mixed to achieve a Si/Al molar ratio of 0.70 to 1.0 in the mixed solution, the pH is adjusted to be 6 to 9 with acid or alkali, the solution is heated at 90 to 110° C. and subsequently subject to desalination treatment in order to synthesize an amorphous aluminum silicate. The obtained amorphous aluminum silicate yields a superior water vapor adsorption performance of 20 wt % or more in a relative humidity of 60%, and can be used as an adsorbent for desiccant air conditioning and as other adsorbents.

摘要翻译： 本发明旨在通过使用低成本试剂作为原料，提供在5〜60重量％的湿度范围内具有20重量％以上的优异吸附性能的吸附剂。 使用硫酸铝作为Al源，将各水溶液混合以在混合溶液中达到0.70至1.0的Si / Al摩尔比，用酸或碱将pH调节至6至9，将溶液加热 在90至110℃下进行脱盐处理，然后进行脱盐处理以合成无定形硅酸铝。 所获得的无定形硅酸铝在相对湿度为60％时获得优异的20重量％以上的水蒸汽吸附性能，并且可以用作干燥剂空调的吸附剂和其它吸附剂。

公开(公告)号：US08865020B2

公开(公告)日：2014-10-21

申请号：US12810533

申请日：2008-12-26

申请人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Sumiko Kawabata ,  Chieko Ikeda ,  Ryousuke Nakanishi ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

发明人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Sumiko Kawabata ,  Chieko Ikeda ,  Ryousuke Nakanishi ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

IPC分类号： C09K3/00 ,  B01J20/16 ,  B01D53/02 ,  C01B33/26 ,  C01B33/40 ,  B01D53/28 ,  B01J29/06 ,  B01D53/047

CPC分类号： B01D53/02 ,  B01D53/047 ,  B01D53/28 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/11 ,  B01D2257/406 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/7022 ,  B01D2257/90 ,  B01J20/16 ,  C01B33/26 ,  C01B33/40 ,  Y02C10/08 ,  Y02C20/20 ,  Y02P20/152

摘要： Provided is an adsorbent having superior adsorption properties for use as a dehumidifying agent for desiccant air conditioning which exhibits high adsorption properties at mid and high humidity ranges, and for use as a gas adsorbent of carbon dioxide, ammonia, formaldehyde and the like. A precursor suspension having a Si/Al ratio of 0.70 to 1.0 is prepared, and the precursor suspension is subsequently heated at 110° C. or higher for 2 days to synthesize a complex of a layered low-crystalline clay mineral and an amorphous aluminum silicate. The obtained complex of the layered low-crystalline clay mineral and the amorphous aluminum silicate yields excellent water vapor adsorption performance of 45 wt % or more at a relative humidity of 60%, and therefore can be used as an adsorbent for desiccant air conditioning. The complex also yields excellent carbon dioxide absorption/desorption performance of 12 wt % or more at 100 kPa to 900 kPa, and therefore can be used as a gas adsorbent for gas such as ammonia and formaldehyde.

摘要翻译： 本发明提供一种具有优异吸附性能的吸附剂，用作干燥剂空调的除湿剂，其在中，高湿度范围内具有高吸附性能，并且用作二氧化碳，氨，甲醛等的气体吸附剂。 制备Si / Al比为0.70〜1.0的前体悬浮液，随后将前体悬浮液在110℃以上加热2天，合成层状低结晶粘土矿物和无定形硅酸铝的配合物 。 得到的层状低结晶性粘土矿物和无定形硅酸铝的复合物在60％的相对湿度下产生45重量％以上的优异的水蒸汽吸附性能，因此可以用作干燥剂空调的吸附剂。 该络合物在100kPa至900kPa下也可获得优异的二氧化碳吸收/脱附性能，为12重量％以上，因此可用作氨，甲醛等气体的气体吸附剂。

公开(公告)号：US20100320418A1

公开(公告)日：2010-12-23

申请号：US12810533

申请日：2008-12-26

申请人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Sumiko Kawabata ,  Chieko Ikeda ,  Ryousuke Nakanishi ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

