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公开(公告)号：US06171372B2
公开(公告)日：2001-01-09
申请号：US09168860
申请日：1998-10-08
申请人： Masayoshi Ichiki , Yuki Sairyo , Atsushi Fukuju
发明人： Masayoshi Ichiki , Yuki Sairyo , Atsushi Fukuju
IPC分类号： B01D5304
CPC分类号： B01J20/20 , B01D53/02 , B01D53/565 , B01D2257/404 , B01J20/0211 , B01J20/0222 , B01J20/0225 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/165 , B01J20/28004 , B01J20/28028 , B01J20/28033 , B01J20/28045 , B01J20/28061 , B01J20/28064 , B01J20/28066 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3248 , B01J20/3251 , B01J20/3289 , B01J20/3293 , B01J2220/42 , B01J2220/4831 , B01J2220/64 , Y02A50/2345 , Y10S95/90
摘要： The present invention provides a nitrogen dioxide absorbent for the exhaust gas purifying facility designed to remove by absorption or adsorption of NO2 from a gas (such as ventilation gas from road tunnels) containing NOx in low concentrations. The absorbent is composed of a porous carrier and a basic amino acid and/or organic amine compound supported thereon. The absorbent is produced by impregnating a porous carrier sequentially with two aqueous solutions each containing in an amount of, for example, 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound, or impregnating a porous carrier with a solution containing 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and/or 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound.
摘要翻译： 本发明提供了一种废气净化设备的二氧化氮吸收剂，其设计用于通过吸收或吸附低浓度的NOx的气体（例如来自道路隧道的通风气体）来除去NO 2。 吸收剂由多孔载体和负载在其上的碱性氨基酸和/或有机胺化合物组成。 吸收剂通过依次用两种水溶液浸渍多孔载体来制备，每种水溶液含有例如0.5-3.0mol / l（优选1.0-2.0mol / l）碱性氨基酸和0.5-3.0mol / l （优选1.0-2.0mol / l）有机胺化合物，或者用含有0.5-3.0mol / l（优选1.0-2.0mol / l）碱性氨基酸和/或0.5-3.0mol / l的溶液浸渍多孔载体， l（优选1.0-2.0mol / l）有机胺化合物。
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公开(公告)号：US5439868A
公开(公告)日：1995-08-08
申请号：US288763
申请日：1994-08-11
申请人： Shigenori Onitsuka , Masayoshi Ichiki , Chikashi Inazumi , Takanobu Watanabe , Atsushi Fukuju , Masaki Akiyama , Yuki Sairyo , Hidetsugu Kobayashi
发明人： Shigenori Onitsuka , Masayoshi Ichiki , Chikashi Inazumi , Takanobu Watanabe , Atsushi Fukuju , Masaki Akiyama , Yuki Sairyo , Hidetsugu Kobayashi
CPC分类号： B01J20/28052 , B01D53/02 , B01J20/06 , B01J20/08 , B01J20/28023 , B01J20/28028 , B01J20/28033 , B01J20/28045 , B01D2253/104 , B01D2253/112 , B01D2253/3425 , B01D2257/404
摘要： The invention provides first to fourth adsorbents for removing low-concentration nitrogen oxides. The first adsorbent comprises a carrier of gamma-alumina, and ruthenium supported thereon. The second adsorbent comprises a carrier of anatase-type titania, and ruthenium supported thereon. The third adsorbent comprises ceramic paper retaining a carrier of anatase-type titania thereon, and ruthenium supported on the ceramic paper. The fourth adsorbent comprises ceramic paper retaining a carrier of anatase-type titania thereon, and a ruthenium halide and a halide of addition metal which are co-supported on the ceramic paper. These adsorbents are free of the influence of moisture and therefore usable without necessitating energy-consuming dehumidification or only with dehumidification on a reduced scale.
