摘要:
The present invention is to provide a production method of chemical reactive substances with stable quality by which solidification, gel formation, and the resulting blockade within material injection nozzles are prevented, and contamination of a reaction system with the gelled matter is prevented, as well as occurrence of problems on a production process due to the gelled matter is suppressed, when the chemical reactive substances are produced by injecting the liquid materials containing reactive substances having unsaturated double bonds into the reaction vessel through the material injection nozzles of the reaction vessel. The present invention is a production method of a chemical reactive substance which comprises injecting a liquid material containing a reactive substance having an unsaturated double bond into a reaction vessel through a material injection nozzle of said reaction vessel and causing a reaction at a reaction temperature of not less than 50° C., said production method of the chemical reactive substance including a step of removing at least a part of residual liquid remained in the material injection nozzle from inside of the material injection nozzle.
摘要:
It is an object of the present invention to provide a production method of a dehydration reaction product by which the occurrence of troubles in the production step or the degradation in performance characteristics or quality of various chemical products can be suppressed to a satisfactory extent.A production method of a dehydration reaction product which comprises a dehydration reaction step of subjecting a reaction solution containing a polymerizable compound to the dehydration reaction, said dehydration reaction step comprising using a dehydration reaction apparatus, said dehydration reaction apparatus comprising a reaction vessel, a condenser and a connecting pipe joining said reaction vessel with said condenser and satisfying the requirement: 0.05
摘要:
A cement composition excelling in the slump retaining property which comprises at least cement admixture comprising as a main ingredient thereof (I) a copolymer (A) of short-chain polyalkylene glycol (meth)acrylate (a), a long-chain polyalkylene glycol (meth)acrylate (b), a carboxylic acid monomer (c), and a monomer copolymerizable with the monomers mentioned above or a salt of the copolymer (B), (II) a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt thereof, (III) a mixture of a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt (B.sub.1) of thereof with a known cement admixture, or (IV) a polycarboxylic acid based polymer (A.sub.3) manifesting to a calcium sulfoaluminate based expansive additive an adsorption ratio of not less than 90% in 5 minutes at room temperature when added in an amount of 0.1% by weight as solids or a salt (B.sub.3) thereof, or (V) a mixture of said polycarboxylic acid polymer with a known cement dispersant; cement; and water.
摘要:
It is an object of the present invention to provide a storing and/or transferring method of polyalkylene glycol monomers by which the gel-like matter formation and/or decomposition reaction can be satisfactorily inhibited and, as a result, troubles can be prevented from occurring in the production process and the performance characteristics or quality of various chemical products can be satisfactorily prevented from being deteriorated.A storing and/or transferring method of a polyalkylene glycol monomer which comprises storing and/or transferring a polyalkylene glycol monomer in the form of an aqueous solution.
摘要:
The present invention is related to a shrinkage reducing agent for hydraulic materials which comprises at least one polymer selected from the group consisting of (a) a polymer having a structure derived from the residue of a compound containing 2 to 30 carbon atoms and one active hydrogen atom by the binding thereto of one oxyalkylene chain having a carboxyl-containing side chain, (b) a polymer having a structure derived from the residue of a compound containing 4 to 30 carbon atoms and two active hydrogen atoms by the binding thereto of at least one oxyalkylene chain having a carboxyl-containing side chain, (c) a polymer having a structure derived from the residue of a compound containing 1 to 30 carbon atoms and at least three active hydrogen atoms by the binding thereto of at least one oxyalkylene chain having a carboxyl-containing side chain and (d) a polymer having a structure derived from the residue of an amine by the binding thereto one oxyalkylene chain having a carboxyl-containing side chain.
摘要:
The present invention provides a method for producing a cement dispersant having high percentage in water reduction-rate and appropriate air-entraining property. This method for producing a polycarboxylic acid for a cement dispersant is characterized in that alkylene oxide is added at a specific temperature range.
摘要:
A storing and/or transferring method of an alkoxy(poly)alkylene glycol-containing material for cement additive polymer which comprises a step of filling a vessel, a step of storing and/or transferring and a step of drawing out, in that order, said alkoxy(poly)alkylene glycol being represented by the following general formula (1); R1O(R2O)nH (1) in the formula, R1 represents a hydrocarbon group containing 1 to 30 carbon atoms, R2O group represents an oxyalkylene group containing 2 to 18 carbon atoms and each R2O group may be the same or different and n represents the average number of moles of the oxyalkylene groups represented by R2O as added and is a number of 0 to 300, and said step of storage and/or transfer being carried out at a temperature not higher than the solidifying point of the material for cement additive polymer.
摘要:
A novel acrylic ester which is represented by general formula (2) ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or an organic residue, R.sub.3 represents an organic residue, n is a positive number among 1 to 3, and m is a positive number among 1 to 100 and which is applicable to various uses, is obtained by reacting an acrylic ester of general formula (3) ##STR2## wherein R.sub.1 represents a hydrogen atom or an organic residue, and R.sub.3 represents an organic residue, with a cyclic ether compound of general formula (4) ##STR3## wherein R.sub.2 represents a hydrogen atom or an organic residue, and n is a positive number among 1 to 3. Moreover, a novel acrylic acid derivative whose use is even wider is obtained by hydrolyzing the acrylic acid derivative.
摘要:
The present invention is thus directed to a cement additive which comprises a copolymer (A) obtained by polymerizing a monomer mixture (K), wherein; said monomer mixture (K) comprises a polyalkylene glycol ester monomer (I) represented by the general formula (1): a polyalkylene glycol ester monomer (II) represented by the general formula (2): and a carboxylic acid monomer (III) represented by the general formula (3):
摘要:
The present invention provides a method for producing a cement dispersant having high percentage in water reduction rate and appropriate air-entraining property. This method for producing a polycarboxylic acid for a cement dispersant is characterized in that alkylene oxide is added at a specific temperature range.