发明人： Masaya Suzuki ,  Katsuhiro Tsukimura ,  Sumiko Kawabata ,  Chieko Ikeda ,  Ryousuke Nakanishi ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

IPC分类号： B01J29/89 ,  C09K3/00

CPC分类号： B01D53/02 ,  B01D53/047 ,  B01D53/28 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/11 ,  B01D2257/406 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/7022 ,  B01D2257/90 ,  B01J20/16 ,  C01B33/26 ,  C01B33/40 ,  Y02C10/08 ,  Y02C20/20 ,  Y02P20/152

摘要： Provided is an adsorbent having superior adsorption properties for use as a dehumidifying agent for desiccant air conditioning which exhibits high adsorption properties at mid and high humidity ranges, and for use as a gas adsorbent of carbon dioxide, ammonia, formaldehyde and the like. A precursor suspension having a Si/Al ratio of 0.70 to 1.0 is prepared, and the precursor suspension is subsequently heated at 110° C. or higher for 2 days to synthesize a complex of a layered low-crystalline clay mineral and an amorphous aluminum silicate. The obtained complex of the layered low-crystalline clay mineral and the amorphous aluminum silicate yields excellent water vapor adsorption performance of 45 wt % or more at a relative humidity of 60%, and therefore can be used as an adsorbent for desiccant air conditioning. The complex also yields excellent carbon dioxide absorption/desorption performance of 12 wt % or more at 100 kPa to 900 kPa, and therefore can be used as a gas adsorbent for gas such as ammonia and formaldehyde.

摘要翻译： 本发明提供一种具有优异吸附性能的吸附剂，用作干燥剂空调的除湿剂，其在中，高湿度范围内具有高吸附性能，并且用作二氧化碳，氨，甲醛等的气体吸附剂。 制备Si / Al比为0.70〜1.0的前体悬浮液，随后将前体悬浮液在110℃以上加热2天，合成层状低结晶粘土矿物和无定形硅酸铝的配合物 。 得到的层状低结晶性粘土矿物和无定形硅酸铝的复合物在60％的相对湿度下产生45重量％以上的优异的水蒸汽吸附性能，因此可以用作干燥剂空调的吸附剂。 该络合物在100kPa至900kPa下也可获得优异的二氧化碳吸收/脱附性能，为12重量％以上，因此可用作氨，甲醛等气体的气体吸附剂。

公开(公告)号：US20100113265A1

公开(公告)日：2010-05-06

申请号：US12595267

申请日：2008-04-11

申请人： Masaya Suzuki ,  Chieko Ikeda ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

发明人： Masaya Suzuki ,  Chieko Ikeda ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

IPC分类号： B01J20/16 ,  B01J20/10

CPC分类号： B01J20/16 ,  B01D53/02 ,  B01D53/047 ,  B01D2253/106 ,  B01D2253/306 ,  B01D2253/311 ,  B01D2257/504 ,  C01B33/26 ,  Y02C10/08 ,  Y02P20/152

摘要： Provided is an adsorbent adapted to adsorb carbon dioxide by increasing the pressure, and to carry out 10% or more adsorption and adsorption of the adsorbed carbon dioxide by lowering the pressure at atmospheric pressure or higher in a range of 100 to 900 kPa without vacuuming or the like. As a result of using amorphous aluminum silicate with a Si/Al ratio of 0.7 to 1.0 and having a peak in the vicinity of −78 ppm and −87 ppm in a 29Si solid NMR spectrum, adsorption and desorption of 10 wt % or more can be performed in a range of 100 to 900 kPa, and this can be used as a carbon dioxide adsorbent mainly in the pressure swing adsorption method.