摘要翻译： 本发明提供了用于除去低浓度氮氧化物的第一至第四吸附剂。 第一种吸附剂包括γ-氧化铝的载体和负载在其上的钌。 第二吸附剂包含锐钛矿型二氧化钛的载体和负载在其上的钌。 第三吸附剂包括在其上保持锐钛矿型二氧化钛的载体的陶瓷纸，和支撑在陶瓷纸上的钌。 第四吸附剂包括在其上保持锐钛矿型二氧化钛的载体的陶瓷纸，以及共同支持在陶瓷纸上的卤化钌和添加金属的卤化物。 这些吸附剂没有水分的影响，因此可以在不需要耗能除湿的情况下或仅在减小的规模上进行除湿。
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公开(公告)号：US5840649A
公开(公告)日：1998-11-24
申请号：US588882
申请日：1996-01-19
申请人： Masayoshi Ichiki , Yuki Sairyo , Kazuhiro Kondo , Atsushi Fukuju
发明人： Masayoshi Ichiki , Yuki Sairyo , Kazuhiro Kondo , Atsushi Fukuju
CPC分类号： B01D53/02 , B01D2253/112 , B01D2253/306 , B01D2257/404 , B01D2257/80
摘要： The present invention relates to a Mn-added titania carrier obtained by adding a Mn salt to amorphous titania and baking the titania. The invention also relates to an NOx adsorbent comprising the above-mentioned titania carrier and adsorbing components comprising oxides of Ru and/or Ce supported on the carrier. The invention also relates to an NOx adsorbent comprising the above-mentioned titania carrier and adsorbing components comprising oxides of Ru and/or Ce and an oxide of at least one metal among Ag, Cu and Mn supported on the carrier. The NOx adsorbents embodying the invention are effectively used for efficiently adsorbing and removing NOx from gases which contain much moisture and low-concentration, for example, a few ppm NOx such as gases discharged by ventilation from highway tunnels.
摘要翻译： 本发明涉及通过向无定形二氧化钛中加入Mn盐并烘烤二氧化钛而获得的添加Mn的二氧化钛载体。 本发明还涉及包含上述二氧化钛载体的NOx吸附剂和包含负载在载体上的Ru和/或Ce的氧化物的吸附组分。 本发明还涉及包含上述二氧化钛载体的NOx吸附剂和包含Ru和/或Ce的氧化物的吸附组分和在载体上负载的Ag，Cu和Mn中的至少一种金属的氧化物。 实施本发明的NOx吸附剂有效地用于有效吸附和除去含有大量水分和低浓度的气体中的NOx，例如少量的NOx，例如通过公路隧道排放的气体。
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公开(公告)号：US5612276A
公开(公告)日：1997-03-18
申请号：US429768
申请日：1995-04-27
申请人： Shigenori Onitsuka , Masayoshi Ichiki , Chikashi Inazumi , Takanobu Watanabe , Atsushi Fukuju , Masaki Akiyama , Yuki Sairyo , Hidetsugu Kobayashi
发明人： Shigenori Onitsuka , Masayoshi Ichiki , Chikashi Inazumi , Takanobu Watanabe , Atsushi Fukuju , Masaki Akiyama , Yuki Sairyo , Hidetsugu Kobayashi
CPC分类号： B01J20/28052 , B01D53/02 , B01J20/06 , B01J20/08 , B01J20/28023 , B01J20/28028 , B01J20/28033 , B01J20/28045 , B01D2253/104 , B01D2253/112 , B01D2253/3425 , B01D2257/404
摘要： The invention provides first to fourth adsorbents for removing low-concention nitrogen oxides. The first adsorbent comprises a carrier of gamma-alumina, and ruthenium supported-thereon. The second adsorbent comprises a carrier of anatase-type titania, and ruthenium supported thereon. The third adsorbent comprises ceramic paper retaining a carrier of anatase-type titania thereon, and ruthenium supported on the ceramic paper. The fourth adsorbent comprises ceramic paper retaining a carrier of anatase-type titania thereon, and a ruthenium halide and a halide of addition metal which are co-supported on the ceramic paper. These adsorbents are free of the influence of moisture and therefore usable without necessitating energy-consuming dehumidification or only with dehumidification on a reduced scale.