摘要翻译： 本发明提供一种适于通过增加压力吸附二氧化碳的吸附剂，并且通过在100-900kPa的范围内降低大气压或更高的压力而进行10％或更多的吸附和吸附，而无需抽真空或 类似。 作为在29Si固体NMR谱中使用Si / Al比为0.7〜1.0，峰值为-78ppm〜-87ppm的无定形硅酸铝的结果，10重量％以上的吸附和脱附可以 可以在100〜900kPa的范围内进行，主要是在变压吸附法中作为二氧化碳吸附剂使用。

公开(公告)号：US20100028237A1

公开(公告)日：2010-02-04

申请号：US12521140

申请日：2007-02-27

申请人： Masaya Suzuki ,  Chieko Ikeda ,  Keiichi Inukai ,  Masaki Maeda

发明人： Masaya Suzuki ,  Chieko Ikeda ,  Keiichi Inukai ,  Masaki Maeda

IPC分类号： C01B33/26

CPC分类号： B01J20/16 ,  C01B33/26

摘要： Provided is an adsorbent having excellent adsorption performance in a medium-humidity range by employing an amorphous aluminum silicate formed from protoimogolite. The amorphous aluminum silicate formed from protoimogolite is synthesized by setting the Si/Al ratio in solution mixing to be of a condition that is higher than synthesizing imogolite or amorphous imogolite, and performing desalting treatment and heating thereto. The obtained amorphous aluminum silicate formed from protoimogolite yields a superior water vapor adsorption performance of 30 wt % or higher at a relative humidity of 60%, and can be used as an adsorbent for desiccant air conditioning.

摘要翻译： 本发明提供一种通过使用由原生胶体形成的无定形硅酸铝在中等湿度范围内具有优异吸附性能的吸附剂。 由原硅沸石形成的无定形硅酸铝是通过将溶液混合中的Si / Al比设定为高于合成粉煤灰或非晶硅沸石的条件，进行脱盐处理和加热而合成的。 所得到的无定形硅酸铝在相对湿度为60％的条件下，具有优异的30重量％以上的水蒸汽吸附性能，可用作干燥剂空调的吸附剂。

公开(公告)号：US08227377B2

公开(公告)日：2012-07-24

申请号：US12595267

申请日：2008-04-11

申请人： Masaya Suzuki ,  Chieko Ikeda ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

发明人： Masaya Suzuki ,  Chieko Ikeda ,  Koji Tajiri ,  Keiichi Inukai ,  Masaki Maeda

IPC分类号： B01J20/10

CPC分类号： B01J20/16 ,  B01D53/02 ,  B01D53/047 ,  B01D2253/106 ,  B01D2253/306 ,  B01D2253/311 ,  B01D2257/504 ,  C01B33/26 ,  Y02C10/08 ,  Y02P20/152

摘要： Provided is an adsorbent adapted to adsorb carbon dioxide by increasing the pressure, and to carry out 10% or more adsorption and adsorption of the adsorbed carbon dioxide by lowering the pressure at atmospheric pressure or higher in a range of 100 to 900 kPa without vacuuming or the like. As a result of using amorphous aluminum silicate with a Si/Al ratio of 0.7 to 1.0 and having a peak in the vicinity of −78 ppm and −87 ppm in a 29Si solid NMR spectrum, adsorption and desorption of 10 wt % or more can be performed in a range of 100 to 900 kPa, and this can be used as a carbon dioxide adsorbent mainly in the pressure swing adsorption method.

摘要翻译： 本发明提供一种适于通过增加压力吸附二氧化碳的吸附剂，并且通过在100-900kPa的范围内降低大气压或更高的压力而进行10％或更多的吸附和吸附，而无需抽真空或 类似。 作为在29Si固体NMR谱中使用Si / Al比为0.7〜1.0，峰值为-78ppm〜-87ppm的无定形硅酸铝的结果，10重量％以上的吸附和脱附可以 可以在100〜900kPa的范围内进行，主要是在变压吸附法中作为二氧化碳吸附剂使用。