摘要翻译： 本发明提供了用于除去低浓度氮氧化物的第一至第四吸附剂。 第一吸附剂包括γ-氧化铝载体和负载在其上的钌。 第二吸附剂包含锐钛矿型二氧化钛的载体和负载在其上的钌。 第三吸附剂包括在其上保持锐钛矿型二氧化钛的载体的陶瓷纸，和支撑在陶瓷纸上的钌。 第四吸附剂包括在其上保持锐钛矿型二氧化钛的载体的陶瓷纸，以及共同支持在陶瓷纸上的卤化钌和添加金属的卤化物。 这些吸附剂没有水分的影响，因此可以在不需要耗能除湿的情况下或仅在减小的规模上进行除湿。
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5.发明申请FUEL CELL WITH ELECTRODE HAVING AN ELECTRICALLY CONDUCTIVE NANO-COLUMN AND PRODUCTION METHOD THEREOF 失效具有电导电纳米柱的电极的燃料电池及其制造方法公开(公告)号：US20100075201A1
公开(公告)日：2010-03-25
申请号：US12293667
申请日：2007-03-15
申请人： Haruyuki Nakanishi , Chikashi Inazumi , Yuki Sairyo , Momoyo Sawai , Kenji Yoshikawa , Tomoya Yamashita
发明人： Haruyuki Nakanishi , Chikashi Inazumi , Yuki Sairyo , Momoyo Sawai , Kenji Yoshikawa , Tomoya Yamashita
CPC分类号： H01M4/8657 , H01M4/8605 , H01M4/92 , H01M4/926 , H01M8/1004 , Y02P70/56
摘要： In a fuel cell including an electrolyte membrane and a pair of electrodes disposed on both sides of the electrolyte membrane, at least one of the electrodes has an electrically conductive nanocolumn that is oriented with an inclination of 60° or less with respect to a planar direction of the electrolyte membrane, a catalyst supported on the electrically conductive nanocolumn, and an electrolyte resin coating the electrically conductive nanocolumn.
摘要翻译： 在包括电解质膜和设置在电解质膜的两侧的一对电极的燃料电池中，至少一个电极具有相对于平面方向倾斜60°或更小的导电纳米柱 的电解质膜，负载在导电性纳米柱上的催化剂和涂覆导电性纳米柱的电解质树脂。
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6.发明授权Fuel cell with electrode having an electrically conductive nano-column and production method thereof 失效具有导电性纳米柱的电极的燃料电池及其制造方法公开(公告)号：US08486583B2
公开(公告)日：2013-07-16
申请号：US12293667
申请日：2007-03-15
申请人： Haruyuki Nakanishi , Chikashi Inazumi , Yuki Sairyo , Momoyo Sawai , Kenji Yoshikawa , Tomoya Yamashita
发明人： Haruyuki Nakanishi , Chikashi Inazumi , Yuki Sairyo , Momoyo Sawai , Kenji Yoshikawa , Tomoya Yamashita
IPC分类号： H01M4/02
CPC分类号： H01M4/8657 , H01M4/8605 , H01M4/92 , H01M4/926 , H01M8/1004 , Y02P70/56
摘要： In a fuel cell including an electrolyte membrane and a pair of electrodes disposed on both sides of the electrolyte membrane, at least one of the electrodes has an electrically conductive nanocolumn that is oriented with an inclination of 60° or less with respect to a planar direction of the electrolyte membrane, a catalyst supported on the electrically conductive nanocolumn, and an electrolyte resin coating the electrically conductive nanocolumn.
摘要翻译： 在包括电解质膜和设置在电解质膜的两侧的一对电极的燃料电池中，至少一个电极具有相对于平面方向倾斜60°或更小的导电纳米柱 的电解质膜，负载在导电性纳米柱上的催化剂和涂覆导电性纳米柱的电解质树脂。
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