公开(公告)号：US07887770B2

公开(公告)日：2011-02-15

申请号：US12521140

申请日：2007-02-27

申请人： Masaya Suzuki ,  Chieko Ikeda ,  Keiichi Inukai ,  Masaki Maeda

发明人： Masaya Suzuki ,  Chieko Ikeda ,  Keiichi Inukai ,  Masaki Maeda

IPC分类号： C01B33/26

CPC分类号： B01J20/16 ,  C01B33/26

摘要： Provided is an adsorbent having excellent adsorption performance in a medium-humidity range by employing an amorphous aluminum silicate formed from protoimogolite. The amorphous aluminum silicate formed from protoimogolite is synthesized by setting the Si/Al ratio in solution mixing to be of a condition that is higher than synthesizing imogolite or amorphous imogolite, and performing desalting treatment and heating thereto. The obtained amorphous aluminum silicate formed from protoimogolite yields a superior water vapor adsorption performance of 30 wt % or higher at a relative humidity of 60%, and can be used as an adsorbent for desiccant air conditioning.

摘要翻译： 本发明提供一种通过使用由原生胶体形成的无定形硅酸铝在中等湿度范围内具有优异吸附性能的吸附剂。 由原硅沸石形成的无定形硅酸铝是通过将溶液混合中的Si / Al比设定为高于合成粉煤灰或非晶硅沸石的条件，进行脱盐处理和加热而合成的。 所得到的无定形硅酸铝在相对湿度为60％的条件下，具有优异的30重量％以上的水蒸汽吸附性能，可用作干燥剂空调的吸附剂。

公开(公告)号：US5667561A

公开(公告)日：1997-09-16

申请号：US586275

申请日：1996-01-16

申请人： Kenzi Suzuki ,  Keiichi Inukai

发明人： Kenzi Suzuki ,  Keiichi Inukai

IPC分类号： B01D53/02 ,  B01D53/62 ,  B01D53/04

CPC分类号： B01D53/02 ,  B01D53/62 ,  B01D2257/50 ,  Y02C10/04 ,  Y02C10/08 ,  Y10S95/90

摘要： Selective separation and recovery of gaseous components of hot waste gas of combustion containing carbon dioxide is attained by causing the hot waste gas to contact an adsorbent containing as a substantial main component thereof an inorganic solid substance exhibiting surface basicity and inducing adsorption of the gaseous components of the hot waste gas on the adsorbent and then selectively separating the adsorbed gaseous components by virtue of differences in retention time among the gaseous components on the adsorbent.

摘要翻译： 通过使热废气与包含其主要组分的吸附剂接触，表现出表面碱性的无机固体物质并诱导气体成分的吸附，从而实现对含有二氧化碳的燃烧的热废气的气态组分的选择性分离和回收 吸附剂上的热废气，然后由于吸附剂上的气态组分之间的保留时间差异，选择性地分离吸附的气体组分。

公开(公告)号：US5653785A

公开(公告)日：1997-08-05

申请号：US653999

申请日：1996-05-28

申请人： Masakazu Horio ,  Kenzi Suzuki ,  Toshiaki Mori ,  Keiichi Inukai ,  Shinji Tomura

发明人： Masakazu Horio ,  Kenzi Suzuki ,  Toshiaki Mori ,  Keiichi Inukai ,  Shinji Tomura

IPC分类号： B01D53/02 ,  B01D53/04 ,  B01D53/62 ,  B01J20/10

CPC分类号： B01D53/04 ,  B01D53/02 ,  B01D53/62 ,  B01J20/10 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2256/22 ,  B01D2257/102 ,  B01D2257/504 ,  Y02C10/04 ,  Y02C10/08 ,  Y10S95/902

摘要： Separation of nitrogen and carbon dioxide is accomplished by a method using as a separating material one member selected from the group consisting of sepiolite in the unmodified form, sepiolite which has been heat-treated, and sepiolite which has had part or the whole of the exchangeable cation thereof replaced with zinc ion and which has been subsequently subjected to a heat treatment.

摘要翻译： 氮气和二氧化碳的分离是通过使用选自以下组分的分离材料的方法来实现的：一种选自非修饰形式的海泡石，已经被热处理的海泡石，和海泡石，其部分或全部是可交换的 其阳离子被锌离子代替，并随后进行热处理。